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1. 发明授权

US07102034B2 Process for preparing sulfonated arylphosphines 失效
标题翻译：制备磺化芳基膦的方法
公开(公告)号：US07102034B2
公开(公告)日：2006-09-05
申请号：US11007399
申请日：2004-12-08
申请人： Michael Riedel , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
发明人： Michael Riedel , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
IPC分类号： C07C45/00
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： A process for preparing sulfonated arylphosphines by reaction of arylphosphines with oleum, wherein, after reaction of the arylphosphines with oleum, the sulfonation mixture is firstly diluted with water, an inert gas stream is then passed through the diluted sulfonation mixture until SO2 is no longer liberated from the diluted sulfonation mixture and the latter is then worked up further in a customary manner and its use.
摘要翻译：通过芳基膦与发烟硫酸的反应制备磺化芳基膦的方法，其中在芳基膦与发烟硫酸反应之后，首先用水稀释磺化混合物，然后使惰性气体流通过稀释的磺化混合物直到SO 2 不再从稀释磺化混合物中释放出来，而后者则以常规方式进一步处理及其用途。

2. 发明授权

US06864387B2 Process for preparing sulfonated arylphosphines 有权
标题翻译：制备磺化芳基膦的方法
公开(公告)号：US06864387B2
公开(公告)日：2005-03-08
申请号：US10413014
申请日：2003-04-14
申请人： Michael Riedel , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
发明人： Michael Riedel , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
IPC分类号： B01J31/24 , B01J31/28 , C07C45/50 , C07F9/50 , C07C304/00
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： A process for preparing solutions of sulfonated arylphosphines comprising reacting arylphosphines with oleum, diluting the sulfonation mixture with water, extracting the diluted sulfonation mixture with a solution of a water-insoluble organic solvent, reacting the organic phase with a solution of an inorganic base in water, adjusting the resulting aqueous solutin of sulfonated arylphosphines to a pH of up to 3 by addition of an acid, and passing an inert gas stream through the aqueous solution comprising sulfonated arylphosphines until sulfur is no longer liberated from the aqueous solution of sulfonated arylphosphines.
摘要翻译：一种制备磺化芳基膦溶液的方法，包括使芳基膦与发烟硫酸反应，用水稀释磺化混合物，用水不溶性有机溶剂的溶液萃取稀释的磺化混合物，将有机相与无机碱溶于水通过加入酸将所得的磺化芳基膦的水溶液调节至最高达3的pH，并使惰性气体流通过包含磺化芳基膦的水溶液，直到硫从磺化芳基膦的水溶液中不再释放出来。

3. 发明授权

US06610881B1 Method for producing sulfonated aryl phosphines 失效
标题翻译：制备磺化芳基膦的方法
公开(公告)号：US06610881B1
公开(公告)日：2003-08-26
申请号：US09937640
申请日：2001-12-12
申请人： Michael Riedel , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf
发明人： Michael Riedel , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf
IPC分类号： C07C30900
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： The invention relates to a method for producing sulfonated aryl phosphines by reacting aryl phosphines with oleum. After reacting the aryl phosphines with oleum, the sulfonation mixture is firstly diluted with water and an inert gas stream is then fed through the diluted sulfonation mixture until SO2 is no longer released from the diluted sulfonation mixture. Afterwards, the sulfonation mixture is subsequently processed in a usual manner. The invention also relates to a method for producing solutions of sulfonated aryl phosphines by reacting the aryl phosphines with oleum, diluting the sulfonation mixture with water, extracting the aqueous solution using an organic solution consisting of an amine, and subsequently carrying out a reextraction using an aqueous solution having an inorganic base. According to the invention, the solution containing aqueous sulfonated aryl phosphines is adjusted to a pH value of up to 3 by adding acid, and an inert gas stream is then fed through the aqueous solution until sulfur dioxide is no longer released. The invention additionally relates to an aqueous catalyst solution containing rhodium and an aqueous solution of sulfonated aryl phosphines, treated as defined by the invention, for carrying out the hydroformylation of olefinically unsaturated compounds, and relates to the use thereof for carrying out the same.
摘要翻译：本发明涉及通过使芳基膦与发烟硫酸反应制备磺化芳基膦的方法。在芳基膦与发烟硫酸反应之后，首先用水稀释磺化混合物，然后将惰性气体流通过稀释的磺化混合物，直到SO 2不再从稀释的磺化混合物中释放出来。之后，磺化混合物随后以常规方式进行处理。本发明还涉及通过使芳基膦与发烟硫酸反应制备磺化芳基膦的溶液的方法，将磺化混合物与水稀释，使用由胺构成的有机溶液萃取水溶液，然后使用具有无机碱的水溶液。根据本发明，通过加入酸将含有磺化芳基膦水溶液的溶液的pH值调至3，然后将惰性气体流通过该水溶液直至二氧化硫不再释放。本发明另外涉及含有铑的水性催化剂溶液和由本发明定义的磺化芳基膦的水溶液，用于进行烯属不饱和化合物的加氢甲酰化，并涉及其用于进行烯属不饱和化合物的加氢甲酰化。

4. 发明申请

US20050171377A1 Process for preparing sulfonated arylphosphines 失效
标题翻译：制备磺化芳基膦的方法
公开(公告)号：US20050171377A1
公开(公告)日：2005-08-04
申请号：US11007399
申请日：2004-12-08
申请人： Michael Riedel , Ernst Wiebus , Carl Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
发明人： Michael Riedel , Ernst Wiebus , Carl Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
IPC分类号： B01J31/24 , B01J31/28 , C07C45/50 , C07F9/50 , C07F9/02
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： A process for preparing sulfonated arylphosphines by reaction of arylphosphines with oleum, wherein, after reaction of the arylphosphines with oleum, the sulfonation mixture is firstly diluted with water, an inert gas stream is then passed through the diluted sulfonation mixture until SO2 is no longer liberated from the diluted sulfonation mixture and the latter is then worked up further in a customary manner and its use.
摘要翻译：通过芳基膦与发烟硫酸的反应制备磺化芳基膦的方法，其中在芳基膦与发烟硫酸反应之后，首先用水稀释磺化混合物，然后使惰性气体流通过稀释的磺化混合物直到SO 2 不再从稀释磺化混合物中释放出来，而后者则以常规方式进一步处理及其用途。

5. 发明申请

US20060276669A1 Process for preparing sulfonated arylphosphines 审中-公开
标题翻译：制备磺化芳基膦的方法
公开(公告)号：US20060276669A1
公开(公告)日：2006-12-07
申请号：US11480178
申请日：2006-06-30
申请人： Michael Riedel , Ernst Wiebus , Carl Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
发明人： Michael Riedel , Ernst Wiebus , Carl Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
IPC分类号： C07F9/02 , C07C45/90
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： An aqueous catalyst solution comprising rhodium and an aqueous solution comprising sulfonated arylphosphines by reacting arylphosphines with oleum to form a sulfonation mixture, diluting the sulfonation mixture with water, extracting the diluted sulfonation mixture with a solution of a water-insoluble amine in a water-insoluble organic solvent, reacting the resulting water-immiscible organic phase with a solution of an inorganic base in water, adjusting the resulting aqueous solution of sulfonated arylphosphines of pH of up to 3 by addition of an acid, and passing an inert gas stream through the aqueous solution comprising sulfonated arylphosphines until sulfur dioxide is no longer liberated from the aqueous solution of sulfonated arylphosphines.
摘要翻译：包含铑的水溶液和包含磺化芳基膦的水溶液，通过使芳基膦与发烟硫酸反应形成磺化混合物，用水稀释磺化混合物，用水不溶性胺在水不溶性的溶液中萃取稀释的磺化混合物有机溶剂，使得到的与水不混溶的有机相与无机碱在水中的溶液反应，通过加入酸调节得到的pH为3的磺化芳基膦水溶液，并将惰性气流通过水溶液包含磺化芳基膦的溶液，直到二氧化硫不再从磺化芳基膦的水溶液中释放出来。

6. 发明授权

US06407290B2 Process for the production of substituted 10-chloro-phenoxaphosphines or 10-bromo-phenoxaphosphines 失效
标题翻译：制备取代的10-氯 - 苯氧基膦或10-溴 - 苯氧膦的方法
公开(公告)号：US06407290B2
公开(公告)日：2002-06-18
申请号：US09845962
申请日：2001-04-30
申请人： Jurgen Herwig , Peter Skutta , Stefanie Sturm
发明人： Jurgen Herwig , Peter Skutta , Stefanie Sturm
IPC分类号： C07F950
CPC分类号： C07F9/657163
摘要： An efficient process for the production of substituted 10-chloro-phenoxaphosphines or 10 bromo-phenoxaphosphines by reaction of substituted diphenyl ethers with phosphorus trihalogenide in the presence of at least one Lewis acid and subsequent treatment with an amine.
摘要翻译：在至少一种路易斯酸存在下，通过使取代的二苯基醚与三卤代磷反应制备取代的10-氯 - 苯氧基膦或10-溴 - 苯氧基膦的有效方法，随后用胺处理。

7. 发明申请

US20070265184A1 PROCESS FOR PREPARING CYCLODODECATRIENE 有权
标题翻译：制备环糊精的方法
公开(公告)号：US20070265184A1
公开(公告)日：2007-11-15
申请号：US11688505
申请日：2007-03-20
申请人： Jurgen Herwig , Wilhelm Brugging , Martin Roos , Norbert Wilczok
发明人： Jurgen Herwig , Wilhelm Brugging , Martin Roos , Norbert Wilczok
IPC分类号： C07C13/277 , A61K8/31 , C07C2/42 , C07C61/00 , C07D225/00 , C07C62/00 , C07C211/00 , A61Q13/00
CPC分类号： C09K21/14 , C07C2/465 , C07C2527/135 , C07C2531/14 , C07C2531/22 , C07C2601/18 , C07C13/277
摘要： Preparation of cyclododecatriene in a continuous or discontinuous process by trimerization of butadiene in the presence of a catalyst system and a solvent, the crude cyclododecatriene obtained being able to be isolated by means of distillation. The cyclooctadiene formed as by-product can likewise be isolated from the crude product.
摘要翻译：在催化剂体系和溶剂的存在下，通过丁二烯的三聚制备连续或不连续的环十二碳三烯，所得的粗环十二碳三烯能够通过蒸馏分离。作为副产物形成的环辛二烯同样可以与粗产物分离。

8. 发明授权

US06995293B2 Method for the production of aldehydes 失效
标题翻译：醛的生产方法
公开(公告)号：US06995293B2
公开(公告)日：2006-02-07
申请号：US10654494
申请日：2003-09-03
申请人： Hans Bohnen , Jurgen Herwig , Dietmar Hoff , Peter Wasserscheid , Roy van Hal
发明人： Hans Bohnen , Jurgen Herwig , Dietmar Hoff , Peter Wasserscheid , Roy van Hal
IPC分类号： C07C45/49 , C07C45/50
CPC分类号： C07C45/50 , C07C47/02
摘要： The present invention relates to a hydroformylation method by conversion of olefins or olefinically unsaturated compounds in the presence of at least one rhodium compound and in the presence of sulfonated arylphosphines in ionic liquids, which are based on a quaternary singly-charged ammonium ion or the equivalent of a multiply charged ammonium ion and organic sulfonates or sulfates.
摘要翻译：本发明涉及通过在至少一种铑化合物的存在下和在离子液体中的磺化芳基膦存在下使烯烃或烯属不饱和化合物转化的加氢甲酰化方法，其基于季铵单电荷铵离子或等同物的多电荷铵离子和有机磺酸盐或硫酸盐。

9. 发明申请

US20050085671A1 Method for the production of aldehydes 失效
标题翻译：醛的生产方法
公开(公告)号：US20050085671A1
公开(公告)日：2005-04-21
申请号：US10654494
申请日：2003-09-03
申请人： Hans Bohnen , Jurgen Herwig , Dietmar Hoff , Peter Wasserscheid , Roy Hal
发明人： Hans Bohnen , Jurgen Herwig , Dietmar Hoff , Peter Wasserscheid , Roy Hal
IPC分类号： C07C45/50 , C07C45/28 , C07C309/00
CPC分类号： C07C45/50 , C07C47/02
摘要： The present invention relates to a hydroformylation method by conversion of olefins or olefinically unsaturated compounds in the presence of at least one rhodium compound and in the presence of sulfonated arylphosphines in ionic liquids, which are based on a quaternary singly-charged ammonium ion or the equivalent of a multiply charged ammonium ion and organic sulfonates or sulfates.
摘要翻译：本发明涉及通过在至少一种铑化合物的存在下和在离子液体中的磺化芳基膦存在下使烯烃或烯属不饱和化合物转化的加氢甲酰化方法，其基于季铵单电荷铵离子或等同物的多电荷铵离子和有机磺酸盐或硫酸盐。

10. 发明授权

US6025524A Single-stage process for the preparation of amines 失效
标题翻译：用于制备胺的单阶段方法
公开(公告)号：US6025524A
公开(公告)日：2000-02-15
申请号：US138718
申请日：1998-08-24
申请人： Jurgen Herwig , Richard Walter Fischer , Heinz Alexander , Burkhard Zimmermann , Matthias Beller
发明人： Jurgen Herwig , Richard Walter Fischer , Heinz Alexander , Burkhard Zimmermann , Matthias Beller
IPC分类号： B01J31/04 , B01J31/12 , B01J31/24 , C07B61/00 , C07C209/26 , C07C209/60 , C07C211/03 , C07C211/06 , C07C211/07 , C07C211/17 , C07C211/19 , C07C209/00
CPC分类号： C07C209/60 , C07C2101/08 , C07C2103/66
摘要： The invention relates to a process for the preparation of an amine by single-stage reaction of a C.sub.2 -C.sub.20 -olefin with a compound having an NH.sub.3 group, hydrogen and carbon monoxide, wherein the reaction takes place in the presence of a catalyst, which is present in water in dissolved or suspended form, and the catalyst contains at least two metals from group VIII of the Periodic Table of the Elements in elemental or bonded form.
摘要翻译：本发明涉及通过C 2 -C 20烯烃与具有NH 3基，氢和一氧化碳的化合物的单步反应制备胺的方法，其中反应在催化剂存在下进行，其中以溶解或悬浮形式存在于水中，并且催化剂含有元素或键合形式的元素周期表第VIII族中的至少两种金属。

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