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    • 1. 发明授权
    • Diketopyrrolopyrroles
    • 二酮吡咯并吡咯
    • US5342955A
    • 1994-08-30
    • US991676
    • 1992-12-16
    • Gary WoodenGuy de WeckOlof Wallquist
    • Gary WoodenGuy de WeckOlof Wallquist
    • C07D487/04C08K5/3412C08K5/3415C08K5/3432C08K5/3435C08K5/3442C08K5/3445C08K5/357C08K5/45C09B57/00C09B67/22C07D403/14C09B7/00
    • C07D487/04C08K5/3415C09B57/004C09B67/0039
    • 1,4-Diketopyrrolo[3,4-c]pyrroles of formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently of one another hydrogen, Cl, Br, CH.sub.3, OCH.sub.3, CN or phenyl, and at least one of the substituents R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is a group--O(CH.sub.2).sub.n X or --O(CH.sub.2 CH.sub.2 O).sub.p CH.sub.2 CH.sub.2 Xwhereinn is an integer from 2 to 12, andp is an integer from 1 to 3,X is a heterocyclic radical selected form the group consisting imidazolyl, pyrazolyl, triazolyl, piperazinyl, pyridinyl, pyrrolyl, thiazolyl, oxazolyl, benzoxazolyl, indolyl, benzthiazolyl, benzimidazolyl, benzotriazolyl, morpholinyl, piperidinyl and pyrrolidinyl, which radical is unsubstituted or substituted by one or two methyl groups, or is a group --NR.sub.5 R.sub.6 or --N[(CH.sub.2).sub.n -NR.sub.5 R.sub.6 ].sub.2, whereinR.sub.5 and R.sub.6 are each independently of the other hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.5 -C.sub.6 cycloalkyl.Pigment compositions comprising a minor amount of said compounds and diketopyrrolopyrrole pigments have excellent rheological and colouristic properties, especially in paint systems and in printing inks.
    • 式(Ⅰ)的1,4-二酮吡咯并[3,4-c]吡咯其中R 1,R 2,R 3和R 4各自独立地为氢,Cl,Br,CH 3,OCH 3,CN或苯基,和 取代基R 1,R 2,R 3和R 4中的至少一个是基团-O(CH 2)n X或-O(CH 2 CH 2 O)p CH 2 CH 2 X,其中n是2至12的整数,p是1至3的整数,X 是选自咪唑基,吡唑基,三唑基,哌嗪基,吡啶基,吡咯基,噻唑基,恶唑基,苯并恶唑基,吲哚基,苯并噻唑基,苯并咪唑基,苯并三唑基,吗啉基,哌啶基和吡咯烷基的基团的杂环基,该基团是未取代的或被一个或多个 或者是-NR5R6或-N [(CH2)n-NR5R6] 2基团,其中R5和R6各自独立地为氢,C1-C6烷基或C5-C6环烷基。 包含少量所述化合物和二酮吡咯并吡咯颜料的颜料组合物具有优异的流变学和颜色特性,特别是在涂料体系和印刷油墨中。
    • 4. 发明授权
    • Diketopyrrolopyrroles
    • 吡咯烷酮
    • US5200528A
    • 1993-04-06
    • US870986
    • 1992-04-20
    • Gary WoodenGuy de WeckOlof Wallquist
    • Gary WoodenGuy de WeckOlof Wallquist
    • C07D487/04C08K5/3412C08K5/3415C08K5/3432C08K5/3435C08K5/3442C08K5/3445C08K5/357C08K5/45C09B57/00C09B67/22
    • C07D487/04C08K5/3415C09B57/004C09B67/0039
    • 1,4-Diketopyrrolo[3,4-c]pyrroles of formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently of one another hydrogen, Cl, Br, CH.sub.3, OCH.sub.3, CN or phenyl, and at least one of the substituents, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is a group--O(CH.sub.2).sub.n X or --O(CH.sub.2 CH.sub.2 O).sub.p CH.sub.2 CH.sub.2 Xwhereinn is an integer from 2 to 12, andp is an integer from 1 to 3,X is a heterocyclic radical selected from the group consisting of imidazolyl, pyrazolyl, triazolyl, piperazinyl, pyridinyl, pyrrolyl, thiazolyl, oxazolyl, benzoxazolyl, indolyl, benzthiazolyl, benzimidazolyl, benzotriazolyl, morpholinyl, piperidinyl and pyrrolidinyl, which radical is unsubstituted or substituted by one or two methyl groups, or is a group--NR.sub.5 R.sub.6or--N[(CH.sub.2).sub.n --NR.sub.5 R.sub.6 ].sub.2, whereinR.sub.5 and R.sub.6 are each independently of the other hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.5 -C.sub.6 cycloalkyl.Pigment compositions comprising a minor amount of said compounds and diketopyrrolopyrrole pigments have excellent rheological and coloristic properties, especially in paint systems and in printing inks.
    • 式(Ⅰ)的1,4-二酮吡咯并[3,4-c]吡咯其中R 1,R 2,R 3和R 4各自独立地为氢,Cl,Br,CH 3,OCH 3,CN或苯基,和 取代基R 1,R 2,R 3和R 4中的至少一个是基团-O(CH 2)n X或-O(CH 2 CH 2 O)pCH 2 CH 2 X,其中n是2至12的整数,p是1至3的整数, X是选自咪唑基,吡唑基,三唑基,哌嗪基,吡啶基,吡咯基,噻唑基,恶唑基,苯并恶唑基,吲哚基,苯并噻唑基,苯并咪唑基,苯并三唑基,吗啉基,哌啶基和吡咯烷基的杂环基。 一个或两个甲基,或者是-NR 5 R 6或-N [(CH 2)n -NR 5 R 6] 2,其中R 5和R 6各自独立地为氢,C 1 -C 6烷基或C 5 -C 6环烷基。 包含少量所述化合物和二酮吡咯并吡咯颜料的颜料组合物具有优异的流变学和着色性能,特别是在涂料体系和印刷油墨中。
    • 5. 发明授权
    • Pigment compositions
    • 颜料组成
    • US5271759A
    • 1993-12-21
    • US877680
    • 1992-05-01
    • Gary WoodenOlof Wallquist
    • Gary WoodenOlof Wallquist
    • C08L23/02C08L23/00C09B67/20C09B67/22C09D11/02D06P3/79C09B67/10
    • C09B67/0034C09B67/0063
    • Pigment compositions comprisinga) at least one organic pigment,b) 0.05 to 10% by weight, based on the organic pigment a), of at least one modified organic pigment of formula ##STR1## wherein A is the radical of an organic pigment, X is H, Na or K and m is an integer from 0.05 to 3, andc) 0.05 to 10% by weight, based on the organic pigment a), of at least one polymeric ammonium salt having an average molecular weight from 500 to 2 500 000 and which is soluble in water or a lower alkanol.These pigment compositions have excellent suitability for the wrap-free pigmenting of polyolefins and, when incorporated in paint systems and printing inks, exhibit excellent rheology.
    • 颜料组合物,其包含a)至少一种有机颜料,b)基于有机颜料a)0.05至10重量%的至少一种式A的改性有机颜料(SO 3 X)m,(I)其中A是 有机颜料的自由基,X是H,Na或K,m是0.05至3的整数,c)基于有机颜料a)的0.05至10重量%的至少一种聚合铵盐,其具有 平均分子量为500至25000,可溶于水或低级链烷醇。 这些颜料组合物对于聚烯烃的无包覆着色具有优异的适用性,并且当结合到涂料体系和印刷油墨中时,显示出优异的流变性。
    • 7. 发明授权
    • Pigment compositions of diketopyrrolopyrroles
    • 二酮吡咯并吡咯的颜料组成
    • US5738719A
    • 1998-04-14
    • US799969
    • 1997-02-14
    • Olof WallquistIngo SchloderGary Wooden
    • Olof WallquistIngo SchloderGary Wooden
    • C07D487/04C08K5/3412C08K5/3415C08L23/00C08L101/00C09B57/00C09B67/20C09B67/22C08K5/00
    • C09B67/0039
    • A pigment composition, comprising a) 80-99.8 mol % of a diketopyrrolopyrrole of formula ##STR1## wherein A and B are each independently of the other a ##STR2## wherein R.sub.1 and R.sub.2 are each independently of the other hydrogen, chloro, bromo, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.8 alkoxy, C.sub.2 -C.sub.19 alkoxycarbonyl, C.sub.2 -C.sub.19 alkylcarbamoyl, C.sub.1 -C.sub.18 alkylmercapto, C.sub.1 -C.sub.18 alkylamino, C.sub.5 -C.sub.6 cycloalkyl, G is a direct bond or --O--, --S--, --SO--, --SO.sub.2 -- or --NR.sub.5 --, R.sub.3 and R.sub.4 are each independently of the other hydrogen, chloro, bromo, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.18 alkoxy or C.sub.1 -C.sub.18 alkylamino, and R.sub.5 is hydrogen or C.sub.1 -C.sub.6 alkyl, and b) 20-0.2 mol % of a diketopyrrolopyrrole of formula ##STR3## wherein one of R.sub.6 or R.sub.7 is hydrogen and the other is --CN. Such pigment compositions are distinguished by excellent resistance to recrystallisation and heat.
    • 一种颜料组合物,其包含a)80-99.8mol%的式(I)的二酮吡咯并吡咯,其中A和B各自独立地为另一个,其中R 1和R 2各自独立于另一个氢 ,氯,溴,C 1 -C 6烷基,C 1 -C 8烷氧基,C 2 -C 19烷氧基羰基,C 2 -C 19烷基氨基甲酰基,C 1 -C 18烷基巯基,C 1 -C 18烷基氨基,C 5 -C 6环烷基,G是直接键或-O - , - S - - ,-SO 2 - 或-NR 5 - ,R 3和R 4各自独立地为氢,氯,溴,C 1 -C 6烷基,C 1 -C 18烷氧基或C 1 -C 18烷基氨基,R 5为氢或C 1 -C 6烷基,b)20 -0.2摩尔%的式(II)的二酮吡咯并吡咯,其中R6或R7中的一个是氢,另一个是-CN。 这种颜料组合物的特征在于优异的耐再结晶和耐热性。