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1. 发明申请

US20110275859A1 METHOD FOR MANUFACTURING CONJUGATED AROMATIC COMPOUND 有权
公开(公告)号：US20110275859A1
公开(公告)日：2011-11-10
申请号：US13144010
申请日：2010-01-18
申请人： Seiji Oda , Takashi Kamikawa , Akio Tanaka
发明人： Seiji Oda , Takashi Kamikawa , Akio Tanaka
IPC分类号： C07C315/04
CPC分类号： C07C45/72 , C07B37/04 , C07C17/269 , C07C41/30 , C07C67/343 , C07C253/30 , C07C303/30 , C08G61/12 , C08G2261/3442 , C08G2261/3444 , C07C25/18 , C07C49/76 , C07C49/84 , C07C69/76 , C07C43/2055 , C07C315/04
摘要： A method for manufacturing a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups selected from the group consisting of an iodine atom, a bromine atom and a chlorine atom are bonded to an aromatic ring and the aromatic compound (A) does not have (c1) a group represented by the following formula (10): wherein A1 represents a C1-C20 alkoxy group etc.; (g1) a C1-C20 alkyl group which may be substituted with a fluorine atom etc.; and (h1) a C2-C20 acyl group which may be substituted with a fluorine atom etc., at the neighboring carbon atom to the carbon atom to which the leaving group is bonded, with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) wherein the aromatic compound (B) is structurally different from the above-mentioned aromatic compound (A), one or two leaving groups selected from the group consisting of an iodine atom, a bromine atom and a chlorine atom are bonded to an aromatic ring and the aromatic compound (B) does not have the above-mentioned (c1), (g1) and (h1) at the neighboring carbon atom to the carbon atom to which the leaving group is bonded, in the presence of (i) a nickel compound, (ii) a metal reducing agent, (iii) at least one ligand (L1) selected from the group consisting of a 2,2′-bipyridine compound having at least one electron-withdrawing group and having no substituent at 3-, 6-, 3′- and 6′-positions, and a 1,10-phenanthroline compound having at least one electron-withdrawing group and having no substituent at 2- and 9-positions, and (iv) at least one ligand (L2) selected from the group consisting of a 2,2′-bipyridine compound having at least one electron-releasing group and having no substituent at 3-, 6-, 3′- and 6′-positions, and a 1,10-phenanthroline compound having at least one electron-releasing group and having no substituent at 2- and 9-positions.

2. 发明申请

US20110275780A1 METHOD FOR PRODUCING CONJUGATED AROMATIC COMPOUND 审中-公开
标题翻译：生产结合芳族化合物的方法
公开(公告)号：US20110275780A1
公开(公告)日：2011-11-10
申请号：US13144026
申请日：2010-01-18
申请人： Seiji Oda , Takashi Kamikawa
发明人： Seiji Oda , Takashi Kamikawa
IPC分类号： C08G2/06 , C08G75/23 , C08G2/20 , C08G2/16
CPC分类号： C07C45/72 , C07C49/84 , C07C315/04 , C08G61/12 , C08G2261/3442 , C08G2261/3444
摘要： A method for producing a conjugated aromatic compound comprising reacting an aromatic compound (A) represented by the formula (1) wherein n represents 0 or 1, m represents (3-n), R1 represents a C1-C20 alkyl group etc., R2 is independently in each occurrence a hydrogen atom etc., X1 and X3 independently each represent a chlorine atom etc., with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) wherein the aromatic compound (B) is structurally different from the above-mentioned aromatic compound (A) and one or two leaving groups selected from the group consisting of an iodine atom, a bromine atom and a chlorine atom are bonded to an aromatic ring, in the presence of a nickel compound, a metal reducing agent, and a 2,2′-bipyridine compound having at least one electron-releasing group and having no substituent at 3-, 6-, 3′- and 6′-positions.
摘要翻译：一种共轭芳香族化合物的制造方法，其特征在于，使由式（1）表示的芳香族化合物（A）（其中n表示0或1）表示，m表示（3-n），R1表示C1-C20烷基等，R2 在每种情况下独立地为氢原子等，X1和X3各自独立地表示氯原子等，与具有与上述芳香族化合物（A）相同结构的芳香族化合物（A）或芳香族化合物（B）其中芳族化合物（B）在结构上不同于上述芳香族化合物（A），并且一个或两个离开基团，选自碘原子，溴原子和氯原子结合到芳族环，在镍化合物，金属还原剂和具有至少一个电子释放基团并且在3，6，3'和6'上没有取代基的2,2'-联吡啶化合物存在下，位置。

3. 发明申请

US20110046336A1 TRANSITION METAL COMPLEX AND PROCESS FOR PRODUCING CONJUGATED AROMATIC COMPOUND USING THE TRANSITION METAL COMPLEX 失效
标题翻译：过渡金属复合物和使用过渡金属络合物生产结合芳族化合物的方法
公开(公告)号：US20110046336A1
公开(公告)日：2011-02-24
申请号：US12673846
申请日：2008-07-25
申请人： Taku Asaumi , Takashi Kamikawa
发明人： Taku Asaumi , Takashi Kamikawa
IPC分类号： C08G75/24 , C07F7/10 , C07F15/04
CPC分类号： C07D213/22 , B01J31/1608 , B01J31/1815 , B01J2531/847 , C07C1/26 , C07C17/269 , C07C41/30 , C07C45/68 , C07C253/30 , C07C2523/06 , C07C2531/22 , C07D215/06 , C07D333/04 , C07F7/0814 , C08G61/10 , C08G2261/1424 , C08G2261/1428 , C08G2261/148 , C08G2261/312 , C08G2261/416 , C07C15/14 , C07C25/18 , C07C49/84 , C07C255/51 , C07C43/2055
摘要： A transition metal complex obtained by contacting a bipyridine compound represented by the formula (1): wherein R1, R2 and R3 represent a C1-C10 alkyl group which may be substituted, etc., and R4 and R5 represent a hydrogen atom etc., with a compound of a transition metal belonging to Group 9, 10 or 11, and a process for producing a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups are bonded to an aromatic ring with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) being structurally different from the above-mentioned aromatic compound (A) and having one or two leaving groups bonded to an aromatic ring, in the presence of said transition metal complex.
摘要翻译：通过使由式（1）表示的联吡啶化合物：其中R 1，R 2和R 3表示可被取代的C 1 -C 10烷基等获得的过渡金属络合物，并且R 4和R 5表示氢原子等，具有属于第9,10或11族的过渡金属的化合物和共轭芳族化合物的制备方法，其包括使芳族化合物（A）与芳族化合物（芳基）键合在一个或两个离去基团上的芳族化合物（A） A）具有与上述芳族化合物（A）或芳香族化合物（B）的结构相同的结构，其与上述芳香族化合物（A）的结构不同且具有与芳香环结合的一个或两个离去基团在所述过渡金属络合物的存在下。

4. 发明申请

US20090326188A1 Method for producing polyarylene 审中-公开
标题翻译：聚亚芳基的制备方法
公开(公告)号：US20090326188A1
公开(公告)日：2009-12-31
申请号：US12310997
申请日：2007-08-31
申请人： Seiji Oda , Takashi Kamikawa
发明人： Seiji Oda , Takashi Kamikawa
IPC分类号： C08G61/10
CPC分类号： C08G61/10 , C08G61/12 , C08G2261/1452 , C08G2261/31 , C08G2261/312 , C08G2261/3442 , C08G2261/412 , H01B1/122 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1039 , H01M8/1072 , H01M2300/0082 , Y02P70/56
摘要： A method for producing a polyarylene comprising polymerizing only a dihalobiphenyl compound represented by the formula (1): wherein A represents a C1-C20 alkoxy group etc., R1 represents a fluorine atom etc., X1 represents a chlorine atom etc., and k represents an integer of 0 to 3, or a dihalobiphenyl compound represented by the formula (1) with an aromatic compound represented by the formula (2): or an aromatic compound represented by the formula (3): X3-Ar5-X3 (3) wherein a, b and c represents 0 or 1, n represents an integer of 5 or more, Ar1, Ar2, Ar3 and Ar4 represents a divalent aromatic group etc., Y1 and Y2 represents a single bond etc., Z1 and Z2 represents —O— or —S—, and X2 and X3 represent a chlorine atom etc., in the presence of catalytic amounts of a divalent nickel compound, a trivalent phosphorus ligand and zinc.
摘要翻译：聚亚芳基的制造方法，其仅包含式（1）表示的二卤代联苯化合物：其中A表示C1-C20烷氧基等，R1表示氟原子等，X1表示氯原子等，k表示（3）表示的芳香族化合物或式（3）所示的芳香族化合物：式（3）表示的芳香族化合物：式（3）表示的芳香族化合物：X3-Ar5-X3 ）其中a，b和c表示0或1，n表示5或更大的整数，Ar 1，Ar 2，Ar 3和Ar 4表示二价芳基等，Y1和Y2表示单键等，Z1和Z2表示 -O-或-S-，X2和X3表示氯原子等，在催化量的二价镍化合物，三价磷配体和锌的存在下。

5. 发明申请

US20090036632A1 Polyarylene and Process for Producing the Same 失效
标题翻译：聚亚芳基及其制备方法
公开(公告)号：US20090036632A1
公开(公告)日：2009-02-05
申请号：US12224672
申请日：2006-09-06
申请人： Noriyuki Hida , Seiji Oda , Takashi Kamikawa , Katsuhiro Suenobu
发明人： Noriyuki Hida , Seiji Oda , Takashi Kamikawa , Katsuhiro Suenobu
IPC分类号： C08G75/23 , C07C317/16 , C08G75/30 , C08G8/02
CPC分类号： C08G61/02 , C07C309/73 , C07C311/16 , C08G61/10 , C08G65/4012 , C08G75/23 , C08G2261/122 , C08G2261/1452 , C08G2261/312 , C08G2261/516
摘要： A dihalobiphenyl compound represented by the formula (1): wherein A represents an amino group substituted with one or two C1-C20 hydrocarbon groups or a C1-C20 alkoxy group, R1 represents a fluorine atom, a C1-C20 alkyl group, etc., X1 represents a chlorine atom, a bromine atom or an iodine atom, an k represents an integer of 0 to 3, and a polyarylene comprising a repeating unit represented by the formula (2): wherein A, R1 and k represent the same meanings as defined above.
摘要翻译：由式（1）表示的二卤代联苯化合物：其中A表示被一个或两个C 1 -C 20烃基或C 1 -C 20烷氧基取代的氨基，R 1表示氟原子，C 1 -C 20烷基等。 X1表示氯原子，溴原子或碘原子，k表示0〜3的整数，以及含有由式（2）表示的重复单元的聚亚芳基：其中，A，R1和k表示相同的含义如上所述。

6. 发明授权

US07238832B2 Production method of a coupling compound 有权
公开(公告)号：US07238832B2
公开(公告)日：2007-07-03
申请号：US10781198
申请日：2004-02-18
申请人： Tamon Itahashi , Takashi Kamikawa
发明人： Tamon Itahashi , Takashi Kamikawa
IPC分类号： C07C69/00 , C07C45/00 , C07C41/00 , C07C22/00 , C07C255/00
CPC分类号： B01J31/1815 , B01J31/183 , B01J2231/4211 , B01J2531/847 , C07B37/04 , C07C1/321 , C07C17/263 , C07C41/30 , C07C45/68 , C07C67/293 , C07C255/33 , C07C255/50 , C07C2601/14 , C07C15/107 , C07C13/28 , C07C22/08 , C07C49/233 , C07C69/017 , C07C69/007 , C07C69/16 , C07C69/157 , C07C43/2055 , C07C43/225
摘要： There is provided a method for producing a coupling compound of formula (1): (Y—)(n−1)R1—R2—(R1)(n′−1) (1) wherein R1, R2 n and n′ are as defined below, Y is R2 or X as defined below, which method comprises reacting an organic halogen compound of formula (2): n′(R1X1n) (2) wherein X1 represents a bromine or iodine, R1 represents a substituted or unsubstituted, linear, branched or cyclic hydrocarbon group of which α and β carbon atoms in relation to X1 are sp3 carbon atoms, n and n′ each independently represent an integer of 1 or 2, and provided that n and n′ do not simultaneously represent 2, with an organic boron compound of formula (3): m{R2(BX22)n′} (3) wherein R2 represents a substituted or unsubstituted aryl group or a substituted or unsubstituted alkenyl group and the boron atom is bonded with a sp2 carbon atom thereof, X2 represents a hydroxyl or alkoxy group, n′ is as defined above, m represents an integer of 1 or 2, and m is not more than n, in the presence of a catalyst comprising a) a nickel compound, and b) b-1) a compound of formula (i): or b-2) a compound of formula (ii):

7. 发明授权

US06723870B2 Method for producing anthracenes 失效
标题翻译：蒽的制备方法
公开(公告)号：US06723870B2
公开(公告)日：2004-04-20
申请号：US10252553
申请日：2002-09-24
申请人： Takashi Kamikawa , Junji Morimoto
发明人： Takashi Kamikawa , Junji Morimoto
IPC分类号： C07C6976
CPC分类号： C07C1/22 , C07C51/377 , C07C2603/24 , C07C13/573 , C07C63/38
摘要： Disclosed is a method for producing anthracene of formula (II) below by mixing a reaction mixture with a primary alcohol, wherein the reaction mixture is a reaction mixture obtained by reacting a metal hydride with an anthraquinone of formula (I):
摘要翻译：公开了通过将反应混合物与伯醇混合制备下式（II）的蒽的方法，其中反应混合物是通过使金属氢化物与式（I）的蒽醌反应获得的反应混合物：

8. 发明授权

US06384231B1 Method of producing 2,4-oxazolidinediones and metal salts thereof 失效
标题翻译： 2,4-恶唑烷二酮及其金属盐的制备方法
公开(公告)号：US06384231B1
公开(公告)日：2002-05-07
申请号：US09955052
申请日：2001-09-19
申请人： Keiko Nakamura , Takashi Kamikawa
发明人： Keiko Nakamura , Takashi Kamikawa
IPC分类号： C07D26344
CPC分类号： C07D263/44
摘要： A method of producing a metal salt of 2,4-oxazolidinedione of the general formula (III) wherein a 2hydroxycarboxylate fo the general formula (I), urea and a metal alkoxide of the formula (II) are reacted in an aromatic hydrocarbon; or a 2-hydroxycarboxylate of the general formula (I) and a metal alkoxide of the formula (II) are added to urea, and, then, they are reacted is provided: wherein, R1 and R2 are each independently represent a hydrogen atom or a lower alkyl group, R3 represents a lower alkyl group, R4 represents a lower alkyl group, and M represents an alkali metal atom; and also provided is a method of producing a 2,4-oxazolidinedione of the general formula (IV) wherein a metal salt of 2,4-oxazolidinedione of the general formula (III) is added to an aqueous solution of an acid.
摘要翻译：制备通式（III）的2,4-恶唑烷二酮金属盐的方法，其中通式（I）的二羟基羧酸酯，脲和式（II）的金属醇盐在芳族烃中反应; 或通式（I）的2-羟基羧酸酯和式（II）的金属醇盐加入到脲中，然后反应：其中，R 1和R 2各自独立地表示氢原子或低级烷基，R3表示低级烷基，R4表示低级烷基，M表示碱金属原子; 并且还提供了通式（IV）的2,4-恶唑烷二酮的制备方法，其中将通式（III）的2,4-恶唑烷二酮的金属盐加入到酸的水溶液中。

9. 发明授权

US07217677B2 Method for producing coupling compound 有权
标题翻译：偶联化合物的制备方法
公开(公告)号：US07217677B2
公开(公告)日：2007-05-15
申请号：US10757148
申请日：2004-01-14
申请人： Tamon Itahashi , Takashi Kamikawa
发明人： Tamon Itahashi , Takashi Kamikawa
IPC分类号： B01J31/00
CPC分类号： C07F15/04 , C07B37/04 , C07C1/321 , C07C17/263 , C07C29/32 , C07C29/34 , C07C41/30 , C07C45/68 , C07C67/293 , C07C253/30 , C07C2523/755 , C07C2531/22 , C07C2601/14 , C07D213/30 , C07D307/42 , C07D307/79 , C07F15/045 , C07C43/205 , C07C15/107 , C07C49/76 , C07C13/28 , C07C33/20 , C07C69/157 , C07C11/02 , C07C43/164 , C07C43/2055 , C07C13/47 , C07C43/23 , C07C33/28 , C07C33/46 , C07C43/225 , C07C22/08 , C07C255/33 , C07C255/34
摘要： A method is provided for producing a specific crosscoupling compound and a specific catalyst for producing the compound. The method includes reacting in the presence of a base and a nickel compound catalyst organic halide of the formula n′(R1X1n), wherein R1 is a hydrocarbon group and the α and β carbons to X′ are sp3 carbon atoms; X1 is a chlorine, bromine, or iodine atoms, and n and n1 and 1 or 2 but not both 2, with a compound having the formula m{R2(BX22)n′} where an R2 is an aryl, heteroaryl, or alkenyl group, and n′ is 1 or 2, X2 is independently a hydroxyl group, an alkoxy or arylalkoxy group or X22 together form an alkylenedioxy or arylenedioxy group, and m represents 1 or 2 but m≦n, and the boron atom is bonded to a sp2 carbon atom of R2 group or a boronic acid trimer anhydride.
摘要翻译：提供了一种用于制备特定的交叉耦合化合物和用于制备该化合物的特定催化剂的方法。该方法包括在碱和镍化合物催化剂存在下反应，式中n'（R 1，X 1，N 2）其中R 1是烃基，X'的α和β碳是sp 3 O 3个碳原子; X 1是一个氯，溴或碘原子，n和n和1和1或2而不是两者与具有式m的化合物{ 其中R 2是芳基，其中R 2是芳基，杂芳基或烯基，n'为1或2，X 2独立地为羟基，烷氧基或芳基烷氧基或X 2 2， / SUB一起形成亚烷基二氧基或亚芳基二氧基，m表示1或2，但m <= n，硼原子与R 2的S SUP>基团或硼酸三聚体酐。

10. 发明授权

US06965037B2 Method for producing aminocarbazoles 失效
标题翻译：生产氨基咔唑的方法
公开(公告)号：US06965037B2
公开(公告)日：2005-11-15
申请号：US10199028
申请日：2002-07-22
申请人： Takashi Kamikawa , Osamu Maruyama
发明人： Takashi Kamikawa , Osamu Maruyama
IPC分类号： B01J25/02 , C07B61/00 , C07D209/88 , C07D209/82
CPC分类号： C07D209/88
摘要： Disclosed is a method for producing an aminocarbazole by catalytically reducing a nitrocarbazole, wherein as a catalyst is used an active nickel-based catalyst prepared by contacting a nickel-based catalyst with an alkali and an iron compound under a hydrogen gas or inert gas atmosphere in an inert solvent, and according to the method of the present invention, decrease in reaction speed, decrease in yield of a product or the like depending upon the lot of the starting nitrocarbazoles can be prevented, and aminocarbazoles can be produced in a good yield constantly.
摘要翻译：公开了通过催化还原硝基咔唑制备氨基咔唑的方法，其中使用催化剂作为催化剂，其通过在氢气或惰性气体气氛下使镍基催化剂与碱和铁化合物接触而制备的活性镍基催化剂惰性溶剂，并且根据本发明的方法，可以防止反应速度的降低，产物的收率降低等，这取决于起始硝基咔唑的批次，氨基咔唑可以以良好的产率不断地产生。

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