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1. 发明授权

US5342955A Diketopyrrolopyrroles 失效
标题翻译：二酮吡咯并吡咯
公开(公告)号：US5342955A
公开(公告)日：1994-08-30
申请号：US991676
申请日：1992-12-16
申请人： Gary Wooden , Guy de Weck , Olof Wallquist
发明人： Gary Wooden , Guy de Weck , Olof Wallquist
IPC分类号： C07D487/04 , C08K5/3412 , C08K5/3415 , C08K5/3432 , C08K5/3435 , C08K5/3442 , C08K5/3445 , C08K5/357 , C08K5/45 , C09B57/00 , C09B67/22 , C07D403/14 , C09B7/00
CPC分类号： C07D487/04 , C08K5/3415 , C09B57/004 , C09B67/0039
摘要： 1,4-Diketopyrrolo[3,4-c]pyrroles of formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently of one another hydrogen, Cl, Br, CH.sub.3, OCH.sub.3, CN or phenyl, and at least one of the substituents R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is a group--O(CH.sub.2).sub.n X or --O(CH.sub.2 CH.sub.2 O).sub.p CH.sub.2 CH.sub.2 Xwhereinn is an integer from 2 to 12, andp is an integer from 1 to 3,X is a heterocyclic radical selected form the group consisting imidazolyl, pyrazolyl, triazolyl, piperazinyl, pyridinyl, pyrrolyl, thiazolyl, oxazolyl, benzoxazolyl, indolyl, benzthiazolyl, benzimidazolyl, benzotriazolyl, morpholinyl, piperidinyl and pyrrolidinyl, which radical is unsubstituted or substituted by one or two methyl groups, or is a group --NR.sub.5 R.sub.6 or --N[(CH.sub.2).sub.n -NR.sub.5 R.sub.6 ].sub.2, whereinR.sub.5 and R.sub.6 are each independently of the other hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.5 -C.sub.6 cycloalkyl.Pigment compositions comprising a minor amount of said compounds and diketopyrrolopyrrole pigments have excellent rheological and colouristic properties, especially in paint systems and in printing inks.
摘要翻译：式（Ⅰ）的1,4-二酮吡咯并[3,4-c]吡咯其中R 1，R 2，R 3和R 4各自独立地为氢，Cl，Br，CH 3，OCH 3，CN或苯基，和取代基R 1，R 2，R 3和R 4中的至少一个是基团-O（CH 2）n X或-O（CH 2 CH 2 O）p CH 2 CH 2 X，其中n是2至12的整数，p是1至3的整数，X 是选自咪唑基，吡唑基，三唑基，哌嗪基，吡啶基，吡咯基，噻唑基，恶唑基，苯并恶唑基，吲哚基，苯并噻唑基，苯并咪唑基，苯并三唑基，吗啉基，哌啶基和吡咯烷基的基团的杂环基，该基团是未取代的或被一个或多个或者是-NR5R6或-N [（CH2）n-NR5R6] 2基团，其中R5和R6各自独立地为氢，C1-C6烷基或C5-C6环烷基。包含少量所述化合物和二酮吡咯并吡咯颜料的颜料组合物具有优异的流变学和颜色特性，特别是在涂料体系和印刷油墨中。

2. 发明授权

US5238984A Dianthraquinonyl compounds 失效
标题翻译：二蒽醌基化合物
公开(公告)号：US5238984A
公开(公告)日：1993-08-24
申请号：US715034
申请日：1991-06-11
申请人： Olof Wallquist , Guy de Weck , Gary Wooden
发明人： Olof Wallquist , Guy de Weck , Gary Wooden
IPC分类号： C07C233/33 , C07C235/56 , C08K5/20 , C09B1/00
CPC分类号： C07C233/33 , C07C235/56 , C08K5/20 , C09B1/005
摘要： Dianthraquinonyl compounds of formula ##STR1## wherein X is a radical R.sub.1, R.sub.2, R.sub.3 or R.sub.4, andR.sub.1 is alkyl or alkenyl of not less than 8 carbon atoms,R.sub.2 is --OR.sub.1 or --SR.sub.1,R.sub.3 is --NHR.sub.1 or --N(R.sub.1).sub.2, andR.sub.4 is a group of formula ##STR2## wherein R.sub.5 is --NHR.sub.1, --N(R.sub.1).sub.2, --OR.sub.1 or --SR.sub.1 and n is 0, 1 or 2, andR.sub.6 and R.sub.7 are each independently of the other hydrogen, halogen, nitro, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy.These dianthraquinonyl compounds are preeminently suitable for the mass coloration of plastics materials, especially of polyolefins.
摘要翻译：式（I）的二蒽醌基化合物，其中X为R 1，R 2，R 3或R 4基团，R 1为不少于8个碳原子的烷基或链烯基，R 2为-OR 1或-SR 1，R 3为-NHR 1或 -N（R 1）2，并且R 4是式（IV）的基团，其中R 5是-NHR 1，-N（R 1）2，-OR 1或-SR 1，n是0,1或2，R 6和R 7各自独立于其它氢，卤素，硝基，C 1 -C 4烷基或C 1 -C 4烷氧基。这些二蒽醌化合物特别适用于塑料材料，特别是聚烯烃的大量着色。

3. 发明授权

US5424452A Diketopyrrolopyrroles and pigments thereof 失效
标题翻译：二酮吡咯并吡咯及其颜料
公开(公告)号：US5424452A
公开(公告)日：1995-06-13
申请号：US257394
申请日：1994-06-09
申请人： Gary Wooden , Guy de Weck , Olof Wallquist
发明人： Gary Wooden , Guy de Weck , Olof Wallquist
IPC分类号： C07D487/04 , C08K5/3412 , C08K5/3415 , C08K5/3432 , C08K5/3435 , C08K5/3442 , C08K5/3445 , C08K5/357 , C08K5/45 , C09B57/00 , C09B67/22 , D06P5/00
CPC分类号： C07D487/04 , C08K5/3415 , C09B57/004 , C09B67/0039
摘要： 1,4-Diketopyrrolo[3,4-c]pyrroles of formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently of one another hydrogen, Cl, Br, CH.sub.3, OCH.sub.3, CN or phenyl, and at least one of the substituents R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is a group--O(CH.sub.2).sub.n X or --O(CH.sub.2 CH.sub.2 O).sub.p CH.sub.2 CH.sub.2 Xwhereinn is an integer from 2 to 12, andp is an integer from 1 to 3,X is a heterocyclic radical selected from the group consisting of pyrrolyl and indolyl, or is a substituted amino group as defined in the specification.Pigment compositions comprising a minor amount of said compounds and diketopyrrolopyrrole pigments have excellent rheological and colouristic properties, especially in paint systems and in printing inks.
摘要翻译：式（Ⅰ）的1,4-二酮吡咯并[3,4-c]吡咯其中R 1，R 2，R 3和R 4各自独立地为氢，Cl，Br，CH 3，OCH 3，CN或苯基，和取代基R 1，R 2，R 3和R 4中的至少一个是基团-O（CH 2）n X或-O（CH 2 CH 2 O）p CH 2 CH 2 X，其中n是2至12的整数，p是1至3的整数，X 是选自吡咯基和吲哚基的杂环基，或是说明书中定义的取代的氨基。包含少量所述化合物和二酮吡咯并吡咯颜料的颜料组合物具有优异的流变学和颜色特性，特别是在涂料体系和印刷油墨中。

4. 发明授权

US5200528A Diketopyrrolopyrroles 失效
标题翻译：吡咯烷酮
公开(公告)号：US5200528A
公开(公告)日：1993-04-06
申请号：US870986
申请日：1992-04-20
申请人： Gary Wooden , Guy de Weck , Olof Wallquist
发明人： Gary Wooden , Guy de Weck , Olof Wallquist
IPC分类号： C07D487/04 , C08K5/3412 , C08K5/3415 , C08K5/3432 , C08K5/3435 , C08K5/3442 , C08K5/3445 , C08K5/357 , C08K5/45 , C09B57/00 , C09B67/22
CPC分类号： C07D487/04 , C08K5/3415 , C09B57/004 , C09B67/0039
摘要： 1,4-Diketopyrrolo[3,4-c]pyrroles of formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently of one another hydrogen, Cl, Br, CH.sub.3, OCH.sub.3, CN or phenyl, and at least one of the substituents, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is a group--O(CH.sub.2).sub.n X or --O(CH.sub.2 CH.sub.2 O).sub.p CH.sub.2 CH.sub.2 Xwhereinn is an integer from 2 to 12, andp is an integer from 1 to 3,X is a heterocyclic radical selected from the group consisting of imidazolyl, pyrazolyl, triazolyl, piperazinyl, pyridinyl, pyrrolyl, thiazolyl, oxazolyl, benzoxazolyl, indolyl, benzthiazolyl, benzimidazolyl, benzotriazolyl, morpholinyl, piperidinyl and pyrrolidinyl, which radical is unsubstituted or substituted by one or two methyl groups, or is a group--NR.sub.5 R.sub.6or--N[(CH.sub.2).sub.n --NR.sub.5 R.sub.6 ].sub.2, whereinR.sub.5 and R.sub.6 are each independently of the other hydrogen, C.sub.1 -C.sub.6 alkyl or C.sub.5 -C.sub.6 cycloalkyl.Pigment compositions comprising a minor amount of said compounds and diketopyrrolopyrrole pigments have excellent rheological and coloristic properties, especially in paint systems and in printing inks.
摘要翻译：式（Ⅰ）的1,4-二酮吡咯并[3,4-c]吡咯其中R 1，R 2，R 3和R 4各自独立地为氢，Cl，Br，CH 3，OCH 3，CN或苯基，和取代基R 1，R 2，R 3和R 4中的至少一个是基团-O（CH 2）n X或-O（CH 2 CH 2 O）pCH 2 CH 2 X，其中n是2至12的整数，p是1至3的整数， X是选自咪唑基，吡唑基，三唑基，哌嗪基，吡啶基，吡咯基，噻唑基，恶唑基，苯并恶唑基，吲哚基，苯并噻唑基，苯并咪唑基，苯并三唑基，吗啉基，哌啶基和吡咯烷基的杂环基。一个或两个甲基，或者是-NR 5 R 6或-N [（CH 2）n -NR 5 R 6] 2，其中R 5和R 6各自独立地为氢，C 1 -C 6烷基或C 5 -C 6环烷基。包含少量所述化合物和二酮吡咯并吡咯颜料的颜料组合物具有优异的流变学和着色性能，特别是在涂料体系和印刷油墨中。

5. 发明授权

US5271759A Pigment compositions 失效
标题翻译：颜料组成
公开(公告)号：US5271759A
公开(公告)日：1993-12-21
申请号：US877680
申请日：1992-05-01
申请人： Gary Wooden , Olof Wallquist
发明人： Gary Wooden , Olof Wallquist
IPC分类号： C08L23/02 , C08L23/00 , C09B67/20 , C09B67/22 , C09D11/02 , D06P3/79 , C09B67/10
CPC分类号： C09B67/0034 , C09B67/0063
摘要： Pigment compositions comprisinga) at least one organic pigment,b) 0.05 to 10% by weight, based on the organic pigment a), of at least one modified organic pigment of formula ##STR1## wherein A is the radical of an organic pigment, X is H, Na or K and m is an integer from 0.05 to 3, andc) 0.05 to 10% by weight, based on the organic pigment a), of at least one polymeric ammonium salt having an average molecular weight from 500 to 2 500 000 and which is soluble in water or a lower alkanol.These pigment compositions have excellent suitability for the wrap-free pigmenting of polyolefins and, when incorporated in paint systems and printing inks, exhibit excellent rheology.
摘要翻译：颜料组合物，其包含a）至少一种有机颜料，b）基于有机颜料a）0.05至10重量％的至少一种式A的改性有机颜料（SO 3 X）m，（I）其中A是有机颜料的自由基，X是H，Na或K，m是0.05至3的整数，c）基于有机颜料a）的0.05至10重量％的至少一种聚合铵盐，其具有平均分子量为500至25000，可溶于水或低级链烷醇。这些颜料组合物对于聚烯烃的无包覆着色具有优异的适用性，并且当结合到涂料体系和印刷油墨中时，显示出优异的流变性。

6. 发明授权

US5492564A Diketopyrrolopyrrole pigment with high chroma 失效
标题翻译：具有高色度的二酮吡咯并吡咯颜料
公开(公告)号：US5492564A
公开(公告)日：1996-02-20
申请号：US216703
申请日：1994-03-23
申请人： Gary Wooden , Ingo Schloder , Olof Wallquist
发明人： Gary Wooden , Ingo Schloder , Olof Wallquist
IPC分类号： C07D487/04 , C08K5/3412 , C08K5/3415 , C09B57/00 , C09B67/10 , C09B67/20 , C09B67/48 , C09D7/12 , C07D471/02
CPC分类号： C07D487/04 , C09B57/004 , C09B67/0014
摘要： The pigment form of the diketopyrrolopyrrole pigment of formula ##STR1## having high saturation, characterised by a chroma C*.sub.ab of at least 45 in the CIELAB system when incorporated in a plasticised PVC pressed sheet. This pigment has superior opacity and an unexpectedly high chroma.
摘要翻译：具有高饱和度的式（I）的二酮吡咯并吡咯颜料的颜料形式，其特征在于当结合到增塑的PVC压片中时，CIELAB体系中的色度C * ab至少为45。该颜料具有优异的不透明度和意想不到的高色度。

7. 发明授权

US5738719A Pigment compositions of diketopyrrolopyrroles 失效
标题翻译：二酮吡咯并吡咯的颜料组成
公开(公告)号：US5738719A
公开(公告)日：1998-04-14
申请号：US799969
申请日：1997-02-14
申请人： Olof Wallquist , Ingo Schloder , Gary Wooden
发明人： Olof Wallquist , Ingo Schloder , Gary Wooden
IPC分类号： C07D487/04 , C08K5/3412 , C08K5/3415 , C08L23/00 , C08L101/00 , C09B57/00 , C09B67/20 , C09B67/22 , C08K5/00
CPC分类号： C09B67/0039
摘要： A pigment composition, comprising a) 80-99.8 mol % of a diketopyrrolopyrrole of formula ##STR1## wherein A and B are each independently of the other a ##STR2## wherein R.sub.1 and R.sub.2 are each independently of the other hydrogen, chloro, bromo, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.8 alkoxy, C.sub.2 -C.sub.19 alkoxycarbonyl, C.sub.2 -C.sub.19 alkylcarbamoyl, C.sub.1 -C.sub.18 alkylmercapto, C.sub.1 -C.sub.18 alkylamino, C.sub.5 -C.sub.6 cycloalkyl, G is a direct bond or --O--, --S--, --SO--, --SO.sub.2 -- or --NR.sub.5 --, R.sub.3 and R.sub.4 are each independently of the other hydrogen, chloro, bromo, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.18 alkoxy or C.sub.1 -C.sub.18 alkylamino, and R.sub.5 is hydrogen or C.sub.1 -C.sub.6 alkyl, and b) 20-0.2 mol % of a diketopyrrolopyrrole of formula ##STR3## wherein one of R.sub.6 or R.sub.7 is hydrogen and the other is --CN. Such pigment compositions are distinguished by excellent resistance to recrystallisation and heat.
摘要翻译：一种颜料组合物，其包含a）80-99.8mol％的式（I）的二酮吡咯并吡咯，其中A和B各自独立地为另一个，其中R 1和R 2各自独立于另一个氢，氯，溴，C 1 -C 6烷基，C 1 -C 8烷氧基，C 2 -C 19烷氧基羰基，C 2 -C 19烷基氨基甲酰基，C 1 -C 18烷基巯基，C 1 -C 18烷基氨基，C 5 -C 6环烷基，G是直接键或-O - ， - S - - ，-SO 2 - 或-NR 5 - ，R 3和R 4各自独立地为氢，氯，溴，C 1 -C 6烷基，C 1 -C 18烷氧基或C 1 -C 18烷基氨基，R 5为氢或C 1 -C 6烷基，b）20 -0.2摩尔％的式（II）的二酮吡咯并吡咯，其中R6或R7中的一个是氢，另一个是-CN。这种颜料组合物的特征在于优异的耐再结晶和耐热性。

8. 发明授权

US5476949A Finely divided highly transparent diketopyrrolopyrrole pigments 失效
标题翻译：细分高度透明的二酮吡咯并吡咯颜料
公开(公告)号：US5476949A
公开(公告)日：1995-12-19
申请号：US278594
申请日：1994-07-21
申请人： Olof Wallquist , Gary Wooden , Thomas Eichenberger , Ingo Schloder
发明人： Olof Wallquist , Gary Wooden , Thomas Eichenberger , Ingo Schloder
IPC分类号： C07D487/04 , C08K5/3412 , C08K5/3415 , C08K5/3417 , C09B57/00 , C09B67/02 , C09B67/22 , C08K5/34
CPC分类号： C07D487/04 , C08K5/3417 , C09B57/004
摘要： Finely divided 1,4-diketopyrrolo[3,4-c]pyrroles of the formula ##STR1## where A and B are each independently of the other a radical of the formula ##STR2## wherein at least 84% by weight of the particles have a Stokes equivalent diameter of .ltoreq.0.25 .mu.m, and mixtures thereof.The substituents R.sub.1 and R.sub.2 are defined in claim 1.These pigments are notable for a very pure hue and outstanding transparency.
摘要翻译：式（I）的细分1,4-二酮吡咯并[3,4-c]吡咯，其中A和B各自独立地为通式（II）的基团，其中至少84％的颗粒具有

9. 发明授权

US4966995A Process for the preparation of chlorides of carboxylic acids 失效
标题翻译：制备羧酸氯化物的方法
公开(公告)号：US4966995A
公开(公告)日：1990-10-30
申请号：US258634
申请日：1988-10-17
申请人： Jeannine Chodorge , Jean-Pierre Senet , Gary Wooden
发明人： Jeannine Chodorge , Jean-Pierre Senet , Gary Wooden
IPC分类号： C07B31/00 , C07B41/10 , C07B61/00 , C07C51/00 , C07C51/60 , C07C53/42 , C07C55/36 , C07C57/66 , C07C57/72 , C07C59/68 , C07C61/04 , C07C63/70 , C07C67/00 , C07C201/00 , C07C201/12 , C07C205/57 , C07D317/42
CPC分类号： C07C51/60
摘要： The invention relates to a new process for the preparation of chlorides of carboxylic acids by reaction of tetrachloroethylene carbonate with a carboxylic acid of formula R(COOH).sub.n at a temperature of between 80.degree. and 160.degree. C.The radical R may be very diverse and n is an integer which can take the values 1 to 4.A solvent is not necessary. A catalyst may be employed.Acyl chlorides of a high purity are obtained.
摘要翻译：本发明涉及通过在80℃和160℃之间的温度下将碳酸四氯乙烯与式R（COOH）n的羧酸反应制备羧酸氯化物的新方法。基团R可以是非常多样的 n是可以取1〜4的整数。不需要溶剂。可以使用催化剂。得到高纯度的酰基氯。

10. 发明授权

US5202454A Process for the manufacture of 1-bromoalkyl hydrocarbyl carbonates 失效
标题翻译：制备1-溴烷基烃基碳酸酯的方法
公开(公告)号：US5202454A
公开(公告)日：1993-04-13
申请号：US794842
申请日：1991-11-21
申请人： Gary Wooden , Gerard Sennyey , Jean-Pierre Senet
发明人： Gary Wooden , Gerard Sennyey , Jean-Pierre Senet
IPC分类号： C07C68/06
CPC分类号： C07C68/06
摘要： The invention relates to a new process for the preparation of 1-bromoalkyl hydrocarbyl carbonates.The carbonates according to the invention are prepared by reacting an alpha-chlorinated carbonate of formula ##STR1## with an anhydrous brominated compound of formula ZBr in which Z represents hydrogen, the group (CH.sub.3).sub.3 -Si-, the group ##STR2## or bromine if R.sub.2 is other than an aromatic radical, in the presence of a catalyst chosen from the group consisting of heteroaromatic amines, quaternary ammonium or phosphonium halides, hexasubstituted guanidinium halides, alkaline earth metal halides or alkali metal halides in combination with a complexing agent for their cation.The carbonates according to the invention find their preferential applications as blocking agents for some antibiotics or as agents for the synthesis of phosphorus-containing carbonates which can be used as insecticides.
摘要翻译：本发明涉及一种制备1-溴烷基烃基碳酸酯的新方法。根据本发明的碳酸酯可通过使式（Ⅰa）的α-氯代碳酸酯与式ZBr的无水溴代化合物（其中Z代表氢，基团（CH3）3-Si-，基团“或” 在选自杂芳族胺，季铵或卤化鏻，六取代卤代卤化物，碱土金属卤化物或碱金属卤化物的催化剂存在下，如果R2不是芳族基团，则溴与络合剂组合，他们的阳离子。根据本发明的碳酸酯可以优选地用作一些抗生素的封闭剂或作为可用作杀虫剂的含磷碳酸酯的合成剂。

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