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1. 发明授权

US5321191A Process for the thermal pyrolysis of hydrocarbons using an electric furnace 失效
标题翻译：使用电炉对烃进行热解的方法
公开(公告)号：US5321191A
公开(公告)日：1994-06-14
申请号：US972782
申请日：1992-11-09
申请人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
发明人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
IPC分类号： C10G9/24 , C07C4/04
CPC分类号： C10G9/24 , Y10S585/921 , Y10S585/926
摘要： A process for the thermal pyrolysis of hydrocarbons in a reactor (1) of elongate shape comprising at a first end supply means (5) for a gaseous mixture containing at least one hydrocarbon, at the opposite end discharge means (10) for the effluents produced and between these two ends supply means (9) for effluent cooling fluid, the reactor comprising in a first part (first end side) a plurality of electric heating means (3) enclosed by casings (4) disposed in substantially mutually parallel layers perpendicular to the axis of the reactor, in such a way as to define between the casings and/or the casings and the walls (22), spaces or passages for circulation of the gaseous mixtures and/or effluents. The heating means heat the passages in successive, individual, transverse sections which are substantially perpendicular to the axis of the reactor. The reactor comprises means for introducing into the casings (4) a gas G known as a casing gas which preferably contains water vapour and/or hydrogen. The permeability of the casings is sufficient to permit diffusion, at least at certain points, of at least a part of the gas G from inside the casings to the outside of the casings, the gas G then being diluted in the gaseous mixture.
摘要翻译：一种用于在细长形状的反应器（1）中热解烃的方法，该方法包括在第一端供应装置（5），用于含有至少一种烃的气态混合物，在相对的端部排出装置（10）用于所产生的流出物并且在这两个端部之间，用于流出物冷却流体的供应装置（9），所述反应器包括在第一部分（第一端侧）中的多个电加热装置（3），所述多个电加热装置（3）由壳体（4）包围，反应器的轴线以限定壳体和/或壳体和壁（22）之间的方式，用于气态混合物和/或流出物循环的空间或通道。加热装置加热基本上垂直于反应器轴线的连续的，单独的横向部分中的通道。反应器包括用于将优选含有水蒸气和/或氢气的称为外壳气体的气体G引入壳体（4）的装置。壳体的渗透性足以允许至少在某些点处将气体G的至少一部分从壳体内部扩散到壳体的外部，然后将气体G稀释在气体混合物中。

2. 发明授权

US5186910A Method and reactor for oxidation with a pressure drop differential, and its use 失效
标题翻译：用于压力差异氧化的方法和反应器及其使用
公开(公告)号：US5186910A
公开(公告)日：1993-02-16
申请号：US582426
申请日：1990-09-12
申请人： Jacques Alagy , Paul Broutin , Christian Busson , Yves Gougne , Jerome Weill
发明人： Jacques Alagy , Paul Broutin , Christian Busson , Yves Gougne , Jerome Weill
IPC分类号： B01F3/02 , B01J4/04 , B01J8/04 , B01J12/00 , B01J19/00 , B01J19/24 , B01J35/04 , C01B3/36 , C01B3/38 , C01B32/40 , C01B32/50
CPC分类号： C01B3/363 , B01J12/005 , B01J19/2415 , B01J4/04 , C01B3/36 , B01J2208/00495 , B01J2219/00162
摘要： An oxidation reactor having elongated shape includes in combination, a mixing member including a pipe for feeding oxidizing gas and a pipe for feeding oxidizable charge; a reaction member, arranged subjacent the mixing member, and a discharge member associated with a discharge pipe for the products of the reaction. The reaction member includes a central zone which has a first lining and the reactor includes at least one peripheral zone which has a second lining, passages in the second lining being smaller than passages in the first lining so that the pressure loss in the second lining is greater than that of the first lining. The second lining forms a sleeve surround the first lining and this sleeve is formed of at least one refractory heat insulating material. The oxidation reactor is provided with an external sleeve steel jacket, a concrete wall and a steel element surrounding the mixing member arranged above the reaction member. The reaction member includes a series of single elements which form juxtaposed channels.
摘要翻译：具有细长形状的氧化反应器组合包括：混合构件，包括用于供给氧化气体的管和用于供给可氧化电荷的管; 布置在混合部件的下方的反应部件和与反应产物的排出管相关联的排出部件。反应构件包括具有第一衬里的中心区，反应器包括具有第二衬里的至少一个周边区，第二衬里中的通道小于第一衬里中的通道，使得第二衬里中的压力损失为大于第一衬里。第二衬里形成围绕第一衬里的套筒，并且该套筒由至少一个难熔绝热材料形成。氧化反应器设置有外部套筒钢护套，混凝土壁和围绕设置在反作用构件上方的混合构件的钢构件。反应构件包括形成并列通道的一系列单一元件。

3. 发明授权

US5160501A Method for thermal conversion of methane and reactor for carrying out the method 失效
标题翻译：甲烷和反应器热转化方法实施方法
公开(公告)号：US5160501A
公开(公告)日：1992-11-03
申请号：US700706
申请日：1991-05-16
申请人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
发明人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
IPC分类号： B01J12/00 , B01J19/24 , C07C2/76
CPC分类号： B01J19/24 , B01J12/005 , C07C2/76 , B01J2219/00135 , Y10S585/911 , Y10S585/913 , Y10S585/924 , Y10S585/926 , Y10S585/943
摘要： Method and apparatus for thermal conversion of methane to hydrocarbons of higher molecular weight, comprising a reactor 1 of elongated shape, connected at a first end to means 5 for supplying gas mixture containing methane (process gas), and connected at the opposite end to discharge means 10, the reactor having a plurality of electric heating means 3 surrounded by sheaths 4 over a first part (towards the first end). The heating means, which are substantially parallel, are arranged in sheets which are substantially parallel and perpendicular to the axis of the reactor, so that spaces or passages for circulation of the process gas and/or effluent are defined between the sheaths and/or between the sheaths and the walls 22 separating two consecutive sheets. The heating means are adapted to heat the passages by successive independent cross sections substantially perpendicular to the axis of the reactor. In a second part 8 (towards the opposite end) adjoining the first part, the reactor further comprises means 9 for cooling the effluent, connected to the means for supplying cooling fluid. The reactor also has means for introducing a gas containing hydrogen into the space surrounding the heating means inside the sheaths 4, at an appropriate pressure. The reactor and particularly the sheaths 4 are designed so that hydrogen is diffused from inside the sheaths to outside them and can then be diluted in the process gas.
摘要翻译：将甲烷热转化成较高分子量的烃的方法和装置，包括细长形状的反应器1，第一端连接到用于提供含有甲烷的气体混合物（工艺气体）的装置5，并在相对端连接以排出装置10，反应器具有在第一部分（朝向第一端）上被护套4包围的多个电加热装置3。基本上平行的加热装置被布置成基本上平行且垂直于反应器的轴线的片材，使得用于循环工艺气体和/或流出物的空间或通道限定在护套之间和/或之间护套和墙壁22分隔两个连续的片材。加热装置适于通过基本上垂直于反应器的轴线的连续的独立横截面来加热通道。在邻接第一部分的第二部分8（朝向相对端），反应器还包括用于冷却流出物的装置9，连接到用于供应冷却流体的装置。该反应器还具有用于在合适的压力下将含氢气体引入护套4内的加热装置周围空间的装置。反应器，特别是护套4被设计成使得氢气从鞘内部扩散到外部，然后可以在工艺气体中稀释。

4. 发明授权

US5270016A Apparatus for the thermal conversion of methane 失效
标题翻译：用于甲烷热转化的装置
公开(公告)号：US5270016A
公开(公告)日：1993-12-14
申请号：US913336
申请日：1992-07-15
申请人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
发明人： Jacques Alagy , Paul Broutin , Christian Busson , Jerome Weill
IPC分类号： B01J12/00 , B01J19/24 , C07C2/76
CPC分类号： C07C2/76 , B01J12/005 , B01J19/24 , B01J2219/00135 , Y10S585/913
摘要： Apparatus suitable for the thermal conversion of methane to hydrocarbons of higher molecular weight, comprising an elongated reactor 1 provided with an inlet 5 for supplying a gas mixture containing methane (process gas) and an outlet at the opposite end, the reactor over a first part towards the inlet end having a plurality of electric heaters 3 surrounded by sheaths 4. The heaters, e.g., electric resistors, which are spaced apart and are substantially parallel with respect to one another, are arranged in substantially parallel rows perpendicular to the axis of the reactor so as to permit circulation of the process gas and/or effluent between the sheaths and/or between the sheaths and walls 22 separating two consecutive rows. The heaters heat the passages by successive independent cross sections substantially perpendicular to the axis of the reaction. Towards the outlet end, the reactor further comprises an injector for supplying cooling fluid, which cools the effluent. The reactor also has a hydrogen inlet for introducing a gas containing hydrogen into the space surrounding the heaters inside the sheaths 4 at an appropriate pressure. The reactor and the sheaths 4 are designed so that hydrogen is diffused from inside the sheaths to outside them and can then be diluted in the process gas.
摘要翻译：适用于将甲烷热转化成较高分子量的烃的装置，包括一个细长的反应器1，该反应器1设有一个入口5，入口5用于提供含有甲烷（工艺气体）的气体混合物和另一端的出口，第一部分朝向入口端具有由护套4围绕的多个电加热器3。间隔开并且相对于彼此大致平行的加热器，例如电阻器，被布置成垂直于反应器，以允许工艺气体和/或流出物在护套之间和/或分离两个连续的行的护套和壁22之间循环。加热器通过基本上垂直于反应轴线的连续的独立横截面来加热通道。朝向出口端，反应器还包括用于供应冷却流体的喷射器，其冷却流出物。反应器还具有氢气入口，用于以适当的压力将含氢的气体引入护套4内的加热器周围的空间。反应器和护套4被设计成使得氢气从鞘内部扩散到外部，然后可以在工艺气体中稀释。

5. 发明授权

US5242574A Use of nickel-based alloys in a process for the thermal cracking of a petroleum charge and reactor for performing the process 失效
标题翻译：镍基合金在石墨炉热裂解工艺中的应用及其应用
公开(公告)号：US5242574A
公开(公告)日：1993-09-07
申请号：US776299
申请日：1991-12-06
申请人： Paul Broutin , Christian Busson , Antoine Montoya , Jerome Weill
发明人： Paul Broutin , Christian Busson , Antoine Montoya , Jerome Weill
IPC分类号： B01J19/24 , C10G9/18 , C10G9/20 , F28D9/00 , F28F19/02 , F28F21/08
CPC分类号： F28F21/087 , B01J19/2485 , C10G9/203 , F28D9/0037 , F28F19/02 , Y10S585/95
摘要： A process and reactor are disclosed for the thermal cracking of a charge containing at least one hydrocarbon with at least one carbon atom, in which the charge is circulated in a metal reaction zone which includes a pyrolysis zone whose external wall is in thermal exchange relationship with a heating liquid. The reaction zone consists of an alloy containing, by weight, 66-82% nickel, 14-18% chromium, and 4-6% aluminum. This alloy, which has already been preoxidized, may be covered, at least in the reaction zone, with at least one layer formed by an oxide of at least one metal and/or at least one metal carbide and/or at least one metal nitride and/or at least one metal silicide. The invention finds application for vapor-phase cracking and dehydrogenation of hydrocarbon charges.
摘要翻译： PCT No.PCT / FR90 / 00392 Sec。 371 1991年12月6日第 102（e）日期1991年12月6日PCT提交1990年6月5日PCT公布。出版物WO90 / 15119 公开了一种用于热分解含有至少一种具有至少一个碳原子的烃的方法和反应器，其中电荷在金属反应区中循环，所述金属反应区包括热解区，其外部壁与加热液体具有热交换关系。反应区由含有重量百分比为66-82％镍，14-18％铬和4-6％铝的合金组成。已经预氧化的该合金可以至少在反应区中被至少一层由至少一种金属和/或至少一种金属碳化物的氧化物形成的层和/或至少一种金属氮化物和/或至少一种金属硅化物。本发明应用于烃电荷的气相裂化和脱氢。

6. 发明授权

US4738769A Process for converting liquid or semi-liquid hydrocarbon charges to lighter fractions 失效
$Process for converting liquid or semi-liquid hydrocarbon charges to lighter fractions$
标题翻译：将液体或半液体碳氢化合物装料转化为较轻馏分的方法
公开(公告)号：US4738769A
公开(公告)日：1988-04-19
申请号：US478428
申请日：1983-03-24
申请人： Christian Busson , Jacques Alagy , Jean-Paul Euzen , Pierre Galtier
发明人： Christian Busson , Jacques Alagy , Jean-Paul Euzen , Pierre Galtier
IPC分类号： B01J8/12 , C10G9/28 , C10G47/24
CPC分类号： B01J8/12 , C10G2400/20
摘要： A process for converting liquid or semi-liquid hydrocarbon charges to lighter fractions comprises a first step (a) heating droplets jets of the charge introduced into a pyrolysis chamber by surrounding them with parallel jets of hot solid particles, of relatively large size, of a heat carrier material, not substantially in contact with the droplet jets, so as to maintain a temperature of 700.degree.-1600.degree. C., and introducing a gas so as to obtain a pressure from 1 to 150 bars. A second step involves (b) separating the gaseous fraction from the solid particles. Thereafter (c) at least a portion of the solid particles are heated and fed back to step (a). The gaseous fraction is (d) cooled by means of a cold gas so as to recover light hydrocarbons therefrom.
摘要翻译：将液体或半液体碳氢化合物装料转化成轻馏分的方法包括第一步骤（a）通过用相当大尺寸的热固体颗粒的平行射流包围引入到热解室中的电荷的液滴射流，热载体材料，基本上不与液滴射流接触，以保持700〜-1600℃的温度，并引入气体以获得1至150巴的压力。第二步涉及（b）从固体颗粒中分离气态馏分。此后（c）将至少一部分固体颗粒加热并反馈到步骤（a）。气态馏分（d）通过冷气体冷却，以从其中回收轻质烃。

7. 发明授权

US4780196A Hydrocarbon steam cracking method 失效
标题翻译：烃蒸汽裂化法
公开(公告)号：US4780196A
公开(公告)日：1988-10-25
申请号：US37353
申请日：1987-04-10
申请人： Jacques Alagy , Christian Busson , Pierre Chaverot
发明人： Jacques Alagy , Christian Busson , Pierre Chaverot
IPC分类号： C10G9/36 , B01J19/24 , C10G9/00 , C10G9/20 , F28F7/02
CPC分类号： C10G9/00 , B01J19/2425 , B01J19/2485 , C10G9/20 , F28F7/02 , B01J2219/00085 , B01J2219/00159
摘要： The invention relates to an improved hydrocarbon steam-cracking method intended to produce more particularly ethylene and propylene.The method is based on the utilization of a multi-channel system made of ceramic material, in which the charge and heat exchange fluids or refrigerants alternatively pass through the channels or rows of channels constituting the continuous assembly comprising a pyrolysis zone followed by a quenching zone.The method according to the invention is applicable to charges ranging from ethane to vacuum gas oils.
摘要翻译： PCT No.PCT / FR86 / 00215 Sec。 371日期：1987年4月10日 102（e）日期1987年4月10日PCT申请1986年6月20日PCT公开号公开号WO87 / 00546 日本1987年1月29日。本发明涉及旨在生产更特别是乙烯和丙烯的改进的烃蒸汽裂解方法。该方法基于利用由陶瓷材料制成的多通道系统，其中充电和热交换流体或制冷剂交替地通过构成连续组件的通道或排的通道，其包括热解区，随后是淬火区。根据本发明的方法适用于从乙烷到减压瓦斯油的电荷。

8. 发明授权

US3935100A Process for the treatment of waste waters containing sulfuric acid and/or ammonium sulfate 失效
标题翻译：处理含硫酸和/或硫酸铵废水的方法
公开(公告)号：US3935100A
公开(公告)日：1976-01-27
申请号：US484228
申请日：1974-06-28
申请人： Jacques Alagy , Christian Busson , Maurice Cessou
发明人： Jacques Alagy , Christian Busson , Maurice Cessou
IPC分类号： C01B17/16 , C01B17/58 , C02F1/52 , C02F1/58 , C02F1/66 , C02B1/34 , C02C5/06
CPC分类号： C02F1/66 , C01B17/58 , C02F1/5236 , C02F1/586
摘要： Process for treating a waste water containing sulfuric acid and/or ammonium sulfate comprising (1) reacting said water with barium sulfide to form barium sulfate, (2) reacting the latter with carbon containing inorganic impurities, at high temperature, thereby forming barium sulfide, at least a major portion of which is recycled to step (1), and a gas which is separated, (3) dissolving in water a minor portion of the barium sulfide produced in step (2), separating the insoluble impurities therefrom and recycling at least one portion of the resulting purified solution to step (1).
摘要翻译：包括（1）使所述水与硫化钡反应形成硫酸钡，（2）使其与含碳的无机杂质在高温下反应，从而形成硫化钡，其至少大部分被再循环到步骤（1），和分离的气体，（3）将在步骤（2）中生产的少量硫化钡溶解在水中，将不溶性杂质从其中分离出来，并在将所得纯化溶液的至少一部分至步骤（1）。

9. 发明授权

US5235117A Process for the preparation of boric oxide by hydrolysis of methyl borate and its use in the oxidation of alcohol-saturated hydrocarbons 失效
标题翻译：通过氢化甲基硼酸盐制备氧化硼的方法及其在醇饱和烃的氧化中的应用
公开(公告)号：US5235117A
公开(公告)日：1993-08-10
申请号：US765276
申请日：1991-09-25
申请人： Jacques Alagy , Christian Busson , Lionel Asselineau
发明人： Jacques Alagy , Christian Busson , Lionel Asselineau
IPC分类号： C01B35/10 , C07B61/00 , C07C29/52 , C07C31/04 , C07C31/135
CPC分类号： C07C29/52 , C01B35/1036 , C01B35/1045 , C07C2101/14
摘要： For preparing at least one boric oxide in an anhydrous or hydrated form and of general formula B.sub.2 O.sub.3, xH.sub.2 O, in which x is a number from 0 to 3, a methyl borate hydrolyzate comprising boric oxide and methanol is introduced into a distillation column is introduced the product from, at least one compound (preferably a hydrocarbon such as, e.g., 2,3-dimethyl butane or 2-methyl pentane) forming a heteroazeotrope with methanol, said heteroazaeotrope having a boiling point below that of the azeotrope formed by methyl borate with methanol and at least one compound having a boiling point higher than that of methyl borate, said compound not forming an azeotrope with a boiling point below that of said heteroazeotrope and then at the head of the column said heteroazeotrope is recovered and at the bottom of the column a suspension containing at least one boric oxide.A description is also given of a process for the oxidation of at least one saturated hydrocarbon into a product incorporating the corresponding alcohol wherein oxidation is carried out with oxygen in the presence of a boric oxide with. The oxidation product is hydrolyzed into orthoboric acid and alcohol, which is recovered by separation from the organic phase. The aqueous phase containing the boric acid is fed into a methyl borate formation zone and the methyl borate is recovered in the form of its azeotrope with methanol. The recovery of the boric oxide from said azeotrope is performed in accordance with the aforementioned process, the recovered boric oxide being recycled to the oxidation stage.
摘要翻译：为了制备至少一种无水或水合形式的氧化硼和通式B 2 O 3，xH 2 O，其中x为0至3的数，将包含氧化硼和甲醇的硼酸甲酯水解产物引入蒸馏塔与来自与甲醇形成杂共聚物的至少一种化合物（优选例如2,3-二甲基丁烷或2-甲基戊烷的烃）形成的产物，所述杂氮杂异动物的沸点低于由硼酸甲酯形成的共沸物的沸点，甲醇和沸点高于硼酸甲酯的沸点的至少一种化合物，所述化合物不形成沸点低于所述杂共生物的沸点的共沸物，然后在塔的头部回收所述杂共生物，并在其底部柱中含有至少一种氧化硼的悬浮液。还描述了将至少一种饱和烃氧化成掺入相应的醇的产物的方法，其中氧化在氧化硼存在下用氧气进行氧化。将氧化产物水解成原硼酸和醇，通过与有机相分离回收。将含有硼酸的水相加入到硼酸甲酯形成区中，以与甲醇共沸的形式回收硼酸甲酯。根据上述方法从所述共沸物中回收氧化硼，回收的氧化硼被循环到氧化阶段。

10. 发明授权

US4926001A Method for the thermal conversion of methane to hydrocarbons of higher molecular weights 失效
标题翻译：将甲烷热分解成较高分子量烃的方法
公开(公告)号：US4926001A
公开(公告)日：1990-05-15
申请号：US927980
申请日：1986-11-07
申请人： Jacques Alagy , Christian Busson
发明人： Jacques Alagy , Christian Busson
IPC分类号： B01J19/24 , C07C2/76
CPC分类号： C07C2/76 , B01J19/2425 , B01J19/2485 , B01J2219/00085 , B01J2219/00135 , B01J2219/00159 , B01J2219/0263 , B01J2219/2453 , B01J2219/2464 , B01J2219/2467 , B01J2219/2487 , B01J2219/2498 , Y10S585/943
摘要： The invention concerns an improved method for the thermal conversion of methane to hydrocarbons of higher molecular weights.The method is based on the utilization of a multichannel system of ceramic material in which the charge and heating fluids or cooling fluids pass alternately through rows of channels, constituting a continuous assembly comprising a pyrolysis zone followed by a quenching zone.
摘要翻译：本发明涉及一种用于将甲烷热分解成较高分子量的烃的改进方法。该方法基于利用陶瓷材料的多通道系统，其中充电和加热流体或冷却流体交替地通过行通道，构成包括热解区域和淬火区域的连续组件。

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