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1. 发明授权

US4443438A Insecticidal and/or acaricidal composition exhibiting low toxicity to mammals and fish 失效
标题翻译：对哺乳动物和鱼类具有低毒性的杀虫和/或杀螨成分
公开(公告)号：US4443438A
公开(公告)日：1984-04-17
申请号：US406014
申请日：1982-08-06
申请人： Kiyoshi Kasamatsu , Masachika Hirano , Takeshi Okuno
发明人： Kiyoshi Kasamatsu , Masachika Hirano , Takeshi Okuno
IPC分类号： A01N53/00 , A01N57/00 , A01N37/34 , A01N57/26
CPC分类号： A01N53/00
摘要： The present invention relates to insecticidal compositions of low toxicity to fishes and mammals characterized by containing m-(p-bromophenoxy)-.alpha.-cyanolbenzyl trans- or trans-rich-2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarboxylate of the formula (I), ##STR1## and at least one of the organo-phosphoric esters of the formula (II), ##STR2## wherein R.sub.1 and R.sub.2 are each a C.sub.1 -C.sub.3 alkyl group, X.sub.1, X.sub.2 and X.sub.3 are each an oxygen or sulfur atom, Y.sub.1 and Y.sub.2, which may be the same or different, are each a C.sub.1 -C.sub.3 lower alkyl, methylmercapto, cyano or nitro group or a halogen atom, Z is a carbon or nitrogen atom and n is 0 or 1, in a ratio of 1 to 1-100 (part by weight) of the former to the latter, and insecticides obtained by mixing said compositions with a carrier or a diluent and if necessary an additive. The term "trans-rich" shows the ratio of trans/cis is not less than 75/25.
摘要翻译：本发明涉及对鱼类和哺乳动物具有低毒性的杀虫组合物，其特征在于含有反式或反式富含2,2-二甲基-3-（2,2-二氯乙烯基）丙基间苯二酚的间 - （对溴苯氧基）式（I）的环丙烷羧酸酯，（I）和至少一种式（II）的有机磷酸酯，其中R 1和R 2各自是C 1 -C 3烷基， X1，X2和X3各自为氧或硫原子，Y1和Y2可以相同或不同，分别为C1-C3低级烷基，甲基巯基，氰基或硝基或卤素原子，Z为碳或氮原子，n为0或1，前者与前者的比例为1〜1-100（重量份），通过将所述组合物与载体或稀释剂混合而得到的杀虫剂，根据需要添加剂。术语“富含”表示反式/顺式的比例不小于75/25。

2. 发明授权

US4357348A Insecticidal and/or acaricidal composition exhibiting low toxicity to mammals and fish 失效
标题翻译：对哺乳动物和鱼类具有低毒性的杀虫和/或杀螨成分
公开(公告)号：US4357348A
公开(公告)日：1982-11-02
申请号：US99482
申请日：1979-12-03
申请人： Kiyoshi Kasamatsu , Masachika Hirano , Takeshi Okuno
发明人： Kiyoshi Kasamatsu , Masachika Hirano , Takeshi Okuno
IPC分类号： A01N53/00 , A01N47/10 , A01N37/34
CPC分类号： A01N53/00
摘要： The present invention relates to insecticidal compositions of low toxicity to fishes and mammals characterized by containing m-(p-bromophenoxy)-.alpha.-cyanobenzyl trans- or trans-rich-2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarboxylate of the formula (I), ##STR1## and a carbamic ester of the formula (III), ##STR2## wherein R is a group of the formula, ##STR3## in which X is a C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxyl group and n is 1 or 2, in a ratio of 1 to 1-100 (part by weight) of the former to the latter, and insecticides obtained by mixing said compositions with a carrier or a diluent and if necessary an additive. The term "trans-rich" shows the ratio of trans/cis is not less than 75/25.
摘要翻译：本发明涉及对鱼类和哺乳动物具有低毒性的杀虫组合物，其特征在于含有间 - （对溴苯氧基）-α-氰基苄基反式或反式富含2,2-二甲基-3-（2,2-二氯乙烯基）式（I）的环丙烷羧酸酯，（I）和式（III）的氨基甲酸酯，其中R是下式的基团，其中X是C1- C4烷基或C1-C4烷氧基，n为1或2，前者与前者相比为1〜1-100（重量份），通过将所述组合物与载体或稀释剂混合而获得的杀虫剂和如果需要添加剂。术语“富含”表示反式/顺式的比例不小于75/25。

3. 发明授权

US4303672A Cyclopropanecarboxylate insecticides and/or acaricides exhibiting low toxicity to mammals and fish 失效
标题翻译：对哺乳动物和鱼类具有低毒性的环丙烷羧酸酯类杀虫剂和/或杀螨剂
公开(公告)号：US4303672A
公开(公告)日：1981-12-01
申请号：US123455
申请日：1980-02-21
申请人： Masachika Hirano , Tadashi Ohsumi , Kiyoshi Kasamatsu , Takashi Kato
发明人： Masachika Hirano , Tadashi Ohsumi , Kiyoshi Kasamatsu , Takashi Kato
IPC分类号： C07C253/00 , A01N53/00 , A01N53/08 , C07C67/00 , C07C255/39 , C07C121/75
CPC分类号： A01N53/00
摘要： The present invention relates to carboxylic esters of the formula (I), ##STR1## wherein X is a chlorine or bromine atom, and their production and use as an insecticide and/or acaricide.
摘要翻译：本发明涉及式（I）的羧酸酯，其中X是氯或溴原子，以及它们作为杀虫剂和/或杀螨剂的生产和用途。

4. 发明授权

US4596796A Dithiolphosphoric acid ester as a soil pesticide 失效
标题翻译：二硫代磷酸酯作为土壤农药
公开(公告)号：US4596796A
公开(公告)日：1986-06-24
申请号：US648986
申请日：1984-09-10
申请人： Haruyasu Yamamoto , Kiyoshi Kasamatsu , Takayuki Okabe
发明人： Haruyasu Yamamoto , Kiyoshi Kasamatsu , Takayuki Okabe
IPC分类号： A01N57/12 , C07F9/17 , C07F9/165
CPC分类号： C07F9/17 , A01N57/12
摘要： A dithiolphosphoric acid ester of the formula, ##STR1## wherein A is sec-butyl or tert-butyl group, and B is iso-propyl, n-butyl, iso-butyl, sec-butyl or tert-butyl group, which is useful as a soil pesticidal composition for pests in soil.
摘要翻译：下式的二硫醇磷酸酯，其中A是仲丁基或叔丁基，B是异丙基，正丁基，异丁基，仲丁基或叔丁基，这是有用的作为土壤中害虫的土壤农药组合物。

5. 发明授权

US5120721A Acaricidal composition 失效
标题翻译：杀虫剂组合物
公开(公告)号：US5120721A
公开(公告)日：1992-06-09
申请号：US589598
申请日：1990-09-28
申请人： Teruichi Morimoto , Haruo Sasayama , Kiyoshi Kasamatsu
发明人： Teruichi Morimoto , Haruo Sasayama , Kiyoshi Kasamatsu
IPC分类号： A01N37/38 , A01N37/44 , A01N53/08 , A01N57/12
CPC分类号： A01N57/12
摘要： An acaricidal composition comprising as active ingredients(A) either .alpha.-cyano-3-phenoxybenzyl 2,2,3,3-tetramethylcyclopropanecarboxylate or .alpha.-cyano-3-phenoxybenzyl N-(2-chloro-.alpha.,.alpha.,.alpha.-trifluoro-p-tolyl)-valinate, and(B) O,O,O',O'-tetraethyl S,S'-methylene bis(phosphorodithioate), is very effectively applicable as a composition for controlling acarine pests such as two-spotted spider mite (Tetranychus urticae Koch), carmine spider mite (Tetranychus cinnabarinus Boisduval), Kanazawa spider mite (Tetranychus Kansawai Kishida), citrus red mite (Panonychus citri McGregor), European red mite (Panonychus ulmi Koch), broad mite (Polyphagotarsonemus latus Banks), etc. in areas cultivated with fruit trees, tea-plant, vegetables, flowering plants, etc.
摘要翻译：一种杀螨组合物，其包含作为活性成分（A）的2,2,3,3-四甲基环丙烷羧酸α-氰基-3-苯氧基苄酯或N-（2-氯-α，α，α-三氟 - 对甲苯基） - 缬氨酸和（B）O，O，O'，O'-四乙基S，S'-亚甲基双（二硫代磷酸酯），非常有效地用作控制螨类害虫如二斑蜘蛛的组合物螨（Tetranychus urticae Koch），胭脂红蜘蛛螨（Tetranychus cinnabarinus Boisduval），金泽蜘蛛螨（Tetranychus Kansawai Kishida），柑橘红螨（Panonychus citri McGregor），欧洲红螨（Panonychus ulmi Koch），螨（Polyphagotarsonemus latus Banks）等等，在种植果树，茶叶，蔬菜，开花植物等地区。

6. 发明授权

US4631347A Dithiolphosphoric acid esters 失效
标题翻译：二硫代磷酸酯
公开(公告)号：US4631347A
公开(公告)日：1986-12-23
申请号：US542709
申请日：1983-10-17
申请人： Haruyasu Yamamoto , Kiyoshi Kasamatsu , Takayuki Okabe , Kunio Mukai
发明人： Haruyasu Yamamoto , Kiyoshi Kasamatsu , Takayuki Okabe , Kunio Mukai
IPC分类号： A01N57/12 , C07F9/17 , C07F9/165
CPC分类号： A01N57/12 , C07F9/17
摘要： A dithiolphosphoric acid ester of the formula, ##STR1## wherein R is methyl or ethyl group, and when R is methyl group, A is iso-butyl, sec-butyl or tert-butyl group and B is methyl, ethyl or n-propyl group, when R is ethyl group and A is sec-butyl or tert-butyl group, B is methyl group, and when R is ethyl group and A is iso-butyl group, B is methyl, ethyl or n-propyl group, which is useful as a soil pesticidal composition for pests in soil.
摘要翻译：下式的二硫醇磷酸酯，其中R是甲基或乙基，当R是甲基时，A是异丁基，仲丁基或叔丁基，B是甲基，乙基或正丙基基团，当R为乙基且A为仲丁基或叔丁基时，B为甲基，当R为乙基且A为异丁基时，B为甲基，乙基或正丙基，作为土壤中害虫的土壤农药组合物是有用的。

7. 发明授权

US4889719A Microencapsulated organophosphorus insecticidal composition for agricultural use 失效
标题翻译：农药用微囊化有机磷杀虫组合物
公开(公告)号：US4889719A
公开(公告)日：1989-12-26
申请号：US215850
申请日：1988-07-06
申请人： Toshiro Ohtsubo , Shigenori Tsuda , Yukio Manabe , Kiyoshi Kasamatsu , Hisami Takeda , Kozo Tsuji
发明人： Toshiro Ohtsubo , Shigenori Tsuda , Yukio Manabe , Kiyoshi Kasamatsu , Hisami Takeda , Kozo Tsuji
IPC分类号： A01N25/28 , A01N57/12 , A01N57/14 , B01J13/16
CPC分类号： A01N25/28 , B01J13/16
摘要： A microencapsulated insecticidal composition has excellent residual effect which comprises an organophosphorus insecticide encapsulated in a wall formed of a polyurea and having an average particle diameter of not more than 80 .mu.m, a wall thickness of not more than 0.3 .mu.m and a ratio of an average particle diameter/wall thickness of not less than 250.
摘要翻译：微胶囊杀虫组合物具有优异的残留效果，其包含被包封在由聚脲形成的壁中的有机磷杀虫剂，其平均粒径不大于80μm，壁厚不大于0.3μm，平均粒径/壁厚不小于250。

8. 发明授权

US4309439A Substituted-acetic acid ester 失效
标题翻译：取代的乙酸酯
公开(公告)号：US4309439A
公开(公告)日：1982-01-05
申请号：US882155
申请日：1978-02-28
申请人： Nobuo Ohno , Isao Ohno , Toshio Nishioka , Hisami Takeda , Kiyoshi Kasamatsu
发明人： Nobuo Ohno , Isao Ohno , Toshio Nishioka , Hisami Takeda , Kiyoshi Kasamatsu
IPC分类号： C07C69/612 , A01N37/00 , A01N37/10 , A01N37/38 , A01N37/42 , A01N37/48 , A01N43/06 , A01N43/08 , A01N43/12 , A01N43/30 , A01N43/32 , A01N43/90 , C07C51/00 , C07C59/46 , C07C59/48 , C07C67/00 , C07C69/62 , C07C69/73 , C07C69/76 , C07C69/767 , C07C69/95 , C07C201/00 , C07C205/56 , C07C253/00 , C07C255/50 , C07C255/57 , C07C313/00 , C07C323/62 , C07D307/00 , C07D307/40 , C07D307/54 , C07D307/79 , C07D307/80 , C07D317/60 , C07D333/24 , C07D333/28 , C07D333/60 , C07D333/78 , C08K5/34 , A61K31/235 , A61K31/60 , C07C69/614 , C07D323/02
CPC分类号： C07D307/79 , C07C205/56 , C07C323/00 , C07C67/14 , C07C69/65 , C07D307/54 , C07D317/60 , C07D333/24 , C07D333/28 , C07D333/60
摘要： A novel substituted-arylacetic acid ester of the formula, ##STR1## wherein R.sub.1 and R.sub.2 are each hydrogen or a halogen atom, a C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkenyl, C.sub.1 -C.sub.4 alkoxy, cyano, nitro, methylthio, C.sub.1 -C.sub.4 alkanoyl, C.sub.1 -C.sub.4 alkanoyloxy, or C.sub.1 -C.sub.4 alkoxycarbonyl group, or R.sub.1 and R.sub.2, taken together, may form methylenedioxy, a C.sub.3 -C.sub.5 alkylene or butadienylene (--CH.dbd.CH--CH.dbd.CH--) ring; R.sub.3 is a C.sub.2 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkenyl, propargyl, C.sub.3 -C.sub.6 cycloalkyl or cyclopropylmethyl group; R.sub.4 is hydrogen or a halogen atom, methyl or ethyl group; R.sub.5 is allyl, propargyl, 3-butenyl, 3-butynyl, phenyl or benzyl group; and A is oxygen or sulfur atom or --CH.dbd.CH-- group, which possesses various useful insecticidal and acaricidal activities and can be prepared by reacting a substituted-arylacetic acid of the formula: ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and A are each as defined above, or a reactive derivative thereof with an alcohol, or halide or sulfonate thereof of the formula, ##STR3## wherein R.sub.4 and R.sub.5 are each as defined above and X is hydroxy group, a halogen atom, alkylsulfonyloxy or arylsulfonyloxy group.
摘要翻译：一种新颖的下式的取代芳基乙酸酯，其中R 1和R 2各自为氢或卤原子，C 1 -C 4烷基，C 2 -C 4烯基，C 1 -C 4烷氧基，氰基，硝基，甲硫基，C 1 -C 4烷酰基，C 1 -C 4烷酰氧基或C 1 -C 4烷氧基羰基，或者R 1和R 2一起可以形成亚甲二氧基，C 3 -C 5亚烷基或亚丁二烯基（-CH = CH-CH = CH-）环; R3是C2-C4烷基，C2-C4烯基，炔丙基，C3-C6环烷基或环丙基甲基; R4是氢或卤素原子，甲基或乙基; R5是烯丙基，炔丙基，3-丁烯基，3-丁炔基，苯基或苄基; 并且A是氧或硫原子或-CH = CH-基团，其具有各种有用的杀虫和杀螨活性，并且可以通过使下式的取代芳基乙酸反应来制备：其中R1，R2，R3和A是或其与醇或其卤化物或磺酸盐的反应性衍生物，其分子式如下：其中R 4和R 5各自如上所定义，X为羟基，卤素原子，烷基磺酰氧基或芳基磺酰氧基。

9. 发明授权

US4293504A Process for preparing optically active .alpha.-cyano-3-(4-halogenophenoxy)-benzyl 2-(4-chlorophenyl)isovalerate 失效
标题翻译：光学活性α-氰基-3-（4-卤代苯氧基）-2-（4-氯苯基）异戊酸苄酯的制备方法
公开(公告)号：US4293504A
公开(公告)日：1981-10-06
申请号：US118716
申请日：1980-02-05
申请人： Yukio Suzuki , Kiyoshi Kasamatsu , Kohichi Aketa
发明人： Yukio Suzuki , Kiyoshi Kasamatsu , Kohichi Aketa
IPC分类号： A01N37/34 , A01N37/38 , C07C59/68 , C07C67/00 , C07C253/00 , C07C255/38 , C07C121/75
CPC分类号： C07C59/68 , A01N37/38
摘要： An optically active .alpha.-cyano-3-(4-halogenophenoxy)-benzyl 2-(4-chlorophenyl)isovalerate, which consists substantially of or is rich in (S)-.alpha.-cyano-3-(4-halogenophenoxy)benzyl (S)-2-(4-chlorophenyl)isovalerate; a method for preparing the same; and an insecticidal and/or acaricidal composition containing the same.
摘要翻译：由（S）-α-氰基-3-（4-卤代苯氧基）苄基（S）-α-氰基-3-（4-卤代苯氧基）苄基（或其盐）组成的光学活性的α-氰基-3-（4-卤代苯氧基）-2-（4-氯苯基）异戊酸苄酯 S）-2-（4-氯苯基）异戊酸酯; 其制备方法; 和含有该组合物的杀虫和/或杀螨组合物。

10. 发明授权

US4091111A Substituted-acetic acid ester 失效
标题翻译：取代的乙酸酯
公开(公告)号：US4091111A
公开(公告)日：1978-05-23
申请号：US728840
申请日：1976-10-01
申请人： Nobuo Ohno , Isao Ohno , Toshio Nishioka , Hisami Takeda , Kiyoshi Kasamatsu
发明人： Nobuo Ohno , Isao Ohno , Toshio Nishioka , Hisami Takeda , Kiyoshi Kasamatsu
IPC分类号： C07C69/612 , A01N37/00 , A01N37/10 , A01N37/38 , A01N37/42 , A01N37/48 , A01N43/06 , A01N43/08 , A01N43/12 , A01N43/30 , A01N43/32 , A01N43/90 , C07C51/00 , C07C59/46 , C07C59/48 , C07C67/00 , C07C69/62 , C07C69/73 , C07C69/76 , C07C69/767 , C07C69/95 , C07C201/00 , C07C205/56 , C07C253/00 , C07C255/50 , C07C255/57 , C07C313/00 , C07C323/62 , C07D307/00 , C07D307/40 , C07D307/54 , C07D307/79 , C07D307/80 , C07D317/60 , C07D333/24 , C07D333/28 , C07D333/60 , C07D333/78 , C08K5/34 , A01N9/24
CPC分类号： C07D307/79 , C07C205/56 , C07C323/00 , C07C67/14 , C07C69/65 , C07D307/54 , C07D317/60 , C07D333/24 , C07D333/28 , C07D333/60
摘要： A novel substituted-arylacetic acid ester of the formula, ##STR1## wherein R.sub.1 and R.sub.2 are each hydrogen or a halogen atom, a C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkenyl, C.sub.1 -C.sub.4 alkoxy, cyano, nitro, methylthio, C.sub.1 -C.sub.4 alkanoyl, C.sub.1 -C.sub.4 alkanoyloxy, or C.sub.1 -C.sub.4 alkoxycarbonyl group, or R.sub.1 and R.sub.2, taken together, may form methylenedioxy, a C.sub.3 -C.sub.5 alkylene or butadienylene (--CH.dbd.CH--CH.dbd.CH--) ring; R.sub.3 is a C.sub.2 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkenyl, propargyl, C.sub.3 -C.sub.6 cycloalkyl or cyclopropylmethyl group; R.sub.4 is hydrogen or a halogen atom, methyl or ethyl group; R.sub.5 is allyl, propargyl, 3-butenyl, 3-butynyl, phenyl or benzyl group; and A is oxygen or sulfur atom or --CH.dbd.CH-- group, which possesses various useful insecticidal and acaricidal activities and can be prepared by reacting a substituted-arylacetic acid of the formula; ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and A are each as defined above, or a reactive derivative thereof with an alcohol, or halide or sulfonate thereof of the formula, ##STR3## wherein R.sub.4 and R.sub.5 are each as defined above and X is hydroxy group, a halogen atom, alkylsulfonyloxy or arylsulfonyloxy group.
摘要翻译：一种新颖的下式的取代芳基乙酸酯，其中R 1和R 2各自为氢或卤原子，C 1 -C 4烷基，C 2 -C 4烯基，C 1 -C 4烷氧基，氰基，硝基，甲硫基，C 1 -C 4烷酰基，C 1 -C 4烷酰氧基或C 1 -C 4烷氧基羰基，或者R 1和R 2一起可以形成亚甲二氧基，C 3 -C 5亚烷基或亚丁二烯基（-CH = CH-CH = CH-）环; R3是C2-C4烷基，C2-C4烯基，炔丙基，C3-C6环烷基或环丙基甲基; R4是氢或卤素原子，甲基或乙基; R5是烯丙基，炔丙基，3-丁烯基，3-丁炔基，苯基或苄基; 并且A是氧或硫原子或-CH = CH-基团，其具有各种有用的杀虫和杀螨活性，并且可以通过使式的取代芳基乙酸反应来制备; 其中R 1，R 2，R 3和A各自如上所定义，或其与醇或其下式的卤化物或磺酸盐的反应性衍生物，其中R 4和R 5各自如上所定义，X是羟基，卤素原子，烷基磺酰氧基或芳基磺酰氧基。

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