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    • 2. 发明专利
    • Organic thin film semiconductor device and method for manufacturing the same
    • 有机薄膜半导体器件及其制造方法
    • JP2012054371A
    • 2012-03-15
    • JP2010195270
    • 2010-09-01
    • National Institute Of Advanced Industrial & Technology独立行政法人産業技術総合研究所
    • YAMADA JUICHIHASEGAWA TATSUO
    • H01L29/786H01L21/336H01L51/05H01L51/30H01L51/40
    • PROBLEM TO BE SOLVED: To provide an organic thin film semiconductor device capable of simplifying a manufacturing process, while simultaneously realizing high mobility, low contact resistance, low threshold voltage and low sub-threshold value, and a method for manufacturing the same.SOLUTION: The organic thin film semiconductor device is a bottom contact type, an electrode end having a tapered slope which is widened from the organic semiconductor side to an insulating layer side, is formed adjacent to at least the insulating layer among sides of the electrode, the rising angle represented by the inclination of slope with respect to a layer direction of the insulating layer of the electrode end, is less than or equal to allowable growth angle θ° of the organic molecule forming the organic semiconductor layer defined by the following formula (1): θ=tan(e/d) (the formula (1)), d represents a thickness of a crystal grain of the organic molecule, e represents a thickness of single layer of the organic molecule.
    • 解决的问题:提供能够简化制造工艺的同时实现高迁移率,低接触电阻,低阈值电压和低亚阈值的有机薄膜半导体器件及其制造方法 。 解决方案:有机薄膜半导体器件是底部接触型的,具有从有机半导体侧加宽到绝缘层侧的锥形斜面的电极端形成在至少绝缘层附近 电极,相对于电极端的绝缘层的层方向的倾斜倾斜度表示的上升角小于或等于容许生长角θ max 形成由下式(1)定义的有机半导体层的有机分子的角度:θ max = tan - 1 e / d)(式(1)),d表示有机分子的晶粒的厚度,e表示有机分子的单层的厚度。 版权所有(C)2012,JPO&INPIT
    • 3. 发明专利
    • Method of manufacturing organic semiconductor thin film
    • 制造有机半导体薄膜的方法
    • JP2012043926A
    • 2012-03-01
    • JP2010182945
    • 2010-08-18
    • National Institute Of Advanced Industrial & Technology独立行政法人産業技術総合研究所
    • HASEGAWA TATSUOMINEMAWARI HIROMIYAMADA JUICHIMATSUI HIROYUKI
    • H01L21/368C09D11/00H01L29/786H01L51/05H01L51/40
    • PROBLEM TO BE SOLVED: To provide a method of manufacturing an organic semiconductor thin film which is homogeneous in the film quality and film thickness and then homogeneous with extremely less pin hole including a peripheral edge part in a certain decided area when the organic semiconductor thin film comprising single-component organic molecules is manufactured by a printing method.SOLUTION: The method of manufacturing the organic semiconductor thin film includes: a step of preparing a first ink obtained by dissolving an organic semiconductor into an organic solvent having high affinity at a high concentration for the organic semiconductor and a second ink comprising the organic solvent having low affinity for the organic semiconductor; and a step of discharging the first and second inks simultaneously or alternately from each ink head and mixing them on a substrate.
    • 要解决的问题:提供一种制造有机半导体薄膜的方法,该有机半导体薄膜在膜质量和膜厚度方面是均匀的,然后在具有特定决定区域的包括周边边缘部分的极少的针孔时均匀,当有机 通过印刷法制造包含单组分有机分子的半导体薄膜。 解决方案:制造有机半导体薄膜的方法包括:制备通过将有机半导体溶解在有机半导体的高浓度的高亲和力的有机溶剂中而获得的第一油墨的步骤和包含有机半导体的第二油墨的步骤 对有机半导体具有低亲和力的有机溶剂; 以及从每个墨头同时或交替地排出第一和第二墨水并将它们混合在基底上的步骤。 版权所有(C)2012,JPO&INPIT
    • 6. 发明专利
    • Evaluation method of organic thin film transistor
    • 有机薄膜晶体管的评估方法
    • JP2013004637A
    • 2013-01-07
    • JP2011132799
    • 2011-06-15
    • National Institute Of Advanced Industrial & Technology独立行政法人産業技術総合研究所Fuji Electric Co Ltd富士電機株式会社
    • HASEGAWA TATSUOMATSUI HIROYUKITSUTSUMI JUNYAYAMADA JUICHIKANAI NAOYUKI
    • H01L21/336H01L29/786H01L51/05
    • PROBLEM TO BE SOLVED: To provide an evaluation method of an organic thin film transistor capable of observing the microscopic aspect of the electrical charge state in the channel region of an organic thin film transistor, and capable of capturing a change in electrical charge density due to a defect such as charge trap.SOLUTION: In the evaluation method of an organic thin film transistor having a gate electrode, a source electrode, a drain electrode, a gate insulating film layer, and an organic semiconductor layer, and in which the electrical charge state in a channel region defined by the electrodes is controlled by a voltage applied via the electrodes, a modulation voltage oscillating with time by a rectangular wave or a sine wave is applied via the electrodes, the channel region is irradiated with laser light and the transmitted light thereof is obtained, the intensity of transmitted light (T) when the modulation voltage is high, and a value (ΔT) obtained by subtracting the intensity of transmitted light when the modulation voltage is low from the intensity of transmitted light (T) are measured, and then the electrical charge density distribution of the channel region is determined based on these values (T and ΔT).
    • 要解决的问题:为了提供能够观察有机薄膜晶体管的沟道区域中的电荷状态的微观方面并且能够捕获电荷变化的有机薄膜晶体管的评估方法 由于诸如电荷陷阱的缺陷导致的密度。 解决方案:在具有栅电极,源电极,漏电极,栅绝缘膜层和有机半导体层的有机薄膜晶体管的评估方法中,其中沟道中的电荷状态 由电极限定的区域由通过电极施加的电压进行控制,经由电极施加随时间被矩形波或正弦波振荡的调制电压,通过激光照射通道区域并获得透射光 ,调制电压高时的透射光强度(T)和从透射光强度(T)减去调制电压为低时的透射光强度而得到的值(ΔT),然后, 基于这些值(T和ΔT)确定通道区域的电荷密度分布。 版权所有(C)2013,JPO&INPIT
    • 7. 发明专利
    • Organic semiconductor device
    • 有机半导体器件
    • JP2006237271A
    • 2006-09-07
    • JP2005049759
    • 2005-02-24
    • National Institute Of Advanced Industrial & Technology独立行政法人産業技術総合研究所
    • TAKAHASHI YUKIHIROHASEGAWA TATSUOABE YASUSHITOKURA YOSHINORI
    • H01L29/786H01L21/28H01L51/05
    • PROBLEM TO BE SOLVED: To realize an organic semiconductor device which has high performance and is provided with an electrode operating as p-type and an electrode operating n-type in a single organic semiconductor layer.
      SOLUTION: The organic semiconductor device is provided with at least two kinds of electrodes 2, 3, 4, and 5 that can efficiently implant electrons and positive holes to an organic semiconductor layer 40, and that are comprised of a conductive charge-transfer complex that is made by the combination of an electron donative material and an electron-accepting molecular material; and that can efficiently implant electrons and another conductive charge-transfer complex that has a different combination of constituent molecular and can efficiently implant positive holes.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 解决的问题:为了实现具有高性能的有机半导体器件,并且在单个有机半导体层中设置有作为p型工作的电极和n型工作的电极。 解决方案:有机半导体器件设置有至少两种电极2,3,4和5,其可以有效地将有机半导体层40的电子和正空穴注入,并且由导电的电荷 - 通过电子供体材料和电子接受分子材料的组合制成的转移络合物; 并且可以有效地注入电子和另一导电电荷转移络合物,其具有不同组成分子的组合并可以有效地注入正孔。 版权所有(C)2006,JPO&NCIPI
    • 8. 发明专利
    • Organic semiconductor device
    • 有机半导体器件
    • JP2006049578A
    • 2006-02-16
    • JP2004228575
    • 2004-08-04
    • National Institute Of Advanced Industrial & Technology独立行政法人産業技術総合研究所
    • HASEGAWA TATSUOTAKAHASHI YUKIHIROABE YASUSHITOKURA YOSHINORI
    • H01L51/05H01L21/28H01L21/285H01L21/288H01L21/336H01L21/8238H01L27/08H01L27/092H01L29/786H01L51/50
    • PROBLEM TO BE SOLVED: To provide an electrode for realizing an n-type organic transistor having high mobility and an organic semiconductor device using electrons as carriers and having high performance.
      SOLUTION: The problem is solved by the organic semiconductor device. The organic semiconductor device has at least an organic semiconductor layer 40. The organic semiconductor device further has at least electrodes 2 and 3 forming a conductive charge transfer complex, by combining an electron donative molecular material with an electron acceptable molecular material having an ionizing energy the same as or similar to a molecular material constituting an organic semiconductor in the electrodes or parts of the electrodes on the sides brought into contact with the organic semiconductor, for improving the injection efficiency of electrons to the organic semiconductor as the electrodes constituting electrical contacts with the organic semiconductor layer.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种用于实现具有高迁移率的n型有机晶体管的电极和使用电子作为载体并具有高性能的有机半导体器件。 解决方案:问题由有机半导体器件解决。 有机半导体器件至少具有有机半导体层40.有机半导体器件至少具有形成导电电荷转移络合物的电极2和3,通过将给电子分子材料与具有电离能的电子可接受分子材料组合 与构成与有机半导体接触的侧面的电极或电极的部分中的构成有机半导体的分子材料相同或类似,为了提高电子与有机半导体的接触的注入效率,因为与 有机半导体层。 版权所有(C)2006,JPO&NCIPI
    • 10. 发明专利
    • Manufacturing method for organic semiconductor device
    • 有机半导体器件的制造方法
    • JP2007305807A
    • 2007-11-22
    • JP2006133068
    • 2006-05-11
    • National Institute Of Advanced Industrial & Technology独立行政法人産業技術総合研究所
    • HASEGAWA TATSUOHIRAOKA MAKIYAMADA JUICHITOKURA YOSHINORI
    • H01L29/786H01L21/28H01L21/288H01L21/336H01L51/05H01L51/30H01L51/40
    • PROBLEM TO BE SOLVED: To make possible the creation of an electrode used for organic semiconductor devices by the solution process of an organic metal thin film, even though there are used conductive charge transferring complex materials whose solutions are formed hardly due to their generally low solubilities in solvents.
      SOLUTION: A manufacturing method for organic semiconductor devices includes a process for forming an organic semiconductor layer, and a process for forming a conductive charge transferring complex electrode on a portion of the organic semiconductor layer. In the formation of the conductive charge transferring complex electrode, electron donating molecules and electron accepting molecules are solved respectively in different organic solvents from each other to obtain two kinds of inks, and to make them react by discharging them simultaneously or alternately from their respective ink heads.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了有可能通过有机金属薄膜的溶液处理来形成用于有机半导体器件的电极,即使使用导电电荷转移复合材料,其解决方案几乎不由于它们的形成 在溶剂中通常溶解度低。 解决方案:有机半导体器件的制造方法包括形成有机半导体层的工艺,以及在有机半导体层的一部分上形成导电电荷转移复电极的工艺。 在导电电荷转移复电极的形成中,给电子分子和电子接受分子分别溶解在不同的有机溶剂中以获得两种油墨,并使它们通过从它们各自的油墨同时或交替地排出而反应 头。 版权所有(C)2008,JPO&INPIT