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    • 1. 发明授权
    • Ultra-thin gate oxide formation using an N2O plasma
    • 使用N2O等离子体的超薄栅极氧化物形成
    • US06258730B1
    • 2001-07-10
    • US09246462
    • 1999-02-09
    • Sey-Ping SunMark I. GardnerShengnian Song
    • Sey-Ping SunMark I. GardnerShengnian Song
    • H01L2131
    • H01L21/28185H01L21/28194H01L21/28211H01L21/31662
    • A fabrication process for semiconductor devices is disclosed for forming ultra-thin gate oxides, whereby a silicon substrate is subjected to an N2O plasma to form the ultra-thin gate oxide. According to one embodiment, the silicon substrate is heated in a deposition chamber and the N2O plasma is created by applying RF power to a showerhead from which the N2O is dispensed. By reacting an N2O plasma directly with the silicon substrate it is possible to achieve gate oxides with thicknesses less than 20 Å and relative uniformities of less than 1% standard deviation. The oxide growth rate resulting from the presently disclosed N2O plasma treatment is much slower than other known oxide formation techniques. One advantage of the disclosed N2O plasma treatment over thermal oxidation lies in the predictability of oxide growth thickness resulting from reaction with N2O plasma versus the strong variation in oxide formation rates exhibited by thermal oxidation. Following gate oxide formation, a high temperature anneal may be performed, preferably in an RTA apparatus. By combining the N2O plasma treatment with an RTA process, the disclosed method is believed to offer a controllable and reproducible method for fabricating highly uniform, ultra-thin gate oxides, having low trapping state densities.
    • 公开了用于形成超薄栅极氧化物的半导体器件的制造工艺,由此使硅衬底经受N 2 O等离子体以形成超薄栅极氧化物。 根据一个实施例,在沉积室中加热硅衬底,并且通过将RF功率施加到分配N2O的喷头来产生N 2 O等离子体。 通过使N2O等离子体直接与硅衬底反应,可以实现厚度小于20的栅极氧化物和小于1%标准偏差的相对均匀性。 由本发明的N2O等离子体处理产生的氧化物生长速度比其它已知的氧化物形成技术慢得多。 所公开的N2O等离子体处理对热氧化的一个优点在于与N2O等离子体反应产生的氧化物生长厚度与热氧化显示的氧化物形成速率的强烈变化的可预测性。 在形成栅极氧化物之后,可以优选在RTA装置中进行高温退火。 通过将N2O等离子体处理与RTA工艺结合,所公开的方法被认为是提供具有低陷阱状态密度的制造高度均匀的超薄栅极氧化物的可控和可再现的方法。
    • 3. 发明授权
    • Method of fabricating conductor structures with metal comb bridging avoidance
    • 使用金属梳齿桥接避免制造导体结构的方法
    • US06492281B1
    • 2002-12-10
    • US09668443
    • 2000-09-22
    • Shengnian SongBradley DavisSey-Ping Sun
    • Shengnian SongBradley DavisSey-Ping Sun
    • H01L21302
    • H01L21/32051H01L21/76838
    • Various methods of inspecting a workpiece for residue are provided. In one aspect, a method of fabricating a conductor layer on a substrate is provided that includes forming an aluminum-copper film on the substrate in a first processing chamber and forming an anti-reflective coating on the aluminum-copper film in a second processing chamber. The substrate is moved from the second processing chamber into a cooling chamber to quench the substrate. A first time interval during which the substrate is in the first processing chamber and second time interval during which the substrate is present in the second processing chamber are measured. The substrate is annealed to restore a uniform equilibrium distribution of copper in the aluminum if the first time interval exceeds about 600 seconds or the second time interval exceeds about 300 seconds. The method substantially reduces the risk of metal comb bridging device failures following etch definition of conductor lines.
    • 提供了检查残留物的各种方法。 一方面,提供一种在基板上制造导体层的方法,其包括在第一处理室中的基板上形成铝 - 铜膜,并在第二处理室中的铝 - 铜膜上形成抗反射涂层 。 将基板从第二处理室移动到冷却室中以淬火基板。 测量基板处于第一处理室的第一时间间隔和第二处理室中存在基板的第二时间间隔。 如果第一时间间隔超过约600秒或第二时间间隔超过约300秒,则将基板退火以恢复铝在铝中的均匀均匀分布。 该方法大大降低了导体线蚀刻定义后金属梳状桥接器件故障的风险。
    • 4. 发明授权
    • In-situ stack for high volume production of isolation regions
    • 原位堆叠用于大批量生产隔离区
    • US06383874B1
    • 2002-05-07
    • US09800862
    • 2001-03-07
    • Sey-Ping SunMark I. GardnerRobert W. Anderson
    • Sey-Ping SunMark I. GardnerRobert W. Anderson
    • H01L21336
    • H01L21/76224
    • A device stack for fabrication of an isolation structure and methods of fabricating the same are provided. In one aspect, a method of processing a substrate is provided that includes exposing the substrate to a plasma ambient containing nitrogen and oxygen to form a nitrogen containing interface. An oxide film is formed on the nitrogen containing interface and a silicon rich nitride film is formed on the oxide film. The silicon rich nitride film is exposed to a plasma ambient containing oxygen to convert an upper portion of the silicon rich nitride film to silicon oxynitride. The optical properties of the nitride film are enhanced so that UV lithographic patterning of etch masking is improved.
    • 提供了用于制造隔离结构的器件堆叠及其制造方法。 在一个方面,提供了一种处理衬底的方法,其包括将衬底暴露于含有氮和氧的等离子体环境中以形成含氮界面。 在含氮界面上形成氧化膜,在氧化物膜上形成富含氮的氮化物膜。 富硅氮化物膜暴露于含有氧的等离子体环境,以将富硅氮化物膜的上部转化为氮氧化硅。 氮化膜的光学特性得到增强,从而提高了蚀刻掩模的UV光刻图案。
    • 6. 发明授权
    • Ultrathin deposited gate dielectric formation using low-power, low-pressure PECVD for improved semiconductor device performance
    • 使用低功率,低压PECVD的超薄沉积栅介质形成,以改善半导体器件性能
    • US06251800B1
    • 2001-06-26
    • US09227513
    • 1999-01-06
    • Sey-Ping SunMark I. GardnerCharles E. May
    • Sey-Ping SunMark I. GardnerCharles E. May
    • H01L2131
    • H01L21/28185C23C16/402H01L21/02164H01L21/02211H01L21/02274H01L21/0228H01L21/02332H01L21/02337H01L21/28194H01L21/31612
    • An ultrathin gate dielectric and a method for forming the same are provided. The gate dielectric is believed to allow enhanced performance of semiconductor devices including transistors and dual-gate memory cells. A low-power, low-pressure plasma-enhanced chemical vapor deposition (PECVD) method employing silane and nitrous oxide sources is used to deposit the dielectric. As compared to conventional PECVD deposition, the method uses lower silane and nitrous oxide flow rates, a more dilute silane in nitrogen mixture, a lower chamber pressure, and a lower radio frequency power density. These settings allow plasma conditions to stabilize so that deposition may be performed in time increments at least as short as 0.1 second, so that oxide thicknesses at least as small as one angstrom may be controllably deposited. The oxide is preferably deposited in portions at multiple substrate mounting positions in a deposition chamber. Combination of oxide portions in this manner is believed to reduce the density of pinholes in the oxide, and the low-power, low-pressure deposition conditions are further believed to reduce plasma damage to the oxide and reduce the density of trap states in the oxide. A rapid thermal anneal of the oxide may be performed after deposition, and may improve the quality of the interface between the oxide and the underlying semiconductor substrate.
    • 提供一种超薄栅极电介质及其形成方法。 认为栅极电介质允许包括晶体管和双栅极存储器单元的半导体器件的增强的性能。 使用采用硅烷和一氧化二氮源的低功率,低压等离子体增强化学气相沉积(PECVD)方法沉积电介质。 与传统的PECVD沉积相比,该方法使用较低的硅烷和一氧化二氮流率,氮混合物中更稀的硅烷,较低的室压力和较低的射频功率密度。 这些设置允许等离子体条件稳定,使得可以以至少短至0.1秒的时间增量执行沉积,使得至少小至一埃的氧化物厚度可以可控地沉积。 优选在沉积室中的多个基板安装位置处部分地沉积氧化物。 认为以这种方式组合氧化物部分可以降低氧化物中针孔的密度,并且进一步认为低功率,低压沉积条件可减少对氧化物的等离子体损伤并降低氧化物中陷阱态的密度 。 可以在沉积之后进行氧化物的快速热退火,并且可以提高氧化物和下面的半导体衬底之间的界面的质量。