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1. 发明申请

US20050171377A1 Process for preparing sulfonated arylphosphines 失效
标题翻译：制备磺化芳基膦的方法
公开(公告)号：US20050171377A1
公开(公告)日：2005-08-04
申请号：US11007399
申请日：2004-12-08
申请人： Michael Riedel , Ernst Wiebus , Carl Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
发明人： Michael Riedel , Ernst Wiebus , Carl Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
IPC分类号： B01J31/24 , B01J31/28 , C07C45/50 , C07F9/50 , C07F9/02
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： A process for preparing sulfonated arylphosphines by reaction of arylphosphines with oleum, wherein, after reaction of the arylphosphines with oleum, the sulfonation mixture is firstly diluted with water, an inert gas stream is then passed through the diluted sulfonation mixture until SO2 is no longer liberated from the diluted sulfonation mixture and the latter is then worked up further in a customary manner and its use.
摘要翻译：通过芳基膦与发烟硫酸的反应制备磺化芳基膦的方法，其中在芳基膦与发烟硫酸反应之后，首先用水稀释磺化混合物，然后使惰性气体流通过稀释的磺化混合物直到SO 2 不再从稀释磺化混合物中释放出来，而后者则以常规方式进一步处理及其用途。

2. 发明申请

US20060276669A1 Process for preparing sulfonated arylphosphines 审中-公开
标题翻译：制备磺化芳基膦的方法
公开(公告)号：US20060276669A1
公开(公告)日：2006-12-07
申请号：US11480178
申请日：2006-06-30
申请人： Michael Riedel , Ernst Wiebus , Carl Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
发明人： Michael Riedel , Ernst Wiebus , Carl Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
IPC分类号： C07F9/02 , C07C45/90
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： An aqueous catalyst solution comprising rhodium and an aqueous solution comprising sulfonated arylphosphines by reacting arylphosphines with oleum to form a sulfonation mixture, diluting the sulfonation mixture with water, extracting the diluted sulfonation mixture with a solution of a water-insoluble amine in a water-insoluble organic solvent, reacting the resulting water-immiscible organic phase with a solution of an inorganic base in water, adjusting the resulting aqueous solution of sulfonated arylphosphines of pH of up to 3 by addition of an acid, and passing an inert gas stream through the aqueous solution comprising sulfonated arylphosphines until sulfur dioxide is no longer liberated from the aqueous solution of sulfonated arylphosphines.
摘要翻译：包含铑的水溶液和包含磺化芳基膦的水溶液，通过使芳基膦与发烟硫酸反应形成磺化混合物，用水稀释磺化混合物，用水不溶性胺在水不溶性的溶液中萃取稀释的磺化混合物有机溶剂，使得到的与水不混溶的有机相与无机碱在水中的溶液反应，通过加入酸调节得到的pH为3的磺化芳基膦水溶液，并将惰性气流通过水溶液包含磺化芳基膦的溶液，直到二氧化硫不再从磺化芳基膦的水溶液中释放出来。

3. 发明授权

US07102034B2 Process for preparing sulfonated arylphosphines 失效
标题翻译：制备磺化芳基膦的方法
公开(公告)号：US07102034B2
公开(公告)日：2006-09-05
申请号：US11007399
申请日：2004-12-08
申请人： Michael Riedel , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
发明人： Michael Riedel , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
IPC分类号： C07C45/00
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： A process for preparing sulfonated arylphosphines by reaction of arylphosphines with oleum, wherein, after reaction of the arylphosphines with oleum, the sulfonation mixture is firstly diluted with water, an inert gas stream is then passed through the diluted sulfonation mixture until SO2 is no longer liberated from the diluted sulfonation mixture and the latter is then worked up further in a customary manner and its use.
摘要翻译：通过芳基膦与发烟硫酸的反应制备磺化芳基膦的方法，其中在芳基膦与发烟硫酸反应之后，首先用水稀释磺化混合物，然后使惰性气体流通过稀释的磺化混合物直到SO 2 不再从稀释磺化混合物中释放出来，而后者则以常规方式进一步处理及其用途。

4. 发明授权

US06864387B2 Process for preparing sulfonated arylphosphines 有权
标题翻译：制备磺化芳基膦的方法
公开(公告)号：US06864387B2
公开(公告)日：2005-03-08
申请号：US10413014
申请日：2003-04-14
申请人： Michael Riedel , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
发明人： Michael Riedel , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Hans Bohnen , Richard Fischer , Kurt Schalapski , Wolfgang Greb
IPC分类号： B01J31/24 , B01J31/28 , C07C45/50 , C07F9/50 , C07C304/00
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： A process for preparing solutions of sulfonated arylphosphines comprising reacting arylphosphines with oleum, diluting the sulfonation mixture with water, extracting the diluted sulfonation mixture with a solution of a water-insoluble organic solvent, reacting the organic phase with a solution of an inorganic base in water, adjusting the resulting aqueous solutin of sulfonated arylphosphines to a pH of up to 3 by addition of an acid, and passing an inert gas stream through the aqueous solution comprising sulfonated arylphosphines until sulfur is no longer liberated from the aqueous solution of sulfonated arylphosphines.
摘要翻译：一种制备磺化芳基膦溶液的方法，包括使芳基膦与发烟硫酸反应，用水稀释磺化混合物，用水不溶性有机溶剂的溶液萃取稀释的磺化混合物，将有机相与无机碱溶于水通过加入酸将所得的磺化芳基膦的水溶液调节至最高达3的pH，并使惰性气体流通过包含磺化芳基膦的水溶液，直到硫从磺化芳基膦的水溶液中不再释放出来。

5. 发明授权

US06610881B1 Method for producing sulfonated aryl phosphines 失效
标题翻译：制备磺化芳基膦的方法
公开(公告)号：US06610881B1
公开(公告)日：2003-08-26
申请号：US09937640
申请日：2001-12-12
申请人： Michael Riedel , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf
发明人： Michael Riedel , Jurgen Herwig , Helmut Bahrmann , Klaus Bergrath , Wolfgang Zgorzel-Ski , Robert Eckl , Ernst Wiebus , Carl D Frohning , Wilfried Fenske , Florian Rampf
IPC分类号： C07C30900
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/28 , B01J2231/321 , B01J2531/822 , B01J2531/96 , C07C45/50 , C07F9/5022 , C07F9/5054 , C07F9/5095 , C07C47/02
摘要： The invention relates to a method for producing sulfonated aryl phosphines by reacting aryl phosphines with oleum. After reacting the aryl phosphines with oleum, the sulfonation mixture is firstly diluted with water and an inert gas stream is then fed through the diluted sulfonation mixture until SO2 is no longer released from the diluted sulfonation mixture. Afterwards, the sulfonation mixture is subsequently processed in a usual manner. The invention also relates to a method for producing solutions of sulfonated aryl phosphines by reacting the aryl phosphines with oleum, diluting the sulfonation mixture with water, extracting the aqueous solution using an organic solution consisting of an amine, and subsequently carrying out a reextraction using an aqueous solution having an inorganic base. According to the invention, the solution containing aqueous sulfonated aryl phosphines is adjusted to a pH value of up to 3 by adding acid, and an inert gas stream is then fed through the aqueous solution until sulfur dioxide is no longer released. The invention additionally relates to an aqueous catalyst solution containing rhodium and an aqueous solution of sulfonated aryl phosphines, treated as defined by the invention, for carrying out the hydroformylation of olefinically unsaturated compounds, and relates to the use thereof for carrying out the same.
摘要翻译：本发明涉及通过使芳基膦与发烟硫酸反应制备磺化芳基膦的方法。在芳基膦与发烟硫酸反应之后，首先用水稀释磺化混合物，然后将惰性气体流通过稀释的磺化混合物，直到SO 2不再从稀释的磺化混合物中释放出来。之后，磺化混合物随后以常规方式进行处理。本发明还涉及通过使芳基膦与发烟硫酸反应制备磺化芳基膦的溶液的方法，将磺化混合物与水稀释，使用由胺构成的有机溶液萃取水溶液，然后使用具有无机碱的水溶液。根据本发明，通过加入酸将含有磺化芳基膦水溶液的溶液的pH值调至3，然后将惰性气体流通过该水溶液直至二氧化硫不再释放。本发明另外涉及含有铑的水性催化剂溶液和由本发明定义的磺化芳基膦的水溶液，用于进行烯属不饱和化合物的加氢甲酰化，并涉及其用于进行烯属不饱和化合物的加氢甲酰化。

6. 发明授权

US06482972B1 Isomeric nonanols and decanols, their preparation, phthalic esters obtained therefrom and their use as plasticizers 失效
标题翻译：异壬醇和癸醇，它们的制备，由其获得的邻苯二甲酸酯及其作为增塑剂的用途
公开(公告)号：US06482972B1
公开(公告)日：2002-11-19
申请号：US08437221
申请日：1995-05-08
申请人： Helmut Bahrmann , Wilfried Fenske , Wolfgang Greb , Peter Heymanns , Peter Lappe , Thomas Müller , Jürgen Szameitat , Ernst Wiebus
发明人： Helmut Bahrmann , Wilfried Fenske , Wolfgang Greb , Peter Heymanns , Peter Lappe , Thomas Müller , Jürgen Szameitat , Ernst Wiebus
IPC分类号： C07C6976
CPC分类号： C08K5/12 , C07C29/175 , C07C45/50 , C07C45/74 , C07C69/80 , C12C11/02 , C07C31/125 , C07C47/21 , C07C47/02
摘要： Mixtures of isomeric nonanols and decanols are obtained by joint aldol condensation of n-butanal and pentanals, and up to 1% by weight of 3-methylbutanal, hydrogenation of the aldol condensation product to the corresponding saturated alcohols, and separation from the reaction mixture of the components boiling at temperatures lower than those of the nonanols and decanols. The pentanals are mixtures of 60 to 90% by weight of n-pentanal and 10 to 40% by weight of 2-methylbutanal. The alcohol mixture is especially suitable for preparing ester plasticizers.
摘要翻译：异构壬醇和癸醇的混合物是通过正丁醛和戊醛的联合醛醇缩合得到的，高达1重量％的3-甲基丁醛，醛醇缩合产物氢化成相应的饱和醇，并从组分在低于壬醇和癸醇的温度下沸腾。戊醛是60至90重量％的正戊醛和10至40重量％的2-甲基丁醛的混合物。醇混合物特别适用于制备酯增塑剂。

7. 发明授权

US5808168A Process for the hydroformylation of olefinically unsaturated compounds 失效
标题翻译：烯属不饱和化合物加氢甲酰化的方法
公开(公告)号：US5808168A
公开(公告)日：1998-09-15
申请号：US839328
申请日：1997-04-17
申请人： Helmut Bahrmann , Dieter Frohning , Wilhelm Gick , Wolfgang Hofs , Heinz Kalbfell , Harald Kappesser , Peter Lappe , Kurt Schalapski , Ernst Wiebus , Wolfgang Zgorzelski
发明人： Helmut Bahrmann , Dieter Frohning , Wilhelm Gick , Wolfgang Hofs , Heinz Kalbfell , Harald Kappesser , Peter Lappe , Kurt Schalapski , Ernst Wiebus , Wolfgang Zgorzelski
IPC分类号： B01J31/24 , C07B61/00 , C07C45/50 , C07C47/02
CPC分类号： C07C45/50
摘要： Waste gas obtained in the hydroformylation of olefinically unsaturated compounds in the presence of an aqueous catalyst solution comprising water-soluble rhodium complexes (1st reaction stage) is fed to a homogeneous reaction system in which residual amounts of the olefinically unsaturated compounds from the first reaction stage are reacted in a homogeneous reaction system (2nd reaction stage).
摘要翻译：在包含水溶性铑络合物的水性催化剂溶液（第一反应阶段）的存在下，在烯属不饱和化合物的加氢甲酰化中获得的废气进料至均相反应体系，其中残余量的来自第一反应阶段的烯属不饱和化合物在均相反应体系（第二反应阶段）中反应。

8. 发明授权

US5516948A Process for making a mixture of isomeric decyl alcohols 失效
标题翻译：制备异构癸醇的混合物的方法
公开(公告)号：US5516948A
公开(公告)日：1996-05-14
申请号：US484589
申请日：1995-06-07
申请人： Helmut Bahrmann , Wolfgang Greb , Peter Heymanns , Peter Lappe , Thomas Muller , Jurgen Szameitat , Ernst Wiebus
发明人： Helmut Bahrmann , Wolfgang Greb , Peter Heymanns , Peter Lappe , Thomas Muller , Jurgen Szameitat , Ernst Wiebus
IPC分类号： C07C31/125 , C07C29/141 , C07C29/16 , C07C45/50 , C07C67/08 , C07C69/80 , C08F8/00 , C08F10/00 , C08F10/06 , C08K5/12 , C07C27/20
CPC分类号： C08K5/12 , C07C29/16 , C07C45/50 , C07C67/08 , C07C69/80
摘要： Mixtures of isomeric decyl alcohols obtained by oligomerization of propylene in the presence of deactivated zeolites as catalysts, followed by separation of the nine carbon olefins from the oligomer mixture, then hydroformylation of the 9 carbon olefins to 10 carbon aldehydes, and hydrogenation of the aldehydes to the corresponding alcohols. The mixtures, when esterified with phthalic acid, or anhydride, provide a mixture of isomeric di-decyl phthalates that can be used as plasticizers.
摘要翻译：通过在失活的沸石作为催化剂的存在下将丙烯低聚获得的异构癸醇的混合物，然后从低聚物混合物中分离出9种碳烯烃，然后将9种碳烯烃加氢甲酰化成10种碳醛，并将醛氢化成相应的醇类。当用邻苯二甲酸或酸酐酯化时，混合物提供可用作增塑剂的异构二癸基邻苯二甲酸酯的混合物。

9. 发明授权

US5463147A Decyl alcohol mixtures, phthalic esters obtainable therefrom and their use as plasticizers 失效
标题翻译：癸醇混合物，可从其获得的邻苯二甲酸酯及其作为增塑剂的用途
公开(公告)号：US5463147A
公开(公告)日：1995-10-31
申请号：US311561
申请日：1994-09-23
申请人： Helmut Bahrmann , Wolfgang Greb , Peter Heymanns , Peter Lappe , Thomas Muller , Jurgen Szameitat , Ernst Wiebus
发明人： Helmut Bahrmann , Wolfgang Greb , Peter Heymanns , Peter Lappe , Thomas Muller , Jurgen Szameitat , Ernst Wiebus
IPC分类号： C07C27/20 , C07C29/17 , C07C29/38 , C07C31/125 , C07C45/50 , C07C45/74 , C07C67/08 , C07C69/80 , C08K5/00 , C08K5/10 , C08K5/105 , C08K5/12 , C08L27/06 , C07C27/22 , C07C29/141
CPC分类号： C08K5/12 , C07C29/175 , C07C31/125 , C07C45/50 , C07C45/74 , C08K5/0016
摘要： Mixtures of isomeric decyl alcohols prepared by hydroformylation of mixtures of butene-1 and butene-2 in two stages to give aldehyde mixtures, and condensation of the aldehyde mixtures to form an aldol mixture, followed by separation and hydrogenation. The first stage of the hydroformylation proceeds in the presence of rhodium catalysts dissolved in water, the second stage in the presence of cobalt catalysts homogeneously dissolved in the reaction medium. The mixture of isomeric decyl alcohols, when esterified with phthalic acid, yields a mixture of isomeric decyl phthalates which are useful as plasticizers.
摘要翻译：通过二阶段丁烯-1和丁烯-2的混合物的加氢甲酰化得到的异构癸醇的混合物得到醛混合物，醛混合物缩合形成醛醇混合物，然后分离和氢化。在溶解在水中的铑催化剂存在下进行加氢甲酰基化的第一阶段，第二阶段在均匀溶解在反应介质中的钴催化剂存在下进行。当用邻苯二甲酸酯化时，异构癸醇的混合物产生可用作增塑剂的异构癸基邻苯二甲酸酯的混合物。

10. 发明授权

US5410072A Mixtures of isomeric pentanoic acids, esters prepared therefrom, and their use as lubricants 失效
标题翻译：异构戊酸的混合物，由其制备的酯及其作为润滑剂的用途
公开(公告)号：US5410072A
公开(公告)日：1995-04-25
申请号：US311557
申请日：1994-09-23
申请人： Helmut Bahrmann , Wolfgang Greb , Georg Dambkes , Peter Heymanns , Heinz Kalbfell , Peter Lappe , Helmut Springer , Eberhard von Mulmann , Jurgen Weber , Ernst Wiebus , Carl D. Frohning , Harald Kappesser
发明人： Helmut Bahrmann , Wolfgang Greb , Georg Dambkes , Peter Heymanns , Heinz Kalbfell , Peter Lappe , Helmut Springer , Eberhard von Mulmann , Jurgen Weber , Ernst Wiebus , Carl D. Frohning , Harald Kappesser
IPC分类号： B01J31/24 , C07B61/00 , C07C45/50 , C07C51/235 , C07C53/126 , C07C53/128 , C07C69/22 , C07C69/33 , C10M105/32 , C10M105/34 , C10M105/38 , C10M171/00 , C10N40/30 , C10N70/00
CPC分类号： C10M171/008 , C07C45/50 , C07C53/126 , C07C53/128 , C10M105/38 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2211/022 , C10M2211/06 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
摘要： Isomeric mixtures of pentanoic acids are prepared by subjecting butene-1/butene-2 mixtures to hydroformylation to form aldehyde mixtures, followed by oxidation of the aldehyde mixtures which have been separated off from the reaction product. The hydroformylation is carried out in a heterogeneous system in the presence of rhodium catalysts which are dissolved in water. The mixture of isomeric 5 carbon monocarboxylic acids produced, when esterified with polyhydric alcohols, yields mixtures of isomeric esters which are useful as lubricants for refrigerant compressors operated with chlorine-free, at least partly fluorinated hydrocarbons as the refrigerant.
摘要翻译：戊烯的异构混合物是通过使丁烯-1 /丁烯-2混合物进行加氢甲酰化形成醛混合物，然后氧化从反应产物中分离的醛混合物来制备的。加氢甲酰化在异相体系中在溶解在水中的铑催化剂存在下进行。当用多元醇酯化时，产生异构体5碳一元羧酸的混合物产生异构酯的混合物，其可用作用于无氯，至少部分氟化的烃作为制冷剂的制冷剂压缩机的润滑剂。

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