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1. 发明授权

US4268700A Process for producing gasoline of high octane number and particularly lead free gasoline, from olefininc C.sub.3 -C.sub.4 cuts 失效
标题翻译：生产高辛烷值汽油，特别是无铅汽油的方法，由烯烃C3-C4馏分制成
公开(公告)号：US4268700A
公开(公告)日：1981-05-19
申请号：US79728
申请日：1979-09-28
申请人： Quang Dang Vu , Bernard Juguin , Bernard Torck , Michel Hellin
发明人： Quang Dang Vu , Bernard Juguin , Bernard Torck , Michel Hellin
IPC分类号： C10G3/00 , C07C2/10 , C07C2/30 , C07C2/62 , C10L1/06 , C07C2/08 , C07C2/58
CPC分类号： C07C2/30 , C07C2/10 , C07C2/62 , C10L1/06 , C07C2521/12 , C07C2527/1206 , C07C2531/14 , Y02P30/20
摘要： Lead free gasoline of high octane number is obtained from C.sub.3 and C.sub.4 olefinic cuts as follows: propylene contained in the C.sub.3 cut is oligomerized, at least 80% of the isobutene and less than 40% of the n-butenes of the C.sub.4 cut are oligomerized to form an oligomerizate distilling in the gasoline range, which is separated from the unreacted C.sub.4 hydrocarbons, the latter are subsequently alkylated to form a gasoline fraction which can be admixed with the oligomerizates of the C.sub.3 and the C.sub.4 cuts to produce the desired high octane gasoline.
摘要翻译：由C3和C4烯烃切割获得高辛烷值的无铅汽油如下：C3馏分中所含的丙烯被低聚，至少80％的异丁烯和小于40％的C4馏分的正丁烯低聚在汽油范围内形成低分子馏出物，其与未反应的C4烃分离，随后烷基化形成汽油馏分，其可与C3和C4馏分的低聚物混合以产生所需的高辛烷值汽油。

2. 发明授权

US4395580A Process for producing an olefin by decomposition of the corresponding ether 失效
标题翻译：通过相应的醚分解生产烯烃的方法
公开(公告)号：US4395580A
公开(公告)日：1983-07-26
申请号：US316376
申请日：1981-10-29
申请人： Bernard Juguin , Jean Miquel , Michel Hellin , Bernard Torck
发明人： Bernard Juguin , Jean Miquel , Michel Hellin , Bernard Torck
IPC分类号： B01J21/00 , B01J21/06 , C07B61/00 , C07C1/00 , C07C1/20 , C07C11/02 , C07C67/00 , C07C1/24
CPC分类号： C07C1/20 , C07C2521/04 , C07C2521/06
摘要： Process for producing very pure olefins of the formula ##STR1## by decomposition of the corresponding ethers of formula ##STR2## wherein R.sub.1 and R.sub.3 are selected from the group of the alkyl, arylalkyl aryl or alkylaryl radicals, R and R.sub.2 being a hydrogen atom or a radical selected from said above mentioned group, in the presence of steam in a molar proportion from 2 to 8 times the ether amount and with the use of a catalyst comprising alumina to which is added 0.01 to 5% by weight of titanium or zirconium or hafnium as metal or as metal compound, said catalyst having a specific surface from 80 to 300 m.sup.2 /g.
摘要翻译：制备式“IMAGE”的非常纯的烯烃的方法是通过分解相应的式“IMAGE”的醚，其中R 1和R 3选自烷基，芳基烷基芳基或烷基芳基，R 2和R 2是氢原子或选自上述基团的基团，在蒸汽存在下，摩尔比例为乙醚量的2至8倍，并且使用包含氧化铝的催化剂，其中加入0.01至5重量％的钛或锆或铪作为金属或金属化合物，所述催化剂具有80至300m 2 / g的比表面积。

3. 发明授权

US4392002A Process for upgrading olefinic C.sub.4 cuts 失效
标题翻译：烯烃C4馏分升级方法
公开(公告)号：US4392002A
公开(公告)日：1983-07-05
申请号：US311828
申请日：1981-10-16
申请人： Jean Cosyns , Bernard Juguin , Jean-Francois Le Page , Jean Miquel
发明人： Jean Cosyns , Bernard Juguin , Jean-Francois Le Page , Jean Miquel
IPC分类号： C10G69/12 , C07C2/10 , C07C5/25 , C07C9/16 , C10G50/00 , C10L1/06 , C07C2/08 , C07C2/58
CPC分类号： C10L1/06 , C07C2/10 , C07C5/2556 , C07C9/16 , C07C2521/02 , C07C2521/04 , C07C2521/12 , C07C2523/44 , C07C2523/75 , C07C2523/755
摘要： A C.sub.4 cut is upgraded according to the following steps:(a) the dried C.sub.4 cut is polymerized in the presence of fluorinated alumina, boron-alumina or silica-alumina, to convert at least 95% of isobutene to dimers and trimers, the conversion of the normal butenes being at most 3%,(b) the whole polymerization effluent is hydro-isomerized in the presence of a group VIII metal catalyst, to isomerize at least 90% of the 1-butene of said effluent,(c) the hydro-isomerization effluent is fractionated and a resultant fraction is alkylated.Resultant alkylate and mixture of dimers and trimers can be mixed and used as gasoline.
摘要翻译： C4馏分根据以下步骤升级：（a）干燥的C4馏分在氟化氧化铝，硼 - 氧化铝或二氧化硅 - 氧化铝的存在下聚合，以将至少95％的异丁烯转化为二聚体和三聚体，转化率（b）在第VIII族金属催化剂存在下将整个聚合流出物加氢异构化，使至少90％的所述流出物的1-丁烯异构化，（c）分批加氢异构化流出物，并将所得馏分烷基化。得到的烷基化物和二聚体和三聚体的混合物可以混合并用作汽油。

4. 发明授权

US4197185A Process for the conversion of olefinic C.sub.4 cuts from steam cracking to high octane gasoline and butane 失效
标题翻译：烯烃C4馏分从蒸汽裂解转化为高辛烷值汽油和丁烷的方法
公开(公告)号：US4197185A
公开(公告)日：1980-04-08
申请号：US936965
申请日：1978-08-25
申请人： Jean-Francois Le Page , Jean Cosyns , Jean Miquel , Bernard Juguin
发明人： Jean-Francois Le Page , Jean Cosyns , Jean Miquel , Bernard Juguin
IPC分类号： B01J21/00 , B01J27/00 , C07B61/00 , C07C1/00 , C07C2/06 , C07C2/10 , C07C2/74 , C07C5/03 , C07C9/10 , C07C9/21 , C07C67/00 , C10G50/00 , C10G69/12 , C10L1/06 , C07C9/20
CPC分类号： C10L1/06 , C07C2/10 , C07C5/03 , C10G69/126 , C07C2521/02 , C07C2521/04 , C07C2521/12 , C07C2523/75 , C07C2523/755 , C10G2400/02
摘要： Process for producing butane and gasoline of high isooctane content, from a C.sub.4 olefin cut issued from a steam cracking unit, comprising the steps of:polymerizing at least 90% of the isobutene of the cut mainly to dimers and trimers thereof,hydrogenating the resulting polymerization mixture to normal butane, isooctane and isododecane,supplying the effluent from the hydrogenation unit to a separation zone to recover a gaseous fraction and a liquid mixture, andfractionating the liquid mixture to separate gasoline of high isooctane content, a C.sub.3.sup.- fraction and a butane fraction which is recycled to the steam cracking unit.
摘要翻译：从蒸汽裂解装置发出的C4烯烃切割制备高异辛烷含量的丁烷和汽油的方法，包括以下步骤：将切割的至少90％的异丁烯聚合成二聚体和三聚体，将所得聚合物氢化与正丁烷，异辛烷和异十二烷的混合物，将来自氢化单元的流出物供应到分离区以回收气态馏分和液体混合物，并将液体混合物分馏分离出高异辛烷含量的汽油，C3馏分和丁烷再循环到蒸汽裂解装置的馏分。

5. 发明授权

US4423264A Process for the joint production of highly pure 1-butene and premium gasoline from a C.sub.4 olefinic cut 失效
标题翻译：从C4烯烃切割联合生产高纯度1-丁烯和优质汽油的方法
公开(公告)号：US4423264A
公开(公告)日：1983-12-27
申请号：US392056
申请日：1982-06-25
申请人： Bernard Juguin , Jean Cosyns , Jean Miquel
发明人： Bernard Juguin , Jean Cosyns , Jean Miquel
IPC分类号： C10G69/12 , C07C11/08 , C10L1/04 , C10L1/06 , C07C2/74
CPC分类号： C07C11/08 , C10L1/04 , C10L1/06
摘要： Highly pure 1-butene and premium gasoline are obtained by(a) subjecting a C.sub.4 olefinic cut to a polymerization-disproportionation to partly convert the isobutene thereof to a gasoline which, in turn, by partial disproportionation, yields a jet fuel base and butenes,(b) fractionating the effluent from step (a) to a mixture (.alpha.) of gasoline and jet fuel base and to a fraction (.beta.) containing isobutane, n-butane, butenes, a small amount of isobutene and a minor amount of butadiene,(c) selectively polymerizing fraction (.beta.) to convert more than 90% of the isobutene thereof to gasoline,(d) fractionating the polymerized fraction (.beta.) to a gasoline cut (.gamma.) containing isobutene dimers and trimers and to a fraction (.delta.) containing isobutane, n-butane and butenes,(e) selectively hydrogenating the fraction (.delta.),(f) removing isobutane from the hydrogenated fraction (.delta.) and(g) fractionating the deisobutanized hydrogenated fraction (.delta.) to obtain a fraction containing at least 99% of 1-butene, the mixture (.alpha.) being admixed with the cut (.gamma.).
摘要翻译：通过以下方法获得高纯度的1-丁烯和优质汽油：（a）使C4烯烃切割物进行聚合歧化，将其异丁烯部分转化成汽油，然后汽油通过部分歧化产生喷气燃料基体和丁烯，（b）将来自步骤（a）的流出物分馏成汽油和喷气燃料基料的混合物（α）和含有异丁烷，正丁烷，丁烯，少量异丁烯和少量丁二烯的馏分（β），（c）选择性地聚合馏分（β）以将其超过90％的异丁烯转化成汽油，（d）将聚合馏分（β）分馏成含有异丁烯二聚体和三聚体的汽油馏分（γ）（e）选择性氢化馏分（δ），（f）从氢化馏分（delta）中除去异丁烷，和（g）分离除异丁氢化氢化馏分（delta）以获得af 反应物含有至少99％的1-丁烯，混合物（α）与切割（γ）混合。

6. 发明授权

US4324646A Process for converting C.sub.4 olefinic cracking cuts to alkylate and gasoline 失效
标题翻译：将C4烯烃裂解馏分转化为烷基化物和汽油的方法
公开(公告)号：US4324646A
公开(公告)日：1982-04-13
申请号：US180205
申请日：1980-08-21
申请人： Jean-Francois Le Page , Jean Cosyns , Jean Miquel , Bernard Juguin
发明人： Jean-Francois Le Page , Jean Cosyns , Jean Miquel , Bernard Juguin
IPC分类号： C10G57/02 , C07C9/16 , C10G35/04 , C10G50/00 , C10G69/12 , C10L1/06
CPC分类号： C07C9/16 , C10L1/06
摘要： A process is provided for selectively polymerizing isobutene in an olefinic C.sub.4 cut comprising isobutene and normal butenes by contacting the cut with a catalyst consisting essentially of silica-alumina; whereby at least 90% of the isobutene and less than 10% of the normal butenes in the cut are converted.
摘要翻译：提供了一种通过使切割与基本上由二氧化硅 - 氧化铝组成的催化剂接触来选择性地聚合包含异丁烯和正丁烯的烯烃C4馏分中的异丁烯的方法; 由此转化了至少90％的异丁烯和小于正丁烯的10％。

7. 发明授权

US3966833A Process for hydrodealkylating alkylaromatic hydrocarbons 失效
标题翻译：加氢脱烷基烷基芳烃的方法
公开(公告)号：US3966833A
公开(公告)日：1976-06-29
申请号：US532618
申请日：1974-12-13
申请人： Jean Cosyns , Bernard Juguin , Jean-Francois Le Page , Jean Miquel
发明人： Jean Cosyns , Bernard Juguin , Jean-Francois Le Page , Jean Miquel
IPC分类号： B01J23/00 , B01J23/56 , B01J35/10 , C07C1/00 , C07C4/18 , C07C15/02 , C07C67/00 , C07C3/58
CPC分类号： B01J35/10 , B01J23/56 , C07C4/18 , B01J35/1009 , B01J35/1014 , B01J35/1038 , B01J35/1042 , B01J35/1061 , C07C2521/04 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/755 , Y02P20/52
摘要： Process for hydrodealkylating an alkylaromatic hydrocarbon charge at a temperature from 400.degree. to 650.degree.C under a pressure from 1 to 30 kg/cm.sup.2 at a space velocity from 1 to 10 by reacting said charge with hydrogen in a molar proportion with respect to the effluent of the reactor in the range from 1 to 10, in the presence of a catalyst containing alumina and at least one metal selected from ruthenium, osmium, palladium, rhodium, iridium, platinum and manganese in an amount from 0.05 to 5 % of the catalyst, said catalyst having a specific surface from 1 to 100 m.sup.2 /g., a total pore volume of 0.2-0.8 g/cc and a heat of neutralization lower than 10 calories per gram are measured by ammonia adsorption at 320.degree. C. under 300 mm Hg.
摘要翻译：通过使所述电荷与氢气相对于流出物的摩尔比例反应，在400至650℃的温度下，在1至30kg / cm 2的压力下以1至10的空间速度对烷基芳烃进行加氢脱烷基化的方法在含有氧化铝和选自钌，锇，钯，铑，铱，铂和锰中的至少一种金属的催化剂存在下，反应器的量为1至10，催化剂的量为催化剂的0.05至5％所述催化剂具有1至100m 2 / g的比表面积，0.2-0.8g / cc的总孔容积和低于10卡路里/克的中和热通过在320℃下在300℃下的氨吸附来测量 mm Hg。

8. 发明授权

US4902847A Method for producing olefin oligomers using a modified mordenite based catalyst 失效
标题翻译：使用改性丝光沸石催化剂生产烯烃低聚物的方法
公开(公告)号：US4902847A
公开(公告)日：1990-02-20
申请号：US245241
申请日：1988-09-16
申请人： Bernard Juguin , Francis Raatz , Christine Travers , Germain Martino
发明人： Bernard Juguin , Francis Raatz , Christine Travers , Germain Martino
IPC分类号： C10G57/02 , B01J29/18 , C10G50/00 , F02B3/06
CPC分类号： B01J29/18 , C10G50/00 , B01J2229/16 , F02B3/06
摘要： Preparation of oligomers of C.sub.2 to C.sub.8 olefins useful in gasoline, yet fuel and diesel fuel is disclosed. The oligomerization is catalyzed by a modified mordenite in the H or NH.sub.4 + to form which has been sequentially treated with steam and an acid.
摘要翻译：公开了可用于汽油的C2至C8烯烃的低聚物，但燃料和柴油燃料的制备。低聚由H或NH4 +中的改性丝光沸石催化形成，其已经用蒸汽和酸依次处理。

9. 发明授权

US4244806A Process for converting C.sub.4 olefinic cracking cuts to alkylate and gasoline 失效
标题翻译：将C4烯烃裂解馏分转化为烷基化物和汽油的方法
公开(公告)号：US4244806A
公开(公告)日：1981-01-13
申请号：US25630
申请日：1979-03-30
申请人： Jean-Francois Le Page , Jean Cosyns , Jean Miquel , Bernard Juguin
发明人： Jean-Francois Le Page , Jean Cosyns , Jean Miquel , Bernard Juguin
IPC分类号： C10G57/02 , C07C9/16 , C10G35/04 , C10G50/00 , C10G69/12 , C10L1/06
CPC分类号： C07C9/16 , C10L1/06
摘要： A C.sub.4 olefinic cracking cut is subjected first to catalytic polymerization and then to fractionation: the resultant isobutene dimers and trimers fraction is hydrogenated, while the remainder is alkylated. The resultant product is a gasoline of high isooctane content.
摘要翻译：首先对C4烯烃裂解馏分进行催化聚合，然后进行分馏：得到的异丁烯二聚体和三聚体部分被氢化，而其余部分被烷基化。所得产物是高异辛烷含量的汽油。

10. 发明授权

US4133841A Process for upgrading effluents from syntheses of the Fischer-Tropsch type 失效
标题翻译：从费 - 托合成方法提高废水的方法
公开(公告)号：US4133841A
公开(公告)日：1979-01-09
申请号：US781277
申请日：1977-03-25
申请人： Jean Cosyns , Yves Chauvin , Bernard Juguin , Jean-Francois Le Page , Jean Miquel
发明人： Jean Cosyns , Yves Chauvin , Bernard Juguin , Jean-Francois Le Page , Jean Miquel
IPC分类号： C10G57/02 , C10L1/04 , C10L1/06 , C07C9/14 , C07C1/04
CPC分类号： C10G17/095 , C10G29/00 , C10G57/02 , C10L1/04 , C10L1/06 , Y10S208/95
摘要： This process for upgrading effluents from syntheses of the Fischer-Tropsch type comprises several steps applied to the three cuts obtained from these effluents, i.e. a "light fraction", a "light oil" and a "decanted oil". The products are mainly gasoline, kerosene and gasoil cuts.
摘要翻译：用于从费 - 托合成方法提高废水的该方法包括几个步骤，其应用于从这些流出物获得的三个馏分，即“轻馏分”，“轻油”和“倾析油”。产品主要是汽油，煤油和油烟。

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