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1. 发明授权

US5026920A Obtaining alkanals having a 2-alkyl branch from alkanal mixtures 失效
标题翻译：从链烷醇混合物中获得具有2-烷基支链的链烷烃
公开(公告)号：US5026920A
公开(公告)日：1991-06-25
申请号：US433661
申请日：1989-11-08
申请人： Michael Roeper , Franz Merger , Joerg Liebe , Armin V. Grenacher , Edgar Hahl
发明人： Michael Roeper , Franz Merger , Joerg Liebe , Armin V. Grenacher , Edgar Hahl
IPC分类号： C07C47/02 , C07C45/50 , C07C45/75 , C07C45/82 , C07C45/85
CPC分类号： C07C45/82 , C07C45/50 , C07C45/75 , C07C45/85
摘要： Alkanals having a 2-alkyl branch are obtained from mixtures which contain the alkanals having a 2-alkyl branch in addition to n-alkanals, 3-alkylalkanals and/or further isomers by a process in whicha) the alkanal mixture is reacted with an aqueous formaldehyde solution in the presence of a secondary amine and of a carboxylic acid as a catalyst,b) the aqueous phase containing the catalyst and any unconverted excess formaldehyde is separated off andc) the alkanals having a 2-alkyl branch are isolated by distillation from the condensates of the other alkanals with formaldehyde.
摘要翻译：具有2-烷基支链的烷烃由含有具有2-烷基支链的亚烷基的链烷烃，3-烷基链烷醇和/或其它异构体的混合物通过以下方法获得：其中a）使所述链烷醛混合物与在仲胺和羧酸作为催化剂存在下的甲醛水溶液，b）分离含有催化剂和任何未转化的过量甲醛的水相，并且c）通过蒸馏分离具有2-烷基支链的链烷烃从其他链烷烃与甲醛的缩合物。

2. 发明授权

US4981913A Bridged, water-soluble copolymers, their preparation and their use 失效
标题翻译：桥接，水溶性共聚物，其制备及其用途
公开(公告)号：US4981913A
公开(公告)日：1991-01-01
申请号：US409747
申请日：1989-09-20
申请人： Dietmar Moench , Andreas Stange , Joerg Liebe , Heinrich Hartman , Franz Merger , Manfred Schwartz
发明人： Dietmar Moench , Andreas Stange , Joerg Liebe , Heinrich Hartman , Franz Merger , Manfred Schwartz
IPC分类号： C08C19/00 , C08F8/12 , C08F8/28 , D21H17/37
CPC分类号： C08F8/12 , C08F2800/10 , C08F2810/50
摘要： Bridged, water-soluble copolymers are obtainable by(A) copolymerization of a monomer mixture of(a) from 50 to 99 mol % of acrylamide and/or methacrylamide,(b) from 50 to 1 mol % of a monoethylenically unsaturated monomer containing actual groups and(c) from 0 to 20 mol % of monomers which differ from (a) and (b), in the presence of a polymerization initiator under conditions such that the acetal groups of the monomers (b) undergo virtually no hydrolysis,(B) hydrolysis of the acetal groups of the monomers (b), present as copolymerized units in the copolymers (A),(C) condensation of the copolymers (B) containing aldehyde groups at a pH above 5, at most to a degree such that the resulting condensates are still water-soluble and(D) stopping of the condensation reaction by adding acid until the pH reaches 3 or less,and are used as paper stock additives in papermaking for increasing the wet strength of paper.
摘要翻译：桥接的水溶性共聚物可通过（A）（a）50至99mol％的丙烯酰胺和/或甲基丙烯酰胺的单体混合物共聚获得，（b）50至1mol％的单烯属不饱和单体含有实际基团和（c）0〜20摩尔％的不同于（a）和（b）的单体，在聚合引发剂存在下，使单体（b）的缩醛基基本上不经水解的条件下， B）在共聚物（A），（C）中作为共聚单元存在的单体（b）的缩醛基团的水解在pH5以上含有醛基的共聚物（B）的缩合最多至一定程度所得缩合物仍然是水溶性的，（D）通过加入酸直到pH达到3以下停止缩合反应，并且在造纸中用作增加纸的湿强度的纸浆添加剂。

3. 发明授权

US4997955A Preparation of 1,1-disubstituted ethylene compounds 失效
标题翻译： 1,1-二取代的乙烯化合物的制备
公开(公告)号：US4997955A
公开(公告)日：1991-03-05
申请号：US205341
申请日：1988-06-10
申请人： Franz Merger , Joerg Liebe , Werner Bertleff
发明人： Franz Merger , Joerg Liebe , Werner Bertleff
IPC分类号： C07B35/06 , C07B31/00 , C07B47/00 , C07B61/00 , C07C45/00 , C07C45/61 , C07C45/66 , C07C49/647 , C07C57/13 , C07C67/00 , C07C67/327 , C07C67/42 , C07C69/533 , C07C69/593 , C07C231/00 , C07C233/47 , C07C253/00 , C07C255/07 , C07C255/31 , C07C255/34 , C07D307/33
CPC分类号： C07C255/00 , C07C253/00 , C07C253/30 , C07C45/61 , C07C49/647
摘要： 1,1-disubstituted ethylene compounds of the general formula I ##STR1## where Z is COOR.sup.2, CN or COR.sup.3, R.sup.1 is an aliphatic, cycloalophatic, araliphatic, aromatic or heterocyclic radical which may be further substituted by functional groups which are inert under the reaction conditions, R.sup.2 is an aliphatic, cycloaliphatic or araliphatic radical of 1 to 15 carbon atoms and R.sup.3 is an aliphatic, cycloaliphatic or araliphatic radical of 1 to 15 carbon atoms which may be substituted by groups which are inert under the reaction conditions, and R.sup.1 together with R.sup.2 or R.sup.1 together with R.sup.3 may furthermore form an alkylene chain of 2 to 10 carbon atoms which may be substituted by groups which are inert under the reaction conditions, are prepared from a formyl compound of the general formula II ##STR2## where Z, R.sup.1, R.sup.2 and R.sup.3 have the above meanings, by a process in which the reaction is carried out in the presence of formaldehyde or paraformaldehyde and(a) a C.sub.1 -C.sub.12 -alkanol or(b) a mixture of a C.sub.1 -C.sub.12 -alkanol and water or(c) with water in the presence of a secondary amine and a protic acidat from 0.degree. to 200.degree. C.
摘要翻译：其中Z是COOR2，CN或COR3的通式I的1,1-二取代的乙烯化合物，R 1是可以进一步被惰性的官能团取代的脂族，环状，芳脂族，芳族或杂环基团反应条件中，R 2为1至15个碳原子的脂族，脂环族或芳脂族基团，R 3为可被反应条件下为惰性基团取代的具有1至15个碳原子的脂族，脂环族或芳脂族基团，以及 R1与R 2或R 1与R 3一起可以形成可以在反应条件下为惰性的基团取代的具有2-10个碳原子的亚烷基链，其由通式II的甲酰基化合物制备其中Z，R 1，R 2和R 3具有上述含义，通过反应在甲醛或多聚甲醛存在下进行的方法和（a）C 1 -C 12烷醇或（b） C 12链烷醇和水，或（c）在0℃至200℃的仲胺和质子酸存在下与水反应。

4. 发明授权

US4672137A Preparation of 1,3-di(alkoxycarbonylamino)propanes 失效
标题翻译：制备1,3-二（烷氧基羰基氨基）丙烷
公开(公告)号：US4672137A
公开(公告)日：1987-06-09
申请号：US856971
申请日：1986-04-29
申请人： Franz Merger , Joerg Liebe
发明人： Franz Merger , Joerg Liebe
IPC分类号： C07B61/00 , B01J23/00 , B01J23/44 , B01J25/00 , B01J25/02 , C07C67/00 , C07C239/00 , C07C269/00 , C07C271/06 , C07C125/07 , C07C125/073 , C07C125/075
CPC分类号： C07C271/06
摘要： 1,3-Di(alkoxycarbonylamino)propanes of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 can be identical or different and each is hydrogen, or an aliphatic, cycloaliphatic, araliphatic or aromatic radical, and R.sup.4 is an aliphatic, cycloaliphatic or araliphatic radical, are prepared by reacting an .alpha.,.beta.-unsaturated aldehyde with a carbamic acid ester by reacting in a first stage as the .alpha.,.beta.-unsaturated aldehyde a compound of the general formula II ##STR2## where R.sup.1, R.sup.2 and R.sup.3 have the abovementioned meanings, with a carbamic acid ester of the general formula III ##STR3## where R.sup.4 has the abovementioned meanings, at 0.degree.-150.degree. C. to give a 1,1,3-tri(alkoxycarbonylamino)propane of the general formua IV ##STR4## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 have the abovementioned meanings, and in a second stage heating the compound of the general formula (IV) in the presence of a hydrogenation catalyst and hydrogen under 1-300 bar at 100.degree.-300.degree. C.
摘要翻译：通式I（I）的1,3-二（烷氧基羰基氨基）丙烷，其中R 1，R 2和R 3可以相同或不同，各自为氢，或脂族，脂环族，芳脂族或芳族基，R4为通过使α，β-不饱和醛与氨基甲酸酯反应，通过在第一阶段中作为α，β-不饱和醛与通式II的化合物（II）反应来制备脂族，脂环族或芳脂族基团）其中R 1，R 2和R 3具有上述含义，与0℃-150℃下具有上述含义的通式III（III）的氨基甲酸酯反应，得到1,1，（IV）的3-三（烷氧基羰基氨基）丙烷，其中R 1，R 2，R 3和R 4具有上述含义，在第二阶段中，在通式（Ⅳ）的化合物存在下加热通式氢化催化剂和在1-300巴下在100-300℃的氢气

5. 发明授权

US4853473A Preparation of 2(5H)-furanones 失效
标题翻译： 2（5H） - 呋喃酮的制备
公开(公告)号：US4853473A
公开(公告)日：1989-08-01
申请号：US201050
申请日：1988-06-01
申请人： Rolf Fischer , Juergen Frank , Franz Merger , Michael Roeper , Uwe Vagt
发明人： Rolf Fischer , Juergen Frank , Franz Merger , Michael Roeper , Uwe Vagt
IPC分类号： C07D315/00
CPC分类号： C07D315/00
摘要： 2(5H)-furanones I ##STR1## where R.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.5 - or C.sub.6 -cycloalkyl, C.sub.7 -C.sub.12 -aralkyl or aryl, are prepared by heating a 3-formylcarboxylate or 3-formylcarboxylic acid II ##STR2## where R.sup.3 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 - or C.sub.6 -cycloalkyl, C.sub.7 -C.sub.12 -aralkyl or aryl, to 100.degree.-450.degree. C. in the presence of an acidic catalyst.
摘要翻译： 2（5H） - 呋喃酮I（I）其中R1和R2各自为氢，C1-C6烷基，C5-或C6-环烷基，C7-C12-芳烷基或芳基，通过加热3-甲酰基羧酸酯或其中R 3为氢，C 1 -C 12 - 烷基，C 5 - 或C 6 - 环烷基，C 7 -C 12 - 芳烷基或芳基的3-甲酰基羧酸II（II）在100-450℃存在下，酸性催化剂。

6. 发明授权

US5689010A Preparation of higher aldehydes 失效
标题翻译：制备较高级的醛
公开(公告)号：US5689010A
公开(公告)日：1997-11-18
申请号：US638592
申请日：1996-04-29
申请人： Rocco Paciello , Franz Merger , Michael Roper , Heinz-Josef Kneuper
发明人： Rocco Paciello , Franz Merger , Michael Roper , Heinz-Josef Kneuper
IPC分类号： B01J31/22 , C07B61/00 , C07C45/50 , C07C45/62 , C07C45/73 , C07C45/74 , C07C47/02 , C07C47/21 , C07C45/49
CPC分类号： C07C45/50 , C07C45/62 , C07C45/74
摘要： Aldehydes with a higher number of carbon atoms and high selection are prepared by reacting olefins, in particular from petrochemical refinery products, by a hydroformylation with aldol condensation using a mixed catalyst of rhodium-carbonyl-phosphines and Mannich catalyst.
摘要翻译：通过使用铑 - 羰基膦和Mannich催化剂的混合催化剂通过使醛醇缩合的加氢甲酰化反应，使烯烃，特别是石油化学品炼油产物反应，制备具有较高碳原子数和高选择性的醛。

7. 发明授权

US5416240A Preparation of poloxy-alkylene glycols 失效
标题翻译：烷氧基 - 亚烷基二醇的制备
公开(公告)号：US5416240A
公开(公告)日：1995-05-16
申请号：US24903
申请日：1993-03-02
申请人： Hans-Juergen Weyer , Rolf Fischer , Gerhard Jeschek , Franz Merger , Herbert Mueller
发明人： Hans-Juergen Weyer , Rolf Fischer , Gerhard Jeschek , Franz Merger , Herbert Mueller
IPC分类号： C08G65/02 , C08G65/08 , C08G65/16 , C08G65/20 , C07C41/01 , C07C41/02
CPC分类号： C08G65/20
摘要： Polyoxyalkylene glycols are prepared by a process in which tetrahydrofuran is polymerized with a total of not more than 95 mol %, based on the amount of tetrahydrofuran used, of one or more comonomers from the group consisting of the cyclic ethers and acetals in the absence of water and in the presence of a monohydric alcohol or of a monocarboxylic acid with the aid of an anhydrous heteropoly acid catalyst, and the polyoxyalkylene glycol is liberated from the resulting polyoxyalkylene glycol monoethers or polyoxyalkylene glycol monoesters by cleavage of the monoether or monoester bond.
摘要翻译：聚氧亚烷基二醇通过以下方法制备，其中四氢呋喃基于所用四氢呋喃的总量不超过95摩尔％，在不存在共聚单体的情况下聚合来自由环醚和缩醛组成的组中的一种或多种共聚单体水和一元醇或单羧酸存在下，借助于无水杂多酸催化剂，通过裂解单醚或单酯键，从所得聚氧亚烷基二醇单醚或聚氧亚烷基二醇单酯中释放出聚氧亚烷基二醇。

8. 发明授权

US5268499A Preparation of mixtures of 3-aminopropionitrile and ethylene cyanohydrin 失效
标题翻译：制备3-氨基丙腈和乙烯氰醇的混合物
公开(公告)号：US5268499A
公开(公告)日：1993-12-07
申请号：US47303
申请日：1993-04-19
申请人： Franz Merger , Martin Brudermueller , Wolfgang Harder , Juergen Hartig , Dieter Franz
发明人： Franz Merger , Martin Brudermueller , Wolfgang Harder , Juergen Hartig , Dieter Franz
IPC分类号： C07C253/30
CPC分类号： C07C253/30
摘要： A process for preparing mixtures of 3-aminopropionitrile of the formula IH.sub.2 N--CH.sub.2 --CH.sub.2 --CN (I)and ethylene cyanohydrin of the formula IIHO--CH.sub.2 --CH.sub.2 --CN (II)comprises reacting bis(2-cyanoethyl) ether of the formula IIINC--CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --CN (III)with ammonia at from 50 to 170.degree. C. and under from 1 to 500 bar thermally or in the presence of a heterogeneous catalyst.
摘要翻译：制备式I H 2 N-CH 2 -CH 2 -N（I）的3-氨基丙腈和式II HO-CH2-CH2-CN（Ⅱ）的乙烯氰醇的混合物的方法包括使双（2-氰乙基）醚式III NC-CH2-CH2-O-CH2-CH2-CN（III）与氨在50至170℃下和在1至500巴下加热或在多相催化剂存在下反应。

9. 发明授权

US5256813A 3-substituted 2-hydroxy-3-formylpropionic esters, the preparation thereof and the use thereof for preparing 3-substituted 3-formylacrylic esters 失效
标题翻译： 3-取代的2-羟基-3-甲酰基丙酸酯，其制备及其用于制备3-取代的3-甲酰基丙烯酸酯的用途
公开(公告)号：US5256813A
公开(公告)日：1993-10-26
申请号：US883342
申请日：1992-05-15
申请人： Franz Merger , Juergen Frank
发明人： Franz Merger , Juergen Frank
IPC分类号： C07C69/675 , C07C69/732
CPC分类号： C07C69/675
摘要： A 3-substituted 2-hydroxy-3-formylpropionic ester of the formula I ##STR1## where R.sup.1 is lower alkyl, and R.sup.2 is straight-chain or branched alkyl of 1 to 10 carbon atoms, is obtained by adding an alkanal of the fomrula II ##STR2## and an alkyl glyoxylate of the formula III ##STR3## simultaneously to a catalyst system composed of a salt or a mixture of a secondary amine and a carboxylic acid in such a way that the temperature does not exceed 90.degree. C., preferably 80.degree. C., or else adding one of the reactants of the formula II or III to a mixture of the catalyst system described above and the other reactant in such a way that the temperature does not exceed 90.degree. C. The 2-hydroxy-3-formylpropionic eater of the formula I can be converted by treatment with dehydrating agents, especially acetic anhydride, into good yields of the corresponding 3-substituted 3-formylacrylic ester.
摘要翻译：其中R1是低级烷基，R2是具有1-10个碳原子的直链或支链烷基的式Ⅰ的3-取代的2-羟基-3-甲酰基丙酸酯是通过将烷基的II型和式III（III）的烷基乙醛酸盐同时与由仲胺和羧酸的盐或混合物组成的催化剂体系，使得温度不超过90℃，优选80℃，或者将一种式II或III的反应物加入到上述催化剂体系和另一种反应物的混合物中，使得温度不超过90℃。式I的2-羟基-3-甲酰基丙酸酯可以通过用脱水剂，特别是乙酸酐处理转化成相应3-取代的3-甲酰基丙烯酸酯的良好产率。

10. 发明授权

US5202461A 3-substituted 2-hydroxy-3-formylpropionic esters, the preparation thereof and the use thereof for preparing 3-substituted 3-formylacrylic esters 失效
标题翻译： 3-取代的2-羟基-3-甲基丙烯酸酯，其制备方法及其用于制备3-取代的3-甲基丙烯酸酯的用途
公开(公告)号：US5202461A
公开(公告)日：1993-04-13
申请号：US593891
申请日：1990-10-05
申请人： Franz Merger , Juergen Frank
发明人： Franz Merger , Juergen Frank
IPC分类号： B01J31/02 , B01J31/04 , C07B61/00 , C07C67/343 , C07C67/44 , C07C69/67 , C07C69/675
CPC分类号： C07C69/675
摘要： A 3-substituted 2-hydroxy3-formylpropionic ester of the formula I ##STR1## where R.sup.1 is lower alkyl, and R.sup.2 is straight-chain or branched alkyl of 1 to 10 carbon atoms, is obtained by adding an alkanal of the formula II ##STR2## and an alkyl glyoxylate of the formula III ##STR3## simultaneously to a catalyst system composed of a salt or a mixture of a secondary amine and a carboxylic acid in such a way that the temperature does not exceed 90.degree. C., preferably 80.degree. C., or else adding one of the reactants of the formula II or III to a mixture of the catalyst system described above and the other reactant in such a way that the temperature does not exceed 90.degree. C. The 2-hydroxy-3-formylpropionic ester of the formula I can be converted by treatment with dehydrating agents, especially acetic anhydride, into good yields of the corresponding 3-substituted 3-formylacrylic ester.
摘要翻译：通过加入式I的3-取代的2-羟基-3-甲酰基丙酸酯，其中R 1是低级烷基，R 2是1-10个碳原子的直链或支链烷基，式II（II）和式III（III）的烷基乙醛酸盐同时加入由盐或仲胺和羧酸的混合物组成的催化剂体系，使得温度不超过90℃，优选80℃，或者将一种式II或III的反应物加入到上述催化剂体系和另一种反应物的混合物中，使得温度不超过90℃ 式I的2-羟基-3-甲酰基丙酸酯可以通过用脱水剂，特别是乙酸酐处理转化成相应3-取代的3-甲酰基丙烯酸酯的良好产率。

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