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1. 发明授权

US4889870A 2-(2,2-Difluorocyclopropyl)alkyl esters, processes for their preparation and their use as insecticides and acaricides 失效
标题翻译： 2-（2,2-二氟环丙基）烷基酯，其制备方法及其作为杀虫剂和杀螨剂的用途
公开(公告)号：US4889870A
公开(公告)日：1989-12-26
申请号：US149732
申请日：1988-01-29
申请人： Peter Wegner , Hans-Rudolf Kruger , Dietrich Baumert , Hartmut Joppien
发明人： Peter Wegner , Hans-Rudolf Kruger , Dietrich Baumert , Hartmut Joppien
IPC分类号： A01N37/00 , A01N37/10 , A01N37/34 , A01N37/38 , A01N37/40 , A01N37/44 , A01N37/48 , A01N37/52 , A01N43/08 , A01N43/10 , A01N43/12 , A01N43/36 , A01N43/38 , A01N43/60 , A01P7/02 , A61K31/215 , C07C67/00 , C07C67/08 , C07C69/02 , C07C69/52 , C07C69/612 , C07C69/614 , C07C69/734 , C07C69/76 , C07C69/78 , C07C69/92 , C07C201/00 , C07C205/56 , C07C205/57 , C07C205/58 , C07C229/42 , C07C229/52 , C07C253/00 , C07C255/16 , C07C301/00 , C07C303/30 , C07C309/65 , C07C309/73 , C07C313/00 , C07C323/62 , C07D207/337 , C07D207/34 , C07D207/40 , C07D207/416 , C07D209/42 , C07D213/79 , C07D213/80 , C07D241/24 , C07D307/68 , C07D307/71 , C07D317/68 , C07D333/38 , C07D333/62 , C07D333/70
CPC分类号： C07D207/416 , A01N37/10 , A01N37/34 , A01N37/38 , A01N37/40 , A01N37/44 , A01N37/48 , A01N37/52 , A01N43/08 , A01N43/10 , A01N43/12 , A01N43/36 , A01N43/38 , A01N43/60 , C07C205/57 , C07C205/58 , C07C309/00 , C07C323/00 , C07D209/42 , C07D213/79 , C07D213/80 , C07D241/24 , C07D307/68 , C07D307/71 , C07D333/38 , C07D333/62
摘要： There are provided new 2-(2,2-difluorocyclopropyl)alkyl esters of general formula I ##STR1## in which Y, R.sub.1-7 and n have the meanings given in the description and processes for their preparation. The new compounds can be used to combat insects and mites.

2. 发明授权

US4791123A Insecticidal triffluormethyl alkane derivatives 失效
标题翻译：杀虫三氟甲烷烷衍生物
公开(公告)号：US4791123A
公开(公告)日：1988-12-13
申请号：US006565
申请日：1987-01-22
申请人： Helga Franke , Heinrich Franke , Hans-Rudolf Kruger , Hartmut Joppien , Dietrich Baumert , David Giles
发明人： Helga Franke , Heinrich Franke , Hans-Rudolf Kruger , Hartmut Joppien , Dietrich Baumert , David Giles
IPC分类号： C07D317/52 , A01N29/02 , A01N29/10 , A01N31/04 , A01N31/14 , A01N31/16 , A01N33/06 , A01N33/10 , A01N33/18 , A01N33/20 , A01N33/22 , A01N37/22 , A01N37/34 , A01N41/04 , A01N43/30 , A01N43/40 , A01N47/02 , A01P7/04 , C07C17/00 , C07C17/26 , C07C19/08 , C07C21/02 , C07C21/17 , C07C21/22 , C07C22/08 , C07C25/13 , C07C25/18 , C07C25/24 , C07C41/00 , C07C43/225 , C07C43/29 , C07C45/44 , C07C67/00 , C07C201/00 , C07C205/11 , C07C209/00 , C07C253/00 , C07C255/37 , C07C255/54 , C07C301/00 , C07C303/30 , C07C309/63 , C07C313/00 , C07C323/03 , C07C323/05 , C07C323/07 , C07C323/12 , C07C323/60 , C07D213/64
CPC分类号： C07C43/29 , A01N29/10 , A01N31/14 , A01N31/16 , A01N33/06 , A01N33/10 , A01N43/30 , A01N43/40 , A01N47/02 , C07C25/18 , C07C309/00 , C07C43/225 , C07C45/44 , Y10S424/08
摘要： There are provided new alkane and alkoxyalkane derivatives of the general formula I ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4 and A have the meanings given in the description, processes for their preparation and insecticidal and acaricidal compositions containing these compounds.
摘要翻译：提供了通式I（I）的新的烷烃和烷氧基烷烃衍生物，其中R1，R2，R3，R4和A具有说明书中给出的含义，其制备方法和含有这些化合物的杀虫和杀螨组合物。

3. 再颁专利

USRE37087E1 Insecticidal triffluormethyl alkane derivatives 失效
标题翻译：杀虫三氟甲烷烷衍生物
公开(公告)号：USRE37087E1
公开(公告)日：2001-03-06
申请号：US07720091
申请日：1991-06-20
申请人： Helga Franke , Heinrich Franke , Hans-Rudolf Kruger , Hartmut Joppien , Dietrich Baumert , David Giles
发明人： Helga Franke , Heinrich Franke , Hans-Rudolf Kruger , Hartmut Joppien , Dietrich Baumert , David Giles
IPC分类号： A01N4340
CPC分类号： C07C43/29 , A01N29/10 , A01N31/14 , A01N31/16 , A01N33/06 , A01N33/10 , A01N43/30 , A01N43/40 , A01N47/02 , C07C25/18 , C07C43/225 , C07C45/44 , C07C309/00 , Y10S424/08 , C07C47/277
摘要： There are provided new alkane and alkoxyalkane derivatives of the general formula I in which R1, R2, R3, R4 and A have the meanings given in the description, processes for their preparation and insecticidal and acaricidal compositions containing these compounds.
摘要翻译：提供了通式Iin的新的烷烃和烷氧基烷烃衍生物，其中R1，R2，R3，R4和A具有说明书中给出的含义，其制备方法和含有这些化合物的杀虫和杀螨组合物。

4. 发明授权

US4233059A 1,2,3-Triazole carboxylic acid amides and biocidal compositions containing the same 失效
标题翻译： 1,2,3-三唑羧酸酰胺和含有它们的杀生物组合物
公开(公告)号：US4233059A
公开(公告)日：1980-11-11
申请号：US062795
申请日：1979-08-01
申请人： Hans-Rudolf Kruger , Friedrich Arndt , Dietrich Baumert , Hartmut Joppien , Ernst A. Pieroh , Reinhart Rusch
发明人： Hans-Rudolf Kruger , Friedrich Arndt , Dietrich Baumert , Hartmut Joppien , Ernst A. Pieroh , Reinhart Rusch
IPC分类号： A01N43/647 , A01N43/653 , A01N47/38 , A01P5/00 , A01P7/04 , A01P13/00 , A01P15/00 , C07D249/04 , A01N9/12 , A01N9/14
CPC分类号： C07D249/04 , A01N47/38
摘要： 1,2,3-Triazole carboxylic acid amides, of the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4 and n have the meaning defined in the specification in connection with formula I. The compounds have a broad biocidal, particularly herbicidal, insecticidal, acaricidal, fungicidal and nematocidal activity. They have a high degree of selectivity towards agriculturally valuable plants.
摘要翻译：其中R 1，R 2，R 3，R 4和n具有在说明书中结合式I定义的含义的式“IMAGE”的1,2,3-三唑羧酸酰胺。该化合物具有广泛的杀生物，特别是除草杀虫，杀螨，杀真菌和杀线虫活性。他们对农业有价值的植物具有很高的选择性。

5. 发明授权

US4314839A 1,2,3-Thiadiazole-5-carboxylic acid amide derivatives, process for making the same and herbicidal growth regulating defoliating and fungicidal compositions containing same 失效
标题翻译： 1,2,3-噻二唑-5-羧酸酰胺衍生物，其制备方法和除草生长调节脱叶剂和含有它们的杀真菌组合物
公开(公告)号：US4314839A
公开(公告)日：1982-02-09
申请号：US131354
申请日：1980-03-18
申请人： Hans-Rudolf Kruger , Friedrich Arndt , Dietrich Baumert , Reinhart Rusch
发明人： Hans-Rudolf Kruger , Friedrich Arndt , Dietrich Baumert , Reinhart Rusch
IPC分类号： A01N43/82 , A01N43/828 , A01N47/12 , A01N47/22 , A01N47/34 , A01N53/00 , C07D285/06
CPC分类号： A01N47/22 , A01N43/82 , A01N47/12 , A01N47/34 , A01N53/00 , C07D285/06
摘要： 1,2,3-Thiadiazole-5-carboxylic acid amide derivatives of the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 have the meaning indicated in the specification. Preferably, R.sub.1 is methyl and R.sub.2 is acetyl, chloroacetyl, propionyl, valeryl, cinnamoyl, cyclohexylcarbonyl, dichlorophenoxyacetyl, benzoyl, halobenzoyl, dichlorobenzoyl or methylbenzoyl, and R.sub.3 is benzyl, halobenzyl, cyclohexyl, methyl-cyclohexyl or cyclohexylmethyl. The compounds have herbicidal, growth regulating, defoliating and fungicidal activity, although not all of these activities will be present in each of the compounds. The compounds are in addition highly selective against agriculturally valuable plants such as various grains, cotton, soybeans and plantation cultures.
摘要翻译：其中R 1，R 2和R 3具有说明书中指出的含义的式“IMAGE”的1,2,3-噻二唑-5-羧酸酰胺衍生物。优选地，R1是甲基，R2是乙酰基，氯乙酰基，丙酰基，戊酰基，肉桂酰基，环己基羰基，二氯苯氧基乙酰基，苯甲酰基，卤代苯甲酰基，二氯苯甲酰基或甲基苯甲酰基，R3是苄基，卤代苄基，环己基，甲基 - 环己基或环己基甲基。这些化合物具有除草，生长调节，脱叶和杀真菌活性，尽管这些活性并不全部存在于每种化合物中。该化合物对农业有价值的植物如各种谷物，棉花，大豆和种植园培养物具有高选择性。

6. 发明授权

US4341551A 1,2,3,-Thiadiazole-5-carboxylic acid derivatives 失效
标题翻译： 1,2,3 - 噻二唑-5-羧酸衍生物
公开(公告)号：US4341551A
公开(公告)日：1982-07-27
申请号：US127496
申请日：1980-03-05
申请人： Hans-Rudolf Kruger , Friedrich Arndt , Dietrich Baumert , Reinhart Rusch
发明人： Hans-Rudolf Kruger , Friedrich Arndt , Dietrich Baumert , Reinhart Rusch
IPC分类号： A01N43/82 , A01N43/828 , C07D285/06 , C07D417/06
CPC分类号： A01N43/82 , C07D285/06
摘要： A process for producing compounds of 1,2,3-thiadiazole-5-carboxylic acid is described. These compounds are effective as herbicides, fungicides and plant growth controllers.
摘要翻译：描述了制备1,2,3-噻二唑-5-羧酸化合物的方法。这些化合物作为除草剂，杀真菌剂和植物生长控制剂是有效的。

7. 发明授权

US5066675A Substituted phenyl acid esters, their preparation and their use as insecticides and acaricides 失效
标题翻译：取代的苯甲酸酯，其制备及其作为杀虫剂和杀虫剂的用途
公开(公告)号：US5066675A
公开(公告)日：1991-11-19
申请号：US575674
申请日：1990-08-31
申请人： Ulrich Buhmann , Hartmut Joppien , Dietrich Baumert
发明人： Ulrich Buhmann , Hartmut Joppien , Dietrich Baumert
IPC分类号： C07C69/612 , A01N37/10 , A01N37/34 , A01N37/38 , A01N37/44 , A01N37/48 , A01N41/02 , A01N41/04 , A01N47/02 , A01P7/04 , C07C67/00 , C07C67/08 , C07C67/14 , C07C69/618 , C07C69/635 , C07C69/65 , C07C69/708 , C07C69/734 , C07C227/00 , C07C227/02 , C07C227/18 , C07C229/12 , C07C229/34 , C07C253/00 , C07C255/57 , C07C301/00 , C07C309/63 , C07C313/00 , C07C315/04 , C07C317/44 , C07C317/46 , C07C323/12 , C07C323/52
CPC分类号： C07C309/00 , A01N37/10 , A01N37/38 , A01N41/04 , A01N47/02 , C07C69/612 , C07C69/65 , C07C69/732 , C07C69/734 , C07C69/736 , C07C2101/02
摘要： There are described new phenylacetic acid derivatives of general formula I ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 have the meanings given in the description, processes for their preparation and insecticidal and acaricidal compositions containing these compounds.

8. 发明授权

US4594095A Biocidal azolyl-propane nitriles 失效
标题翻译：杀生物唑类 - 丙烷腈
公开(公告)号：US4594095A
公开(公告)日：1986-06-10
申请号：US640156
申请日：1984-08-10
申请人： Carlo Skotsch , Dietrich Baumert , Hansjorg Krahmer
发明人： Carlo Skotsch , Dietrich Baumert , Hansjorg Krahmer
IPC分类号： A01N43/50 , A01N43/653 , C07D233/60 , C07D233/61 , C07D249/08 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： Azolyl-propanenitriles are disclosed, of the formula ##STR1## in which R is an aromatic hydrocarbon or an aromatic hydrocarbon substituted one or more times, the same or differently by halogen, (C.sub.1 -C.sub.4)-alkyl, (C.sub.1 -C.sub.4)-alkoxy, trifluoromethyl, cyano or nitro, R.sub.1 is C.sub.3 -C.sub.8 cycloalkyl or C.sub.3 -C.sub.8 cycloalkyl substituted by C.sub.1 -C.sub.3 alkyl andY is N or CH,and its acid addition salt with an inorganic or an organic acid, as well as processes for the production of these compounds and biocidal compositions containing the same. The compounds display fungicidal activity, growth-regulatory activity, and bactericidal activity.
摘要翻译：公开了具有下式的其中R是芳族烃或芳烃的一次或多次，卤素，（C 1 -C 4） - 烷基，（C 1 -C 4）烷基，C 1 -C 4烷基， - 烷氧基，三氟甲基，氰基或硝基，R 1是C 3 -C 8环烷基或被C 1 -C 3烷基取代的C 3 -C 8环烷基，Y是N或CH，并且其与无机或有机酸的酸加成盐以及用于生产这些化合物和含有它们的杀生物组合物。该化合物显示出杀真菌活性，生长调节活性和杀菌活性。

9. 发明授权

US4517367A Azolyl-pentene derivatives and biocidal compositions containing the same 失效
标题翻译：唑基 - 戊烯衍生物和含有它们的杀生物组合物
公开(公告)号：US4517367A
公开(公告)日：1985-05-14
申请号：US447624
申请日：1982-12-06
申请人： Carlo Skotsch , Dietrich Baumert , Hansjorg Krahmer , Friedrich Arndt
发明人： Carlo Skotsch , Dietrich Baumert , Hansjorg Krahmer , Friedrich Arndt
IPC分类号： A01N43/50 , A01N43/653 , C07D233/60 , C07D249/08 , C07D333/00 , C07D401/06 , C07D405/06 , C07D409/06 , C07D521/00 , A01N43/64
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08
摘要： Azolyl-pentene derivatives of the general formula ##STR1## in which R is C.sub.1 -C.sub.10 -alkyl or C.sub.3 -C.sub.8 -alkenyl,R.sub.1 is imidazol-1-yl or 1,2,4-triazol-1-yl,R.sub.2 is aromatic hydrocarbon, aromatic hydrocarbon substituted one or more times, the same or differently, by halogen, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkylthio, trifluoromethyl or nitro, or a heterocyclic hydrocarbon, andZ is ##STR2## and their acid addition salts with inorganic and organic acids. Also disclosed are processes for the production of these compounds as well as biocidal compositions containing the same.
摘要翻译：其中R是C 1 -C 10 - 烷基或C 3 -C 8 - 链烯基，R 1是咪唑-1-基或1,2,4-三唑-1-基的通式为：其中R 2是被卤素，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷基，C 1 -C 4 - 烷硫基，三氟甲基或硝基或杂环烃取代一次或多次的芳烃，芳烃，相同或不同， IMAGE>及其与无机酸和有机酸的酸加成盐。还公开了用于生产这些化合物的方法以及含有它们的杀生物组合物。

10. 发明授权

US4281121A 1,3,4-Thiadiazole-2-carboxylic acid derivatives, process for making the same and fungicidal and nematocidal compositions containing same 失效
标题翻译： 1,3,4-噻二唑-2-羧酸衍生物，其制备方法和含有相同的杀真菌剂和杀线虫剂的组合物
公开(公告)号：US4281121A
公开(公告)日：1981-07-28
申请号：US101061
申请日：1979-12-06
申请人： Ludwig Nusslein , Dietrich Baumert , Ernst A. Pieroh
发明人： Ludwig Nusslein , Dietrich Baumert , Ernst A. Pieroh
IPC分类号： A01N43/82 , A01N43/824 , C07D285/12 , C07D285/125 , C07D417/06
CPC分类号： C07D285/125 , A01N43/82 , Y10S514/949
摘要： 1,3,4-thiadiazole-2-carboxylic acid derivatives of the formula ##STR1## wherein R is C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkinyl or C.sub.3 -C.sub.6 -cycloalkyl,R.sub.1 is C.sub.1 -C.sub.6 -alkoxycarbonyl, aminocarbonyl, C.sub.1 -C.sub.8 -alkylaminocarbonyl, C.sub.3 -C.sub.6 -cycloalkylaminocarbonyl, di-C.sub.1 -C.sub.8 alkylaminocarbonyl, cyclohexylmethylaminocarbonyl, alkoxyalkylaminocarbonyl, morpholinocarbonyl, pyrrolidinocarbonyl, piperidinocarbonyl or cyano,and n is 0.1 or 2.The compounds wherein n is 1 or 2 have both a high fungicidal and nematocidal activity. The compounds in which n is 0 are the starting products or intermediate products in making the compound in which a sulfonyl or sulfinyl group is present (n=1 or 2) but have also nematocidal properties of their own. All compounds of the invention avoid the undesirable environmental properties and other shortcomings of the prior art products, particularly those of the broadly used mercury compounds.
摘要翻译：式I的1,3,4-噻二唑-2-羧酸衍生物其中R是C 1 -C 6 - 烷基，C 2 -C 6 - 烯基，C 2 -C 6 - 炔基或C 3 -C 6环烷基，R 1是C 1 C 1-6 - 烷氧基羰基，氨基羰基，C 1 -C 8 - 烷基氨基羰基，C 3 -C 6 - 环烷基氨基羰基，二-C 1 -C 8烷基氨基羰基，环己基甲基氨基羰基，烷氧基烷基氨基羰基，吗啉代羰基，吡咯烷基羰基，哌啶子基羰基或氰基，n为0.1或2.其中n为 1或2具有高杀菌和杀线虫活性。其中n为0的化合物是制备其中存在磺酰基或亚磺酰基的化合物（n = 1或2）的起始产物或中间产物，但也具有自己的杀线虫性质。本发明的所有化合物避免了现有技术产品，特别是广泛使用的汞化合物的不良环境特性和其它缺点。

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