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    • 3. 发明授权
    • Mass spectrometer and mass spectrometry method for analyzing compounds
contained in a solution
    • 用于分析溶液中所含化合物的质谱仪和质谱法
    • US6114693A
    • 2000-09-05
    • US299638
    • 1999-04-27
    • Atsumu HirabayashiYukiko HirabayashiMinoru SakairiYasuaki TakadaTakayuki NabeshimaHideaki Koizumi
    • Atsumu HirabayashiYukiko HirabayashiMinoru SakairiYasuaki TakadaTakayuki NabeshimaHideaki Koizumi
    • G01N27/62G01N27/447G01N30/72H01J49/04H01J49/10
    • G01N30/7266H01J49/0468H01J49/167
    • A mass spectrometer comprising a passage through which a sample solution flows, the passage including a capillary having an open tip, the sample solution flowing through the capillary out of the open tip of the capillary, a gas passage which forms a gas flow around the open tip of the capillary, the gas flow spraying the sample solution flowing out of the open tip of the capillary, a first electrode which contacts the sample solution flowing in the passage and applies an electric potential to the sample solution flowing in the passage, a second electrode disposed around the capillary near the open tip of the capillary, the second electrode being downstream from the first electrode with respect to a direction in which the sample solution flows in the passage, there being no gap extending downstream from the open tip of the capillary to the second electrode in a direction in which the sample solution flows out of the open tip of the capillary, the second electrode being electrically isolated from the sample solution flowing in the capillary and applying an electric field to the sample solution flowing in the capillary, and an analyzer which analyzes a mass of gaseous ions formed from the sample solution sprayed by the gas flow.
    • 一种质谱仪,包括样品溶液流过的通道,所述通道包括具有开口尖端的毛细管,所述样品溶液从毛细管的开口尖端流过毛细管,气体通道围绕开口形成气流 毛细管的尖端,气流喷射从毛细管的开口尖端流出的样品溶液,第一电极,其接触在通道中流动的样品溶液,并向在通道中流动的样品溶液施加电位,第二电极 设置在毛细管附近的毛细管周围的电极,第二电极相对于样品溶液在通道中流动的方向从第一电极下游,在毛细管的开口尖端的下游没有间隙 在样品溶液从毛细管的开口尖端流出的方向到第二电极,第二电极是电隔离的 从在毛细管中流动的样品溶液流出并向在毛细管中流动的样品溶液施加电场,以及分析器,其分析由气流喷射的样品溶液形成的气态离子的质量。
    • 7. 发明授权
    • Ion source and mass spectrometer instrument using the same
    • 离子源和质谱仪使用相同
    • US6147347A
    • 2000-11-14
    • US328664
    • 1999-06-09
    • Atsumu HirabayashiMinoru SakairiYasuaki TakadaHideaki KoizumiKaoru Umemura
    • Atsumu HirabayashiMinoru SakairiYasuaki TakadaHideaki KoizumiKaoru Umemura
    • H01J49/04H01J49/24B01D59/44G01N27/26H01J49/00
    • H01J49/045
    • A mass spectrometer includes a sample passage through which a sample solution flows towards a tip of the sample passage, a gas passage which produces a gas flow along the sample passage towards an orifice of the gas passage, a gas supplier which supplies a gas to the gas passage so that the gas flow has a velocity effective for spraying the sample solution near the tip of the sample passage, and an analyzer which analyzes a mass of gaseous ions formed from the sample solution sprayed by the gas flow. The gas flow has a characteristic value F/S between 350 meters/second (m/s) and 700 m/s, where F is a flow rate of the gas at standard conditions (20.degree. C., 1 atmosphere), and S is a difference between a cross section of the orifice and a cross section of the sample passage at the orifice. An exposed length of the sample passage between an external opening of the orifice and the tip of the sample passage may be between -0.25 mm and 1.2 mm.
    • 质谱仪包括样品通道,样品溶液通过该样品通道流向样品通道的尖端,气体通道,其沿着样品通道朝向气体通道的孔口产生气流;气体供应器,其向 气体通道使得气流具有用于喷射样品通道末端附近的样品溶液的速度,以及分析器,其分析由气流喷射的样品溶液形成的气态离子的质量。 气体流量在350米/秒(m / s)和700m / s之间具有特征值F / S,其中F是在标准条件(20℃,1个大气压)下气体的流速,S 是孔口的横截面和孔口处的样品通道的横截面之间的差异。 在孔的外部开口和样品通道的尖端之间的样品通道的暴露长度可以在-0.25mm和1.2mm之间。
    • 9. 发明授权
    • Ion source and mass spectrometer instrument using the same
    • 离子源和质谱仪使用相同
    • US07645983B2
    • 2010-01-12
    • US10139241
    • 2002-05-07
    • Atsumu HirabayashiMinoru SakairiYasuaki TakadaHideaki KoizumiKaoru Umemura
    • Atsumu HirabayashiMinoru SakairiYasuaki TakadaHideaki KoizumiKaoru Umemura
    • H01J49/00
    • H01J49/045
    • An ion source includes a body having a gas passage and an orifice. A capillary is inserted into the gas passage so that a tip portion of the capillary extends into the orifice. A gas supplier supplies a gas into the gas passage to form a gas flow through the gas passage along the capillary and through the orifice past a tip of the capillary so that the gas flow sprays a sample solution flowing through the capillary from the tip of the capillary. A flow controller regulates a pressure of the gas in the gas passage to adjust a characteristic value F/S to a predetermined value, where F is a flow rate of the gas flow at standard conditions (20° C., 1 atmosphere), and S is a difference between a cross section of the orifice and a cross section of the tip portion of the capillary in the orifice.
    • 离子源包括具有气体通道和孔的主体。 毛细管插入到气体通道中,使得毛细管的尖端部分延伸到孔中。 气体供应商将气体供应到气体通道中以形成沿着毛细管的气体通道的气流,并且通过孔经过毛细管的尖端,使得气流从其中的尖端喷射流过毛细管的样品溶液 毛细管。 流量控制器调节气体通道中的气体的压力,以将特征值F / S调节到预定值,其中F是在标准条件(20℃,1个大气压)下气流的流量,以及 S是孔口的截面与孔口中的毛细管的尖端部分的横截面之间的差异。