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    • 3. 发明授权
    • Electrophotographic photoreceptor, process for production thereof, and
image-forming apparatus using same
    • 电子照相感光体及其制造方法以及使用其的图像形成装置
    • US6136485A
    • 2000-10-24
    • US188342
    • 1998-11-09
    • Kazuya IshidaSatoshi KatayamaTakahiro TeramotoAkihiko KawaharaKazushige MoritaTomoko Kanazawa
    • Kazuya IshidaSatoshi KatayamaTakahiro TeramotoAkihiko KawaharaKazushige MoritaTomoko Kanazawa
    • G03G5/05C08K3/22C08L29/14G03G5/14
    • G03G5/144G03G5/142
    • The object of the invention is to provide a highly characteristic and lesser defective image using an electrophotographic photoreceptor which can be produced with a better coating property and which is highly sensitive and hardly loses the electrostatic stability during repeated use. A water-soluble or water/alcohol-soluble polyvinyl acetal and an inorganic pigment are involved in an underlayer provided between a conductive support and a photoconductive layer. Particularly, it is favorable to use titanium oxide as the inorganic pigment, make the ratio of polyvinyl acetal/titanium oxide 1/9-9/1 by weight, make the underlayer 0.5-5 .mu.m in thickness, use the titanium oxide of which the surface is treated with alumina, use the titanium oxide of which the titanium oxide component is 95% by weight or lower and of which the surface is treated with alumina, use the polyvinyl acetal of which the sodium ion concentration is 40 ppm or lower, and use the photo-conductive layer which contains a vinyl chloride-vinyl acetate type copolymer. As for a dispersing medium for coating the underlayer, water/alcohol=1/9-7/3 (ratio by weight) is selected. The aforementioned photoreceptor is applied to an image-forming apparatus using an inversion development process.
    • 本发明的目的是提供一种使用电子照相感光体的高度特征和较小的缺陷图像,该电子照相感光体可以以更好的涂层性能制造,并且在反复使用中高度敏感并且几乎不损失静电稳定性。 水溶性或水/醇可溶性聚乙烯醇缩醛和无机颜料参与设置在导电载体和光电导层之间的底层。 特别是,优选使用氧化钛作为无机颜料,使聚乙烯醇缩醛/氧化钛的比例为1 / 9-9 / 1,使底层的厚度为0.5-5μm,使用其中的氧化钛 用氧化铝处理表面,使用氧化钛成分为95重量%以下的氧化钛,其表面用氧化铝处理,使用钠离子浓度为40ppm以下的聚乙烯醇缩醛, 并使用含有氯乙烯 - 乙酸乙烯酯型共聚物的光导层。 对于用于涂覆底层的分散介质,选择水/醇= 1 / 9-7 / 3(重量比)。 使用反转显影处理将上述感光体应用于图像形成装置。
    • 5. 发明授权
    • Electrophotographic photoreceptor and production method thereof
    • 电子照相感光体及其制备方法
    • US06869740B2
    • 2005-03-22
    • US10307861
    • 2002-12-02
    • Yuriko ShindohHiroko IshibashiKazushige MoritaYoshihide Shimoda
    • Yuriko ShindohHiroko IshibashiKazushige MoritaYoshihide Shimoda
    • G03G5/00G03G5/047G03G5/05G03G5/06
    • G03G5/047G03G5/0614G03G5/0616G03G5/0629
    • An electrophotographic photoreceptor, in which the increase of VL is controlled below 15 V by controlling the content ratio M (ppm) of a charge transporting material CTM2 to a charge transporting material CTM1 within a specific range, wherein the ionization potential Ip(2) of the CTM2 is smaller than the ionization potential Ip(1) of the CTM1 in the constituent of the photosensitive layer, and thereby the electrophotographic photoreceptor has only a little reduction of image concentration. A method for producing an electrophotographic photoreceptor having ΔVL which is controlled below 15 V, wherein, in a case where the ionization potential of the charge transporting material used in the previous run of production is small, ΔVL can be set below 15 V by using, in the next production, a dip coating liquid, which comprises, as a constitutive material, a charge transporting material in which the difference between the ionization potential of the current material and that of the previous material is set below 0.25 eV.
    • 通过将特定范围内的电荷输送材料CTM2的电荷输送材料CTM2的含有比M(ppm)控制在特定范围内,将VL的增加控制在15V以下的电子照相感光体,其特征在于,电离电位Ip(2) CTM2小于感光层的成分中的CTM1的电离电位Ip(1),因此电子照相感光体仅有少量的图像浓度降低。 一种控制在15V以下的具有DeltaVL的电子照相感光体的制造方法,其特征在于,在前次生产中使用的电荷输送材料的电离电位小的情况下,通过使用ΔVV,将ΔVV设定为15V以下, 在下一次生产中,包含作为组成材料的电荷输送材料的浸涂液体,其中当前材料的电离电位与先前材料的电离电位之间的差设定在低于0.25eV。
    • 8. 发明授权
    • Electrophotographic photoreceptor and method for producing the same
    • 电子照相感光体及其制造方法
    • US07078143B2
    • 2006-07-18
    • US10627719
    • 2003-07-28
    • Masaki HashimotoKazushige MoritaMikio KakuiYuji TanakaMasayuki Sakamoto
    • Masaki HashimotoKazushige MoritaMikio KakuiYuji TanakaMasayuki Sakamoto
    • G03G5/10
    • G03G5/10
    • The object of the invention is to prevent interference fringes of images and allow precise measurement of the thickness of a layer by the optical interferometry by limiting the surface roughness of a conductive substrate. The surface roughness of the conductive substrate provided in an electrophotographic photoreceptor is such that the maximum peak-to-valley roughness height (Ry)=0.8 to 1.4 μm, the centerline average roughness (Ra)=0.10 to 0.15 μm, the ten-point average roughness (Rz)=0.7 to 1.3 μm, the average peak-to-peak distance (Sm)=5 to 30 μm, and the peak count Pc=60 to 100. In such an electrophotographic photoreceptor, light for exposure can be scattered to an appropriate extent, so that interference fringes can be prevented, and an interference pattern is formed during measurement of the thickness of the photosensitive layer by the optical interferometry so that the thickness of the layer can be measured with a high precision.
    • 本发明的目的是防止图像的干涉条纹,并且通过限制导电基底的表面粗糙度,通过光学干涉测量精确测量层的厚度。 设置在电子照相感光体中的导电性基材的表面粗糙度使得最大峰 - 谷粗糙度高度(Ry)= 0.8〜1.4μm,中心线平均粗糙度(Ra)= 0.10〜0.15μm,十点 平均粗糙度(Rz)= 0.7〜1.3μm,平均峰峰距离(Sm)= 5〜30μm,峰值Pc = 60〜100。在这样的电子照相感光体中,曝光用的光可以散射 从而可以防止干涉条纹,并且通过光学干涉测量在感光层的厚度测量期间形成干涉图案,从而可以高精度地测量该层的厚度。
    • 9. 发明授权
    • Electrophotographic photoreceptor, process for producing the same, and
image forming apparatus using same
    • 电子照相感光体及其制造方法以及使用其的成像装置
    • US6054237A
    • 2000-04-25
    • US210785
    • 1998-12-15
    • Kazuya IshidaKiyofumi MorimotoSatoshi KatayamaTakahiro TeramotoAkihiko KawaharaKazushige Morita
    • Kazuya IshidaKiyofumi MorimotoSatoshi KatayamaTakahiro TeramotoAkihiko KawaharaKazushige Morita
    • G03G5/00C08K5/56C08L27/06C08L31/04G03G5/05G03G5/06
    • G03G5/0539G03G5/0542G03G5/0696
    • An object of the invention is to provide a highly characteristic image using an electrophotographic photoreceptor of which a charge-generating layer can be produced with a better coating property and which is highly sensitive and electrostatically highly stable in repeated use. The charge-generating layer of a function-separated type photoreceptor contains a n-type non-metallic phthalocyanine and a copolymer of vinyl chloride-vinyl acetate type. Particularly, the ratio of the .tau.-type non-metallic phthalocyanine to the copolymer of vinyl chloride-vinyl acetate type is fixed at 1/3-3/1 by weight. The thickness of the charge-generating layer is fixed at 0.1-0.6 .mu.m. As the copolymer of vinyl chloride-vinyl acetate type, copolymers of vinyl chloride-vinyl acetate, vinyl chloride-vinyl acetate-maleic acid, or vinyl chloride-vinyl acetate-vinyl alcohol are selected. Particularly, it is favorable to select those containing at least 10% by weight of the vinyl alcohol component. The charge-generating layer is formed with a liquid coating material using a ketone solvent as dispersant. The aforementioned photoreceptor is applied to an image-forming apparatus using an inversion development process.
    • 本发明的目的是提供使用电子照相感光体的高度特征的图像,其中可以制备具有更好涂层性能的电荷产生层,并且其在重复使用中是高度敏感的和静电性高度稳定的。 功能分离型感光体的电荷产生层含有n型非金属酞菁和氯乙烯 - 乙酸乙烯酯类共聚物。 特别地,将T型非金属酞菁与氯乙烯 - 乙酸乙烯酯类共聚物的比例固定为1 / 3-3 / 1重量比。 电荷产生层的厚度固定在0.1-0.6μm。 作为氯乙烯 - 乙酸乙烯酯型共聚物,选择氯乙烯 - 乙酸乙烯酯,氯乙烯 - 乙酸乙烯酯 - 马来酸或氯乙烯 - 乙酸乙烯酯 - 乙烯醇的共聚物。 特别地,选择含有至少10重量%的乙烯醇组分的那些。 电荷产生层由使用酮溶剂作为分散剂的液体涂料形成。 使用反转显影处理将上述感光体应用于图像形成装置。