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1. 发明授权

US4847430A Process for manufacturing a tertiary alkyl ether by reactive distillation 失效
标题翻译：通过反应蒸馏制备叔烷基醚的方法
公开(公告)号：US4847430A
公开(公告)日：1989-07-11
申请号：US171339
申请日：1988-03-21
申请人： Dang Vu Quang , Pierre Amigues , Jean-Ferdinand Gaillard , Jacques Leonard , Jean-Luc Nocca
发明人： Dang Vu Quang , Pierre Amigues , Jean-Ferdinand Gaillard , Jacques Leonard , Jean-Luc Nocca
IPC分类号： C07B61/00 , B01D3/00 , B01J8/04 , B01J31/10 , C07C41/00 , C07C41/06 , C07C41/42 , C07C43/04 , C07C67/00
CPC分类号： C07C41/06 , B01D3/009 , B01J8/0453 , C07C41/42 , Y02P20/127 , Y10S203/06
摘要： The invention concerns a process for manufacturing methyl tert-butyl ether (MTBE) by reacting methanol with an isobutene-containing hydrocarbon mixture.This process is characterized by the steps of:introducing the reactants into a reaction-distillation zone containing at least two superposed and non-contiguous fixed beds (2a, 2b) of catalyst of the sulfonated resin type, wherein passage-ways are provided for a vapor phase, at least one distillation tray (4a), at least one liquid redistribution tray (5),maintaining distillation conditions in said zone so as to have a descending liquid phase and an ascending vapor phase,maintaining a continuous liquid phase in the lower part of said beds,discharging a vapor phase containing a high proportion of unconverted hydrocarbons from the top (8) of said zone, andwithdrawing a liquid phase of high MTBE content from the bottom (10) of said zone.
摘要翻译：本发明涉及通过使甲醇与含异丁烯的烃混合物反应制备甲基叔丁基醚（MTBE）的方法。该方法的特征在于以下步骤：将反应物引入含有至少两个磺化树脂类型的催化剂的重叠和不连续的固定床（2a，2b）的反应 - 蒸馏区，其中为蒸气相，至少一个蒸馏塔板（4a），至少一个液体再分配托盘（5），保持所述区域中的蒸馏条件以具有下降的液相和上升的气相，将下一个液相保持在下部所述床的一部分，从所述区域的顶部（8）排出含有高比例未转化烃的气相，并从所述区域的底部（10）排出高MTBE含量的液相。

2. 发明授权

US4847431A Process for manufacturing a tertiary alkyl ether by reactive distillation 失效
标题翻译：通过反应蒸馏制备叔烷基醚的方法
公开(公告)号：US4847431A
公开(公告)日：1989-07-11
申请号：US171340
申请日：1988-03-21
申请人： Jean-Luc Nocca , Jacques Leonard , Jean-Ferdinand Gaillard , Pierre Amigues
发明人： Jean-Luc Nocca , Jacques Leonard , Jean-Ferdinand Gaillard , Pierre Amigues
IPC分类号： C07B61/00 , B01D3/00 , B01D3/14 , B01D3/22 , B01D3/24 , B01J8/04 , B01J31/10 , C07C41/00 , C07C41/06 , C07C41/42 , C07C43/04 , C07C67/00
CPC分类号： B01J8/0492 , B01D3/009 , B01D3/22 , B01D3/24 , B01J8/0453 , C07C41/06 , C07C41/42 , Y02P20/127 , Y10S203/06
摘要： Process for manufacturing methyl tert-butyl ether (MTBE) by reacting methanol with isobutene-containing hydrocarbons in a reaction zone comprising alternate beds of sulfonated resin catalyst and catalyst-free distillation zones, said zones also comprising liquid redistribution plates.
摘要翻译：在包含磺化树脂催化剂和无催化剂的蒸馏区的交替床的反应区中使甲醇与含异丁烯的烃反应制备甲基叔丁基醚（MTBE）的方法，所述区域还包括液体再分布板。

3. 发明授权

US4647703A Process for producing a hydrocarbon cut of high octane number by etherification of olefins 失效
标题翻译：通过烯烃醚化生产高辛烷值的烃馏分的方法
公开(公告)号：US4647703A
公开(公告)日：1987-03-03
申请号：US753465
申请日：1985-07-10
申请人： Bernard Torck , Pierre Amigues , Yves Glaize , Henri Grangette , Jean Laurent , Fred Fitoussi
发明人： Bernard Torck , Pierre Amigues , Yves Glaize , Henri Grangette , Jean Laurent , Fred Fitoussi
IPC分类号： C10G3/00 , C10L1/02
CPC分类号： C10L1/023 , Y02P30/20
摘要： Process for producing a hydrocarbon cut of high octane number by etherification of an olefin-containing hydrocarbon cut.The olefinic cut, to which methanol is added, passes into an etherification reactor (1) wherefrom are separated (3) a bottom product (15) containing ethers, and a top product (14) containing residual methanol and unreacted light olefins. This top product passes into an etherification reactor (2) and then is washed with water (8).The top product is finally admixed with the bottom product.The so-obtained motor-fuel has a higher octane number than that of the initial hydrocarbon cut.
摘要翻译：通过含烯烃的烃馏分的醚化生产高辛烷值的烃馏分的方法。向其中加入甲醇的烯属馏分进入醚化反应器（1），从其中分离出（3）含有醚的底部产物（15）和含有残余甲醇和未反应的轻质烯烃的顶部产物（14）。该顶部产物进入醚化反应器（2），然后用水（8）洗涤。最终的产品最终与底部产品混合。所得到的电动机燃料具有比初始碳氢化合物馏分高的辛烷值。

4. 发明授权

US4366327A Process for producing ethers by reacting olefins with alcohols 失效
标题翻译：通过烯烃与醇反应制备醚的方法
公开(公告)号：US4366327A
公开(公告)日：1982-12-28
申请号：US258317
申请日：1981-04-28
申请人： Alain Convers , Bernard Torck , Jean-Paul Euzen , Pierre Amigues
发明人： Alain Convers , Bernard Torck , Jean-Paul Euzen , Pierre Amigues
IPC分类号： C07C41/05 , B01J27/00 , B01J31/00 , C07C41/00 , C07C41/06 , C07C67/00
CPC分类号： C07C41/06
摘要： Process for producing ethers by reacting a catalytic cracking C.sub.4 olefinic cut which may contain such impurities as NaOH, an alkanolamine, an alkaline earth metal compound or an iron, copper or lead compound, with an alcohol, in the liquid phase, in the presence of an expanded bed of an etherification solid catalyst of the sulfonic resin type in acid form, in a circuit of two or more successive reaction zones wherethrough the order of passage of the reactants is periodically modified by disconnecting the first zone from the circuit, feeding the reactants to the second zone, replacing the catalyst of the first zone with fresh catalyst and thereafter connecting said first zone at the end of the circuit.
摘要翻译：通过在液相中存在下使可能含有诸如NaOH，链烷醇胺，碱土金属化合物或铁，铜或铅化合物的杂质的催化裂解C4烯烃切割物与醇反应来制备醚的方法在两个或更多个连续反应区的电路中，酸性磺酸树脂的醚化固体催化剂的膨胀床通过使第一区与电路断开而周期性地改变反应物的通过顺序，将反应物到第二区域，用新鲜催化剂代替第一区域的催化剂，然后在回路的末端连接所述第一区域。

5. 发明授权

US5026459A Apparatus for reactive distillation 失效
标题翻译：反应蒸馏装置
公开(公告)号：US5026459A
公开(公告)日：1991-06-25
申请号：US356087
申请日：1989-05-24
申请人： Dang Vu Quang , Pierre Amigues , Jean-Ferdinand Gaillard
发明人： Dang Vu Quang , Pierre Amigues , Jean-Ferdinand Gaillard
IPC分类号： B01D3/00 , C07C41/06 , C07C41/42
CPC分类号： B01D3/009 , C07C41/06 , C07C41/42 , Y02P20/127 , Y10S203/06
摘要： The invention concerns a process and apparatus for manufacturing methyl tert-butyl ether (MTBE) by reacting methanol with an isobutene-containing hydrocarbon mixture.This process is characterized by the steps of:introducing the reactants into a reaction-distillation zone containing at least two superposed and non-contiguous fixed beds (2a, 2b) of catalyst of the sulfonated resin type, wherein passageways are provided for a vapor phase, at least one distillation tray (4a), at least one liquid redistribution tray (5),maintaining distillation conditions in the zone so as to have a descending liquid phase and an ascending vapor phase,maintaining a continuous liquid phase in the lower part of the beds,discharging a vapor phase containing a high proportion of unconverted hydrocarbons from the top (8) of the zone, andwithdrawing a liquid phase of high MTBE content from the bottom (10) of the zone.
摘要翻译：本发明涉及通过使甲醇与含异丁烯的烃混合物反应制备甲基叔丁基醚（MTBE）的方法和装置。该方法的特征在于以下步骤：将反应物引入反应 - 蒸馏区，该反应蒸馏区包含磺化树脂型催化剂的至少两个重叠和不连续的固定床（2a，2b），其中为气相提供通道，至少一个蒸馏塔板（4a），至少一个液体再分布托盘（5），保持该区域中的蒸馏条件以具有下降的液相和上升的气相，在床，从该区域的顶部（8）排出含有高比例的未转化的烃的气相，并从该区域的底部（10）排出高MTBE含量的液相。

6. 发明授权

US4664675A Process for upgrading olefinic gasolines by etherification 失效
标题翻译：通过醚化提纯烯烃汽油的方法
公开(公告)号：US4664675A
公开(公告)日：1987-05-12
申请号：US745985
申请日：1985-06-18
申请人： Bernard Torck , Pierre Amigues , Jerome Weill , Claude Gueguen , Michel Llinares , Henri Bourgognon
发明人： Bernard Torck , Pierre Amigues , Jerome Weill , Claude Gueguen , Michel Llinares , Henri Bourgognon
IPC分类号： C10G35/00 , C10G57/00 , C10L1/02 , C10L1/10
CPC分类号： C10L1/023
摘要： The invention concerns a process for upgrading olefinic gasolines containing C.sub.5 hydrocarbons, but free of C.sub.4 hydrocarbons, by etherification. It is characterized in that the tertiary olefins of the charge are reacted (1 and 2) with methanol; the reaction effluent being then extracted (3) with water, in order to separate an aqueous phase containing the major part of the unreacted methanol from a hydrocarbon phase containing the major part of the formed ethers. The aqueous phase is then introduced in a distillation zone (4) where water is separated from methanol and recycled to the extraction zone (3), whereas methanol is recycled to the etherification zone (1 and 2).
摘要翻译：本发明涉及一种通过醚化提纯含有C5烃但不含C4烃的烯烃汽油的方法。其特征在于电荷的叔烯烃与甲醇反应（1和2）; 然后将反应流出物用水萃取（3），以便将含有主要部分未反应的甲醇的水相与含有主要部分形成的醚的烃相分离。然后将水相引入蒸馏区（4），其中将水从甲醇中分离并再循环至萃取区（3），而甲醇被再循环至醚化区（1和2）。

7. 发明授权

US4132745A Process for isomerizing 1-butene to 2-butene 失效
标题翻译：将1-丁烯异构化为2-丁烯的方法
公开(公告)号：US4132745A
公开(公告)日：1979-01-02
申请号：US879579
申请日：1978-02-21
申请人： Pierre Amigues , Jean Gaillard , Jean-Francois Le Page , Robert Stern
发明人： Pierre Amigues , Jean Gaillard , Jean-Francois Le Page , Robert Stern
IPC分类号： B01J23/40 , B01J37/20 , C07C5/22 , C07C5/25 , C07C5/24 , C07C5/30
CPC分类号： C07C5/226 , B01J23/40 , B01J37/20 , C07C5/2556 , C07C2521/04 , C07C2523/40 , C07C2523/44
摘要： Process for isomerizing 1-butene to 2-butene by contacting 1-butene, at a temperature from 50 to 140.degree. C, in the presence of hydrogen, with an isomerization catalyst containing a noble metal from group VIII of the periodic classification of elements, which catalyst was previously contacted with a sulfur compound at a temperature from 50 to 400.degree. C and then with hydrogen at a temperature of at least 50.degree. C.
摘要翻译：通过在氢存在下，在50-140℃的温度下使1-丁烯与包含元素周期分类的VIII族的贵金属的异构化催化剂接触，将1-丁烯异构化为2-丁烯的方法，该催化剂预先在50-400℃的温度下与硫化合物接触，然后在至少50℃的温度下与氢气接触。

8. 发明授权

US5013407A Apparatus for reactive distillation 失效
标题翻译：反应蒸馏装置
公开(公告)号：US5013407A
公开(公告)日：1991-05-07
申请号：US356090
申请日：1989-05-24
申请人： Jean-Luc Nocca , Jacques Leonard , Jean-Ferdinand Gaillard , Pierre Amigues
发明人： Jean-Luc Nocca , Jacques Leonard , Jean-Ferdinand Gaillard , Pierre Amigues
IPC分类号： B01D3/00 , B01J8/04 , C07C41/06 , C07C41/42
CPC分类号： C07C41/06 , B01D3/009 , B01J8/0453 , B01J8/0492 , C07C41/42 , Y02P20/127 , Y10S203/06
摘要： The invention relates to a process and apparatus for manufacturing methyl tert-butyl ether (MTBE) by reacting methanol with isobutene-containing hydrocarbons in a reaction zone having alternate beds of sulfonated resin catalyst and catalyst-free distillation zones wherein the zones also contain liquid redistribution plates.
摘要翻译：本发明涉及通过在具有磺化树脂催化剂和无催化剂的蒸馏区的交替床的反应区中使甲醇与含异丁烯的烃反应制备甲基叔丁基醚（MTBE）的方法和装置，其中该区还含有液体再分布盘子

9. 发明授权

US4390431A Process for treating aqueous streams containing aluminum 失效
标题翻译：用于处理含铝的水流的方法
公开(公告)号：US4390431A
公开(公告)日：1983-06-28
申请号：US261818
申请日：1981-05-08
申请人： Pierre Amigues , Yves Chauvin , Dominique Commereuc , Jean Gaillard , Nhu H. Phung
发明人： Pierre Amigues , Yves Chauvin , Dominique Commereuc , Jean Gaillard , Nhu H. Phung
IPC分类号： C02F1/58 , C01F7/02 , C07C7/148 , C22B21/00 , C02F1/52
CPC分类号： C01F7/02 , C07C7/1485 , C22B21/0015 , Y02P10/234 , Y10S210/912
摘要： A process for treating an aqueous phase obtained by acidic or basic washing of a hydrocarbon phase comprising a soluble aluminum compound in solution, characterized in that it is neutralized at a pH of from 6 to 8.5, treated with an additive selected from the alkaline-earth metal oxides, hydroxides and carbonates, at a temperature ranging from 90.degree. C. to the boiling point, the molar ratio of the additive to aluminum being from 1/10 to 10/1, and separated thereafter from the insoluble phase of precipitate.
摘要翻译：一种处理由在溶液中包含可溶性铝化合物的烃相酸洗或碱洗而获得的水相的方法，其特征在于其在6至8.5的pH下中和，用选自碱土金属金属氧化物，氢氧化物和碳酸盐，在90℃至沸点的温度下，添加剂与铝的摩尔比为1/10至10/1，然后从沉淀物的不溶相分离。

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