会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 5. 发明授权
    • Insecticidal and/or acaricidal composition exhibiting low toxicity to
mammals and fish
    • 对哺乳动物和鱼类具有低毒性的杀虫和/或杀螨成分
    • US4443438A
    • 1984-04-17
    • US406014
    • 1982-08-06
    • Kiyoshi KasamatsuMasachika HiranoTakeshi Okuno
    • Kiyoshi KasamatsuMasachika HiranoTakeshi Okuno
    • A01N53/00A01N57/00A01N37/34A01N57/26
    • A01N53/00
    • The present invention relates to insecticidal compositions of low toxicity to fishes and mammals characterized by containing m-(p-bromophenoxy)-.alpha.-cyanolbenzyl trans- or trans-rich-2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarboxylate of the formula (I), ##STR1## and at least one of the organo-phosphoric esters of the formula (II), ##STR2## wherein R.sub.1 and R.sub.2 are each a C.sub.1 -C.sub.3 alkyl group, X.sub.1, X.sub.2 and X.sub.3 are each an oxygen or sulfur atom, Y.sub.1 and Y.sub.2, which may be the same or different, are each a C.sub.1 -C.sub.3 lower alkyl, methylmercapto, cyano or nitro group or a halogen atom, Z is a carbon or nitrogen atom and n is 0 or 1, in a ratio of 1 to 1-100 (part by weight) of the former to the latter, and insecticides obtained by mixing said compositions with a carrier or a diluent and if necessary an additive. The term "trans-rich" shows the ratio of trans/cis is not less than 75/25.
    • 本发明涉及对鱼类和哺乳动物具有低毒性的杀虫组合物,其特征在于含有反式或反式富含2,2-二甲基-3-(2,2-二氯乙烯基)丙基间苯二酚的间 - (对溴苯氧基) 式(I)的环丙烷羧酸酯,(I)和至少一种式(II)的有机磷酸酯,其中R 1和R 2各自是C 1 -C 3烷基, X1,X2和X3各自为氧或硫原子,Y1和Y2可以相同或不同,分别为C1-C3低级烷基,甲基巯基,氰基或硝基或卤素原子,Z为碳或 氮原子,n为0或1,前者与前者的比例为1〜1-100(重量份),通过将所述组合物与载体或稀释剂混合而得到的杀虫剂,根据需要添加剂。 术语“富含”表示反式/顺式的比例不小于75/25。
    • 7. 发明授权
    • Novel cyclopropanecarboxylates
    • 新型环丙烷羧酸酯
    • US4003945A
    • 1977-01-18
    • US461029
    • 1974-04-15
    • Shigeyoshi KitamuraNobushige ItayaYoshitoshi OkunoNobuo OhnoTakashi MatsuoMasachika HiranoToshio MizutaniHisami Takeda
    • Shigeyoshi KitamuraNobushige ItayaYoshitoshi OkunoNobuo OhnoTakashi MatsuoMasachika HiranoToshio MizutaniHisami Takeda
    • C07C69/743A01N53/10C07C69/74C07D307/28C07D307/45C07D309/06C07D309/22C07D317/54C07D333/16
    • C07D307/42C07C403/12C07D307/28C07D309/06C07D309/22C07D317/54C07D333/16C07C2101/02C07C2101/08C07C2101/14C07C2101/16Y10S514/937Y10S514/952Y10S514/953Y10S514/957
    • Novel alkynylcyclopropanecarboxylic acid esters represented by the formula, ##STR1## wherein R.sub.1 represents hydrogen, halogen, lower alkyl having up to 5 carbon atoms, lower alkenyl having up to 5 carbon atoms, lower alkynyl having up to 5 carbon atoms, C.sub.1 -C.sub.4 alkoxy C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkylthio C.sub.1 -C.sub.4 alkyl, aryl, aryl C.sub.1 -C.sub.4 alkyl, furyl, substituted furyl, thienyl, substituted thienyl, furfuryl, substituted furfuryl, thenyl, substituted thenyl, cyclo C.sub.3 -C.sub.6 alkyl, substituted cyclo C.sub.3 -C.sub.6 alkyl, cyclo C.sub.3 -C.sub.6 alkenyl or substituted cyclo C.sub.3 -C.sub.6 alkenyl; R.sub.2 and R.sub.3 individually represent hydrogen, halogen, lower alkyl having up to 5 carbon atoms, lower alkenyl having up to 5 carbon atoms, lower alkynyl having up to 5 carbon atoms, aryl, aryl C.sub.1 -C.sub.4 alkyl or may form a carbon-carbon bond; or R.sub.1 and R.sub.3 are bonded to each other at the ends to form a polymethylene chain containing or not containing an oxygen or a sulfur atom, or R.sub.1 and R.sub.2 are bonded to each other at the ends to form a polymethylene chain containing or not containing an oxygen or a sulfur atom; R.sub.4 represents hydrogen or methyl; R.sub.5 represents hydrogen, methyl, vinyl, 1-propenyl, 2-methyl-1-propenyl, 2-methoxymethyl-1-propenyl, 2-methoxycarbonyl-1-propenyl, 2,2-dichlorovinyl or cyclopentyl-idenemethyl when R.sub.4 is hydrogen, and R.sub.5 represents methyl when R.sub.4 is methyl; and R.sub.6 and R.sub.7 represent hydrogen or methyl. These novel esters are produced by reacting an alcohol or its halide or arylsulfonate of the formula, ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.6 are defined above, and A is hydroxy, halogen or arylsulfoxy, with a cyclopropane-carboxylic acid of the formula, ##STR3## wherein R.sub.4, R.sub.5 and R.sub.7 are as defined above, or its reactive derivative. These esters are useful as an insecticide harmless to mammals.
    • 由式表示的新型炔基环丙烷羧酸酯,其中R 1表示氢,卤素,具有至多5个碳原子的低级烷基,具有至多5个碳原子的低级链烯基,低至5个碳原子的低级炔基,C1-C4烷氧基 C 1 -C 4烷基,C 1 -C 4烷硫基C 1 -C 4烷基,芳基,芳基C 1 -C 4烷基,呋喃基,取代的呋喃基,噻吩基,取代的噻吩基,糠基,取代的糠基,噻吩基,取代的芳基,环C 3 -C 6烷基,取代的环 C 3 -C 6烷基,环C 3 -C 6烯基或取代的环C 3 -C 6烯基; R 2和R 3各自表示氢,卤素,具有至多5个碳原子的低级烷基,具有至多5个碳原子的低级链烯基,具有至多5个碳原子的低级炔基,芳基,芳基C 1 -C 4烷基或可形成碳 - 碳 键; 或者R 1和R 3在末端彼此键合以形成含有或不含有氧原子或硫原子的多亚甲基链,或者R 1和R 2在末端彼此结合形成含有或不含有 氧或硫原子; R4代表氢或甲基; 当R4为氢时,R5代表氢,甲基,乙烯基,1-丙烯基,2-甲基-1-丙烯基,2-甲氧基甲基-1-丙烯基,2-甲氧基羰基-1-丙烯基,2,2-二氯乙烯基或环戊基 - 当R 4为甲基时,R 5表示甲基; 并且R 6和R 7表示氢或甲基。 这些新型酯通过使下式的醇或其卤化物或芳基磺酸盐与其中R1,R2,R3和R6定义如上,A是羟基,卤素或芳基磺酰基的醇或其卤化物或芳基磺酸酯与 式,其中R 4,R 5和R 7如上所定义,或其反应性衍生物。 这些酯可用作对哺乳动物无害的杀虫剂。