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1. 发明申请

WO1998009936A1 METHOD OF PURIFYING GLYOXYLIC ESTERS AND DISTILLATION EQUIPMENT FOR PURIFYING GLYOXYLIC ESTERS 审中-公开
标题翻译：净化葡萄糖酵母和蒸馏设备的方法
公开(公告)号：WO1998009936A1
公开(公告)日：1998-03-12
申请号：PCT/JP1997003043
申请日：1997-08-29
申请人： NIPPON SHOKUBAI CO., LTD. , BABA, Hideyuki , MIURA, Satoru , NONOGUCHI, Masanori , SAITO, Noboru
发明人： NIPPON SHOKUBAI CO., LTD.
IPC分类号： C07C69/67
CPC分类号： C07C67/54 , C07C69/716
摘要： A method of purifying glyoxylic esters which comprises the step of continuous crude distillation of crude glyoxylic esters in a filmy state in the presence of water and the step of azeotropic dehydration of the crude glyoxylic esters thus purified in the presence of an azeotropic agent such as propyl acetate, thus permitting high-purity glyoxylic esters to be prepared efficiently, readily and at a low cost.
摘要翻译：一种净化乙醛酸酯的方法，其包括在水存在下连续粗蒸馏粗乙醛酸酯的步骤，以及在共沸剂如丙基的存在下如此纯化的粗乙醛酸酯的共沸脱水步骤乙酸酯，从而容易且低成本地制备高纯度乙醛酸酯。

2. 发明申请

WO1998005420A1 WATER-ABSORBENT AND PROCESS FOR PREPARING THE SAME 审中-公开
标题翻译：吸水剂及其制备方法
公开(公告)号：WO1998005420A1
公开(公告)日：1998-02-12
申请号：PCT/JP1997002706
申请日：1997-08-05
申请人： NIPPON SHOKUBAI CO., LTD. , YANASE, Toru , KIMURA, Kazuki , FUJINO, Shin-ichi , NAGASUNA, Kinya , ISHIZAKI, Kunihiko , FUJIMARU, Hirotama , HARADA, Nobuyuki
发明人： NIPPON SHOKUBAI CO., LTD.
IPC分类号： B01J20/26
CPC分类号： A61L15/60 , B01J20/26 , C08F8/00 , C08F8/44 , C08F2800/20 , C08F2810/20 , C08F220/06
摘要： A hydrous gel polymer prepared by polymerizing a monomer component containing acrylic acid (or a salt thereof) is post-neutralized so that each polymer particle derived from a polymer prepared by neutralizing the hydrous gel polymer has an acceptable degree of neutralization. Thereafter, the polymer prepared by neutralizing the hydrous gel polymer is reacted with a cross-linking agent reactive with the functional groups contained in the polymer. The acceptable degree of neutralization refers to, for example, a degree of neutralization which is at most 20 mol % lower than the average degree of neutralization of the agglomerate of the polymer particles or a degree of neutralization which exceeds at least 55 mol % of the average degree of polymerization of the agglomerate of the polymer particles. The post-neutralization is conducted so that, among 200 particles of the polymer, the number of polymer particles having an unacceptable degree of neutralization outside the obove range of the acceptable degree of neutralization is 10 or less. The water-absorbent thus prepared has a high absorption ratio under ordinary or high pressure, is reduced in the water-solubles content as compared with the conventional water-absorbent, and causes no significant change in the pH of swollen gel.
摘要翻译：通过聚合含有丙烯酸（或其盐）的单体组分制备的含水凝胶聚合物被后中和，使得衍生自通过中和含水凝胶聚合物制备的聚合物的每个聚合物颗粒具有可接受的中和度。此后，通过中和含水凝胶聚合物制备的聚合物与与聚合物中包含的官能团反应的交联剂反应。可接受的中和度是指例如比聚合物粒子的凝聚体的平均中和度低20摩尔％以上的中和度或超过聚合物粒子的至少55摩尔％的中和度聚合物颗粒的附聚物的平均聚合度。进行后中和，使得在聚合物的200个颗粒中，在可接受的中和度的超出范围之外具有不可接受的中和度的聚合物颗粒的数量为10以下。如此制备的吸水剂在常压或高压下具有高吸收比，与常规吸水剂相比，水溶性物质的含量降低，并且不会引起溶胀凝胶的pH的显着变化。

3. 发明申请

WO1997050015A1 SPACER FOR LIQUID CRYSTAL DISPLAY PANELS, METHOD OF MANUFACTURING THE SAME, AND LIQUID CRYSTAL DISPLAY PANEL 审中-公开
标题翻译：用于液晶显示面板的间隔件，其制造方法和液晶显示面板
公开(公告)号：WO1997050015A1
公开(公告)日：1997-12-31
申请号：PCT/JP1997002183
申请日：1997-06-24
申请人： NIPPON SHOKUBAI CO., LTD. , SAKAI, Yasuhiro , TAKASAKI, Shinji , SASAKI, Yoshikuni , KURAMOTO, Shigefumi
发明人： NIPPON SHOKUBAI CO., LTD.
IPC分类号： G02F01/1339
CPC分类号： G02F1/13392 , G02F1/1339
摘要： A spacer (1A) for liquid crystal display panels which is rarely coagulated when the spacer is dry-sprayed on a substrate (110), a method of manufacturing the same, and a liquid crystal display panel provided with the spacers (1A). The spacer (1A) comprises a particle having an average diameter of 0.5-25 mu m, a coefficient of variation of particle diameter of not more than 10 % and a fluidity of not less than 30 %. This spacer (1A) preferably has a charge retention rate, determined 5 minutes after the corona charging, of not less than 40 %.
摘要翻译：一种用于液晶显示面板的间隔物（1A），其在间隔物被干燥喷涂在基底（110）上时很少凝固，其制造方法和具有间隔物（1A）的液晶显示面板。间隔物（1A）包含平均直径为0.5〜25μm，粒径变化系数为10％以下且流动性为30％以上的粒子。该间隔物（1A）优选在电晕充电5分钟后具有不小于40％的电荷保持率。

4. 发明申请

WO1997033942A1 UNSATURATED POLYESTER RESIN COMPOSITION AND SHEETLIKE MOLDING MATERIAL 审中-公开
标题翻译：不饱和聚酯树脂组合物和薄片成型材料
公开(公告)号：WO1997033942A1
公开(公告)日：1997-09-18
申请号：PCT/JP1997000673
申请日：1997-03-05
申请人： NIPPON SHOKUBAI CO., LTD.
发明人： NIPPON SHOKUBAI CO., LTD. , KAWANO, Takaaki , YAGI, Hirofumi , YAMAMOTO, Takashi , MAEDA, Sizuko
IPC分类号： C08L67/06
CPC分类号： C08J5/18 , C08J2325/06 , C08J2367/06 , C08L25/06 , C08L67/06 , C08L2666/14 , C08L25/00
摘要： An unsaturated polyester resin composition is prepared by blending an unsaturated polyester resin having a hydrogenated bisphenol skeleton with a shrinkage lowering agent comprising a three-dimensional styrene polymer and a viscosity depressant. This composition is inhibited from shrinkage both in curing and in cooling after molding. Thus, the composition can give molded articles excellent in surface smoothness, gloss and so on.
摘要翻译：通过将具有氢化双酚骨架的不饱和聚酯树脂与包含三维苯乙烯聚合物和降粘剂的收缩降低剂共混来制备不饱和聚酯树脂组合物。该成分在成型后的固化和冷却中被抑制。因此，组合物可以赋予表面平滑性，光泽度等优异的成型体。

5. 发明申请

WO1997019136A1 MOLDING MATERIAL COMPOSITION, MOLDING MATERIAL CONTAINING THE COMPOSITION, AND PROCESS FOR PRODUCING THE MATERIAL 审中-公开
标题翻译：成型材料组合物，包含该组合物的成型材料以及生产该材料的方法
公开(公告)号：WO1997019136A1
公开(公告)日：1997-05-29
申请号：PCT/JP1996003156
申请日：1996-10-28
申请人： NIPPON SHOKUBAI CO., LTD. , TAKABATAKE, Kouji , HAYASHI, Katsura , UTIKOSHI, Yoshinori
发明人： NIPPON SHOKUBAI CO., LTD.
IPC分类号： C08L101/00
CPC分类号： C08L101/00 , B29C70/502 , C08F283/01 , C08K5/092
摘要： A molding material composition comprising a resin composition such as an unsaturated polyester, a succinic acid derivative and a thickener such as magnesium oxide, wherein the water content is regulated to be within the range of 0.1 to 0.45 wt. %; and a molding material comprising the above composition and reinforcing fibers such as glass fibers and having a water content regulated to be within the range of 0.1 to 0.4 wt. %. The molding material composition is, as shown in the figure, reduced in initial thickening caused by the thickener, thus exhibiting excellent viscosity characteristics. Further, the composition is lowered in surface tackiness, though the viscosity of the composition after thickening is lower than that of the prior art. The composition has high fluidity and excellent impregnation properties, while it causes such a rapid viscosity increase after impregnation that it can be thickened in a time shorter than that of the prior art.
摘要翻译：包含树脂组合物如不饱和聚酯，琥珀酸衍生物和增稠剂如氧化镁的成型材料组合物，其中水含量被调节在0.1至0.45重量％的范围内。％; 以及包含上述组合物的成型材料和玻璃纤维等增强纤维，其水分含量在0.1〜0.4重量％的范围内。％。如图所示，成型材料组合物由增稠剂引起的初始增稠减少，因此表现出优异的粘度特性。此外，尽管组合物在增稠后的粘度低于现有技术，但组合物的表面粘性降低。该组合物具有高流动性和优异的浸渍性能，而在浸渍之后其引起这种快速的粘度增加，使得其可以在比现有技术更短的时间内变稠。

6. 发明申请

WO1997014498A1 ADSORBENT AND METHOD FOR ADSORBING SURFACTANT AND CARRIER FOR SURFACTANT 审中-公开
标题翻译：用于吸附表面活性剂和载体的吸附剂和方法
公开(公告)号：WO1997014498A1
公开(公告)日：1997-04-24
申请号：PCT/JP1996003014
申请日：1996-10-17
申请人： NIPPON SHOKUBAI CO., LTD. , SHIOJI, Shorbu , GOMI, Tomoki , NAMBA, Takashi
发明人： NIPPON SHOKUBAI CO., LTD.
IPC分类号： B01J20/26
CPC分类号： B01J20/26 , C08F8/00 , C08F2800/10 , C08F2810/20 , C08F20/00 , C08F220/04 , C08F2220/286
摘要： An adsorbent and adsorbing method which enable a surfactant to be easily, inexpensively and satisfactorily recovered and removed from a surfactant-containing solution, such as waste water. Adsorbents usable herein include, for example, a cross-linked polymer having a polyoxyalkylene chain. The surfactant is adsorbed by bringing the adsorbent having the above constitution into contact with the solution. The cross-linked polymer is particularly preferably one prepared by cross-linking a polyalkylene glycol or one prepared by polymerizing a monomer component containing a (meth)acrylic ester monomer represented by the following general formula: CH2 = CR-CO-(X )n-Y wherein R represents hydrogen or methyl; X represents oxyalkylene having 1 to 5 carbon atoms; Y represents hydrogen, alkoxy having 1 to 5 carbon atoms, phenoxy, or oxyalkylphenyl having 1 to 3 alkyl groups with 1 to 9 carbon atoms as substituents; and n is a positive number of 8 to 100 on the average.
摘要翻译：一种使表面活性剂容易，廉价，令人满意地回收并从含有表面活性剂的溶液（例如废水）中除去的吸附剂和吸附方法。可用于本文的吸附剂包括例如具有聚氧化烯链的交联聚合物。通过使具有上述结构的吸附剂与溶液接触来吸附表面活性剂。交联聚合物特别优选通过交联聚亚烷基二醇或通过聚合含有由以下通式表示的（甲基）丙烯酸酯单体的单体组分制备的交联聚合物：CH 2 = CR-CO-（X <1） >）nY 1其中R表示氢或甲基; X 1表示具有1至5个碳原子的氧化烯; Y 1表示氢，具有1至5个碳原子的烷氧基，苯氧基或具有1至3个碳原子数1〜3的烷基的氧烷基苯基作为取代基; n是平均8到100的正数。

7. 发明申请

WO1997011978A1 RAW MATERIAL FOR THE PRODUCTION OF HEAT-RESISTANT RESIN, HEAT-RESISTANT RESIN AND PROCESS FOR THE PRODUCTION OF THE RESIN 审中-公开
标题翻译：用于生产耐热树脂，耐热树脂和生产树脂的方法的原料
公开(公告)号：WO1997011978A1
公开(公告)日：1997-04-03
申请号：PCT/JP1996002763
申请日：1996-09-25
申请人： NIPPON SHOKUBAI CO., LTD. , KANTO, Teruyuki , UEDA, Kenichi , FUJIOKA, Kazumi , KISHINO, Kazuo
发明人： NIPPON SHOKUBAI CO., LTD.
IPC分类号： C08F222/40
CPC分类号： C08F220/18 , C08F222/40
摘要： N-Cyclohexylmaleimide having a cyclohexylaminosuccinic anhydride content of 0.001 to 1 wt.% is used as the main raw material for the production of heat-resistant resins. The resins are produced by a process of copolymerizing the above material with at least one monomer copolymerizable therewith which is characterized by the use of a monomer having a low yellowness, the addition of a compound which can inhibit the evaporation of the non-radical compounds contained in the monomer through reactions, the addition of an antioxidant, the use of a solvent containing alcohol, or the presence of a non-radical-polymerizable acid anhydride or carboxylic acid. The heat-resistant resins produced by the use of the above raw material or the above process are excellent in transparency, i.e., less discolorable, even when an increased amount of N-cyclohexylmaleimide is used for the purpose of imparting more excellent heat resistance. Accordingly, the heat-resistant resins can be suitably used in the fields necessitating both a low discolorability and a high heat resistance.
摘要翻译：使用环己基氨基琥珀酸酐含量为0.001〜1重量％的N-环己基马来酰亚胺作为生产耐热树脂的主要原料。树脂通过使上述材料与至少一种可与其共聚的单体共聚而成，其特征在于使用具有低黄度的单体，加入可抑制所含非自由基化合物蒸发的化合物在单体通过反应中，加入抗氧化剂，使用含醇的溶剂，或存在非自由基聚合性酸酐或羧酸。通过使用上述原料或上述方法制造的耐热性树脂，即使使用增加量的N-环己基马来酰亚胺来赋予更优异的耐热性，透明性也不易变色。因此，耐热树脂可以适用于需要低变色性和高耐热性的领域。

8. 发明申请

WO1997000295A1 CARBON BLACK GRAFT POLYMER, PROCESS FOR THE PRODUCTION OF THE POLYMER AND USE THEREOF 审中-公开
标题翻译：碳黑玻璃聚合物，生产聚合物的方法及其用途
公开(公告)号：WO1997000295A1
公开(公告)日：1997-01-03
申请号：PCT/JP1996001645
申请日：1996-06-14
申请人： NIPPON SHOKUBAI CO., LTD. , IKEDA, Hayato , ANDO, Nobuyuki , ASAKO, Yoshinobu , ANAN, Kazuhiro , MATSUDA, Tatsuhito , ARAKAWA, Motohiro , OHTSUKI, Nobuaki , AWAJI, Toshio , TORIBUCHI, Hironobu , KUSHINO, Mitsuo , UEHARA, Keiichi , MORI, Yoshikuni
发明人： NIPPON SHOKUBAI CO., LTD.
IPC分类号： C09C01/56
CPC分类号： B41M5/385 , C08F292/00 , C08K9/08 , C09D11/324 , G02F1/133512 , G03C7/12 , G03F7/0007 , G03F7/0388 , G03G9/08786 , G03G9/0904 , G03G9/122 , Y10T428/2989 , Y10T428/2998
摘要： A carbon black graft polymer that is prepared by mixing a block or graft polymer comprising a segment (A) having groups reactive with the functional groups present on the surface of carbon black and a segment (B) having a skeletal structure different from that of the segment (A) with carbon black under heating and is excellent in the dispersibility in various media, pigmentation and light screening properties. A graft polymer produced by further incorporating an ethylenically unsaturatred double bond and/or a carbonyl group into the graft chain of the above graft polymer exhibits also photosensitivity, alkali developability, insulating characteristics or the like, thus being useful as a black photo-curable resin composition suitable for forming the black matrix of a color filter.
摘要翻译：通过混合包含具有与存在于炭黑表面上的官能团反应的基团的链段（A）的嵌段或接枝聚合物和具有不同于碳黑的骨架结构的链段（B）而制备的炭黑接枝聚合物片段（A）加热炭黑，在各种介质中的分散性优异，色素沉着和遮光性能优异。通过在上述接枝聚合物的接枝链中进一步掺入烯键式不饱和双键和/或羰基而生产的接枝聚合物还具有光敏性，碱显影性，绝缘特性等，因此可用作黑色光固化树脂适用于形成滤色器的黑矩阵的组合物。

9. 发明申请

WO1996023822A1 WATER-SOLUBLE POLYMER, PROCESS FOR PRODUCING THE SAME, AND DETERGENT COMPOSITION COMPRISING WATER-SOLUBLE POLYMER 审中-公开
标题翻译：水溶性聚合物，其制造方法和包含水溶性聚合物的洗涤剂组合物
公开(公告)号：WO1996023822A1
公开(公告)日：1996-08-08
申请号：PCT/JP1996000222
申请日：1996-02-02
申请人： NIPPON SHOKUBAI CO., LTD. , YAMAGUCHI, Shigeru , MAEDA, Yoshihiro , NISHIBAYASHI, Hideyuki
发明人： NIPPON SHOKUBAI CO., LTD.
IPC分类号： C08F283/06
CPC分类号： C11D3/3757 , C08F283/02 , C08F283/06 , C11D3/3707 , C11D3/3715 , C08F222/04 , C08F220/06
摘要： A water-soluble polymer having a gelation resistance of not more than 0.16 and another water-soluble polymer having a capability of trapping calcium ions of not less than 40 mg CaCO3/g and a gelation resistance of not more than 1.5, both prepared by polymerizing a polyester compound with a monomer component containing an ethylenically unsaturated monomer. These polymers are prepared by reacting a polyester compound with a monomer component comprising an ethylenically unsaturated monomer and an unsaturated dicarboxylic acid monomer and are used as a detergent builder and the like.
摘要翻译：具有不高于0.16的耐凝胶性的水溶性聚合物和具有捕获不少于40mg CaCO 3 / g的钙离子和不高于1.5的凝胶电阻的能力的另一种水溶性聚合物，均通过聚合具有含有烯属不饱和单体的单体成分的聚酯化合物。这些聚合物通过使聚酯化合物与包含烯属不饱和单体和不饱和二羧酸单体的单体组分反应制备，并用作洗涤剂助洗剂等。

10. 发明申请

WO1996022827A1 DEODORANT MATERIAL, PROCESS FOR PRODUCING THE SAME, AND METHOD OF DEODORIZATION 审中-公开
标题翻译：除臭材料，其制造方法，以及去除方法
公开(公告)号：WO1996022827A1
公开(公告)日：1996-08-01
申请号：PCT/JP1996000140
申请日：1996-01-24
申请人： NIPPON SHOKUBAI CO., LTD.
发明人： NIPPON SHOKUBAI CO., LTD. , KITAGUCHI, Shinya , YAMAMOTO, Koichi , MIYAKE, Junichi
IPC分类号： B01D53/38
CPC分类号： B01D53/48 , B01D53/54 , B01J23/8986
摘要： A deodorant material comprising a deodorant component supported on a carrier material mainly comprising activated carbon, wherein the deodorant component comprises 0.5-10 parts by weight (in terms of CuO) of copper oxide, 1-20 parts by weight (in terms of MnO2) of manganese oxide and 1-20 parts by weight (in terms of AgNO3) of silver nitrate, and the total content of copper oxide, manganese oxide and silver nitrate accounts for 3-30 wt.% of the deodorant material as a whole. The material has an excellent performance of eliminating various malodorous components, such as a hydrogen sulfide, mercaptans, ammonia and amines, contained in gases.
摘要翻译：一种除臭剂材料，其包含负载在主要包含活性炭的载体材料上的除臭剂组分，其中所述除臭剂组分包含0.5-10重量份（以CuO换算）的氧化铜，1-20重量份（以MnO 2换算）的氧化锰和1-20重量份（以AgNO 3换算）的硝酸银，氧化铜，氧化锰和硝酸银的总含量占整个除臭材料的3-30重量％。该材料具有消除气体中所含的各种恶臭成分如硫化氢，硫醇，氨和胺的优异性能。

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