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1. 发明授权

US5698265A Calcium phosphate compound-cellulose fiber composite material and method for production thereof 失效
标题翻译：磷酸钙复合纤维素纤维复合材料及其制造方法
公开(公告)号：US5698265A
公开(公告)日：1997-12-16
申请号：US607885
申请日：1996-02-27
申请人： Michael Roger Mucalo , Yoshiyuki Yokogawa , Motohiro Toriyama , Yukari Kawamoto , Takahiro Suzuki , Kaori Nishizawa , Fukue Nagata , Hajime Nagae
发明人： Michael Roger Mucalo , Yoshiyuki Yokogawa , Motohiro Toriyama , Yukari Kawamoto , Takahiro Suzuki , Kaori Nishizawa , Fukue Nagata , Hajime Nagae
IPC分类号： B01J20/281 , C01B25/32 , D06M11/00 , D06M11/71 , D06M101/00 , D06M101/02 , D06M101/06 , D21C9/00 , D21H17/67 , G01N30/88 , B05D3/04
CPC分类号： D21C9/002 , D06M11/71
摘要： A method for the production of a composite consisting of cellulose fibers coated with a calcium phosphate compound consists essentially of phosphorylating the surface of cellulose fibers, immersing the surface-phosphorylated cellulose fibers in an aqueous solution containing calcium ions and hydroxyl ions, removing the cellulose fibers from the aqueous solution and subsequently immersing them in an aqueous solution containing calcium ions and phosphoric acid ions, and then removing the cellulose fibers from the aqueous solution. Also disclosed is a composite produced by the method.
摘要翻译：制备由磷酸钙化合物涂覆的纤维素纤维组成的复合材料的方法主要包括磷酸化纤维素纤维的表面，将表面磷酸化的纤维素纤维浸入含有钙离子和羟基离子的水溶液中，除去纤维素纤维然后将其浸入含有钙离子和磷酸离子的水溶液中，然后从水溶液中除去纤维素纤维。还公开了通过该方法制备的复合材料。

2. 发明授权

US5427754A Method for production of platelike hydroxyapatite 失效
标题翻译：板状羟基磷灰石的生产方法
公开(公告)号：US5427754A
公开(公告)日：1995-06-27
申请号：US174264
申请日：1993-12-28
申请人： Fukue Nagata , Yoshiyuki Yokogawa , Motohiro Toriyama , Yukari Kawamoto , Takahiro Suzuki , Kaori Nishizawa , Hajime Nagae
发明人： Fukue Nagata , Yoshiyuki Yokogawa , Motohiro Toriyama , Yukari Kawamoto , Takahiro Suzuki , Kaori Nishizawa , Hajime Nagae
IPC分类号： B01J20/281 , C01B25/32 , C30B29/14 , C30B29/64 , G01N30/88
CPC分类号： C01B25/327
摘要： A platelike hydroxyapatite is produced by preparing from a phosphate and a calcium salt an aqueous slurry of amorphous calcium phosphate having an atomic ratio of calcium atoms to phosphorus atoms in the range of 1.3:1 to 2.0:1, adding to the aqueous slurry not less than 10% by weight of alcohol based on the amount of the aqueous slurry, and subjecting the resultant mixture to a hydrothermal treatment.
摘要翻译：通过从磷酸盐和钙盐制备具有1.3:1至2.0:1的钙原子与磷原子之比的无定形磷酸钙的水性浆料制备板状羟基磷灰石，不少于相对于含水浆料的量为10重量％以上的醇，并对所得混合物进行水热处理。

3. 发明授权

US5290692A Bioadaptable porous crystalline glass containing an immobilized fibrinolytic enzyme for dissolving blood clots 失效
标题翻译：含有溶解血块的固定化纤维蛋白溶解酶的生物适应性多孔结晶玻璃
公开(公告)号：US5290692A
公开(公告)日：1994-03-01
申请号：US852539
申请日：1992-03-17
申请人： Takahiro Suzuki , Sukezo Kawamura , Motohiro Toriyama , Yoshiyuki Yokogawa , Yukari Kawamoto
发明人： Takahiro Suzuki , Sukezo Kawamura , Motohiro Toriyama , Yoshiyuki Yokogawa , Yukari Kawamoto
IPC分类号： A61K38/16 , A61K38/46 , A61K38/49 , A61K47/02 , A61K47/48 , A61L33/00 , A61P7/02 , C12N11/14 , A61K37/54
CPC分类号： A61K47/48861 , A61K38/166 , A61K38/49 , A61L33/0047 , C12N11/14
摘要： A fibrinolytic enzyme such as urokinase, tissue plasminogen activator or streptokinase is covalently bounded to a bioadaptable porous crystalline glass to produce a thrombolytic material. Production of the glass involves combining 40-50 mol% calcium oxide, 20-30 mol% titanium dioxide and 25-35 mol% diphosphorous pentoxide to form a mixture, and combining the mixture with 0.5-4.0 mol% disodium oxide. A bioreactor for converting plasminogen in blood into plasmin can be prepared by packing the material in a column. When finely comminuted, the material can be administered into the blood of a patient for removing blood clots.
摘要翻译：纤维蛋白溶解酶如尿激酶，组织纤溶酶原激活剂或链激酶与生物适应性多孔结晶玻璃共价结合以产生溶栓物质。玻璃的生产涉及组合40-50摩尔％的氧化钙，20-30摩尔％的二氧化钛和25-35摩尔％的二氧化磷二氧化物以形成混合物，并将该混合物与0.5-4.0摩尔％的二氧化钠组合。用于将血液中的纤溶酶原转化成纤溶酶的生物反应器可以通过在柱中包装材料来制备。当细粉碎时，可以将该物质施用于患者的血液中以除去血块。

4. 发明授权

US5077079A Method for formation of calcium phosphate compound coating on surface of ceramic article 失效
标题翻译：在陶瓷制品表面形成磷酸钙复合涂层的方法
公开(公告)号：US5077079A
公开(公告)日：1991-12-31
申请号：US652995
申请日：1991-02-08
申请人： Sukezo Kawamura , Yoshiyuki Yokogawa , Yukari Kawamoto , Motohiro Toriyama , Takahiro Suzuki
发明人： Sukezo Kawamura , Yoshiyuki Yokogawa , Yukari Kawamoto , Motohiro Toriyama , Takahiro Suzuki
IPC分类号： A61L27/00 , A61F2/00 , A61F2/28 , A61L27/32 , C04B41/50 , C04B41/85 , C04B41/89
CPC分类号： C04B41/009 , A61L27/32 , C04B41/5092 , C04B41/85 , A61F2310/00796 , C04B2111/00836
摘要： A dense coating of a calcium phosphate compound is formed on the surface of a bioadaptable ceramic substrate by applying to the ceramic calcium metaphosphate alone or a mixture of calcium metaphosphate with calcium pyrophosphate, heat-treating the applied layer thereby fusing the applied layer to the surface of the ceramic, then applying to the fused layer a slurry resulting from the mixture of calcium metaphosphate with tetracalcium phosphate, and subsequently heat-treating the applied layer of the slurry thereby inducing reaction of the slurry.
摘要翻译：通过将陶瓷钙偏磷酸盐或偏磷酸钙与焦磷酸钙的混合物应用于生物适应性陶瓷基材的表面上，形成致密的磷酸钙化合物涂层，对施加的层进行热处理，从而将施加的层融合到表面的陶瓷，然后向熔融层施加由偏磷酸钙与磷酸四钙的混合物产生的浆料，随后对所施加的浆料层进行热处理，从而引起浆料的反应。

5. 发明授权

US5178901A Titanium metal-coating material, method for production thereof, method for coating therewith, and product coated therewith 失效
标题翻译：钛金属涂层材料，其制造方法，涂布方法和涂覆的产品
公开(公告)号：US5178901A
公开(公告)日：1993-01-12
申请号：US618750
申请日：1990-11-27
申请人： Motohiro Toriyama , Sukezo Kawamura , Yukari Kawamoto , Yoshiyuki Yokogawa , Takahiro Suzuki
发明人： Motohiro Toriyama , Sukezo Kawamura , Yukari Kawamoto , Yoshiyuki Yokogawa , Takahiro Suzuki
IPC分类号： A61L27/00 , A61C8/00 , A61F2/00 , A61F2/30 , A61L27/32 , C01G23/00 , C03C3/21 , C03C8/08 , C23D1/02 , C23D5/02
CPC分类号： C23D5/02 , A61C8/0012 , A61F2/30767 , A61L27/32 , C03C3/21 , C03C8/08 , A61C8/0013 , A61F2310/00796
摘要： A powder for coating the surface of a titanium metal is obtained by mixing compounds as raw materials for CaO, TiO.sub.2, and P.sub.2 O.sub.5 with a small amount of a Na.sub.2 O-containing compound, fusing the resultant mixture, and solidifying and pulverizing the fused mixture. A coating of a calcium phosphate compound adhering with great fastness to the surface of the titanium metal is formed by preparing an aqueous slurry containing the powder mentioned above, applying the aqueous slurry to the surface of the titanium metal, and heat-treating the coated titanium metal.
摘要翻译：通过将化合物作为CaO，TiO 2和P 2 O 5的原料与少量含有Na 2 O的化合物混合，将所得混合物熔合并固化和粉碎熔融混合物，得到用于涂覆钛金属表面的粉末。通过制备含有上述粉末的含水浆料，将该水性浆液施加到钛金属的表面，并对该涂覆的钛进行热处理，形成具有坚固牢度的钛金属表面的磷酸钙化合物的涂层金属。

6. 发明授权

US5491082A Plasminogen activator covalently bonded to a porous body of .beta.-tricalcium phosphate 失效
标题翻译：共价键合到β-磷酸三钙的多孔体上的纤溶酶原激活物
公开(公告)号：US5491082A
公开(公告)日：1996-02-13
申请号：US246940
申请日：1994-05-20
申请人： Takahiro Suzuki , Sukezo Kawamura , Motohiro Toriyama , Yoshiyuki Yokokawa , Yukari Kawamoto , Yasuharu Hakamatsuka , Hiroyuki Irie
发明人： Takahiro Suzuki , Sukezo Kawamura , Motohiro Toriyama , Yoshiyuki Yokokawa , Yukari Kawamoto , Yasuharu Hakamatsuka , Hiroyuki Irie
IPC分类号： A61K38/00 , C12N9/72 , C12N11/14 , A61K38/48
CPC分类号： C12N9/6456 , C12N11/14 , A61K38/00
摘要： A plasminogen activator such as urokinase or tissue plasminogen activator is covalently bonded to a porous body composed of calcium phosphate to form a plasminogen activator-porous body complex. The tricalcium phosphate can be .alpha.-tricalcium phosphate, .beta.-tricalcium phosphate, hydroxyapatite, tetracalcium phosphate, octacalcium phosphate and mixtures thereof. In a preferred embodiment, .beta.-tricalcium phosphate which has excellent biocompatibility with the body or a mixture of .beta.-tricalcium phosphate and hydroxyapatite is used. Preferably, synthetic calcium phosphate is used is to avoid impurities contained by natural calcium phosphate. Covalent bonding is by crosslinking with glutaraldehyde, bismaleimides, dihalogenic aryls or diisocyanates, or by using cyanogen bromide, diazotization or periodic acid. The complex can be filled into a column to form a bioreactor. A granular complex can be intravascularly injected into the blood of a patient to provide thrombotic activity for a long period of time. In another embodiment, a complex of a predetermined shape can be implanted to provide thrombotic activity.
摘要翻译：纤维蛋白溶酶原激活剂如尿激酶或组织纤溶酶原激活剂共价键合到由磷酸钙组成的多孔体上以形成纤溶酶原激活剂多孔体复合体。磷酸三钙可以是α-磷酸三钙，β-磷酸三钙，羟基磷灰石，磷酸四钙，磷酸八钙及其混合物。在优选的实施方案中，使用与身体具有优异生物相容性的β-磷酸三钙或磷酸β-磷酸钙和羟基磷灰石的混合物。优选地，合成磷酸钙是为了避免天然磷酸钙含有的杂质。共价键是通过与戊二醛，双马来酰亚胺，二卤代芳基或二异氰酸酯交联，或通过使用溴化氰，重氮化或高碘酸进行交联。复合物可以填充到柱中以形成生物反应器。颗粒状复合物可以血管内注射到患者的血液中以长时间提供血栓形成活性。在另一个实施方案中，可以植入预定形状的复合物以提供血栓形成活性。

7. 发明授权

US5985802A High-performance lubricant oil 失效
标题翻译：高性能润滑油
公开(公告)号：US5985802A
公开(公告)日：1999-11-16
申请号：US89321
申请日：1998-06-02
申请人： Koji Watari , Hae Jin Hwang , Motohiro Toriyama , Akira Osuka , Osamu Yamamoto
发明人： Koji Watari , Hae Jin Hwang , Motohiro Toriyama , Akira Osuka , Osamu Yamamoto
IPC分类号： B23Q11/10 , C09K3/14 , C10M103/00 , C10M125/20 , C10M173/00 , C10N20/06 , C10N30/04 , C10N40/22 , C10N50/04 , C10M125/26
CPC分类号： C10M173/00 , C10M125/20 , C10M2201/00 , C10M2201/02 , C10M2201/061 , C10M2201/082 , C10M2201/083 , C10M2201/16 , C10M2201/18 , C10N2240/401 , C10N2250/02
摘要： An inexpensive high-performance cutting or grinding oil capable of significantly improving the cutting efficiency. Into a liquid component of the cutting or grinding oil are dispersed fine powders of boron nitride of hexagonal system and/or crystal line turbostratic structure, particularly crystalline turbostratic structure, having a mean particle size of primary particles not larger than 1 .mu.m.
摘要翻译：一种廉价的高性能切割或研磨油，能够显着提高切割效率。将切割或研磨油的液体成分分散为具有不大于1μm的一次粒子的平均粒径的六方晶系的氮化硼和/或晶体管涡旋结构的细粉末，特别是结晶的多孔结构。

8. 发明授权

US5902542A Method of producing silicon nitride ceramics having thermal high conductivity 失效
标题翻译：具有导热性高的氮化硅陶瓷的制造方法
公开(公告)号：US5902542A
公开(公告)日：1999-05-11
申请号：US766317
申请日：1996-12-13
申请人： Kiyoshi Hirao , Koji Watari , Motohiro Toriyama , Syuzo Kanzaki , Masaaki Obata
发明人： Kiyoshi Hirao , Koji Watari , Motohiro Toriyama , Syuzo Kanzaki , Masaaki Obata
IPC分类号： C04B35/584 , C04B35/593 , C04B35/638 , C04B35/64 , C04B35/645
CPC分类号： C04B35/5935
摘要： The present invention provides silicon nitride ceramics having high thermal conductivity and a method for production thereof. This invention relates to a method for producing a silicon nitride sintered body having a microstructure with silicon nitride crystals oriented uniaxially and exhibiting high thermal conductivity of 100 to 150 W/mK in the direction parallel to the orientation direction of the crystals, which comprises of preparing a slurry by mixing a mixed powder of a sintering auxiliary, beta-silicon nitride single crystals as seed crystals and a silicon nitride raw powder with a dispersing medium, forming the slurry by tape casting or extrusion forming, calcining the formed silicon nitride body with beta-silicon nitride single crystals oriented parallel to the casting plane to remove the organic components, densifying it by hot pressing and the like if required, and further annealing it at 1700 to 2000.degree. C. under the nitrogen pressure of 1 to 100 atmospheres.
摘要翻译：本发明提供了具有高导热性的氮化硅陶瓷及其制造方法。本发明涉及一种具有氮化硅结构的氮化硅烧结体的制造方法，该氮化硅烧结体具有在与晶体取向方向平行的方向上单轴取向并具有100〜150W / mK的高导热率的微结构，通过将烧结助剂，β-氮化硅单晶的混合粉末作为晶种和氮化硅原料粉末与分散介质混合来形成浆料，通过带状流延或挤出成型形成浆料，用β - 氮化硅单晶，其平行于铸造平面取向以去除有机组分，如果需要，通过热压等来致密化，并且在1〜100个大气压的氮气压力下，在1700〜2000℃进一步退火。

9. 发明授权

US5837633A Method for production of aluminum nitride sintered body and aluminum nitride powder 失效
标题翻译：生产氮化铝烧结体和氮化铝粉末的方法
公开(公告)号：US5837633A
公开(公告)日：1998-11-17
申请号：US741218
申请日：1996-10-29
申请人： Motohiro Toriyama , Kiyoshi Hirao , Masayoshi Ohashi , Syuzo Kanzaki , Masaaki Obata
发明人： Motohiro Toriyama , Kiyoshi Hirao , Masayoshi Ohashi , Syuzo Kanzaki , Masaaki Obata
IPC分类号： C04B35/64 , C01B21/06 , C01B21/072 , C04B35/581 , C04B35/645 , C04B35/65
CPC分类号： C04B35/581 , C01B21/0602 , C01B21/0722 , C04B35/65 , C01P2002/54 , C01P2004/03 , C01P2004/20
摘要： The present invention provides a method for producing an aluminum nitride sintered body having excellent characteristics and an aluminum nitride powder conveniently and inexpensively. The present invention relates to a method for production of an aluminum nitride sintered body comprising forming a metal aluminum power into a thin-plate like shape, heating the formed body to a temperature not exceeding the melting point of aluminum in a vacuum atmosphere, and then sintering it under N.sub.2 pressure (1-150 kg/cm.sup.2), and a method for production of an aluminum nitride powder comprising heating a metal aluminum powder to a temperature not exceeding the melting point of aluminum in a vacuum atmosphere, sintering it under N.sub.2 pressure (1-150 kg/cm.sup.2, and further cooling and pulverizing it.
摘要翻译：本发明提供一种方便且廉价地制造具有优异特性的氮化铝烧结体和氮化铝粉末的方法。本发明涉及一种氮化铝烧结体的制造方法，其特征在于，将金属铝电力形成为薄板状，在真空气氛中将成形体加热至不超过铝的熔点，然后在氮气压力（1-150kg / cm2）下烧结，以及一种生产氮化铝粉末的方法，包括在真空气氛中将金属铝粉末加热至不超过铝熔点的温度，在氮气压力下烧结（1-150kg / cm2，进一步冷却粉碎。

10. 发明授权

US4988362A Composition for coating bioceramics, method for coating bioceramics therewith, and composite bioceramics produced therewith 失效
标题翻译：用于涂覆生物陶瓷的组合物，用于涂覆生物陶瓷的方法，以及由其制备的复合生物陶瓷
公开(公告)号：US4988362A
公开(公告)日：1991-01-29
申请号：US319757
申请日：1989-03-07
申请人： Motohiro Toriyama , Sukezo Kawamura
发明人： Motohiro Toriyama , Sukezo Kawamura
IPC分类号： A61L27/00 , A61F2/00 , A61L27/12 , A61L27/32 , C12P7/08
CPC分类号： A61L27/12 , A61L27/32 , A61F2310/00293 , A61F2310/00796 , Y10S623/92
摘要： A composition produced as a result of mixing alumina, silica, and a calcium phosphate compound in a specific ratio exhibits high affinity for bioceramics. When a bioceramic is coated with this composition and the coated bioceramic is heated, the composite is fused fast with the bioceramic to produce a composition bioceramic which is active to vital tissues.
摘要翻译：通过以特定比例混合氧化铝，二氧化硅和磷酸钙化合物而生产的组合物对生物陶瓷具有高亲和力。当用该组合物涂覆生物陶瓷并且涂覆的生物陶瓷被加热时，复合材料与生物陶瓷快速熔合以产生对生物组织有活性的组合物生物陶瓷。

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