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1. 发明授权

US5733514A Process and device for manufacturing synthesis gas and application 失效
标题翻译：制造合成气和应用的工艺和装置
公开(公告)号：US5733514A
公开(公告)日：1998-03-31
申请号：US782496
申请日：1997-01-10
申请人： Pierre Boucot , Paul Gateau , Michel Maute , Philippe Courty , Jerome Weill
发明人： Pierre Boucot , Paul Gateau , Michel Maute , Philippe Courty , Jerome Weill
IPC分类号： B01J8/02 , B01J8/04 , B01J23/00 , B01J23/78 , C01B3/36 , C01B3/38 , C01B3/24
CPC分类号： B01J23/002 , B01J23/005 , B01J23/78 , B01J8/02 , B01J8/0278 , B01J8/0403 , C01B3/36 , C01B3/382 , B01J2208/00495 , B01J2208/0053 , B01J2219/182 , Y02P20/52
摘要： The present invention relates to a process and a device for manufacturing synthesis gas. The reactor according to the invention comprises within a single housing: A non catalytic combustion chamber (1) comprising at least one device (2) for injecting a fuel and at least one device (3) for injecting an oxidizer so as to achieve a partial combustion in said chamber, and at least one catalytic bed (4) which the gases coming from combustion chamber (1) run into, and also comprising at least one device (6) for injecting an additional oxidizer. The reactor and the process according to the invention may be applied to any chemical manufacturing utilizing synthesis gas, such as the manufacturing of ammonia, urea, methanol, higher hydrocarbons, etc.
摘要翻译：本发明涉及一种制造合成气的方法和装置。根据本发明的反应器包括在单个壳体内：非催化燃烧室（1），其包括用于喷射燃料的至少一个装置（2）和用于注入氧化剂的至少一个装置（3），以实现部分所述室中的燃烧和来自燃烧室（1）的气体的至少一个催化床（4）进入，并且还包括用于注入另外的氧化剂的至少一个装置（6）。根据本发明的反应器和方法可以应用于利用合成气的任何化学制造，例如氨，尿素，甲醇，高级烃等的制造。

2. 发明授权

US5632787A Process and device for manufacturing synthesis gas and application 失效
标题翻译：制造合成气和应用的工艺和装置
公开(公告)号：US5632787A
公开(公告)日：1997-05-27
申请号：US382587
申请日：1995-02-02
申请人： Pierre Boucot , Paul Gateau , Michel Maute , Philippe Courty , Jerome Weill
发明人： Pierre Boucot , Paul Gateau , Michel Maute , Philippe Courty , Jerome Weill
IPC分类号： B01J8/02 , B01J8/04 , B01J23/00 , B01J23/78 , C01B3/36 , C01B3/38 , C01B3/24
CPC分类号： B01J23/002 , B01J23/005 , B01J23/78 , B01J8/02 , B01J8/0278 , B01J8/0403 , C01B3/36 , C01B3/382 , B01J2208/00495 , B01J2208/0053 , B01J2219/182 , Y02P20/52
摘要： A reactor for manufacturing synthesis gas as a single housing, equipped with a non-catalytic combustion chamber having at least one device for injecting a fuel and at least one device for injecting an oxidizer so as to achieve partial combustion in said chamber, and at least one catalytic bed from which the gases coming from the combustion chamber discharge into, said catalytic bed being equipped with at least one device for injecting an additional oxidizer. A process for operating the reactor may be applied to any chemical manufacturing utilizing synthesis gas, such as the manufacturing of ammonia, urea, methanol, higher hydrocarbons, etc.
摘要翻译：一种用于制造合成气作为单个壳体的反应器，其装备有具有至少一个用于喷射燃料的装置的非催化燃烧室和至少一个用于注入氧化剂的装置，以便在所述室中实现部分燃烧，并且至少一个催化床，来自燃烧室的气体从该催化床排出，所述催化床配备有至少一个用于注入另外的氧化剂的装置。用于操作反应器的方法可以应用于使用合成气的任何化学制造，例如氨，尿素，甲醇，高级烃等的制造。

3. 发明授权

US5755841A Process and device for manufacturing synthesis gas and application 失效
标题翻译：制造合成气和应用的工艺和装置
公开(公告)号：US5755841A
公开(公告)日：1998-05-26
申请号：US631909
申请日：1996-04-12
申请人： Pierre Boucot , Paul Gateau , Jerome Weill
发明人： Pierre Boucot , Paul Gateau , Jerome Weill
IPC分类号： B01J8/04 , C01B3/02 , C01B3/36 , C01B3/38 , C07C1/04 , C07C29/151 , C07C31/04 , C01B3/24
CPC分类号： B01J8/0484 , B01J8/0453 , B01J8/0492 , C01B3/025 , C01B3/36 , C01B3/382 , C07C1/041 , C07C29/1516 , B01J2208/025 , C01B2203/142 , C01B2203/82
摘要： The present invention relates to a process and to a device for manufacturing synthetic gas. The reactor in accordance with the invention comprises within a single housing: a non catalytic combustion chamber (1) comprising at least one fuel injection element (2) and at least one oxidizer injection element (3) so as to achieve a partial combustion in said chamber referred to as "sufficient residence time chamber", and at least one catalytic bed (4) into which the gases coming from combustion chamber (1) run, and further comprising at least one additional oxidizer injection element (6) and at least one fuel injection element (7). The reactor and the process in accordance with the invention may be applied to any chemical manufacturing utilizing synthetic gas.
摘要翻译：本发明涉及一种制造合成气体的方法和装置。根据本发明的反应器包括在单个壳体内：非催化燃烧室（1），其包括至少一个燃料喷射元件（2）和至少一个氧化剂注入元件（3），以便在所述称为“足够的停留时间室”的室，以及至少一个催化床（4），来自燃烧室（1）的气体流入其中，并且还包括至少一个附加的氧化剂注入元件（6）和至少一个燃料喷射元件（7）。根据本发明的反应器和方法可以应用于利用合成气体的任何化学制造。

4. 发明授权

US4433157A Process for manufacturing anhydrides of alkenyl dicarboxylic acids 失效
标题翻译：烯基二羧酸酐的制备方法
公开(公告)号：US4433157A
公开(公告)日：1984-02-21
申请号：US377114
申请日：1982-05-11
申请人： Jerome Weill , Jacques Garapon , Bernard Sillion
发明人： Jerome Weill , Jacques Garapon , Bernard Sillion
IPC分类号： C07C51/567 , C08F8/46 , C10L1/198 , C07D307/60
CPC分类号： C10L1/198 , C07C51/567 , C08F8/22 , C08F8/46
摘要： A process for manufacturing an alkenyl dicarboxylic acid, anhydride comprises reacting at least one halogenated polyolefin with at least one unsaturated dicarboxylic acid anhydride in substantially stoichiometrical proportion, in the presence of a minor proportion of at least one organic compound containing at least one double bond bearing at least one electron attracting substituent.
摘要翻译：一种制备烯基二羧酸，酸酐的方法包括使至少一种卤代聚烯烃与至少一种不饱和二羧酸酐基本上以化学计量比例在少量比例的至少一种含有至少一个双键轴承的有机化合物的存在下反应至少一个电子吸引取代基。

5. 发明授权

US5270016A Apparatus for the thermal conversion of methane 失效
标题翻译：用于甲烷热转化的装置
公开(公告)号：US5270016A
公开(公告)日：1993-12-14
申请号：US913336
申请日：1992-07-15
申请人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
发明人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
IPC分类号： B01J12/00 , B01J19/24 , C07C2/76
CPC分类号： C07C2/76 , B01J12/005 , B01J19/24 , B01J2219/00135 , Y10S585/913
摘要： Apparatus suitable for the thermal conversion of methane to hydrocarbons of higher molecular weight, comprising an elongated reactor 1 provided with an inlet 5 for supplying a gas mixture containing methane (process gas) and an outlet at the opposite end, the reactor over a first part towards the inlet end having a plurality of electric heaters 3 surrounded by sheaths 4. The heaters, e.g., electric resistors, which are spaced apart and are substantially parallel with respect to one another, are arranged in substantially parallel rows perpendicular to the axis of the reactor so as to permit circulation of the process gas and/or effluent between the sheaths and/or between the sheaths and walls 22 separating two consecutive rows. The heaters heat the passages by successive independent cross sections substantially perpendicular to the axis of the reaction. Towards the outlet end, the reactor further comprises an injector for supplying cooling fluid, which cools the effluent. The reactor also has a hydrogen inlet for introducing a gas containing hydrogen into the space surrounding the heaters inside the sheaths 4 at an appropriate pressure. The reactor and the sheaths 4 are designed so that hydrogen is diffused from inside the sheaths to outside them and can then be diluted in the process gas.
摘要翻译：适用于将甲烷热转化成较高分子量的烃的装置，包括一个细长的反应器1，该反应器1设有一个入口5，入口5用于提供含有甲烷（工艺气体）的气体混合物和另一端的出口，第一部分朝向入口端具有由护套4围绕的多个电加热器3。间隔开并且相对于彼此大致平行的加热器，例如电阻器，被布置成垂直于反应器，以允许工艺气体和/或流出物在护套之间和/或分离两个连续的行的护套和壁22之间循环。加热器通过基本上垂直于反应轴线的连续的独立横截面来加热通道。朝向出口端，反应器还包括用于供应冷却流体的喷射器，其冷却流出物。反应器还具有氢气入口，用于以适当的压力将含氢的气体引入护套4内的加热器周围的空间。反应器和护套4被设计成使得氢气从鞘内部扩散到外部，然后可以在工艺气体中稀释。

6. 发明授权

US4664675A Process for upgrading olefinic gasolines by etherification 失效
标题翻译：通过醚化提纯烯烃汽油的方法
公开(公告)号：US4664675A
公开(公告)日：1987-05-12
申请号：US745985
申请日：1985-06-18
申请人： Bernard Torck , Pierre Amigues , Jerome Weill , Claude Gueguen , Michel Llinares , Henri Bourgognon
发明人： Bernard Torck , Pierre Amigues , Jerome Weill , Claude Gueguen , Michel Llinares , Henri Bourgognon
IPC分类号： C10G35/00 , C10G57/00 , C10L1/02 , C10L1/10
CPC分类号： C10L1/023
摘要： The invention concerns a process for upgrading olefinic gasolines containing C.sub.5 hydrocarbons, but free of C.sub.4 hydrocarbons, by etherification. It is characterized in that the tertiary olefins of the charge are reacted (1 and 2) with methanol; the reaction effluent being then extracted (3) with water, in order to separate an aqueous phase containing the major part of the unreacted methanol from a hydrocarbon phase containing the major part of the formed ethers. The aqueous phase is then introduced in a distillation zone (4) where water is separated from methanol and recycled to the extraction zone (3), whereas methanol is recycled to the etherification zone (1 and 2).
摘要翻译：本发明涉及一种通过醚化提纯含有C5烃但不含C4烃的烯烃汽油的方法。其特征在于电荷的叔烯烃与甲醇反应（1和2）; 然后将反应流出物用水萃取（3），以便将含有主要部分未反应的甲醇的水相与含有主要部分形成的醚的烃相分离。然后将水相引入蒸馏区（4），其中将水从甲醇中分离并再循环至萃取区（3），而甲醇被再循环至醚化区（1和2）。

7. 发明授权

US4465609A Method of operating a heat pump or a thermal engine with a chloro-fluorinated hydrocarbon having an increased thermal stability 失效
标题翻译：用具有增加的热稳定性的氯氟化烃来操作热泵或热机的方法
公开(公告)号：US4465609A
公开(公告)日：1984-08-14
申请号：US407218
申请日：1982-08-11
申请人： Jacques Denis , Jerome Weill , Alexandre Rojey
发明人： Jacques Denis , Jerome Weill , Alexandre Rojey
IPC分类号： C09K5/04
CPC分类号： C09K5/047
摘要： A method of operating a heat pump or a thermal engine with the vaporization and the condensation of a heat transfer fluid. The fluid is a chlorofluorinated hydrocarbon with 2 or 3 carbon atoms, a hydrogen atom, at least one chlorine atom per molecule and at most one chlorine atom per carbon atom, with the remainder consisting of fluorine, and said fluid having a critical temperature of at least 140.degree. C.
摘要翻译：一种在传热流体的蒸发和冷凝下操作热泵或热发动机的方法。流体是具有2或3个碳原子的氯氟化烃，氢原子，每分子至少一个氯原子和至多一个氯原子/碳原子，其余由氟组成，所述流体的临界温度为至少140℃

8. 发明授权

US5365005A Process for the thermal conversion of methane and a reactor for carrying out the process 失效
标题翻译：用于甲烷热转化和用于进行该方法的反应器的方法
公开(公告)号：US5365005A
公开(公告)日：1994-11-15
申请号：US962453
申请日：1992-10-19
申请人： Jerome Weill , Laure Capogna , Veronique Arrondel , Jean-Jack Boumendil
发明人： Jerome Weill , Laure Capogna , Veronique Arrondel , Jean-Jack Boumendil
IPC分类号： B01J12/00 , B01J19/00 , B01J19/24 , C07C2/76 , C07C2/00
CPC分类号： B01J19/24 , B01J12/005 , B01J19/0013 , C07C2/76 , B01J2219/00135 , Y10S585/913 , Y10S585/921 , Y10S585/943
摘要： A process and apparatus for the thermal conversion of methane into hydrocarbons of higher molecular weight, comprising a reactor (1) of elongate form, connected on the one hand, at a first end, to means (5) for supplying gaseous mixture containing methane (process gas) and on the other, at the opposite end, to discharge means (10), the said reactor comprising on a first part (the first end side) a plurality of elements disposed in at least two layers, substantially parallel inter se and substantially perpendicular to the axis of the reactor, at least one of these layers comprising a series of sheaths (4) inside which there are electric heating means (3) which thus form a layer of heating elements, the said elements being disposed in such a way as to define between them and/or between the layers which they form and/or between them and the walls of the spaces or passages for the circulation of gaseous mixtures and/or effluents, the said heating means and the said sheaths being adapted to heat the said passages by successive independent cross-sections substantially at right-angles to the axis of the reactor, each cross-section comprising at least one transverse row of elements and the said reactor also comprising automatic heating control and modulation means connected to the said heating means and comprising in a second part (8) (the same side as the opposite end) contiguous with the first part, means (9) for cooling effluents and connected to the said cooling medium supply means.
摘要翻译：一种用于将甲烷热转化成较高分子量的烃的方法和装置，其包括在第一端连接的细长形式的反应器（1），用于提供含有甲烷的气体混合物的装置（5）另一方面，在另一端，排出装置（10），所述反应器包括在第一部分（第一端侧）上的多个元件，其设置在至少两层中，基本平行的间隔和基本上垂直于反应器的轴线，这些层中的至少一个包括一系列护套（4），其中有电加热装置（3），因此形成一层加热元件，所述元件设置在在它们之间和/或它们之间形成的层之间和/或它们之间以及/或它们与用于气体混合物和/或流出物的循环的空间或通道的壁之间限定的方式，所述加热装置和所述护套适于通过基本上与反应器的轴线成直角的连续独立横截面来加热所述通道，每个横截面包括至少一个横向排的元件，并且所述反应器还包括自动加热控制和调制装置，其连接到所述加热装置，并且包括与第一部分邻接的第二部分（8）（与相对端相同的一侧），用于冷却流出物并连接到所述冷却介质供应装置的装置（9）。

9. 发明授权

US5242574A Use of nickel-based alloys in a process for the thermal cracking of a petroleum charge and reactor for performing the process 失效
标题翻译：镍基合金在石墨炉热裂解工艺中的应用及其应用
公开(公告)号：US5242574A
公开(公告)日：1993-09-07
申请号：US776299
申请日：1991-12-06
申请人： Paul Broutin , Christian Busson , Antoine Montoya , Jerome Weill
发明人： Paul Broutin , Christian Busson , Antoine Montoya , Jerome Weill
IPC分类号： B01J19/24 , C10G9/18 , C10G9/20 , F28D9/00 , F28F19/02 , F28F21/08
CPC分类号： F28F21/087 , B01J19/2485 , C10G9/203 , F28D9/0037 , F28F19/02 , Y10S585/95
摘要： A process and reactor are disclosed for the thermal cracking of a charge containing at least one hydrocarbon with at least one carbon atom, in which the charge is circulated in a metal reaction zone which includes a pyrolysis zone whose external wall is in thermal exchange relationship with a heating liquid. The reaction zone consists of an alloy containing, by weight, 66-82% nickel, 14-18% chromium, and 4-6% aluminum. This alloy, which has already been preoxidized, may be covered, at least in the reaction zone, with at least one layer formed by an oxide of at least one metal and/or at least one metal carbide and/or at least one metal nitride and/or at least one metal silicide. The invention finds application for vapor-phase cracking and dehydrogenation of hydrocarbon charges.
摘要翻译： PCT No.PCT / FR90 / 00392 Sec。 371 1991年12月6日第 102（e）日期1991年12月6日PCT提交1990年6月5日PCT公布。出版物WO90 / 15119 公开了一种用于热分解含有至少一种具有至少一个碳原子的烃的方法和反应器，其中电荷在金属反应区中循环，所述金属反应区包括热解区，其外部壁与加热液体具有热交换关系。反应区由含有重量百分比为66-82％镍，14-18％铬和4-6％铝的合金组成。已经预氧化的该合金可以至少在反应区中被至少一层由至少一种金属和/或至少一种金属碳化物的氧化物形成的层和/或至少一种金属氮化物和/或至少一种金属硅化物。本发明应用于烃电荷的气相裂化和脱氢。

10. 发明授权

US5321191A Process for the thermal pyrolysis of hydrocarbons using an electric furnace 失效
标题翻译：使用电炉对烃进行热解的方法
公开(公告)号：US5321191A
公开(公告)日：1994-06-14
申请号：US972782
申请日：1992-11-09
申请人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
发明人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
IPC分类号： C10G9/24 , C07C4/04
CPC分类号： C10G9/24 , Y10S585/921 , Y10S585/926
摘要： A process for the thermal pyrolysis of hydrocarbons in a reactor (1) of elongate shape comprising at a first end supply means (5) for a gaseous mixture containing at least one hydrocarbon, at the opposite end discharge means (10) for the effluents produced and between these two ends supply means (9) for effluent cooling fluid, the reactor comprising in a first part (first end side) a plurality of electric heating means (3) enclosed by casings (4) disposed in substantially mutually parallel layers perpendicular to the axis of the reactor, in such a way as to define between the casings and/or the casings and the walls (22), spaces or passages for circulation of the gaseous mixtures and/or effluents. The heating means heat the passages in successive, individual, transverse sections which are substantially perpendicular to the axis of the reactor. The reactor comprises means for introducing into the casings (4) a gas G known as a casing gas which preferably contains water vapour and/or hydrogen. The permeability of the casings is sufficient to permit diffusion, at least at certain points, of at least a part of the gas G from inside the casings to the outside of the casings, the gas G then being diluted in the gaseous mixture.
摘要翻译：一种用于在细长形状的反应器（1）中热解烃的方法，该方法包括在第一端供应装置（5），用于含有至少一种烃的气态混合物，在相对的端部排出装置（10）用于所产生的流出物并且在这两个端部之间，用于流出物冷却流体的供应装置（9），所述反应器包括在第一部分（第一端侧）中的多个电加热装置（3），所述多个电加热装置（3）由壳体（4）包围，反应器的轴线以限定壳体和/或壳体和壁（22）之间的方式，用于气态混合物和/或流出物循环的空间或通道。加热装置加热基本上垂直于反应器轴线的连续的，单独的横向部分中的通道。反应器包括用于将优选含有水蒸气和/或氢气的称为外壳气体的气体G引入壳体（4）的装置。壳体的渗透性足以允许至少在某些点处将气体G的至少一部分从壳体内部扩散到壳体的外部，然后将气体G稀释在气体混合物中。

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