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    • 4. 发明授权
    • Permeable cements
    • 透水泥
    • US06883609B2
    • 2005-04-26
    • US10276186
    • 2001-05-11
    • Bruno DrochonPierre Maroy
    • Bruno DrochonPierre Maroy
    • C04B7/52C04B28/02C09K8/46C09K8/473E21B43/02
    • C04B28/02C04B7/527C04B2111/00284C09K8/46C09K8/473C09K8/572Y02W30/92C04B14/28C04B14/308C04B18/082C04B20/0076C04B38/00
    • The present invention concerns a cement slurry with high permeability and good compressive strength, comprising a solid fraction constituted by: 35% to 80% (by volume) of particles with a mean size in the range 100 microns (μ) to 800μ; 0% to 15% (by volume) of particles with a mean particle diameter in the range 0.1 microns to 10 microns; and 10% to 40% (by volume) of particles with a mean particle diameter in the range 20μ to 50μ; a fraction of said-solid particles being constituted by a cement, and preferably a further fraction by self-destructive particles; a liquid fraction in a water/solid ratio in the range 38% to 50% by volume; and a percentage of cells, provided by a gas or a liquid which is not miscible with water, in the range 30% to 60% of the final volume of the slurry.
    • 本发明涉及一种具有高渗透性和良好抗压强度的水泥浆料,其包含由以下组成的固体部分:35%至80%(体积)的平均粒径在100微米至800微米范围内的颗粒; 0%至15%(体积)的平均粒径为0.1微米至10微米的颗粒; 和10〜40%(体积)的平均粒径在20μm〜50μm的范围内的颗粒; 所述固体颗粒的一部分由水泥构成,优选由自毁颗粒构成另外的部分; 水/固体比在38%至50%体积比范围内的液体部分; 和由不与水混溶的气体或液体提供的细胞的百分比在浆液的最终体积的30%至60%的范围内。
    • 5. 发明授权
    • Process for controlling iron
    • 控制铁的工艺
    • US5972849A
    • 1999-10-26
    • US553964
    • 1995-11-06
    • Jean-Pierre FeraudHerve PerthuisPhilippe DejeuxPierre Maroy
    • Jean-Pierre FeraudHerve PerthuisPhilippe DejeuxPierre Maroy
    • C09K8/528C09K8/74C09K7/00E21B43/00
    • C09K8/528C09K8/74
    • In the presence of certain crude oils, when ferric iron exists in very acidic fluid, it practically instantaneously forms precipitates known as sludges which lead to irreversible damage. Iron control compositions and acid fluids containing such iron control compositions are disclosed. For acid fluids containing up to 15% acid, the iron control composition includes a reducing agent selected from a substituted and unsubstituted thiourea compounds, and a reduction catalyst including a copper (cuprous or cupric) compound. When the acid fluid contains more than 15% acid, for example from 15 to 28% acid, the reducing agent is again selected from substituted or unsubstituted thiourea compounds, and the reduction catalyst is a combination of a copper (cuprous or cupric) compound and iodine (iodine or iodide ions). The invention also includes a process for treatment of oil, water, gas, geothermal or analogous wells using an acid fluid containing an iron control composition according to the present invention, and an industrial cleaning process using a cleaning fluid including an acid fluid containing an iron control agent according to the present invention.
    • 在某些原油的存在下,当三价铁存在于非常酸性的流体中时,它几乎瞬间形成称为淤泥的沉淀物,这导致不可逆的损伤。 公开了含铁控制组合物的铁控制组合物和酸流体。 对于含有高达15%酸的酸性流体,铁控制组合物包括选自取代和未取代的硫脲化合物的还原剂和包含铜(亚铜或铜)化合物的还原催化剂。 当酸性流体含有超过15%的酸,例如15至28%的酸时,还原剂再次选自取代或未取代的硫脲化合物,还原催化剂是铜(亚铜或铜)化合物和 碘(碘或碘离子)。 本发明还包括使用含有根据本发明的铁控制组合物的酸性流体处理油,水,气体,地热或类似井的方法,以及使用包括含有铁的酸性流体的清洁流体的工业清洁方法 根据本发明的控制剂。
    • 6. 发明授权
    • Polymer solutions with shear reversible properties
    • 具有剪切可逆性质的聚合物溶液
    • US07385019B2
    • 2008-06-10
    • US10481148
    • 2002-06-11
    • Pierre MaroyArnaud CadixDominique HourdetIlias IliopoulosFrançoise Lafuma
    • Pierre MaroyArnaud CadixDominique HourdetIlias IliopoulosFrançoise Lafuma
    • C08F26/06C08F126/06C08F226/06
    • C09K8/035C09K3/00
    • Water-based fluids that can viscosify under shear or can produce a gel or form a gel under shear are obtained by dissolving polymers in an aqueous phase. These polymers comprise three types of functional groups: non-ionic functional groups that are hydrosoluble at the temperature under consideration, ionic functional groups, and functional groups that are hydrophobic at the temperature under consideration. These three types of functional groups can be distributed or spread in a random distribution along the polymer chain. A slightly block distribution is acceptable. For applications to oil wells, functional groups are used which exhibit LCST (Lower Critical Solution Temperature) behavior (i.e., a low critical solution temperature) instead of hydrophobic functional groups. At temperatures below the LCST, the functional groups are hydrophobic.
    • 通过将聚合物溶解在水相中,可以获得在剪切下可以粘稠或可以在剪切下产生凝胶或形成凝胶的水基流体。 这些聚合物包括三种类型的官能团:在所考虑的温度下可溶于水的非离子官能团,离子官能团和在所考虑的温度下是疏水的官能团。 这三种类型的官能团可以沿着聚合物链分布或分布在随机分布中。 稍微块分布是可以接受的。 对于油井的应用,使用显示LCST(较低临界溶液温度)行为(即低临界溶解温度)而不是疏水官能团的官能团。 在低于LCST的温度下,官能团是疏水的。
    • 9. 发明授权
    • Well cementing aids
    • 固井助剂
    • US06277900B1
    • 2001-08-21
    • US09196668
    • 1998-11-19
    • Reinhard OswaldVolker FrenzJuergen TonhauserAranka TardiPierre MaroyFlorence L'Alloret
    • Reinhard OswaldVolker FrenzJuergen TonhauserAranka TardiPierre MaroyFlorence L'Alloret
    • C09K700
    • C09K8/46C04B24/163C04B28/02C08F220/54C08F220/58C04B22/0026
    • The present invention relates to copolymers consisting of (a) 1-99% by weight of structural units of the formula (1)  where R1 is hydrogen or methyl, R4 is C1-C22-alkylene, R5 is C1-C22-alkyl or hydrogen, and X is ammonium, lithium, sodium, potassium, an amine or a mixture of these substances, and (b) 99-1% by weight of structural units of the formula (2)  where R1 is hydrogen or methyl, R2 and R3, independently of one another, are hydrogen, or C2-C22-alkyl, wherein component b) is not hydrolysed and the copolymers have been prepared by a solution precipitation polymerization in a nonaqueous solvent or a water-miscible, organic solvent having a low water content which is a precipitant for the copolymer. The invention furthermore relates to a process for cementing subterranean wells using a cement slurry comprising the following components: a) water of various salinity cement a novel copolymer in a concentration of 0.01-5% bwoc, preferably from 0.05 to 0.9% bwoc.
    • 本发明涉及由(a)1-99重量%的式(1)结构单元,其中R 1是氢或甲基,R 4是C 1 -C 22 - 亚烷基,R 5是C 1 -C 22 - 烷基或氢 ,和X是铵,锂,钠,钾,胺或这些物质的混合物,和(b)99-1重量%的式(2)的结构单元,其中R 1是氢或甲基,R 2和R 3 彼此独立地为氢或C 2 -C 22 - 烷基,其中组分b)未水解,并且该共聚物通过在非水溶剂或具有低水的水混溶性有机溶剂中的溶液沉淀聚合制备 作为共聚物的沉淀剂的含量。 本发明还涉及一种使用包含以下组分的水泥浆料固井地下井的方法:a)浓度为0.01-5%bwoc,优选0.05-0.9%bwoc的各种盐酸盐型新型共聚物的水。