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    • 9. 发明授权
    • Method of converting amine hydrohalide into free amine
    • 将胺氢卤化物转化为游离胺的方法
    • US5906722A
    • 1999-05-25
    • US914603
    • 1997-08-18
    • Peter C. FollerDavid G. RobertsRobert H. Tang
    • Peter C. FollerDavid G. RobertsRobert H. Tang
    • B01D61/44C02F1/469C25B3/00C25B9/08C25B7/00C25B1/00C25B9/00
    • C25B9/08C25B3/00
    • Describes a method of electrochemically converting amine hydrohalide, e.g., ethyleneamine hydrochloride, into free amine, e.g., free ethyleneamine. A three compartment electrolytic cell is provided having (1) a catholyte compartment containing a cathode assembly comprising a cathode and an anion exchange membrane, (2) an anode compartment containing an anode assembly comprising either (a) a hydrogen consuming gas diffusion anode and a current collecting electrode or (b) a hydrogen consuming gas diffusion anode which is fixedly held between a hydraulic barrier and a current collecting electrode, and (3) an intermediate compartment separated from the catholyte and anode compartments by the anion exchange membrane and either (i) the hydrogen consuming gas diffusion anode or (ii) the hydraulic barrier respectively. An aqueous solution of amine hydrohalide is charged to the catholyte compartment, while hydrogen gas is charged to the anode compartment and an aqueous conductive electrolyte solution is charged to the intermediate compartment. Direct current is passed through the electrolytic cell and an aqueous solution comprising free amine is removed from the catholyte compartment.
    • 描述了将胺氢卤化物(例如乙烯胺盐酸盐)电化学转化成游离胺,例如游离亚乙基胺的方法。 提供一种三室电解池,其具有:(1)阴极电解室,其包含阴极组件,阴极组件包括阴极和阴离子交换膜;(2)阳极室,其包含阳极组件,阳极组件包括(a)消耗氢的气体扩散阳极和 电流收集电极或(b)固定保持在液压屏障和集电电极之间的消耗氢的气体扩散阳极,以及(3)通过阴离子交换膜与阴极电解液和阳极隔室分离的中间室和(i )氢消耗气体扩散阳极或(ii)液压屏障。 将胺氢卤化物的水溶液加入到阴极电解液室中,同时将氢气加入到阳极室中,并将水性导电电解质溶液装入中间室。 直流电流通过电解槽,并从阴极电解液隔室除去包含游离胺的水溶液。
    • 10. 发明授权
    • Method of electrochemically producing epoxides
    • 电化学生产环氧化物的方法
    • US5997716A
    • 1999-12-07
    • US112660
    • 1998-07-09
    • David G. RobertsPeter C. FollerRobert H. TangYingchao Zhang
    • David G. RobertsPeter C. FollerRobert H. TangYingchao Zhang
    • C25B3/00
    • C25B3/00
    • Described is a method of electrochemically converting .alpha.-halohydrins, e.g., 1-chloro-2-hydroxypropane and 1,3-dichloro-2-hydroxypropane, to epoxides, e.g., propylene oxide and epichlorohydrin. A three compartment electrolytic cell is provided having (1) a catholyte compartment containing a cathode assembly comprising a cathode and an anion exchange membrane, (2) an anode compartment containing an anode assembly comprising either (a) a hydrogen consuming gas diffusion anode and a current collecting electrode or (b) a hydrogen consuming gas diffusion anode which is fixedly held between a hydraulic barrier and a current collecting electrode, and (3) an intermediate compartment separated from the catholyte and anode compartments by the anion exchange membrane and either (i) the hydrogen consuming gas diffusion anode or (ii) the hydraulic barrier respectively. An aqueous solution of .alpha.-halohydrin is charged to the catholyte compartment, while hydrogen gas is charged to the anode compartment and an aqueous electrolyte solution is charged to the intermediate compartment. Direct current is passed through the electrolytic cell and an aqueous solution comprising epoxide is removed from the catholyte compartment.
    • 描述了将α-卤代醇如1-氯-2-羟基丙烷和1,3-二氯-2-羟基丙烷电化学转化为环氧化物,例如环氧丙烷和表氯醇的方法。 提供一种三室电解池,其具有:(1)阴极电解室,其包含阴极组件,阴极组件包括阴极和阴离子交换膜;(2)阳极室,其包含阳极组件,阳极组件包括(a)消耗氢的气体扩散阳极和 电流收集电极或(b)固定保持在液压屏障和集电电极之间的消耗氢的气体扩散阳极,以及(3)通过阴离子交换膜与阴极电解液和阳极隔室分离的中间室和(i )氢消耗气体扩散阳极或(ii)液压屏障。 将α-卤代醇的水溶液加入到阴极电解液室中,同时将氢气加入到阳极室中,并将电解质水溶液装入中间室。 直流电流通过电解槽,从阴极电解液隔室除去包含环氧化物的水溶液。