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1. 发明授权

US5498657A Fluorine-containing polymer composition 失效
标题翻译：含氟聚合物组合物
公开(公告)号：US5498657A
公开(公告)日：1996-03-12
申请号：US296469
申请日：1994-08-26
申请人： Norihide Sugiyama , Atsushi Watakabe , Shunsuke Yokotsuka , Atsuo Hiroi , Masaki Naritomi , Naoko Shirota , Ko Aosaki , Masaru Nakamura
发明人： Norihide Sugiyama , Atsushi Watakabe , Shunsuke Yokotsuka , Atsuo Hiroi , Masaki Naritomi , Naoko Shirota , Ko Aosaki , Masaru Nakamura
IPC分类号： C08J3/09 , C08K5/00 , H05K1/00 , C08J5/00 , B32B27/00 , C08F14/18 , C08F14/26
CPC分类号： C08J3/091 , C08J3/093 , C08K5/0008 , C08J2327/12 , H05K3/4676 , Y10T428/3154 , Y10T428/31544
摘要： A fluorine-containing polymer composition comprising a polymer having a functional group and a fluorine-containing aliphatic cyclic structure dissolved in a solvent mixture of an aprotic fluorine-containing solvent and a protic fluorine-containing solvent.
摘要翻译：一种包含溶解在非质子含氟溶剂和质子性含氟溶剂的溶剂混合物中的具有官能团和含氟脂肪族环状结构的聚合物的含氟聚合物组合物。

2. 再颁专利

USRE37022E1 Fluorine-containing polymer composition 失效
标题翻译：含氟聚合物组合物
公开(公告)号：USRE37022E1
公开(公告)日：2001-01-16
申请号：US09037887
申请日：1998-03-10
申请人： Norihide Sugiyama , Atsushi Watakabe , Shunsuke Yokotsuka , Atsuo Hiroi , Masaki Naritomi , Naoko Shirota , Ko Aosaki , Masaru Nakamura
发明人： Norihide Sugiyama , Atsushi Watakabe , Shunsuke Yokotsuka , Atsuo Hiroi , Masaki Naritomi , Naoko Shirota , Ko Aosaki , Masaru Nakamura
IPC分类号： C08J500
CPC分类号： C08J3/091 , C08J3/093 , C08J2327/12 , C08K5/0008 , H05K3/4676 , Y10T428/3154 , Y10T428/31544 , C08L27/12
摘要： A fluorine-containing polymer composition comprising a polymer having a functional group and a fluorine-containing aliphatic cyclic structure dissolved in a solvent mixture of an aprotic fluorine-containing solvent and a protic fluorine-containing solvent.
摘要翻译：一种包含溶解在非质子含氟溶剂和质子性含氟溶剂的溶剂混合物中的具有官能团和含氟脂肪族环状结构的聚合物的含氟聚合物组合物。

3. 发明授权

US6111062A Method for producing a fluorinated alicyclic structure-containing polymer 有权
标题翻译：含氟脂环结构体聚合物的制造方法
公开(公告)号：US6111062A
公开(公告)日：2000-08-29
申请号：US195687
申请日：1998-11-19
申请人： Naoko Shirota , Yasuo Etoh , Norihide Sugiyama
发明人： Naoko Shirota , Yasuo Etoh , Norihide Sugiyama
IPC分类号： C08F8/22 , C08G65/22 , C08G73/24
CPC分类号： C08F8/22 , Y10S528/935
摘要： A method for producing a fluorinated alicyclic structure-containing polymer, which comprises contacting a fluorinated alicyclic structure-containing polymer having an unstable terminal group derived from a polymerization initiator and/or a chain transfer agent with fluorine gas in a fluorine-containing solvent, to convert the unstable terminal group to a stable terminal group and thereby to obtain a fluorinated alicyclic structure-containing polymer having substantially no unstable terminal group.
摘要翻译：一种含氟脂环结构的聚合物的制造方法，其特征在于，将含有聚合引发剂的不稳定末端基团的含氟脂环式结构体和/或链转移剂与含氟溶剂中的氟气接触，将不稳定末端基转化为稳定的末端基，得到基本上不具有不稳定末端基的含氟脂环结构的聚合物。

4. 发明授权

US08236901B2 Fluorinated compound, fluoropolymer and method for producing the compound 失效
标题翻译：氟化合物，含氟聚合物及其制造方法
公开(公告)号：US08236901B2
公开(公告)日：2012-08-07
申请号：US12858752
申请日：2010-08-18
申请人： Koichi Murata , Naoko Shirota , Osamu Yokokoji , Yoko Takebe
发明人： Koichi Murata , Naoko Shirota , Osamu Yokokoji , Yoko Takebe
IPC分类号： C08F14/18
CPC分类号： C07C57/32 , C07C69/65 , C07C2601/08 , C07C2601/14 , C07C2602/42 , C07C2603/74 , C07D307/20 , C08F14/18 , C08F36/20 , C08F214/18 , Y10S430/146 , C08F2/00
摘要： Provided is a novel fluorinated compound, a fluoropolymer, and a method for producing the compound. A monomer of the compound has a formula F2═CFCF2C(X)(C(O)OZ)(CH2)nCR═CHR, wherein X is a hydrogen atom, a cyano group, or a group of formula —C(O)OZ; Z is a hydrogen atom or a C1-20 monovalent organic group, n is 0, 1, or 2; and R is a hydrogen atom or a C1-20 monovalent organic group.
摘要翻译：提供了一种新的氟化化合物，含氟聚合物及其制备方法。化合物的单体具有式F2 = CFCF 2 C（X）（C（O）OZ）（CH 2）n CR = CHR，其中X为氢原子，氰基或式-C（O）OZ ; Z为氢原子或C1-20一价有机基团，n为0,1或2; 且R为氢原子或C 1-20二价一价有机基团。

5. 发明授权

US08134033B2 Fluorocompound having highly fluorinated norbornane structure, fluoropolymer, and their production processes 失效
标题翻译：具有高氟化降冰片烷结构的氟化合物，含氟聚合物及其制备方法
公开(公告)号：US08134033B2
公开(公告)日：2012-03-13
申请号：US12351905
申请日：2009-01-12
申请人： Yasuhisa Matsukawa , Daisuke Shirakawa , Eisuke Murotani , Naoko Shirota , Yoko Takebe
发明人： Yasuhisa Matsukawa , Daisuke Shirakawa , Eisuke Murotani , Naoko Shirota , Yoko Takebe
IPC分类号： C07C49/467 , C07C67/14 , C07C69/653 , C08F20/22
CPC分类号： C07C49/477 , C07C29/143 , C07C29/147 , C07C31/44 , C07C35/52 , C07C45/54 , C07C61/40 , C07C67/14 , C07C69/653 , C07C69/753 , C07C2602/42 , C08F220/24
摘要： To provide a novel polymerizable fluorocompound having a highly fluorinated norbornane structure, and a polymer obtained from the compound. Further, their production processes and a novel intermediate useful for the processes.A novel compound (1) such as a compound (11) or a compound (12), and its polymer. A compound (2) such as a compound (21) or (22), and a compound (3) such as a compound (31) or (32M), which are useful as an intermediate for the production of the compound (1), and its production process. However, each of ZA to ZE represents such as —CH(—OC(O)C(CH3)═CH2)— or —CF2, Each of WA and WB represents such as F, each of YA to YE represents such as —CH(—OH)— or —CF(CH2OH), and each of XA to XE represents such as —C(O)— or —CF2—.
摘要翻译：提供具有高氟化降冰片烷结构的新型可聚合氟化合物和由该化合物获得的聚合物。此外，它们的制备方法和用于该方法的新型中间体。新化合物（1）如化合物（11）或化合物（12）及其聚合物。作为化合物（1）的制造中间体的化合物（21）或（22）的化合物（2）和化合物（31）或（32M）等化合物（3），及其生产工艺。然而，ZA至ZE各自表示-CH（-OC（O）C（CH 3)≡CH2） - 或-CF 2，WA和WB各自表示F，YA至YE各自表示-CH （-OH） - 或-CF（CH 2 OH），XA至XE各自表示-C（O） - 或-CF 2 - 。

6. 发明授权

US07790811B2 Pellicle and novel fluoropolymer 有权
标题翻译：薄膜和新型含氟聚合物
公开(公告)号：US07790811B2
公开(公告)日：2010-09-07
申请号：US11446242
申请日：2006-06-05
申请人： Ikuo Matsukura , Hiromasa Yamamoto , Yuichiro Ishibashi , Shinji Okada , Naoko Shirota
发明人： Ikuo Matsukura , Hiromasa Yamamoto , Yuichiro Ishibashi , Shinji Okada , Naoko Shirota
IPC分类号： C08F114/18
CPC分类号： G03F1/62 , C08G65/007 , C08G65/226 , G03F7/0046 , Y10T428/24331 , Y10T428/3154
摘要： A useful fluoropolymer excellent in transparency and durability to a short wavelength light (an ArF excimer laser having an irradiation wavelength of 193 nm and a F2 excimer laser having an irradiation wavelength of 157 nm) as e.g. a pellicle material, wherein a polymer (I) to be used for a pellicle membrane and/or an adhesive is a polymer essentially containing the following fluorine atom-containing unit (1), wherein a chain forming the polymer main chain comprises a carbon atom and an etheric oxygen atom, at least one carbon atom forming the main chain is a carbon atom forming a cyclic group, and at least one etheric oxygen atom forming the main chain is an oxygen atom forming no cyclic group.
摘要翻译：对于短波长的光（具有193nm的照射波长的ArF准分子激光和具有157nm的照射波长的F2准分子激光）的透明性和耐久性优异的有用氟聚合物，例如，防护薄膜组件，其中用于防护薄膜和/或粘合剂的聚合物（I）是基本上含有以下含氟原子的单元（1）的聚合物，其中形成聚合物主链的链包含碳原子和醚性氧原子，形成主链的至少一个碳原子是形成环状基团的碳原子，形成主链的至少一个醚性氧原子是不形成环状基团的氧原子。

7. 发明申请

US20090281239A1 OIL REPELLENT COPOLYMER, METHOD FOR ITS PRODUCTION AND OIL REPELLENT TREATMENT SOLUTION 失效
标题翻译：油脂共聚物，其生产方法和油剂处理方法
公开(公告)号：US20090281239A1
公开(公告)日：2009-11-12
申请号：US12499321
申请日：2009-07-08
申请人： Taiki Hoshino , Naoko Shirota , Nobuyuki Otozawa , Akihiko Asakawa
发明人： Taiki Hoshino , Naoko Shirota , Nobuyuki Otozawa , Akihiko Asakawa
IPC分类号： C08L75/00 , C08G18/81
CPC分类号： C09D133/066 , C08G18/807 , C08G18/8116 , C09D133/14
摘要： To provide an oil repellent copolymer capable of forming an oil repellent film which is excellent in durability.An oil repellent copolymer characterized by comprising a repeating unit (A) having a polyfluoroalkyl group, a repeating unit (B) having a fluorescent functional group, and a repeating unit (C) having an ester bond other than an ester bond derived from acrylic acid, and/or a hydroxyl group.
摘要翻译：提供能够形成耐久性优异的防油膜的防油性共聚物。一种斥油剂共聚物，其特征在于包含具有多氟烷基的重复单元（A），具有荧光官能团的重复单元（B）和具有除丙烯酸酯键之外的酯键的重复单元（C），和/或羟基。

8. 发明申请

US20090061360A1 MATERIAL FOR RESIST PROTECTIVE FILM FOR IMMERSION LITHOGRAPHY 审中-公开
标题翻译：材料用于耐久性保护薄膜
公开(公告)号：US20090061360A1
公开(公告)日：2009-03-05
申请号：US12254030
申请日：2008-10-20
申请人： Yoko Takebe , Shu-zhong Wang , Osamu Yokokoji , Naoko Shirota , Yasuhisa Matsukawa , Daisuke Shirakawa
发明人： Yoko Takebe , Shu-zhong Wang , Osamu Yokokoji , Naoko Shirota , Yasuhisa Matsukawa , Daisuke Shirakawa
IPC分类号： C08F20/24 , C08F20/12 , C08F20/26 , G03F7/20
CPC分类号： G03F7/2041 , C08F214/18 , C08F220/24 , G03F7/11
摘要： To provide a resist protective film material for immersion lithography.An alkali soluble resist protective film material for immersion lithography, which comprises a polymer (F) containing repeating units (FU) formed by polymerizing a polymerizable compound (fm) having a fluorine-containing bridged cyclic structure. For example, repeating units (FU) are repeating units formed by polymerizing a compound (f) selected from the group consisting of the following formulae (f1) to (f4) (RF represents H, F, a C1-3 alkyl group or a C1-3 fluoroalkyl group, and XF represents F, OH or CH2OH.)
摘要翻译：提供用于浸没光刻的抗蚀保护膜材料。一种用于浸渍光刻的碱溶性抗蚀剂保护膜材料，其包含通过聚合具有含氟桥连环状结构的可聚合化合物（fm）形成的重复单元（FU）的聚合物（F）。例如，重复单元（FU）是通过使从下述式（f1）〜（f4）中选择的化合物（f）聚合形成的重复单元（RF表示H，F，C1-3烷基或 C 3氟烷基，X F表示F，OH或CH 2 OH）

9. 发明授权

US06548129B2 Pellicle 有权
标题翻译：薄膜
公开(公告)号：US06548129B2
公开(公告)日：2003-04-15
申请号：US09803965
申请日：2001-03-13
申请人： Ikuo Matsukura , Naoko Shirota , Jun Irisawa
发明人： Ikuo Matsukura , Naoko Shirota , Jun Irisawa
IPC分类号： B32B300
CPC分类号： G03F1/62 , G03F1/64 , Y10T428/3154 , Y10T428/31544
摘要： A pellicle for a photolithographic patterning process by means of a light having a wavelength of at most 200 nm, comprising a frame and a pellicle membrane bonded to the frame by means of an adhesive, wherein the pellicle membrane or the adhesive comprises the following fluorine-containing polymer (A): fluorine-containing polymer (A): a substantially linear fluorine-containing polymer having a chain of carbon atoms as the main chain, and containing as carbon atoms in its main chain, a carbon atom having one or two hydrogen atoms bonded thereto and a carbon atom having no hydrogen atom bonded thereto and having a fluorine atom or a fluorine-containing organic group bonded thereto.
摘要翻译：一种用于通过波长为至多200nm的光进行光刻图案化处理的防护薄膜组件，其包括通过粘合剂粘合到框架上的框架和防护薄膜组件，其中防护薄膜组件或粘合剂包含以下氟 - 含氟聚合物（A）：含氟聚合物（A）：具有碳原子链为主链的基本上呈直链状的含氟聚合物，在其主链中含有碳原子，具有一个或两个氢原子的碳原子与其键合的原子和与其结合的氟原子或含氟有机基团的不具有氢原子的碳原子键合。

10. 发明授权

US09012565B2 Water/oil repellent agent and water/oil repellent composition 有权
标题翻译：防水/防油剂和防水/防油剂组合物
公开(公告)号：US09012565B2
公开(公告)日：2015-04-21
申请号：US13333374
申请日：2011-12-21
申请人： Taiki Hoshino , Naoko Shirota
发明人： Taiki Hoshino , Naoko Shirota
IPC分类号： C08G18/28 , C08G18/76 , C09K3/18
CPC分类号： C08G18/2825 , C08G18/2885 , C08G18/7664 , C08G18/7671 , C09K3/18
摘要： To provide a water/oil repellent agent and a water/oil repellent composition which is capable of providing an article surface with a sufficient water/oil repellency, while placing little burden on the environment.One comprising a reaction product obtained by reacting a fluoromonool having a polyfluoroalkyl moiety having at most 6 carbon atoms as an alcohol, an alkane monool having at least 18 carbon atoms, and MDI or a polymeric MD, and by treating an article with such a water/oil repellent agent, a sufficient water/oil repellency can be imparted, while placing little burden on the environment. By treating the above-mentioned article with the water/oil repellent composition of the present invention, a high quality water/oil repellency can be imparted to the article.
摘要翻译：为了提供防水/拒油剂和斥水斥油剂组合物，其能够使物品表面具有足够的斥水斥油性，同时对环境施加很小的负担。一种包括通过使具有至多6个碳原子的多氟烷基部分的氟莫诺醇作为醇，具有至少18个碳原子的烷烃一元醇和MDI或聚合物MD反应而获得的反应产物，并通过用这种水处理制品 /防油剂，可以赋予足够的防水/防油性，同时对环境施加很小的负担。通过用本发明的斥水斥油剂组合物处理上述制品，可以赋予制品高品质的拒水拒油性。

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