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1. 发明授权

US5003089A Preparation of cyclic 6-membered to 8-membered vinylene-1,2-dioxy compounds 失效
标题翻译：环状6元至8元亚乙烯基-1,2-二氧化合物的制备
公开(公告)号：US5003089A
公开(公告)日：1991-03-26
申请号：US379412
申请日：1989-07-13
申请人： Franz Merger , Juergen Frank , Wolfgang Hoelderich , Toni Dockner , Manfred Sauerwald
发明人： Franz Merger , Juergen Frank , Wolfgang Hoelderich , Toni Dockner , Manfred Sauerwald
IPC分类号： B01J29/04 , C07B61/00 , C07C43/13 , C07C47/198 , C07D319/06 , C07D319/08 , C07D319/12 , C07D321/08 , C07D321/10 , C07D321/12 , C07D335/02 , C07D495/10 , C07D521/00
CPC分类号： C07D495/10 , C07C43/13 , C07D319/06 , C07D319/12 , C07D321/08 , C07D321/12 , Y02P20/582
摘要： Cyclic 6-membered to 8-membered 1,2-vinylenedioxy compounds of the general formula I ##STR1## where A is ##STR2## R.sup.1 to R.sup.7 independently of one another are each hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.2 -C.sub.16 -alkoxyalkyl, C.sub.2 -C.sub.8 -alkenyl, C.sub.2 -C.sub.8 -alkynyl, C.sub.5 -C.sub.8 -cycloalkyl, aryl, C.sub.7 -C.sub.10 -alkylphenyl, C.sub.7 -C.sub.10 -phenalkyl, C.sub.8 -C.sub.10 -phenalkenyl or a heterocyclic structure, or R.sup.2 and R.sup.3, R.sup.2 and R.sup.4, R.sup.3 and R.sup.4, R.sup.2 and R.sup.6, R.sup.3 and R.sup.6, R.sup.4 and R.sup.5 or R.sup.6 and R.sup.7 together form a cycloaliphatic or heterocyclic ring, and R.sup.1 to R.sup.7 may furthermore carry substituents which are inert under the reaction conditions, and n is 0 or 1, are prepared by a process in which a cyclic 2-oxymethyl-1,3-dioxa compound or one of its derivatives of the general formula II ##STR3## where R.sup.1 to R.sup.7, A and n have the abovementioned meanings, and R.sup.8 is hydrogen or C.sub.1 -C.sub.12 -alkyl, is converted in the presence of an acidic catalyst at from 150.degree. to 450.degree. C. and under from 0.001 to 50 bar, some of the compounds obtained being novel.
摘要翻译：其中A为彼此独立的通式I（I）的环状6元至8元1,2-亚乙烯基二氧基化合物各自为氢，C 1 -C 8 - 烷基，C 2 -C 18 - C16 - 烷氧基烷基，C2-C8-烯基，C2-C8-炔基，C5-C8-环烷基，芳基，C7-C10-烷基苯基，C7-C10-苯基烷基，C8-C10-苯基烯基或杂环结构，或R2和R3 ，R 2和R 4，R 3和R 4，R 2和R 6，R 3和R 6，R 4和R 5或R 6和R 7共同形成脂环族或杂环，并且R 1至R 7还可以具有在反应条件下为惰性的取代基，n为 0或1的化合物通过其中R 1至R 7，A和n具有上述通式II的环状2-氧甲基-1,3-二氧杂化合物或其衍生物之一的方法制备意义，R8是氢或C1-C12烷基，在酸性催化剂存在下，在150-450℃下，在0.001至50巴下进行转化，得到的一些化合物是新的。

2. 发明授权

US5256813A 3-substituted 2-hydroxy-3-formylpropionic esters, the preparation thereof and the use thereof for preparing 3-substituted 3-formylacrylic esters 失效
标题翻译： 3-取代的2-羟基-3-甲酰基丙酸酯，其制备及其用于制备3-取代的3-甲酰基丙烯酸酯的用途
公开(公告)号：US5256813A
公开(公告)日：1993-10-26
申请号：US883342
申请日：1992-05-15
申请人： Franz Merger , Juergen Frank
发明人： Franz Merger , Juergen Frank
IPC分类号： C07C69/675 , C07C69/732
CPC分类号： C07C69/675
摘要： A 3-substituted 2-hydroxy-3-formylpropionic ester of the formula I ##STR1## where R.sup.1 is lower alkyl, and R.sup.2 is straight-chain or branched alkyl of 1 to 10 carbon atoms, is obtained by adding an alkanal of the fomrula II ##STR2## and an alkyl glyoxylate of the formula III ##STR3## simultaneously to a catalyst system composed of a salt or a mixture of a secondary amine and a carboxylic acid in such a way that the temperature does not exceed 90.degree. C., preferably 80.degree. C., or else adding one of the reactants of the formula II or III to a mixture of the catalyst system described above and the other reactant in such a way that the temperature does not exceed 90.degree. C. The 2-hydroxy-3-formylpropionic eater of the formula I can be converted by treatment with dehydrating agents, especially acetic anhydride, into good yields of the corresponding 3-substituted 3-formylacrylic ester.
摘要翻译：其中R1是低级烷基，R2是具有1-10个碳原子的直链或支链烷基的式Ⅰ的3-取代的2-羟基-3-甲酰基丙酸酯是通过将烷基的II型和式III（III）的烷基乙醛酸盐同时与由仲胺和羧酸的盐或混合物组成的催化剂体系，使得温度不超过90℃，优选80℃，或者将一种式II或III的反应物加入到上述催化剂体系和另一种反应物的混合物中，使得温度不超过90℃。式I的2-羟基-3-甲酰基丙酸酯可以通过用脱水剂，特别是乙酸酐处理转化成相应3-取代的3-甲酰基丙烯酸酯的良好产率。

3. 发明授权

US5202461A 3-substituted 2-hydroxy-3-formylpropionic esters, the preparation thereof and the use thereof for preparing 3-substituted 3-formylacrylic esters 失效
标题翻译： 3-取代的2-羟基-3-甲基丙烯酸酯，其制备方法及其用于制备3-取代的3-甲基丙烯酸酯的用途
公开(公告)号：US5202461A
公开(公告)日：1993-04-13
申请号：US593891
申请日：1990-10-05
申请人： Franz Merger , Juergen Frank
发明人： Franz Merger , Juergen Frank
IPC分类号： B01J31/02 , B01J31/04 , C07B61/00 , C07C67/343 , C07C67/44 , C07C69/67 , C07C69/675
CPC分类号： C07C69/675
摘要： A 3-substituted 2-hydroxy3-formylpropionic ester of the formula I ##STR1## where R.sup.1 is lower alkyl, and R.sup.2 is straight-chain or branched alkyl of 1 to 10 carbon atoms, is obtained by adding an alkanal of the formula II ##STR2## and an alkyl glyoxylate of the formula III ##STR3## simultaneously to a catalyst system composed of a salt or a mixture of a secondary amine and a carboxylic acid in such a way that the temperature does not exceed 90.degree. C., preferably 80.degree. C., or else adding one of the reactants of the formula II or III to a mixture of the catalyst system described above and the other reactant in such a way that the temperature does not exceed 90.degree. C. The 2-hydroxy-3-formylpropionic ester of the formula I can be converted by treatment with dehydrating agents, especially acetic anhydride, into good yields of the corresponding 3-substituted 3-formylacrylic ester.
摘要翻译：通过加入式I的3-取代的2-羟基-3-甲酰基丙酸酯，其中R 1是低级烷基，R 2是1-10个碳原子的直链或支链烷基，式II（II）和式III（III）的烷基乙醛酸盐同时加入由盐或仲胺和羧酸的混合物组成的催化剂体系，使得温度不超过90℃，优选80℃，或者将一种式II或III的反应物加入到上述催化剂体系和另一种反应物的混合物中，使得温度不超过90℃ 式I的2-羟基-3-甲酰基丙酸酯可以通过用脱水剂，特别是乙酸酐处理转化成相应3-取代的3-甲酰基丙烯酸酯的良好产率。

4. 发明授权

US4853473A Preparation of 2(5H)-furanones 失效
标题翻译： 2（5H） - 呋喃酮的制备
公开(公告)号：US4853473A
公开(公告)日：1989-08-01
申请号：US201050
申请日：1988-06-01
申请人： Rolf Fischer , Juergen Frank , Franz Merger , Michael Roeper , Uwe Vagt
发明人： Rolf Fischer , Juergen Frank , Franz Merger , Michael Roeper , Uwe Vagt
IPC分类号： C07D315/00
CPC分类号： C07D315/00
摘要： 2(5H)-furanones I ##STR1## where R.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.5 - or C.sub.6 -cycloalkyl, C.sub.7 -C.sub.12 -aralkyl or aryl, are prepared by heating a 3-formylcarboxylate or 3-formylcarboxylic acid II ##STR2## where R.sup.3 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 - or C.sub.6 -cycloalkyl, C.sub.7 -C.sub.12 -aralkyl or aryl, to 100.degree.-450.degree. C. in the presence of an acidic catalyst.
摘要翻译： 2（5H） - 呋喃酮I（I）其中R1和R2各自为氢，C1-C6烷基，C5-或C6-环烷基，C7-C12-芳烷基或芳基，通过加热3-甲酰基羧酸酯或其中R 3为氢，C 1 -C 12 - 烷基，C 5 - 或C 6 - 环烷基，C 7 -C 12 - 芳烷基或芳基的3-甲酰基羧酸II（II）在100-450℃存在下，酸性催化剂。

5. 发明授权

US5162552A Preparation of 4-acetals of butene-1,4-dial and novel acetals of butene-1,4-dial 失效
标题翻译：保护1,4-DIAL的4-乙酸丁酯和1,4-DIAL的新型乙烯的制备
公开(公告)号：US5162552A
公开(公告)日：1992-11-10
申请号：US44805
申请日：1987-04-30
申请人： Franz Merger , Rolf Fischer , Hans Horler , Juergen Frank
发明人： Franz Merger , Rolf Fischer , Hans Horler , Juergen Frank
IPC分类号： C07C45/00 , C07C45/74 , C07C47/277 , C07C67/00 , C07D319/06
CPC分类号： C07C45/74 , C07D319/06
摘要： A process for the preparation of 4-acetals of butene-1,4-dial of the formula ##STR1## where R is an alkyl, alkenyl, cycloalkyl or aralkyl radical of 1 to 12 carbon atoms which may contain alkoxy groups, or the two radicals R together form an alkylene or alkenylene radical of 2 to 10 carbon atoms which may contain alkoxy groups, and R.sup.1 is an alkyl, alkenyl or alkynyl radical of 1 to 12 carbon atoms which may be substituted by cycloaliphatic, aromatic or heterocyclic radicals or by hydroxyl, ether, thioether, acyl, alkylamino, carboxyl or carbalkoxy groups, or is an unsubstituted or substituted aryl radical or an alkoxy, alkylthio or acyloxy group, wherein a glyoxal monoacetal of the formula ##STR2## is reacted with an aldehyde of the formulaR.sup.1 --CH.sub.2 --CHO IIIat up to 150.degree. C., and novel acetals of butene-1,4-dial.
摘要翻译：制备式Ia的1,4-缩醛的4-缩醛的方法，其中R是可以含有烷氧基的具有1至12个碳原子的烷基，烯基，环烷基或芳烷基，或两个基团R一起形成可含有烷氧基的2至10个碳原子的亚烷基或亚烯基，R 1是可以被脂环族，芳族或杂环基取代的具有1至12个碳原子的烷基，烯基或炔基，或通过羟基，醚，硫醚，酰基，烷基氨基，羧基或烷氧基，或者是未取代或取代的芳基或烷氧基，烷硫基或酰氧基，其中式II的乙二醛单缩醛与式式R1-CH2-CHOⅢ在最高达150℃，新戊烯-1,4-表盘的缩醛。

6. 发明授权

US4879406A Preparation of pentenoic esters from formylvaleric esters 失效
标题翻译：从甲酰戊酸酯制备戊烯酸酯
公开(公告)号：US4879406A
公开(公告)日：1989-11-07
申请号：US205354
申请日：1988-06-10
申请人： Franz Merger , Juergen Frank , Uwe Vagi , Rolf Fischer
发明人： Franz Merger , Juergen Frank , Uwe Vagi , Rolf Fischer
IPC分类号： B01J27/053 , B01J23/40 , B01J23/89 , B01J31/24 , C07B61/00 , C07C67/293 , C07C67/333 , C07C69/533
CPC分类号： C07C69/533
摘要： Pentenoic esters are prepared by a process in which 4- and/or 3-formylvaleric esters are heated to 50.degree.-400.degree. C. in the presence of a catalyst which contains one or more elements of subgroup VIII of the Periodic Table.
摘要翻译：在含有一种或多种元素周期表第VIII族元素的催化剂存在下，将4-和/或3-甲酰基戊酸酯加热至50-400℃的方法制备戊烯酸酯。

7. 发明授权

US5536854A Preparation of 2-methyl-1,4-butanediol and 3-methyltetrahydrofuran 失效
标题翻译：制备2-甲基-1,4-丁二醇和3-甲基四氢呋喃
公开(公告)号：US5536854A
公开(公告)日：1996-07-16
申请号：US380134
申请日：1995-01-26
申请人： Hans-Juergen Weyer , Rolf Fischer , Franz Merger , Juergen Frank , Jochem Henkelmann , Hardo Siegel , Thomas Ruehl
发明人： Hans-Juergen Weyer , Rolf Fischer , Franz Merger , Juergen Frank , Jochem Henkelmann , Hardo Siegel , Thomas Ruehl
IPC分类号： C07C29/141 , C07C29/149 , C07C29/17 , C07D307/06 , C07D307/08
CPC分类号： C07D307/06 , C07C29/141 , C07C29/149 , C07C29/177
摘要： 2-Methyl-1,4-butanediol and 3-methyltetrahydrofuran are prepared by reacting a compound of the general formula I or II ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 -C.sub.8 -alkyl and the formyl group of II may also be present as acetal with a C.sub.1 -C.sub.8 -alkanol, is reacted with hydrogen in the presence of copper or of a metal of groups 7 to 10 of the Periodical Table of elements or of a compound of these metals.
摘要翻译： 2-甲基-1,4-丁二醇和3-甲基四氢呋喃通过使通式I或II的化合物（其中R 1和R 2各自为氢或C 1 -C 8 - 烷基）和甲酰基 II族基团也可以与C 1 -C 8 - 链烷醇一起作为缩醛存在，在铜或金属元素周期表第7至10族的金属或这些金属的化合物的存在下与氢反应。

8. 发明授权

US5008408A Preparation of 1,4-butanediol and tetrahydrofuran 失效
标题翻译： 1,4-丁二醇和四氢呋喃的制备
公开(公告)号：US5008408A
公开(公告)日：1991-04-16
申请号：US489709
申请日：1990-03-07
申请人： Rolf Fischer , Juergen Frank , Franz Merger , Hans-Juergen Weyer
发明人： Rolf Fischer , Juergen Frank , Franz Merger , Hans-Juergen Weyer
IPC分类号： C07C29/141 , C07D307/20
CPC分类号： C07D307/20 , C07C29/141
摘要： Mixtures which contain 1,4-butanediol and tetrahydrofuran are prepared by heating 4-hydroxybutyraldehyde of the formula ##STR1## at 20.degree.-300.degree. C. in the presence or absence of 1,4-butanediol and subjecting the resulting acetals of the formulae ##STR2## to a catalytic hydrogenation at 50.degree.-300.degree. C. and 1-350 bar.
摘要翻译：含有1,4-丁二醇和四氢呋喃的混合物通过在存在或不存在1,4-丁二醇的情况下，在20-300℃下加热式Ia的4-羟基丁醛来制备，并将所得的缩醛公式 + TR 在50°-300℃和1-350巴下进行催化氢化。

9. 发明授权

US5689010A Preparation of higher aldehydes 失效
标题翻译：制备较高级的醛
公开(公告)号：US5689010A
公开(公告)日：1997-11-18
申请号：US638592
申请日：1996-04-29
申请人： Rocco Paciello , Franz Merger , Michael Roper , Heinz-Josef Kneuper
发明人： Rocco Paciello , Franz Merger , Michael Roper , Heinz-Josef Kneuper
IPC分类号： B01J31/22 , C07B61/00 , C07C45/50 , C07C45/62 , C07C45/73 , C07C45/74 , C07C47/02 , C07C47/21 , C07C45/49
CPC分类号： C07C45/50 , C07C45/62 , C07C45/74
摘要： Aldehydes with a higher number of carbon atoms and high selection are prepared by reacting olefins, in particular from petrochemical refinery products, by a hydroformylation with aldol condensation using a mixed catalyst of rhodium-carbonyl-phosphines and Mannich catalyst.
摘要翻译：通过使用铑 - 羰基膦和Mannich催化剂的混合催化剂通过使醛醇缩合的加氢甲酰化反应，使烯烃，特别是石油化学品炼油产物反应，制备具有较高碳原子数和高选择性的醛。

10. 发明授权

US5416240A Preparation of poloxy-alkylene glycols 失效
标题翻译：烷氧基 - 亚烷基二醇的制备
公开(公告)号：US5416240A
公开(公告)日：1995-05-16
申请号：US24903
申请日：1993-03-02
申请人： Hans-Juergen Weyer , Rolf Fischer , Gerhard Jeschek , Franz Merger , Herbert Mueller
发明人： Hans-Juergen Weyer , Rolf Fischer , Gerhard Jeschek , Franz Merger , Herbert Mueller
IPC分类号： C08G65/02 , C08G65/08 , C08G65/16 , C08G65/20 , C07C41/01 , C07C41/02
CPC分类号： C08G65/20
摘要： Polyoxyalkylene glycols are prepared by a process in which tetrahydrofuran is polymerized with a total of not more than 95 mol %, based on the amount of tetrahydrofuran used, of one or more comonomers from the group consisting of the cyclic ethers and acetals in the absence of water and in the presence of a monohydric alcohol or of a monocarboxylic acid with the aid of an anhydrous heteropoly acid catalyst, and the polyoxyalkylene glycol is liberated from the resulting polyoxyalkylene glycol monoethers or polyoxyalkylene glycol monoesters by cleavage of the monoether or monoester bond.
摘要翻译：聚氧亚烷基二醇通过以下方法制备，其中四氢呋喃基于所用四氢呋喃的总量不超过95摩尔％，在不存在共聚单体的情况下聚合来自由环醚和缩醛组成的组中的一种或多种共聚单体水和一元醇或单羧酸存在下，借助于无水杂多酸催化剂，通过裂解单醚或单酯键，从所得聚氧亚烷基二醇单醚或聚氧亚烷基二醇单酯中释放出聚氧亚烷基二醇。

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