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1. 发明授权

US4386017A Preparation of improved catalyst composition 失效
标题翻译：改进的催化剂组合物的制备
公开(公告)号：US4386017A
公开(公告)日：1983-05-31
申请号：US205594
申请日：1980-11-10
申请人： Tadasi Nakamura , Minoru Osugi , Yoriko Obata , Shuji Ebata
发明人： Tadasi Nakamura , Minoru Osugi , Yoriko Obata , Shuji Ebata
IPC分类号： C07C29/15 , B01J23/80 , C07B61/00 , C07C27/00 , C07C29/154 , C07C31/04 , C07C67/00 , B01J23/08 , B01J21/02 , B01J27/24
CPC分类号： B01J23/80 , C07C29/154 , Y02P20/52
摘要： A process for preparing a catalyst composition comprising copper oxide, zinc oxide and aluminum oxide as essential ingredients and optionally containing boron oxide, which comprises(a) a step of precipitating from an aqueous solution of a water-soluble copper salt optionally containing a water-soluble boron compound the copper component, together with the boron component if it is present, using an alkaline substance selected from alkali carbonates and alkali bicarbonates as a precipitant;(b) a step of blowing carbon dioxide gas into an aqueous dispersion of a zinc compound selected from zinc oxide and zinc hydroxide optionally containing a water-soluble boron compound to convert the zinc compound to basic zinc carbonate and simultaneously precipitate the boron component if it is present; and(c) a step of calcining a mixture of the solid products obtained in steps (a) and (b) in the presence of an alumina precursor compound.The resulting catalyst is useful for synthesizing methanol from a gaseous mixture of carbon monoxide and/or carbon dioxide and hydrogen.
摘要翻译：一种制备包含氧化铜，氧化锌和氧化铝作为必要成分并任选地含有氧化硼的催化剂组合物的方法，其包括（a）从任选含有水溶性铜盐的水溶性铜盐的水溶液中沉淀出的步骤，使用选自碱金属碳酸盐和碱金属碳酸氢盐的碱性物质作为沉淀剂，将铜组分与硼组分一起存在; （b）将任选含有水溶性硼化合物的锌化合物的锌化合物的水分散体吹入二氧化碳气体的步骤，将锌化合物转化为碱式碳酸锌，同时使硼成分沉淀存在; 和（c）在氧化铝前体化合物的存在下煅烧步骤（a）和（b）中获得的固体产物的混合物的步骤。所得催化剂可用于从一氧化碳和/或二氧化碳和氢气的气体混合物合成甲醇。

2. 发明授权

US4547482A Catalyst composition suited for synthesis of methanol 失效
标题翻译：适用于合成甲醇的催化剂组合物
公开(公告)号：US4547482A
公开(公告)日：1985-10-15
申请号：US515933
申请日：1983-07-20
申请人： Minoru Osugi , Tadasi Nakamura , Shuji Ebata
发明人： Minoru Osugi , Tadasi Nakamura , Shuji Ebata
IPC分类号： C07C29/15 , B01J27/16 , B01J27/18 , C07B61/00 , C07C27/00 , C07C29/153 , C07C29/154 , C07C31/04 , C07C67/00 , B01J23/80
CPC分类号： B01J27/1817 , C07C29/153 , Y02P20/52
摘要： A catalyst composition comprising copper oxide, zinc oxide and an oxyacid of phosphorus or its salt; and a method for producing methanol by reacting carbon monoxide and/or carbon dioxide with hydrogen in the vapor phase in the presence of a catalyst, wherein the catalyst is the aforesaid catalyst composition which has been activated by reduction with a hydrogen-containing gas.
摘要翻译：包含氧化铜，氧化锌和磷或其盐的含氧酸的催化剂组合物; 以及在催化剂存在下，使气相中的一氧化碳和/或二氧化碳与氢气反应生成甲醇的方法，其中催化剂是通过用含氢气体还原而活化的上述催化剂组合物。

3. 发明授权

US4305842A Preparation of improved catalyst composition 失效
标题翻译：改进的催化剂组合物的制备
公开(公告)号：US4305842A
公开(公告)日：1981-12-15
申请号：US119778
申请日：1980-02-08
申请人： Kazuo Asakawa , Yasuo Yamamoto , Shuji Ebata , Tadasi Nakamura
发明人： Kazuo Asakawa , Yasuo Yamamoto , Shuji Ebata , Tadasi Nakamura
IPC分类号： C07C29/15 , B01J23/80 , B01J37/03 , C07B61/00 , C07C27/00 , C07C29/154 , C07C31/04 , C07C67/00 , B01J21/02 , B01J27/24
CPC分类号： B01J23/80 , B01J37/03 , C07C29/154 , Y02P20/52
摘要： A process for preparing a catalyst composition containing a copper oxide, a zinc oxide and an aluminum oxide as essential components and, if desired, containing a boron oxide, which comprises the following steps:(a) a step of precipitating from an aqueous solution of a water-soluble copper salt, which solution, if desired, may contain a water-soluble boron compound, a copper component, together with a boron component if the boron compound is present, with the use of ammonium carbonate or ammonium bicarbonate as a precipitant;(b) a step of precipitating from an aqueous solution of a water-soluble zinc salt, which solution, if desired, may contain a water-soluble boron compound, a copper component, together with a boron component if the boron compound is present, with the use of an alkali hydroxide as a precipitant; and(c) a step of calcing a mixture of the precipitates obtained in the steps (a) and (b) in the presence of an alumina precursor compound.The catalyst thus obtained is useful in synthesizing methanol from a mixed gas comprising carbon monoxide and/or carbon dioxide and hydrogen.
摘要翻译：一种制备含有氧化铜，氧化锌和氧化铝作为必要组分的催化剂组合物的方法，以及如果需要，含有氧化硼，其包括以下步骤：（a）从水溶液中沉淀如果需要，该溶液可以含有水溶性硼化合物，铜组分，如果存在硼化合物则与硼组分一起使用，使用碳酸铵或碳酸氢铵作为沉淀剂 ; （b）从水溶性锌盐的水溶液中析出的步骤，如果需要，该溶液可以含有水溶性硼化合物，铜成分以及含硼化合物的硼成分，使用碱性氢氧化物作为沉淀剂; 和（c）在氧化铝前体化合物的存在下压制步骤（a）和（b）中得到的沉淀物的混合物的步骤。由此获得的催化剂可用于从包含一氧化碳和/或二氧化碳和氢气的混合气体中合成甲醇。

4. 发明授权

US07179945B2 High-selective production method of di(aminomethyl)-substituted aromatic compound 有权
标题翻译：二（氨基甲基）取代芳族化合物的高选择性生产方法
公开(公告)号：US07179945B2
公开(公告)日：2007-02-20
申请号：US10781884
申请日：2004-02-20
申请人： Yoshinori Kanamori , Shuji Ebata , Kengo Tsukahara , Yoshiaki Yamamoto
发明人： Yoshinori Kanamori , Shuji Ebata , Kengo Tsukahara , Yoshiaki Yamamoto
IPC分类号： C07C211/00
CPC分类号： C07C253/30 , C07C209/48 , C07C211/27 , C07C211/30 , C07C255/58
摘要： A di(aminomethyl)-substituted aromatic compound is produced by a two-stage hydrogenation. In the first stage, an aromatic dinitrile is hydrogenated into a cyano(aminomethyl)-substituted aromatic compound in the presence of a Pd-containing catalyst. The resultant cyano(aminomethyl)-substituted aromatic compound is then hydrogenated in the second stage into the target di(aminomethyl)-substituted aromatic compound in the presence of a Ni- and/or Co-containing catalyst. By the above method, the di(aminomethyl)-substituted aromatic compound is produced in a high selectivity and a sufficiently high yield without reducing the catalyst life.
摘要翻译：二（氨基甲基）取代的芳族化合物是通过两阶段氢化制备的。在第一阶段中，在含Pd催化剂的存在下，将芳族二腈氢化为氰基（氨基甲基）取代的芳族化合物。然后将所得的氰基（氨基甲基）取代的芳香族化合物在Ni-和/或含Co催化剂存在下，在第二阶段中氢化成目标二（氨基甲基） - 取代的芳族化合物。通过上述方法，在不降低催化剂寿命的情况下以高选择性和足够高的产率制备二（氨基甲基）取代的芳族化合物。

5. 发明授权

US07161021B2 Process for producing a polynitrile compound 有权
标题翻译：腈化合物的制备方法
公开(公告)号：US07161021B2
公开(公告)日：2007-01-09
申请号：US10313022
申请日：2002-12-06
申请人： Kenichi Nakamura , Shuji Ebata , Fumio Tanaka , Takuji Shitara
发明人： Kenichi Nakamura , Shuji Ebata , Fumio Tanaka , Takuji Shitara
IPC分类号： C07C253/18 , C07C255/04
CPC分类号： C07C253/28 , C07C255/51
摘要： In a process for producing a polynitrile compound comprising introducing a polysubstituted organic compound (POC) which is a carbon ring or heterocyclic compounds having a plurality of organic substituents into a reactor with ammonia and a gas containing oxygen and ammoxidizing POC in the presence of a catalyst, at least a portion of the unreacted POC and a mononitrile compound of an intermediate product in the reaction gas discharged from the reactor is separated, recovered and recycled to the reactor so that the flow rate of the mononitrile compound at the outlet of the reactor is 2 to 16% by mole of the total flow rate of POC and the mononitrile compound supplied to the reactor.Burning reaction of the side reaction is suppressed and the loss of POC can be decreased without adverse effects on productivity and the polynitrile compound can be obtained at a high yield.
摘要翻译：在制备多腈化合物的方法中，包括在催化剂存在下，将具有多个有机取代基的多取代有机化合物（POC）或具有多个有机取代基的杂环化合物引入反应器中，所述反应器具有氨和含氧气和氨氧化POC的气体，将从反应器排出的反应气体中的至少一部分未反应的POC和中间产物的单腈化合物分离，回收并再循环至反应器，使得反应器出口处的单腈化合物的流速为相对于供给到反应器的POC和单腈化合物的总流量为2〜16摩尔％。抑制副反应的燃烧反应，可以降低POC的损失，而不会对生产率产生不利影响，并且可以以高产率获得腈化合物。

6. 发明授权

US06541632B2 Process for producing heterocyclic nitriles 有权
标题翻译：制备杂环腈的方法
公开(公告)号：US06541632B2
公开(公告)日：2003-04-01
申请号：US10173619
申请日：2002-06-19
申请人： Hideaki Ogino , Takashi Okawa , Shuji Ebata , Yoshinori Kanamori
发明人： Hideaki Ogino , Takashi Okawa , Shuji Ebata , Yoshinori Kanamori
IPC分类号： C07D24124
CPC分类号： C07C253/28 , C07D213/85 , C07C255/51
摘要： A carbocyclic or heterocyclic compound, ammonia and an oxygen-containing gas are subjected to fluid catalytic reaction in vapor phase in the presence of a catalyst containing alkali metal to produce an aromatic or heterocyclic nitrile. The use of the catalyst containing a specific amount of alkali metal enables the stable production of the aromatic or heterocyclic nitrile in high yields with little change with time even when water is present in the reaction system. The use of the catalyst containing the alkali metal also enables the recycle and reuse of unreacted ammonia which is usually accompanied by water, thereby reducing production costs.
摘要翻译：在含有碱金属的催化剂存在下，将碳环或杂环化合物，氨和含氧气体在气相中进行流化催化反应以产生芳族或杂环腈。使用含有特定量的碱金属的催化剂能够以高产率稳定地生产芳族或杂环腈，即使在反应体系中存在水时也几乎不改变。使用含有碱金属的催化剂也能够再循环和再利用通常伴有水的未反应的氨，从而降低生产成本。

7. 发明授权

US4987256A Process for production of .alpha.-hydroxycarboxylic acid amide 失效
标题翻译： α-羟基羧酸酰胺的制备方法
公开(公告)号：US4987256A
公开(公告)日：1991-01-22
申请号：US550150
申请日：1990-07-09
申请人： Shuji Ebata , Hiroyuki Hirayama , Takako Uchiyama
发明人： Shuji Ebata , Hiroyuki Hirayama , Takako Uchiyama
IPC分类号： B01J23/34 , C07B61/00 , C07C231/06 , C07C235/06
CPC分类号： C07C231/065
摘要： Process for production of .alpha.-hydroxycarboxylic acid amide of the general formula (A), comprising hydrating cyanhydrin of the general formula (B) by the use of a modified manganese dioxide catalyst containing one or more of zirconium, vanadium, and tin, and an alkali metal element. ##STR1## wherein all the symbols are as defined in the appended claims.

8. 发明授权

US06429330B1 Process for producing carbocyclic nitriles 有权
标题翻译：制备碳环腈的方法
公开(公告)号：US06429330B1
公开(公告)日：2002-08-06
申请号：US09613632
申请日：2000-07-11
申请人： Hideaki Ogino , Takashi Okawa , Shuji Ebata , Yoshinori Kanamori
发明人： Hideaki Ogino , Takashi Okawa , Shuji Ebata , Yoshinori Kanamori
IPC分类号： C07C25328
CPC分类号： C07C253/28 , C07D213/85 , C07C255/51
摘要： A carbocyclic or heterocyclic compound, ammonia and an oxygen-containing gas are subjected to fluid catalytic reaction in vapor phase in the presence of a catalyst containing alkali metal to produce an aromatic or heterocyclic nitrile. The use of the catalyst containing a specific amount of alkali metal enables the stable production of the aromatic or heterocyclic nitrile in high yields with little change with time even when water is present in the reaction system. The use of the catalyst containing the alkali metal also enables the recycle and reuse of unreacted ammonia which is usually accompanied by water, thereby reducing production costs.
摘要翻译：在含有碱金属的催化剂存在下，将碳环或杂环化合物，氨和含氧气体在气相中进行流化催化反应以产生芳族或杂环腈。使用含有特定量的碱金属的催化剂能够以高产率稳定地生产芳族或杂环腈，即使在反应体系中存在水时也几乎不改变。使用含有碱金属的催化剂也能够再循环和再利用通常伴有水的未反应的氨，从而降低生产成本。

9. 发明授权

US06284893B1 Process for producing nitrile compounds 有权
公开(公告)号：US06284893B1
公开(公告)日：2001-09-04
申请号：US09742359
申请日：2000-12-22
申请人： Takuji Shitara , Takashi Okawa , Shuji Ebata , Fumisada Kosuge
发明人： Takuji Shitara , Takashi Okawa , Shuji Ebata , Fumisada Kosuge
IPC分类号： C07C25328
摘要： There is disclosed a process for producing a nitrile compounds by ammoxidation of a carbocyclic or heterocyclic compound having organic substituent(s) by reacting the compound with ammonia and an oxygen-containing gas, wherein unreacted ammonia is recovered from the reaction product gas and recycled to the reaction system.

10. 发明授权

US5587349A Process for preparing silica-titania catalyst 失效
标题翻译：制备二氧化硅 - 二氧化钛催化剂的方法
公开(公告)号：US5587349A
公开(公告)日：1996-12-24
申请号：US366812
申请日：1994-12-30
申请人： Mariko Abe , Shuji Ebata , Takafumi Abe , Hirofumi Higuchi
发明人： Mariko Abe , Shuji Ebata , Takafumi Abe , Hirofumi Higuchi
IPC分类号： B01J21/06 , B01J21/08 , B01J37/03 , C07C67/08
CPC分类号： B01J21/063 , B01J21/08 , B01J37/03 , C07C67/08
摘要： A process for preparing a silica-titania catalyst by adding an acidic solution containing a silicon compound such as sodium silicate and a titanium compound such as titanium sulfate dissolved therein to a solution of a compound such as ammonium bicarbonate to bring about co-precipitation, in which the acidic solution is a highly concentrated nitric acid-acidic or sulfuric acid-acidic solution, and a ratio of the dissolved titanium compound in the acidic solution is regulated in a certain range.According to this process, a catalyst capable of exerting a high performance in an esterification reaction and the like can be efficiently obtained.
摘要翻译：一种二氧化硅 - 二氧化钛催化剂的制备方法，该方法是将含有硅化钠等硅化合物的酸性溶液和溶解在其中的硫酸钛等钛化合物的酸性溶液加入到碳酸氢铵等化合物的溶液中，进行共沉淀，酸性溶液是高浓度硝酸 - 酸性或硫酸 - 酸性溶液，并且将溶解的钛化合物在酸性溶液中的比例调节在一定范围内。根据该方法，可以有效地获得能够在酯化反应等中发挥高性能的催化剂。

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