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1. 发明授权

US06429330B1 Process for producing carbocyclic nitriles 有权
标题翻译：制备碳环腈的方法
公开(公告)号：US06429330B1
公开(公告)日：2002-08-06
申请号：US09613632
申请日：2000-07-11
申请人： Hideaki Ogino , Takashi Okawa , Shuji Ebata , Yoshinori Kanamori
发明人： Hideaki Ogino , Takashi Okawa , Shuji Ebata , Yoshinori Kanamori
IPC分类号： C07C25328
CPC分类号： C07C253/28 , C07D213/85 , C07C255/51
摘要： A carbocyclic or heterocyclic compound, ammonia and an oxygen-containing gas are subjected to fluid catalytic reaction in vapor phase in the presence of a catalyst containing alkali metal to produce an aromatic or heterocyclic nitrile. The use of the catalyst containing a specific amount of alkali metal enables the stable production of the aromatic or heterocyclic nitrile in high yields with little change with time even when water is present in the reaction system. The use of the catalyst containing the alkali metal also enables the recycle and reuse of unreacted ammonia which is usually accompanied by water, thereby reducing production costs.
摘要翻译：在含有碱金属的催化剂存在下，将碳环或杂环化合物，氨和含氧气体在气相中进行流化催化反应以产生芳族或杂环腈。使用含有特定量的碱金属的催化剂能够以高产率稳定地生产芳族或杂环腈，即使在反应体系中存在水时也几乎不改变。使用含有碱金属的催化剂也能够再循环和再利用通常伴有水的未反应的氨，从而降低生产成本。

2. 发明授权

US06541632B2 Process for producing heterocyclic nitriles 有权
标题翻译：制备杂环腈的方法
公开(公告)号：US06541632B2
公开(公告)日：2003-04-01
申请号：US10173619
申请日：2002-06-19
申请人： Hideaki Ogino , Takashi Okawa , Shuji Ebata , Yoshinori Kanamori
发明人： Hideaki Ogino , Takashi Okawa , Shuji Ebata , Yoshinori Kanamori
IPC分类号： C07D24124
CPC分类号： C07C253/28 , C07D213/85 , C07C255/51
摘要： A carbocyclic or heterocyclic compound, ammonia and an oxygen-containing gas are subjected to fluid catalytic reaction in vapor phase in the presence of a catalyst containing alkali metal to produce an aromatic or heterocyclic nitrile. The use of the catalyst containing a specific amount of alkali metal enables the stable production of the aromatic or heterocyclic nitrile in high yields with little change with time even when water is present in the reaction system. The use of the catalyst containing the alkali metal also enables the recycle and reuse of unreacted ammonia which is usually accompanied by water, thereby reducing production costs.
摘要翻译：在含有碱金属的催化剂存在下，将碳环或杂环化合物，氨和含氧气体在气相中进行流化催化反应以产生芳族或杂环腈。使用含有特定量的碱金属的催化剂能够以高产率稳定地生产芳族或杂环腈，即使在反应体系中存在水时也几乎不改变。使用含有碱金属的催化剂也能够再循环和再利用通常伴有水的未反应的氨，从而降低生产成本。

3. 发明授权

US6107510A Process for producing nitrile compound and catalyst used therefor 有权
标题翻译：制备腈化合物的方法和用于其的催化剂
公开(公告)号：US6107510A
公开(公告)日：2000-08-22
申请号：US225553
申请日：1999-01-05
申请人： Shuji Ebata , Hideaki Ogino , Takashi Okawa , Kinya Tsuji
发明人： Shuji Ebata , Hideaki Ogino , Takashi Okawa , Kinya Tsuji
IPC分类号： C07C253/28 , C07C253/00
CPC分类号： C07C253/28 , C07D213/85
摘要： There are disclosed a process for producing a nitrile compound which comprises catalytically reacting an alkyl group-substituted aromatic compound or an alkyl group-substituted heterocyclic compound with a mixed gas containing ammonia and oxygen in the presence of 1 a catalyst comprising a vanadium oxide, a chromium oxide, a boron oxide, a molybdenum oxide, and an oxide of an alkali metal or an alkaline earth metal or 2 a catalyst comprising a vanadium oxide, a chromium oxide, a boron oxide, an alkali metal oxide, and a heteropolyacid. According to the above process and by virtue of the specific catalyst, it is made possible to produce a nitrile compound having an aromatic ring or a heterocyclic ring in an extremely advantageous manner, that is, in high yield at high selectivity to the objective product.
摘要翻译：公开了一种制备腈化合物的方法，该方法包括在+ E，crc 1 + EE催化剂存在下使烷基取代的芳族化合物或烷基取代的杂环化合物与含有氨和氧的混合气体催化反应包括氧化钒，氧化铬，氧化硼，氧化钼和碱金属或碱土金属的氧化物，或+ E，crc 2 + EE，包含氧化钒，氧化铬，硼氧化物，碱金属氧化物和杂多酸。根据上述方法，通过具体的催化剂，可以非常有利地制备具有芳香环或杂环的腈化合物，即高目标产物的高选择性。

4. 发明授权

US08455677B2 Methanol dehydrogenation catalyst for producing of methyl formate and method for producing methyl formate 有权
标题翻译：用于生产甲酸甲酯的甲醇脱氢催化剂和甲酸甲酯的制备方法
公开(公告)号：US08455677B2
公开(公告)日：2013-06-04
申请号：US13121245
申请日：2009-09-14
申请人： Kenji Nakamura , Hideaki Ogino , Yoriko Obata
发明人： Kenji Nakamura , Hideaki Ogino , Yoriko Obata
IPC分类号： C07C67/40
CPC分类号： B01J23/80 , B01J27/1806 , B01J27/1817 , B01J37/031 , C07C67/40 , C07C69/06
摘要： A methanol dehydrogenating catalyst used for production of methyl formate, which contains a copper-zinc-aluminum oxide, a phosphoric acid compound, and an alkali metal bromide, wherein the catalyst has high methyl formate selectivity and excellent durability and heat resistance; and a method of producing methyl formate by using the catalyst.
摘要翻译：用于生产含有铜 - 锌 - 氧化铝，磷酸化合物和碱金属溴化物的甲酸甲酯的甲醇脱氢催化剂，其中催化剂具有高甲酸甲酯选择性和优异的耐久性和耐热性; 以及使用该催化剂生产甲酸甲酯的方法。

5. 发明申请

US20110245532A1 METHANOL DEHYDROGENATION CATALYST FOR PRODUCING OF METHYL FORMATE AND METHOD FOR PRODUCING METHYL FORMATE 有权
标题翻译：用于生产甲基丙烯酸甲酯脱氢催化剂和生产甲基丙烯酸甲酯的方法
公开(公告)号：US20110245532A1
公开(公告)日：2011-10-06
申请号：US13121245
申请日：2009-09-14
申请人： Kenji Nakamura , Hideaki Ogino , Yoriko Obata
发明人： Kenji Nakamura , Hideaki Ogino , Yoriko Obata
IPC分类号： C07C67/40 , B01J27/18
CPC分类号： B01J23/80 , B01J27/1806 , B01J27/1817 , B01J37/031 , C07C67/40 , C07C69/06
摘要： A methanol dehydrogenating catalyst used for production of methyl formate, which contains a copper-zinc-aluminum oxide, a phosphoric acid compound, and an alkali metal bromide, wherein the catalyst has high methyl formate selectivity and excellent durability and heat resistance; and a method of producing methyl formate by using the catalyst.
摘要翻译：用于生产含有铜 - 锌 - 氧化铝，磷酸化合物和碱金属溴化物的甲酸甲酯的甲醇脱氢催化剂，其中催化剂具有高甲酸甲酯选择性和优异的耐久性和耐热性; 以及使用该催化剂生产甲酸甲酯的方法。

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