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1. 发明授权

US07374667B2 Process for the production of gasoline with a low sulfur content comprising a stage for transformation of sulfur-containing compounds, an acid-catalyst treatment and a desulfurization 有权
标题翻译：用于生产低硫含量的汽油的方法，包括用于转化含硫化合物的阶段，酸催化剂处理和脱硫
公开(公告)号：US07374667B2
公开(公告)日：2008-05-20
申请号：US10095293
申请日：2002-03-12
申请人： Quentin Debuisschert , Denis Uzio , Jean-Luc Nocca , Florent Picard , David B Arnett , Mike Grayson , Donald E Zeek , Carl Snider
发明人： Quentin Debuisschert , Denis Uzio , Jean-Luc Nocca , Florent Picard , David B Arnett , Mike Grayson , Donald E Zeek , Carl Snider
IPC分类号： C10G45/04 , C07C2/54
CPC分类号： C10G67/08 , C10G2400/02
摘要： For the production of gasoline with a low sulfur content, a process comprises at least one stage for transformation of sulfur-containing compounds consisting of an alkylation or adsorption of sulfur-containing compounds and/or an increasing of the weight of light sulfur-containing compounds, at least one stage for treatment in the presence of an acid catalyst and at least one desulfurization treatment of at least a portion of the gasoline. The process can also optionally comprise at least one stage for selective hydrogenation of diolefins and optionally at least one fractionation of the gasoline that is obtained into at least two fractions: light gasoline and heavy gasoline.
摘要翻译：为了生产硫含量低的汽油，一种方法包括至少一个阶段，用于转化由含硫化合物的烷基化或吸附组成的含硫化合物和/或轻质含硫化合物的重量的增加，在酸催化剂存在下处理的至少一个阶段和至少一部分汽油的至少一个脱硫处理。该方法还可以任选地包含至少一个阶段，用于二烯烃的选择性氢化和任选的至少一种汽油的分馏，其被获得至少两个馏分：轻汽油和重汽油。

2. 发明授权

US08652321B2 Process for the production of a desulfurized gasoline from a gasoline fraction that contains conversion gasoline 有权
$Process for the production of a desulfurized gasoline from a gasoline fraction that contains conversion gasoline$
标题翻译：从含有转化汽油的汽油馏分中生产脱硫汽油的方法
公开(公告)号：US08652321B2
公开(公告)日：2014-02-18
申请号：US12791492
申请日：2010-06-01
申请人： Quentin Debuisschert , Denis Uzio , Jean-Luc Nocca , Florent Picard
发明人： Quentin Debuisschert , Denis Uzio , Jean-Luc Nocca , Florent Picard
IPC分类号： C10G65/12
CPC分类号： C10G67/08 , C10G65/06 , C10G2400/02
摘要： Production of gasolines with low sulfur contents from a starting gasoline containing sulfur-containing compounds comprising a stage a) for selective hydrogenation of non-aromatic polyunsaturated compounds present in the starting gasoline, a stage b) for increasing the molecular weight of the light sulfur-containing products that are initially present in the gasoline that enters this stage, a stage c) for alkylation of at least a portion of the sulfur-containing compounds present in the product that originates from stage b), a stage d) for fractionation of the gasoline that originates from stage c) into at least two fractions, one fraction virtually lacking in sulfur-containing compounds, whereby the other contains a larger proportion of sulfur-containing compounds (heavy gasoline), a stage e) for catalytic treatment of the heavy gasoline for transformation of sulfur-containing compounds under conditions for the at least partial decomposition of hydrogenation of these sulfur-containing compounds.
摘要翻译：从含有硫化合物的起始汽油中制备含硫低的汽油，包括a）用于选择氢化存在于起始汽油中的非芳族多不饱和化合物的步骤，b）用于提高轻质硫化物的分子量，最初存在于进入该阶段的汽油中的含有产物，c）用于烷基化存在于产物中的步骤b）中的至少一部分含硫化合物的阶段d），用于分馏起始于阶段c）的汽油至少有两个馏分，一个实际上不含硫化合物的馏分，另一个馏分含有较大比例的含硫化合物（重汽油），e）用于催化处理重质用于在含硫化合物的至少部分分解氢化的条件下转化含硫化合物的汽油化合物。

3. 发明授权

US07052598B2 Process for the production of gasoline with a low sulfur content comprising a hydrogenation, a fractionation, a stage for transformation of sulfur-containing compounds and a desulfurization 有权
$Process for the production of gasoline with a low sulfur content comprising a hydrogenation, a fractionation, a stage for transformation of sulfur-containing compounds and a desulfurization$
标题翻译：用于生产低硫含量的汽油的方法包括氢化，分馏，用于转化含硫化合物的阶段和脱硫
公开(公告)号：US07052598B2
公开(公告)日：2006-05-30
申请号：US10095295
申请日：2002-03-12
申请人： Quentin Debuisschert , Denis Uzio , Jean-Luc Nocca , Florent Picard
发明人： Quentin Debuisschert , Denis Uzio , Jean-Luc Nocca , Florent Picard
IPC分类号： C10G45/00 , C10G65/00
CPC分类号： C10G65/06 , C10G2400/02
摘要： A process for the production of gasoline with a low sulfur content that comprises at least one selective hydrogenation of diolefins, optionally at least one stage for transformation, preferably to increase their weight, for light sulfur-containing compounds that are present in the gasoline, at least one fractionation of the gasoline that is obtained into at least two fractions: light gasoline and heavy gasoline, then optionally a stage for transformation, preferably for alkylation or adsorption, of sulfur-containing compounds and a desulfurization treatment in a stage of at least a portion of the heavy fraction.
摘要翻译：一种生产低硫含量的汽油的方法，该方法包括至少一种二烯烃的选择性氢化，任选的至少一个转化阶段，优选增加其重量，用于存在于汽油中的轻质含硫化合物，在将至少两种馏分中的汽油的至少一次分馏：轻质汽油和重质汽油，然后任选地用于转化，优选用于烷基化或吸附的含硫化合物和脱硫处理的阶段至少为部分重部分。

4. 发明授权

US06972086B2 Process comprising two gasoline hydrodesulfurization stages and intermediate elimination of H2S formed during the first stage 有权
标题翻译：包括在第一阶段形成的两个汽油加氢脱硫阶段和中间消除H 2 S的方法
公开(公告)号：US06972086B2
公开(公告)日：2005-12-06
申请号：US09897757
申请日：2001-07-03
申请人： Blaise Didillon , Denis Uzio , Jean-Luc Nocca , Quentin Debuisschert
发明人： Blaise Didillon , Denis Uzio , Jean-Luc Nocca , Quentin Debuisschert
IPC分类号： C10G47/06 , C10G25/00 , C10G29/16 , C10G31/00 , C10G45/06 , C10G45/08 , C10G65/04 , C10G67/02 , C10G67/06 , C10G69/04 , C10G45/00
CPC分类号： C10G67/02 , C10G65/04 , C10G67/06
摘要： The invention relates to a process for the production of gasoline with a low sulfur content comprising at least three stages: a first stage in which the sulfur-containing compounds present in the gasoline are at least partially transformed into H2S and into saturated sulfur-containing compounds; a second stage whose purpose is to eliminate the H2S from the gasoline produced in the first stage; and a third stage in which the saturated sulfur-containing compounds remaining in the gasoline are transformed into H2S. The process according to the invention optionally also comprises a pretreatment stage whose purpose is to hydrogenate the diolefins of the feedstock before the first stage.
摘要翻译：本发明涉及一种生产低硫含量的汽油的方法，该方法至少包括三个阶段：其中存在于汽油中的含硫化合物至少部分转化为H 2 S的第一阶段和饱和的含硫化合物 ; 第二阶段的目的是消除第一阶段生产的汽油中的硫化氢; 以及残留在汽油中的饱和含硫化合物转化为H 2 S的第三阶段。根据本发明的方法任选地还包括预处理阶段，其目的是在第一阶段之前氢化原料的二烯烃。

5. 发明授权

US06830678B2 Process of desulphurizing gasoline comprising desulphurization of the heavy and intermediate fractions resulting from fractionation into at least three cuts 有权
$Process of desulphurizing gasoline comprising desulphurization of the heavy and intermediate fractions resulting from fractionation into at least three cuts$
标题翻译：包括脱硫汽油的方法，包括由分馏得到的重馏分和中间馏分脱硫至至少三个馏分
公开(公告)号：US06830678B2
公开(公告)日：2004-12-14
申请号：US09819949
申请日：2001-03-29
申请人： Blaise Didillon , Denis Uzio , Quentin Debuisschert , Jean-Luc Nocca
发明人： Blaise Didillon , Denis Uzio , Quentin Debuisschert , Jean-Luc Nocca
IPC分类号： C10G6506
CPC分类号： C10G65/00 , C10G69/00
摘要： The invention relates to a process of producing gasoline with a low sulphur content from a feedstock containing sulphur. This process comprises at least one step a1 of selectively hydrogenating the diolefins and acetylenic compounds, at least one separation of the gasoline (step b) obtained at step a1 into at least three fractions, at least one step c1 of treating the heavy gasoline separated at step b on a catalyst enabling the unsaturated sulphur compounds to be at least partially decomposed or hydrogenated and at least one step d to remove the sulphur and nitrogen from at least one intermediate fraction, followed by catalytic reforming.
摘要翻译：本发明涉及从含硫原料生产低硫含量的汽油的方法。该方法包括至少一个选择性氢化二烯烃和炔属化合物的步骤a1，至少一个步骤a1中获得的汽油（步骤b）分离成至少三个馏分，至少一个步骤c1处理在步骤b使得不饱和硫化合物至少部分分解或氢化并且至少一个步骤d从至少一个中间馏分中除去硫和氮，然后进行催化重整。

6. 发明申请

US20100016645A1 Process for hydrogenation of benzene 有权
标题翻译：苯氢化方法
公开(公告)号：US20100016645A1
公开(公告)日：2010-01-21
申请号：US12244208
申请日：2008-10-02
申请人： Jean COSYNS , Quentin Debuisschert , Jean-Luc Nocca , Delphine Largeteau
发明人： Jean COSYNS , Quentin Debuisschert , Jean-Luc Nocca , Delphine Largeteau
IPC分类号： C07C7/163
CPC分类号： C10G45/48 , C01B3/26 , C01B3/50 , C01B2203/0277 , C01B2203/047 , C10G7/02 , C10G35/04 , C10G2300/1096 , C10G2300/4006 , C10G2400/02 , C10G2400/04
摘要： This invention relates to a process for hydrogenation of benzene contained in a catalytic reformate, in which: The hydrogen that is present in the catalytic reformate is separated from the remainder of the reformate with separation means, A light benzene-enriched fraction is separated from the heavy reformate, The light reformate that contains the benzene is brought into contact with a nickel-based hydrogenation catalyst at a temperature of between 90° C. and 150° C., a VVH of between 0.5 and 10, and with at least one portion of hydrogen that is obtained during the separation stage of the hydrogen at the top of the separator tank and used at the output pressure of said separator.
摘要翻译：本发明涉及催化重整油中所含的苯氢化方法，其中：催化重整产物中存在的氢气与分离装置与剩余的重整产物分离，将轻的富含苯的馏分与重质量重组体，含有苯的轻质重整油在90℃〜150℃，VVH为0.5〜10℃的温度下与镍系氢化催化剂接触，并与至少一部分在分离罐顶部的氢分离阶段期间获得的氢气，并在所述分离器的输出压力下使用。

7. 发明授权

US09074144B2 Process for hydrogenation of benzene 有权
标题翻译：苯氢化方法
公开(公告)号：US09074144B2
公开(公告)日：2015-07-07
申请号：US12244208
申请日：2008-10-02
申请人： Jean Cosyns , Quentin Debuisschert , Jean-Luc Nocca , Delphine Largeteau
发明人： Jean Cosyns , Quentin Debuisschert , Jean-Luc Nocca , Delphine Largeteau
IPC分类号： C10G45/48 , C01B3/26 , C01B3/50 , C10G7/02 , C10G35/04
CPC分类号： C10G45/48 , C01B3/26 , C01B3/50 , C01B2203/0277 , C01B2203/047 , C10G7/02 , C10G35/04 , C10G2300/1096 , C10G2300/4006 , C10G2400/02 , C10G2400/04
摘要： This invention relates to a process for hydrogenation of benzene contained in a catalytic reformate, in which: The hydrogen that is present in the catalytic reformate is separated from the remainder of the reformate with separation means, A light benzene-enriched fraction is separated from the heavy reformate, The light reformate that contains the benzene is brought into contact with a nickel-based hydrogenation catalyst at a temperature of between 90° C. and 150° C., a VVH of between 0.5 and 10, and with at least one portion of hydrogen that is obtained during the separation stage of the hydrogen at the top of the separator tank and used at the output pressure of said separator.
摘要翻译：本发明涉及催化重整油中所含的苯氢化方法，其中：催化重整产物中存在的氢气与分离装置与剩余的重整产物分离，将轻的富含苯的馏分与重质量重组体，含有苯的轻质重整油在90℃〜150℃，VVH为0.5〜10℃的温度下与镍系氢化催化剂接触，并与至少一部分在分离罐顶部的氢分离阶段期间获得的氢气，并在所述分离器的输出压力下使用。

8. 发明授权

US06334948B1 Process for producing gasoline with a low sulphur content 有权
标题翻译：生产硫含量低的汽油的方法
公开(公告)号：US06334948B1
公开(公告)日：2002-01-01
申请号：US09443152
申请日：1999-11-18
申请人： Blaise Didillon , Denis Uzio , Jean-Luc Nocca , Jean Cosyns
发明人： Blaise Didillon , Denis Uzio , Jean-Luc Nocca , Jean Cosyns
IPC分类号： C10G4506
CPC分类号： C10G65/16
摘要： A process for producing a gasoline with a low sulphur content comprises: separating a sulphur-containing gasoline into a light fraction and a heavy fraction, hydrodesulphurising the light gasoline on a nickel-based catalyst, hydrodesulphurising the heavy fraction on a catalyst comprising at least one group VIII metal and/or at least one group VIB metal, and mixing the desulphurised fractions.
摘要翻译：一种生产低硫含量的汽油的方法包括：将含硫汽油分离成轻馏分和重馏分，将轻汽油加氢脱硫在镍基催化剂上，对重馏分进行加氢脱硫，所述催化剂包含至少一种 VIII族金属和/或至少一种VIB族金属，并混合脱硫馏分。

9. 发明授权

US5633416A Fuel produced by a process comprising etherification of a hydrocarbon fraction comprising olefins containing 5 to 8 carbon atoms 失效
$Fuel produced by a process comprising etherification of a hydrocarbon fraction comprising olefins containing 5 to 8 carbon atoms$
标题翻译：通过包含含有5至8个碳原子的烯烃的烃馏分的醚化的方法产生的燃料
公开(公告)号：US5633416A
公开(公告)日：1997-05-27
申请号：US459691
申请日：1995-06-02
申请人： Yves Chauvin , Alain Forestiere , Marie-Claire Marion , H el ene Olivier , Patrick Sarrazin , Jean-Luc Nocca
发明人： Yves Chauvin , Alain Forestiere , Marie-Claire Marion , H el ene Olivier , Patrick Sarrazin , Jean-Luc Nocca
IPC分类号： C10L1/02 , C07C5/22 , C07C5/27 , C07C41/00
CPC分类号： C10L1/023
摘要： An internal combustion engine fuel is produced from a mixture of hydrocarbons comprising olefinic hydrocarbons containing 5 to 8 carbon atoms characterized in that it is produced by a process comprising a) a catalytic etherification step for at least a portion of the etherifiable olefins contained in said hydrocarbon mixture, using at least one alcohol containing 1 to 4 carbon atoms, the quantity of alcohol employed being such that the alcohol:etherifiable olefin molar ratio is at least 1:1, and b) a water washing step for the ether-containing product before recovery as a fuel.
摘要翻译：由含有5-8个碳原子的烯烃的烃的混合物产生内燃机燃料，其特征在于它是通过以下方法生产的：a）催化醚化步骤，用于至少部分所述烃中所含的可醚化烯烃混合物，使用至少一种含有1至4个碳原子的醇，所使用的醇的量使得醇：可醚化烯烃摩尔比至少为1:1，和b）含醚产物的水洗步骤作为燃料的回收。

10. 发明授权

US4847431A Process for manufacturing a tertiary alkyl ether by reactive distillation 失效
标题翻译：通过反应蒸馏制备叔烷基醚的方法
公开(公告)号：US4847431A
公开(公告)日：1989-07-11
申请号：US171340
申请日：1988-03-21
申请人： Jean-Luc Nocca , Jacques Leonard , Jean-Ferdinand Gaillard , Pierre Amigues
发明人： Jean-Luc Nocca , Jacques Leonard , Jean-Ferdinand Gaillard , Pierre Amigues
IPC分类号： C07B61/00 , B01D3/00 , B01D3/14 , B01D3/22 , B01D3/24 , B01J8/04 , B01J31/10 , C07C41/00 , C07C41/06 , C07C41/42 , C07C43/04 , C07C67/00
CPC分类号： B01J8/0492 , B01D3/009 , B01D3/22 , B01D3/24 , B01J8/0453 , C07C41/06 , C07C41/42 , Y02P20/127 , Y10S203/06
摘要： Process for manufacturing methyl tert-butyl ether (MTBE) by reacting methanol with isobutene-containing hydrocarbons in a reaction zone comprising alternate beds of sulfonated resin catalyst and catalyst-free distillation zones, said zones also comprising liquid redistribution plates.
摘要翻译：在包含磺化树脂催化剂和无催化剂的蒸馏区的交替床的反应区中使甲醇与含异丁烯的烃反应制备甲基叔丁基醚（MTBE）的方法，所述区域还包括液体再分布板。

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