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    • 1. 发明授权
    • Silver halide photographic material
    • 卤化银照相材料
    • US4916053A
    • 1990-04-10
    • US245922
    • 1988-09-16
    • Naoto OhshimaToshiaki HayakawaShunji Takada
    • Naoto OhshimaToshiaki HayakawaShunji Takada
    • G03C1/34G03C1/035G03C1/053
    • G03C1/053G03C1/035
    • A negative-tupe silver halide photographic material is provided, having high sensitivity and good graininess with low fog. The material has at least one silver halide emulsion layer on a support, wherein chemically-sensitized silver halide grains contained in the emulsion of said emulsion layer comprise normal crystalline grains, and said emulsion layer containing said normal crystalline silver halide grains contains a polymer having a repeating unit represented by formula (I): ##STR1## wherein R.sub.1 represents a hydrogen atom or an alkyl group; Q represents one group selected from formulae (i), (ii), (iii), and (iv); ##STR2## wherein q is an integer of from 2 to 4; ##STR3## wherein R.sup.2 and R.sup.3 each represents a hydrogen atom or an alkyl group; ##STR4## wherein Z.sup.1 represents an atomic group forming a lactam ring, an oxazolidone ring, or a pyridone ring;A represents a single bond, ##STR5## B represents --O-- or ##STR6## wherein R.sup.4 represents a hydrogen atom or an alkyl group; and l is an integer of from 1 to 6; and ##STR7## wherein a has the same meaning as defined for formula (iii);D represents a single bond, --O-- or ##STR8## wherein R.sup.5 represents a hydrogen atom, an alkyl group, or ##STR9## wherein R.sup.6 represents an alkyl group; andm and n each represents an integer of from 1 to 6, provided that the sum of m and n is an integer of from 4 to 7.
    • 提供了一种负型卤化银照相材料,具有高灵敏度和低雾度的良好颗粒感。 所述材料在载体上具有至少一个卤化银乳剂层,其中包含在所述乳剂层的乳液中的化学增感卤化银颗粒包含正常晶粒,并且含有所述正常结晶卤化银颗粒的所述乳剂层含有具有 由式(I)表示的重复单元:其中R 1表示氢原子或烷基; Q表示选自式(i),(ii),(iii)和(iv)中的一个; (i)其中q是2至4的整数; (ⅱ)其中R2和R3各自表示氢原子或烷基; (iii)其中Z1表示形成内酰胺环的原子团,恶唑烷酮环或吡啶酮环; A表示单键,图像B表示-O-或,其中R 4表示氢原子或烷基; 且l为1至6的整数; (iv)其中a具有与式(iii)所定义相同的含义; D表示单键,-O-或,其中R5表示氢原子,烷基或者其中R6表示烷基; m和n各自表示1〜6的整数,条件是m和n的和为4〜7的整数。
    • 2. 发明授权
    • Silver halide photographic light sensitive materials
    • 卤化银照相感光材料
    • US4668614A
    • 1987-05-26
    • US917318
    • 1986-10-10
    • Shunji TakadaNaoto OhshimaShingo Ishimaru
    • Shunji TakadaNaoto OhshimaShingo Ishimaru
    • G03C1/005G03C1/035G03C1/08
    • G03C1/035G03C2001/03535G03C2001/03558
    • An improvement in silver halide photographic light-sensitive materials having at least one silver halide emulsion layer on a support is disclosed. The improvement is that chemically sensitized silver halide grains contained in at least one of the emulsion layers have a distinct stratiform structure having substantially two parts comprising an inside core part and a shell part of the uppermost layer, wherein the inside core part of said grains is composed of silver halide containing 10 to 45% by mol of silver iodide, the shell part of the uppermost layer of the grains is composed of silver halide containing 5% by mol or less of silver iodide, and the emulsion containing silver halide grains having the distinct stratiform structure have an average silver iodide content of 7% by mol or more. The materials have high sensitivity, low fog and excellent graininess.
    • 公开了在载体上具有至少一个卤化银乳剂层的卤化银照相感光材料的改进。 改善的是,至少一个乳剂层中包含的化学增感的卤化银颗粒具有明显的层状结构,其基本上包括两个部分,其包含内部芯部分和最上层的壳部分,其中所述颗粒的内部核心部分 由含有10〜45摩尔%碘化银的卤化银构成,粒子的最上层的壳部由含有5摩尔%以下的碘化银的卤化银构成,含有卤化银粒子的乳液 不同的层状结构的平均碘化银含量为7摩尔%以上。 材料灵敏度高,雾度低,颗粒性好。
    • 7. 发明授权
    • Color photographic light-sensitive material and method of developing the
same
    • 彩色摄影感光材料及其开发方法
    • US4960689A
    • 1990-10-02
    • US201406
    • 1988-06-02
    • Toshihiro NishikawaShunji TakadaKazunori Hasebe
    • Toshihiro NishikawaShunji TakadaKazunori Hasebe
    • G03C7/26G03C1/035G03C1/06G03C7/30G03C7/392
    • G03C7/39236
    • A silver halide color photographic light-sensitive material includes a support having thereon at least one silver halide emulsion layer, wherein the emulsion layer contains a silver halide emulsion which comprises silver halide grains consisting of at least 50 mol % of silver chloride and contains at least one of the compounds represented by formulas [I] to [III]: ##STR1## wherein Z represents alkyl (the number of carbon atoms is 1 to 18), aryl (the number of carbon atom is 6 to 18), or heterocyclic,Y represents an atom group required for forming heterocyclic or aryl (the number of carbon atoms of the aryl is 6 to 18),M represents metal cation, organic cation, or hydrogen atom, andn represents an integer from 2 to 10.A silver halide color photographic light-sensitve material includes a support having thereon at least one silver halide emulsion layer, wherein the emulsion layer contains a silver halide emulsion which comprises silver grains consisting of at least 50 mol % of a chloride and chemically sensitized in the presence of at least one of the compounds represented by formulas [I] to [III].A method of developing a silver halide color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, characterized in that said emulsion layer contains a silver halide emulsion which comprises silver halide grains consisting of at least 50 mol % of silver chloride and contains at least one of the compounds represented by formulas [I] to [III], and that the method comprises the steps of: color-developing the silver halide color photographic light-sensitive material in the presence of a color coupler; and desilverizing the silver halide color photographic light-sensitive material.
    • 9. 发明授权
    • Highly-sensitive high-contrast photographic materials
    • 高度敏感的高对比度感光材料
    • US4241164A
    • 1980-12-23
    • US949480
    • 1978-10-10
    • Hiroyuki MifuneShunji TakadaYoshitaka AkimuraNobuo Sakai
    • Hiroyuki MifuneShunji TakadaYoshitaka AkimuraNobuo Sakai
    • C07C67/00C07C241/00C07C243/28C07C243/38C07C253/00C07C255/57G03C1/06G03C1/08G03C1/10G03C1/28G03C5/30
    • C07C243/00C07C243/38G03C1/061G03C1/28Y10S430/15
    • A silver halide photographic material providing very high contrast and negative image photographic characteristics comprising a support having thereon at least one silver halide photographic emulsion layer containing substantially surface latent image type mono-dispersed silver halide grains and providing a negative image, at least one hydrophilic colloid layer of the photographic material containing a compound represented by the general formula (I)R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an aryl group and R.sup.2 represents a hydrogen atom, a phenyl group, or an unsubstituted alkyl group having 1 to 3 carbon atoms; and a compound represented by the general formula (II) or (III) ##STR1## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6, which may be the same or different, each represents a hydrogen atom, an alkyl group which may be substituted, an aryl group which may be substituted, an amino group which may be substituted, a hydroxyl group, an alkoxy group, an alkylthio group, a carbamoyl group which may be substituted, a halogen atom, a cyano group, a carboxyl group, an alkoxycarbonyl group, or a heterocyclic group; wherein R.sup.3 and R.sup.4 or R.sup.4 and R.sup.5 may combine and form a 5-membered or 6-membered ring and at least one of R.sup.3 and R.sup.5 represents a hydroxyl group.
    • 提供非常高的对比度和负影像照相特征的卤化银照相材料,包括其上具有至少一个含有基本上表面潜影型单分散卤化银颗粒并提供负像的卤化银照相乳剂层的载体,至少一种亲水胶体 含有通式(I)R1NHNHCOR2(I)表示的化合物的照相材料层,其中R1表示芳基,R2表示氢原子,苯基或未取代的碳原子数1〜3的烷基; 和由通式(II)或(III)表示的化合物,其中可以相同或不同的R 3,R 4,R 5和R 6各自表示氢原子, 可以被取代的烷基,可以被取代的芳基,可以被取代的氨基,羟基,烷氧基,烷硫基,可被取代的氨基甲酰基,卤素原子,氰基 基团,羧基,烷氧基羰基或杂环基; 其中R3和R4或R4和R5可以组合并形成5元或6元环,并且R 3和R 5中的至少一个表示羟基。
    • 10. 发明授权
    • Contrasty light-sensitive silver halide material containing a hydrazine
derivative and a heterocyclic mercaptan
    • 含有肼衍生物和杂环硫醇的感光卤化银材料
    • US4166742A
    • 1979-09-04
    • US841855
    • 1977-10-13
    • Hiroyuki MifuneShunji TakadaYoshitaka AkimuraTadao Shishido
    • Hiroyuki MifuneShunji TakadaYoshitaka AkimuraTadao Shishido
    • C07C255/57C07C67/00C07C241/00C07C243/28C07C243/38C07C253/00G03C1/06G03C1/09G03C1/28
    • G03C1/061G03C1/09Y10S430/15
    • A silver halide photographic light-sensitive material containing at least one negative image silver halide photographic emulsion layer comprising silver halide grains that have an average grain size of not more than about 0.7 .mu. and are substantially of the surface latent image type and containing a binder in an amount of not more than about 250 g per mol of silver halide, and containing a compound represented by the following general formula (I):r.sup.1 nhnhcor.sup.2 (i)wherein R.sup.1 represents an aryl group; and R.sup.2 represents a hydrogen atom, a phenyl group or an unsubstituted alkyl group having 1 to 3 carbon atoms; in at least one of the hydrophilic colloid layers, and a compound represented by the following general formula (II) or (III): ##STR1## wherein Y represents a sulfur atom, a selenium atom, an oxygen atom, a nitrogen atom or a divalent residue; --NR.sup.4 --, wherein R.sup.4 represents a hydrogen atom, an alkyl group or an aryl group; Z represents an atomic group required for completing a 5- or 6-membered heterocyclic ring; R.sup.5 and R.sup.6, which may be the same or different, each represents a hydrogen atom, a halogen atom, a carboxy group, an alkoxycarbonyl group, an alkyl group, an aryl group, a hydroxy group, a mercapto group or an alkylthio group or R.sup.5 and R.sup.6 may combine and represent an atomic group required for forming a 5- or 6-membered ring; m is 0 or 1, m being 0 where Y represents a sulfur atom, a selenium atom or an oxygen atom; and R.sup.3 represents a hydrogen atom, an alkylthiocarbonyl group or a moiety of the formula: ##STR2## wherein Y, Z, R.sup.5, R.sup.6 and m are each as described above; in the same or a different hydrophilic colloid layer.
    • 一种卤化银照相感光材料,其含有至少一种负型图像卤化银照相乳剂层,其包含平均粒径不超过约0.7μm的卤化银颗粒,并且基本上具有表面潜影型并且含有粘合剂 每摩尔卤化银不超过约250g,并含有由以下通式(I)表示的化合物: