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    • 1. 发明授权
    • Process for producing a nitrile compound
    • 腈化合物的制造方法
    • US07307181B2
    • 2007-12-11
    • US10865824
    • 2004-06-14
    • Kenichi NakamuraShuji EbataFumio TanakaTakuji Shitara
    • Kenichi NakamuraShuji EbataFumio TanakaTakuji Shitara
    • C07C253/24
    • C07C253/28C07C255/51
    • In a process for producing a nitrile compound comprising introducing a carbon ring or heterocyclic compound having organic substituents, ammonia and the air into a reactor and reacting the introduced compounds in the presence of a catalyst, during the reaction, a residual gas obtained after the formed nitrile compound is separated from a reaction gas discharged from the reactor is recycled to the reactor in an amount of 10 to 60% by volume based on the amount of the fresh raw material gas supplied to the reactor and the ratio of the amount by mole of molecular oxygen to the amount by mole of the organic substituent in the carbon ring or heterocyclic compound having organic substituents supplied to the reactor (O2/organic substituent) is kept within 1.5 to 7. The reaction is achieved under an advantageous condition and the nitrile compound can be produced industrially advantageously at a higher yield.
    • 在制备腈化合物的方法中,包括将具有有机取代基的碳环或杂环化合物,氨和空气引入反应器中并在催化剂存在下使引入的化合物反应,在反应过程中获得的残余气体 将从反应器排出的反应气体中分离的腈化合物以供给反应器的新鲜原料气体的量为基准,以10〜60体积%的量循环至反应器, 具有提供给反应器(O 2 2 /有机取代基)的有机取代基的碳环或杂环化合物中的有机取代基的分子氧保持在1.5〜7范围内。 在有利条件下,腈化合物可以在工业上有利地以更高的产率生产。
    • 2. 发明授权
    • Process for producing a polynitrile compound
    • 腈化合物的制备方法
    • US07161021B2
    • 2007-01-09
    • US10313022
    • 2002-12-06
    • Kenichi NakamuraShuji EbataFumio TanakaTakuji Shitara
    • Kenichi NakamuraShuji EbataFumio TanakaTakuji Shitara
    • C07C253/18C07C255/04
    • C07C253/28C07C255/51
    • In a process for producing a polynitrile compound comprising introducing a polysubstituted organic compound (POC) which is a carbon ring or heterocyclic compounds having a plurality of organic substituents into a reactor with ammonia and a gas containing oxygen and ammoxidizing POC in the presence of a catalyst, at least a portion of the unreacted POC and a mononitrile compound of an intermediate product in the reaction gas discharged from the reactor is separated, recovered and recycled to the reactor so that the flow rate of the mononitrile compound at the outlet of the reactor is 2 to 16% by mole of the total flow rate of POC and the mononitrile compound supplied to the reactor.Burning reaction of the side reaction is suppressed and the loss of POC can be decreased without adverse effects on productivity and the polynitrile compound can be obtained at a high yield.
    • 在制备多腈化合物的方法中,包括在催化剂存在下,将具有多个有机取代基的多取代有机化合物(POC)或具有多个有机取代基的杂环化合物引入反应器中,所述反应器具有氨和含氧气和氨氧化POC的气体 ,将从反应器排出的反应气体中的至少一部分未反应的POC和中间产物的单腈化合物分离,回收并再循环至反应器,使得反应器出口处的单腈化合物的流速为 相对于供给到反应器的POC和单腈化合物的总流量为2〜16摩尔%。 抑制副反应的燃烧反应,可以降低POC的损失,而不会对生产率产生不利影响,并且可以以高产率获得腈化合物。
    • 3. 发明申请
    • Process for producing a nitrile compound
    • 腈化合物的制造方法
    • US20050014944A1
    • 2005-01-20
    • US10865824
    • 2004-06-14
    • Kenichi NakamuraShuji EbataFumio TanakaTakuji Shitara
    • Kenichi NakamuraShuji EbataFumio TanakaTakuji Shitara
    • C07C253/28C07C255/51C07D213/84C07D241/02C07D333/38
    • C07C253/28C07C255/51
    • In a process for producing a nitrile compound comprising introducing a carbon ring or heterocyclic compound having organic substituents, ammonia and the air into a reactor and reacting the introduced compounds in the presence of a catalyst, during the reaction, a residual gas obtained after the formed nitrile compound is separated from a reaction gas discharged from the reactor is recycled to the reactor in an amount of 10 to 60% by volume based on the amount of the fresh raw material gas supplied to the reactor and the ratio of the amount by mole of molecular oxygen to the amount by mole of the organic substituent in the carbon ring or heterocyclic compound having organic substituents supplied to the reactor (O2/organic substituent) is kept within 1.5 to 7. The reaction is achieved under an advantageous condition and the nitrile compound can be produced industrially advantageously at a higher yield.
    • 在制备腈化合物的方法中,包括将具有有机取代基的碳环或杂环化合物,氨和空气引入反应器中并在催化剂存在下使引入的化合物反应,在反应过程中获得的残余气体 将从反应器排出的反应气体中分离的腈化合物以供给反应器的新鲜原料气体的量为基准,以10〜60体积%的量循环至反应器, 分子氧与提供给反应器的有机取代基的碳环或杂环化合物(O 2 /有机取代基)中的有机取代基的摩尔比保持在1.5〜7的范围内。在有利条件下进行反应,并且腈化合物 可以以较高的产率在工业上有利地生产。
    • 6. 发明授权
    • Barrel mounting device in cartridge-type dental injection device
    • 筒式牙科注射装置中的桶安装装置
    • US06572589B2
    • 2003-06-03
    • US10138707
    • 2002-04-30
    • Fumio TanakaYukio Kawagishi
    • Fumio TanakaYukio Kawagishi
    • A61M500
    • A61M5/24A61M5/20A61M2005/2407A61M2005/2492
    • A cartridge type dental injection device capable of easily and quickly mounting or removing a cartridge loaded barrel in or from a socket therein and capable of altering orientations of a viewing window in the barrel and of a cut surface of a needle as desired. The cartridge type dental injection device comprises a barrel (9) adapted to be inserted in a socket (5) defined by a mounting member (5a) and having diametrically oppositee viewing windows (11) formed therein, the mounting member (5a) having a plurality of circumferentially spaced apart ball retaining holes (7), and a locking ball (8) placed in each of the holes, the barrel (9) being provided with an annular groove (12) adapted to receive a portion of each locking ball therein, and a locking ring (13) having an annular cam surface (14) and a relieving surface (15) positioned adjacent to each other and movable between a position where when the locking balls (8) are in alignment with the annular groove (12), the annular cam surface (14) pushes the locking balls (8) toward the annular groove (12) to bring portions of the locking balls into engagement with the annular groove and a position where the relieving surface (15) faces the locking balls (8) to release them from the annular groove (12).
    • 一种筒式牙科注射装置,其能够容易且快速地将筒体装载在其中或从插座中移除,并且能够根据需要改变针筒中的观察窗和针的切割面的取向。筒型 牙科注射装置包括适于插入由安装构件(5a)限定的并具有形成在其中的直径对立观察窗(11)的插座(5)的筒体(9),所述安装构件(5a)具有多个周向 间隔开的球保持孔(7)和放置在每个孔中的锁定球(8),筒体(9)设置有适于容纳每个锁定球的一部分的环形槽(12),并且 锁定环(13)具有环形凸轮表面(14)和释放表面(15),该释放表面邻近彼此定位,并且可在锁定球(8)与环形槽(12)对准的位置之间移动, 环形凸轮表面处理 e(14)将锁定球(8)推向环形槽(12)以使锁定球的一部分与环形槽接合,并且释放表面(15)面向锁定球(8)释放的位置 它们来自环形槽(12)。