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    • 9. 发明专利
    • SEPARATION AND PURIFICATION OF GAS
    • JP2000317245A
    • 2000-11-21
    • JP12775899
    • 1999-05-07
    • NIPPON STEEL CORP
    • TAKEDA TAKUWAKAMURA OSAMUKOSUGE KATSUSHIYUKI YOSHIYUKI
    • B01D53/04C10K1/32
    • PROBLEM TO BE SOLVED: To efficiently operate a PSA process, to enhance the throughput and recovery rate while restraining a raise in cost and to conduit efficient and safe operation. SOLUTION: When an inflammable component comprising hydrocarbons and/or H2 is recovered from a gaseous starting material mainly comprising the inflammable component and a noninflammable component comprising CO2 and/or N2, at least three adsorption towers and an adsorbent having pore size between molecular diameters of the inflammable component and the noninflammable component are used so that a cycle comprising an adsorption step, a pressure-reducing step, a desorption step and a pressurizing step is carried out at each adsorption tower while postponing the cycle time. It is preferable that the exhaust gas at the pressure-reducing step is supplied to the adsorption step as a recycle gas together with the gaseous starting material and that the desorption step is carried out after carrying out a washing step using the gas exhausted at the desorption step as a washing gas after the pressure-reducing step is ended. It is also preferable that a pressure-equalizing step is carried out by connecting the tower where the adsorption step is ended to the tower where the desorption step is ended. According to this method, a high calorie town gas can be steadily supplied from a coke furnace gas, etc.
    • 10. 发明专利
    • METHOD FOR RECOVERING HIGH-PURITY GASEOUS CO OR CO2 FROM GASEOUS MIXTURE
    • JPH06170144A
    • 1994-06-21
    • JP32574492
    • 1992-12-04
    • NIPPON STEEL CORP
    • KAWAMURA YASUSHIKOSUGE KATSUSHIHIGUCHI TOSHIYA
    • B01D53/04C01B32/40C01B32/50C01B31/18C01B31/20
    • PURPOSE:To efficiently recover high-purity gaseous CO or CO2, from a gaseous mixture having low gas concentration by adding a pressure equalization stage common to the pressure equalization stage of the other adsorption tower to an operation process having the respective stages of pressurizing, adsorption, washing and desorption of the adsorption tower. CONSTITUTION:In a first time cycle, pressure equalization before pressurizing an adsorption tower A is made common to pressure equalization before washing an adsorption tower C as a first pressure equalization stage. Pressure equalization after desorbing an adsorption tower B is made common to pressure equalization after washing the adsorption tower C as a second pressure equalization stage. Further in a second time cycle, pressure equalization before pressurizing the adsorption tower B is made common to pressure equalization before washing the adsorption tower A. Pressure equalization after desorbing the adsorption tower C is made common to pressure equalization after washing the adsorption tower A. Furthermore in a third time cycle, pressure equalization before pressurizing the adsorption tower C is made common to pressure equalization before washing the adsorption tower B. Pressure equalization after desorbing the adsorption tower A is made common to pressure equalization after washing the adsorption tower B.