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1. 发明授权

US4997955A Preparation of 1,1-disubstituted ethylene compounds 失效
标题翻译： 1,1-二取代的乙烯化合物的制备
公开(公告)号：US4997955A
公开(公告)日：1991-03-05
申请号：US205341
申请日：1988-06-10
申请人： Franz Merger , Joerg Liebe , Werner Bertleff
发明人： Franz Merger , Joerg Liebe , Werner Bertleff
IPC分类号： C07B35/06 , C07B31/00 , C07B47/00 , C07B61/00 , C07C45/00 , C07C45/61 , C07C45/66 , C07C49/647 , C07C57/13 , C07C67/00 , C07C67/327 , C07C67/42 , C07C69/533 , C07C69/593 , C07C231/00 , C07C233/47 , C07C253/00 , C07C255/07 , C07C255/31 , C07C255/34 , C07D307/33
CPC分类号： C07C255/00 , C07C253/00 , C07C253/30 , C07C45/61 , C07C49/647
摘要： 1,1-disubstituted ethylene compounds of the general formula I ##STR1## where Z is COOR.sup.2, CN or COR.sup.3, R.sup.1 is an aliphatic, cycloalophatic, araliphatic, aromatic or heterocyclic radical which may be further substituted by functional groups which are inert under the reaction conditions, R.sup.2 is an aliphatic, cycloaliphatic or araliphatic radical of 1 to 15 carbon atoms and R.sup.3 is an aliphatic, cycloaliphatic or araliphatic radical of 1 to 15 carbon atoms which may be substituted by groups which are inert under the reaction conditions, and R.sup.1 together with R.sup.2 or R.sup.1 together with R.sup.3 may furthermore form an alkylene chain of 2 to 10 carbon atoms which may be substituted by groups which are inert under the reaction conditions, are prepared from a formyl compound of the general formula II ##STR2## where Z, R.sup.1, R.sup.2 and R.sup.3 have the above meanings, by a process in which the reaction is carried out in the presence of formaldehyde or paraformaldehyde and(a) a C.sub.1 -C.sub.12 -alkanol or(b) a mixture of a C.sub.1 -C.sub.12 -alkanol and water or(c) with water in the presence of a secondary amine and a protic acidat from 0.degree. to 200.degree. C.
摘要翻译：其中Z是COOR2，CN或COR3的通式I的1,1-二取代的乙烯化合物，R 1是可以进一步被惰性的官能团取代的脂族，环状，芳脂族，芳族或杂环基团反应条件中，R 2为1至15个碳原子的脂族，脂环族或芳脂族基团，R 3为可被反应条件下为惰性基团取代的具有1至15个碳原子的脂族，脂环族或芳脂族基团，以及 R1与R 2或R 1与R 3一起可以形成可以在反应条件下为惰性的基团取代的具有2-10个碳原子的亚烷基链，其由通式II的甲酰基化合物制备其中Z，R 1，R 2和R 3具有上述含义，通过反应在甲醛或多聚甲醛存在下进行的方法和（a）C 1 -C 12烷醇或（b） C 12链烷醇和水，或（c）在0℃至200℃的仲胺和质子酸存在下与水反应。

2. 发明授权

US5003102A Preparation of 5-formylvaleric esters 失效
标题翻译： 5-甲酰戊酸酯的制备
公开(公告)号：US5003102A
公开(公告)日：1991-03-26
申请号：US206751
申请日：1988-06-15
申请人： Werner Bertleff , Rolf Fischer , Rudolf Kummer , Franz Merger , Heinz-Walter Schneider
发明人： Werner Bertleff , Rolf Fischer , Rudolf Kummer , Franz Merger , Heinz-Walter Schneider
IPC分类号： C07B61/00 , C07C67/313 , C07C69/66 , C07C69/67
CPC分类号： C07C67/347
摘要： 5-Formylvaleric esters are prepared by a process which comprises the following steps:(a) Hydroformylation of a pentenoic ester by reaction with carbon monoxide and hydrogen at elevated temperatures and under superatmospheric pressure in the presence of a carbonyl complex of a metal of group 8 of the Periodic Table with formation of a mixture of 5-, 4- and 3-formylvaleric esters,(b) Isolation of the 5-formylvaleric ester from the resulting mixture of 5-, 4- and 3-formylvaleric esters, a mixture essentially consisting of 4- and 3-formylvaleric esters remaining,(c) Cleavage of the mixture essentially consisting of 4- and 3-formylvaleric esters at from 50.degree. to 400.degree. C. in the presence of a catalyst to give pentenoic esters and(d) Recycling of the pentenoic esters to stage (a).
摘要翻译： 5-甲酰戊酸酯通过包括以下步骤的方法制备：（a）在升高的温度和超大气压下，在第8组的金属的羰基络合物存在下，通过与一氧化碳和氢气反应来进行戊烯基酯的加氢甲酰化的化合物，形成5-，4-和3-甲酰基戊酸酯的混合物，（b）从得到的5-，4-和3-甲酰基戊酸酯混合物中分离5-甲酰基戊酸酯，基本上由4-和3-甲酰基戊酸酯组成，（c）在催化剂存在下，在50-400℃下将基本上由4-和3-甲酰基戊酸酯组成的混合物切割，得到戊烯酸酯和（d ）将戊烯酸酯循环回到（a）阶段。

3. 发明授权

US4931590A Preparation of adipic acid 失效
标题翻译：己二酸的制备
公开(公告)号：US4931590A
公开(公告)日：1990-06-05
申请号：US205340
申请日：1988-06-10
申请人： Rudolf Kummer , Franz Merger , Werner Bertleff , Rolf Fischer
发明人： Rudolf Kummer , Franz Merger , Werner Bertleff , Rolf Fischer
IPC分类号： B01J31/20 , C07B61/00 , C07C51/00 , C07C51/09 , C07C55/14 , C07C67/00 , C07C67/29 , C07C67/347 , C07C67/39 , C07C69/44 , C07C69/67
CPC分类号： C07C67/347 , C07C51/09 , C07C67/39
摘要： Adipic acid is prepared by a process which comprises the following steps:(a) Hydroformylation of a pentenoic ester by reaction with carbon monoxide and hydrogen at elevated temperatures and under superatmospheric pressure in the presence of a cobalt carbonyl or rhodium carbonyl complex with formation of a mixture of 5-, 4- and 3-formylvaleric esters,(b) isolation of the 5-formylvaleric ester from the resulting mixture of 5-, 4- and 3-formylvaleric esters, a mixture essentially consisting of 4- and 3-formylvaleric esters remaining,(c) dehydrocarbonylation of the mixture consisting essentially of 4- and 3-formylvaleric esters in the presence of one or more elements of subgroup 8 of the Periodic Table at from 50.degree. to 400.degree. C. with formation of pentenoic esters, and recycling of the latter to stage (a) for hydroformylation,(d) oxidation of the 5-formylvaleric ester from stage (b) with molecular oxygen or a gas containing molecular oxygen to give a monoester of adipic acid, and(e) hydrolysis of the monoester of adipic acid to give adipic acid.
摘要翻译：己二酸通过包括以下步骤的方法制备：（a）在羰基或羰基铑羰基络合物的存在下，在一氧化碳和氢气下，在升高的温度和超大气压下与戊烯酸酯反应，加氢甲酰化形成 5-，4-和3-甲酰基戊酸酯的混合物，（b）从得到的5-，4-和3-甲酰基戊酸酯混合物中分离出5-甲酰基戊酸酯，基本上由4-甲酰基戊酰胺剩余的酯，（c）在50℃至400℃下在元素周期表第8族的一种或多种元素存在下，基本上由4-甲酰基戊酸酯组成的混合物的脱氢羰基化，形成戊烯酸酯，并将后者再循环到步骤（a）进行加氢甲酰化，（d）用分子氧或含有分子氧的气体从阶段（b）氧化5-甲酰基戊酸酯，得到己二酸的单酯，和（e）水解己二酸的单酯得到己二酸。

4. 发明授权

US06916778B1 UV absorbers with affinity for textile fiber 失效
标题翻译：对纺织纤维具有亲和力的紫外线吸收剂
公开(公告)号：US06916778B1
公开(公告)日：2005-07-12
申请号：US09926412
申请日：2000-04-17
申请人： Jürgen Detering , Werner Bertleff , Gerhard Wagenblast , Christian Ott , Elisabeth Kappes , Thorsten Habeck
发明人： Jürgen Detering , Werner Bertleff , Gerhard Wagenblast , Christian Ott , Elisabeth Kappes , Thorsten Habeck
IPC分类号： C07C235/34 , C08F8/00 , C08G73/02 , C11D3/00 , C11D3/37 , C11D3/42 , D06L3/12 , D06M13/123 , D06M13/224 , D06M13/372 , D06M13/402 , D06M13/41 , D06M13/415 , D06M13/419 , D06M13/46 , D06M15/356 , D06M15/59 , D06M15/61 , D06P5/06 , D06P5/08 , C11D3/32
CPC分类号： D06P5/08 , C07C235/34 , C08F8/00 , C08G73/0206 , C08G73/028 , C11D3/0063 , C11D3/3703 , C11D3/3715 , C11D3/3719 , C11D3/3723 , C11D3/42 , D06L4/60 , D06M13/123 , D06M13/224 , D06M13/2246 , D06M13/372 , D06M13/402 , D06M13/41 , D06M13/415 , D06M13/419 , D06M13/46 , D06M13/461 , D06M15/3562 , D06M15/59 , D06M15/61 , D06P5/06 , C08F26/02
摘要： The invention relates to the use of compounds (A) with at least one structural unit of formula (I), wherein X represents groups of formula —CR1═CR2— or a carbonyl group C═O, R1 and R2 meaning hydrogen or essentially organic radicals, Z means essentially organic radicals, n means a number from 0 to 3 and p means a number from 0 to 5, as UV absorbers with an affinity for textile fibres, for protecting the human skin from harmful UV radiation and for protecting dyed textile materials from fading.
摘要翻译：本发明涉及化合物（A）与至少一种式（I）结构单元的用途，其中X代表式-CR 1 -CR 2 - 或羰基CO，R 1和R 2表示氢或基本上有机基团，Z表示基本上有机基团，n表示0至3的数，p表示数字为0至5，作为对纺织纤维具有亲和力的紫外线吸收剂，用于保护人体皮肤免受有害紫外线辐射，并用于保护染色的纺织材料免于褪色。

5. 发明授权

US06878683B2 Polymers used as controllable dispersing agents 失效
标题翻译：聚合物用作可控分散剂
公开(公告)号：US06878683B2
公开(公告)日：2005-04-12
申请号：US10297490
申请日：2001-06-06
申请人： Peter Neumann , Werner Bertleff , Matthias Kroner , Bernard Mohr
发明人： Peter Neumann , Werner Bertleff , Matthias Kroner , Bernard Mohr
IPC分类号： C08F290/06 , C08G81/02 , C11D3/37 , C11D11/00
CPC分类号： C11D11/0082 , C11D3/3761
摘要： Polymers of a poly(meth)acrylic acid main chain in which, based on the main chain, 0 to 30% by weight of the (meth)acrylic acid basic building blocks may be replaced by maleic acid (anhydride) basic building blocks, fumaric acid basic building blocks or mixtures thereof and 0 to 10% by weight of the (meth)acrylic acid basic building blocks may be replaced by other copolymerizable ethylenic basic building blocks,and C1-30-alkylpoly-C2-4-alkylene glycols, bonded to the main chain via ester groups, having an average molecular weight of from 250 to 10 000 as side chains,where, based on the polymer, 1 to 19% by weight of the main chain and 81 to 99% by weight of the side chains are present and this ratio and the average molecular weight of the side chains are chosen such that free carboxyl groups are present in the polymer,are used as controllable dispersants for detergents or cleaners or constituents thereof.
摘要翻译：聚（甲基）丙烯酸主链的聚合物，其中以主链为基准的0〜30重量％的（甲基）丙烯酸碱性结构单元可以用马来酸（酸酐）碱性结构单元代替富马酸酸性碱性结构单元或其混合物，和0〜10重量％的（甲基）丙烯酸碱性结构单元可以被其它可共聚的烯属碱性结构单元和C1-30烷基聚-C2-4-亚烷基二醇替代，通过酯基，其平均分子量为250至10000作为侧链，其中基于聚合物，1至19重量％的主链和81至99重量％的侧面链，并且该比例和侧链的平均分子量被选择为使得游离羧基存在于聚合物中，用作洗涤剂或清洁剂或其组分的可控分散剂。

6. 发明授权

US06586010B1 Method for producing agglomerates comprising a core-shell structure 失效
标题翻译：用于生产包含核 - 壳结构的附聚物的方法
公开(公告)号：US06586010B1
公开(公告)日：2003-07-01
申请号：US09857065
申请日：2001-05-31
申请人： Werner Bertleff , Ulrich Bröckel , Helmut Fricke , Hans-Peter Harz , Reiner Witt
发明人： Werner Bertleff , Ulrich Bröckel , Helmut Fricke , Hans-Peter Harz , Reiner Witt
IPC分类号： A61K914
CPC分类号： B01J2/006
摘要： A process for producing agglomerates with a core/shell structure, in which i) initial agglomerates containing a first particulate solid are prepared; ii) a second particulate solid is agglomerated in the presence of the initial agglomerates with the addition of a binder liquid to give second stage agglomerates and, where appropriate, iii) an nth (n≧3) solid is agglomerated in the presence of the (n−1)th stage agglomerates with the addition of a binder liquid to give nth stage agglomerates.
摘要翻译：制备具有核/壳结构的附聚物的方法，其中i）含有第一颗粒固体的初始附聚物; ii）第二颗粒固体在初始附聚物存在下与添加粘合剂液体一起凝聚，得到第二阶段附聚物，并且在适当情况下，iii）第n（n> = 3）固体在存在（n-1）级附聚物，加入粘合剂液体以产生第n级附聚物。

7. 发明授权

US5043487A Preparation of octadienols 失效
标题翻译：辛二烯醇的制备
公开(公告)号：US5043487A
公开(公告)日：1991-08-27
申请号：US547813
申请日：1990-07-02
申请人： Alfred Thome , Werner Bertleff
发明人： Alfred Thome , Werner Bertleff
IPC分类号： B01J31/24 , C07B61/00 , C07C29/36 , C07C33/02
CPC分类号： C07C29/36
摘要： Octadienols are prepared by reacting 1,3-butadiene with water in the presence of a catalyst system comprising a palladium compound, a triorganophosphorus compound and carbon dioxide and in the additional presence of a triorganophosphine oxide.
摘要翻译：在包含钯化合物，三有机磷化合物和二氧化碳的催化剂体系的存在下，以及另外存在三有机膦氧化物的情况下，通过使1,3-丁二烯与水反应制备辛二烯醇。

8. 发明授权

US4894474A Preparation of alkyl pentenoates 失效
标题翻译：戊烯酸烷基酯的制备
公开(公告)号：US4894474A
公开(公告)日：1990-01-16
申请号：US225823
申请日：1988-07-29
申请人： Robert Maerkl , Werner Bertleff , Hans J. Wilfinger , Gunter Schuch , Wolfgang Harder , Gebhard Kuehn , Paul Panitz
发明人： Robert Maerkl , Werner Bertleff , Hans J. Wilfinger , Gunter Schuch , Wolfgang Harder , Gebhard Kuehn , Paul Panitz
IPC分类号： C07C67/38 , B01J31/20 , C07B61/00 , C07C69/533
CPC分类号： C07C69/533
摘要： Alkyl pentenoates are prepared by reacting butadiene with carbon monoxide and an alkanol in the presence of a cobalt carbonyl complex and a tertiary, aromatic heterocyclic nitrogen base at from 80.degree. to 160.degree. C. under from 100 to 1,000 bar in the presence of from 0.1 to 10% by volume of hydrogen, based on the amount of carbon monoxide used.
摘要翻译：烷基戊烯酸酯是通过使丁二烯与一氧化碳和链烷醇在羰基钴配合物和叔芳族杂环氮碱存在下，在80-160℃，100-1,000巴下，存在0.1当量至10体积％的氢气，基于所用一氧化碳的量。

9. 发明授权

US4777284A Continuous preparation of carbalkoxy-containing aliphatic compounds 失效
标题翻译：连续制备含有烷氧基的脂族化合物
公开(公告)号：US4777284A
公开(公告)日：1988-10-11
申请号：US116877
申请日：1987-11-05
申请人： Robert Maerkl , Werner Bertleff , Gebhard Kuehn , Paul Panitz , Peter Stops , Rudolf Kummer , Guenter Schuch
发明人： Robert Maerkl , Werner Bertleff , Gebhard Kuehn , Paul Panitz , Peter Stops , Rudolf Kummer , Guenter Schuch
IPC分类号： B01J31/20 , B01J31/00 , C07B61/00 , C07C67/30 , C07C67/38 , C07C69/003 , C07C69/34 , C07C69/44 , C07C69/533 , C07C69/593
CPC分类号： C07C67/38
摘要： Carbalkoxy-containing aliphatic compounds are prepared continuously by reacting an olefinically unsaturated aliphatic compound with carbon monoxide and an alkanol in the presence of a cobalt carbonyl catalyst and a tertiary nitrogen base at from 80.degree. to 200.degree. C. and under from 100 to 1,200 bar by an improved process in which carbon monoxide is circulated, and a carbon dioxide content of from 0.1 to 2% by volume is maintained in the carbon monoxide fed to the reaction.
摘要翻译：在羰基催化剂和叔氮碱的存在下，在80〜200℃，100〜1200巴下，使烯属不饱和脂肪族化合物与一氧化碳和链烷醇反应制备含有链烷烃基的脂肪族化合物通过一氧化碳循环的改进方法，并且在进料到反应中的一氧化碳中维持二氧化碳含量为0.1-2体积％。

10. 发明申请

US20120101306A1 PROCESS FOR THE PREPARATION OF 1-METHYLCYCLOPENTANE DERIVATIVES 审中-公开
标题翻译：制备1-甲基环戊烷衍生物的方法
公开(公告)号：US20120101306A1
公开(公告)日：2012-04-26
申请号：US13278688
申请日：2011-10-21
申请人： Andreas LANVER , Klaus Ebel , Rainer Klopsch , Werner Bertleff , Richard Dehn , Joaquim Henrique Teles , Helmut Kronemayer , Marcus Georg Schrems
发明人： Andreas LANVER , Klaus Ebel , Rainer Klopsch , Werner Bertleff , Richard Dehn , Joaquim Henrique Teles , Helmut Kronemayer , Marcus Georg Schrems
IPC分类号： C07C41/14 , C07C1/20 , C07C5/29 , C07C29/04
CPC分类号： C07C1/20 , C07C5/29 , C07C29/04 , C07C41/06 , C07C2601/10 , Y02P20/127 , C07C13/12 , C07C35/06 , C07C43/184
摘要： Process for the preparation of 1-methylcyclopentene by thermal reaction of cyclohexanol or cyclohexene or mixtures of both compounds to give 1-methylcyclopentene, wherein the resulting by-products 3-methylcyclopentene and 4-methylcyclopentene (double-bond isomers of 1-methylcyclopentene) are returned to the reaction.
摘要翻译：通过环己醇或环己烯或两种化合物的混合物的热反应制备1-甲基环戊烯得到1-甲基环戊烯的方法，其中得到的副产物3-甲基环戊烯和4-甲基环戊烯（1-甲基环戊烯的双键异构体）是回到了反应。

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