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    • 2. 发明授权
    • Automatic digital wavelength calibration system for a spectrophotometer
    • 用于分光光度计的自动数字波长校准系统
    • US4692883A
    • 1987-09-08
    • US704356
    • 1985-02-21
    • Michael R. NelsonRoy E. BoostromJerry E. CahillTzong Hwang
    • Michael R. NelsonRoy E. BoostromJerry E. CahillTzong Hwang
    • G01J3/10G01J3/28G01C25/00G06F15/46
    • G01J3/28G01J3/10G01J2003/2866G01J3/2803
    • This invention is directed to a digital wavelength calibration system for a spectrophotometer, which includes a photodiode array that forms an output detector for the spectrophotometer, a light source for generating at least one reference emission line of known peak wavelength, a computer controlled mechanism for causing the peak of said reference line to fall in close proximity to the center of a preselected pixel of said photodiode array, peak location computing apparatus for computing the exact position data of the peak relative to the pixel center in terms of the pixel spacing and the ordinal number of the preselected pixel and for retaining this position data for subsequent wavelength computation, wavelength identification computing apparatus for computing the numerical relationship data of the ordinate number of each pixel to the wavelength falling on that pixel and for retaining this relationship data for subsequent correlation with data generated by the pixel, and apparatus for computational processing and display of the data correlated with the associated wavelength value.
    • 本发明涉及一种用于分光光度计的数字波长校准系统,其包括形成用于分光光度计的输出检测器的光电二极管阵列,用于产生已知峰值波长的至少一个参考发射线的光源,用于引起 所述参考线的峰值落在靠近所述光电二极管阵列的预选像素的中心的峰值位置计算装置,用于根据像素间隔计算峰相对于像素中心的精确位置数据, 预定像素的数量和用于保留用于后续波长计算的位置数据的波长识别计算装置,用于计算每个像素的纵坐标数量与落入该像素的波长的数值关系数据,并保留该关系数据以便随后与之相关 由像素生成的数据,以及用于的像素的装置 与相关波长值相关的数据的计算处理和显示。
    • 4. 发明授权
    • Optical switching apparatus with retroreflector
    • 具有回射器的光开关装置
    • US5481631A
    • 1996-01-02
    • US201848
    • 1994-02-25
    • Jerry E. CahillDavid H. Tracy
    • Jerry E. CahillDavid H. Tracy
    • G02B26/08G02B5/122G02B6/35H04B10/02G02B6/26
    • G02B6/352G02B5/122G02B6/355G02B6/3574
    • An optical switch includes a primary optical fiber terminating in a primary window, and a plurality of secondary optical fibers each terminating in a secondary window facing in the same direction as and spaced laterally from the primary window. A primary lens on a primary axis has a focal point positioned on the axis at the central window. Each of a plurality of secondary lenses has an axis and a focal point positioned on such axis at a secondary window. The secondary axes are parallel to and equidistant from the primary axis. A retroreflector is spaced from the lenses oppositely from each window and has an optical axis centered parallel to the primary axis midway between the primary axis and any of the secondary fibers. A stepper motor rotates the retroreflector about the primary axis to each of a plurality of selected positions to provide optical switching for light transmission between the primary fiber and any selected secondary fiber.
    • 光开关包括终端在主窗口中的主光纤,以及多个次光纤,每个次光纤终止于与主窗口相同的方向和与主窗口横向相隔的次窗口。 主轴上的主透镜具有位于中心窗口的轴上的焦点。 多个次级透镜中的每一个具有在次视窗处定位在该轴上的轴和焦点。 次轴与主轴平行并等距离。 后向反射器与透镜相反地与每个窗口间隔开,并且具有在主轴线和任何次级光纤之间的中间平行于主轴线的光轴。 步进电机将回射器围绕主轴旋转到多个选定位置中的每一个,以提供用于主光纤和任何选定次级光纤之间的光传输的光学切换。
    • 5. 发明授权
    • Method and apparatus to compensate for gas chromatograph column
permeability
    • 补偿气相色谱柱渗透性的方法和装置
    • US5915269A
    • 1999-06-22
    • US59927
    • 1998-04-14
    • Jerry E. CahillDavid H. Tracy
    • Jerry E. CahillDavid H. Tracy
    • G01N30/02G01N30/60G01N30/86G01N30/88B01D15/08G06F15/20
    • G01N30/8693G01N30/88G01N2030/025G01N2030/8804G01N30/6095G01N30/8658
    • In a gas chromatograph system having a column with a stationary phase and a carrier gas moving through the column to contact the stationary phase, the system being useful for detecting analytes in a sample, a method and apparatus for predicting the retention times for the analytes under various conditions, the method utilizing the steps of:a) detecting the analytes under a number of sets of given conditions;b) calculating values for various parameters characteristic of the system based on a mathematical model that includes a correction to compensate for the permeability of said column to said carrier gas;c) entering into the model the values for the characteristic parameters and at least one further set of conditions; andd) using the model to predict retention times for conditions other than those of step a;the apparatus composed of a data handling system including a model for predicting retention times at a variety of conditions of operation of the system, the model having a first set of inputs including retention times determined during a number of operating condition sets; and a second input representative of the permeability of the column to the carrier gas, the data handling system possessing a prediction mechanism for putting into the model a set of conditions other than those of a) above and for putting in the set of parameters, and for predicting retention times for those conditions other than those of a).
    • 在具有固定相的柱和载气通过柱接触固定相的气相色谱系统中,该系统可用于检测样品中的分析物,用于预测分析物的保留时间的方法和装置 各种条件,所述方法采用以下步骤:a)在多种给定条件下检测分析物; b)基于包括补偿所述柱对所述载气的渗透性的校正的数学模型计算系统的各种参数特性的值; c)向模型中输入特征参数的值和至少一组另外的条件; 以及d)使用该模型预测除了步骤a之外的条件的保留时间; 该装置由包括用于在系统的各种操作条件下预测保留时间的模型的数据处理系统组成,该模型具有包括在多个操作条件集合中确定的保留时间的第一组输入; 以及表示所述列对所述载气的磁导率的第二输入,所述数据处理系统具有预测机构,用于将与上述a)不同的一组条件放入所述模型中,并用于投入所述参数集合;以及 用于预测除a)之外的条件的保留时间。
    • 6. 发明授权
    • Standardizing a spectrometric instrument
    • 标准化光谱仪
    • US6049762A
    • 2000-04-11
    • US993482
    • 1997-12-18
    • Alan M. GanzYongdong WangDavid H. TracyRobert A. HoultJerry E. CahillDavid A. Huppler
    • Alan M. GanzYongdong WangDavid H. TracyRobert A. HoultJerry E. CahillDavid A. Huppler
    • G01J3/28G01J3/453G01R35/00
    • G01J3/453G01J2003/2866
    • Standardization is achieved for FTIR spectrometric instruments that effect an intrinsic distortion in spectral information, the distortion being associated with an aperture size. An idealized function of spectral line shape is specified. With a small calibration aperture, spectral data is obtained for a basic sample having known "true" spectral data, and standard spectral data also is obtained for a standard sample. With a larger, normal sized aperture, standard spectral data is obtained again for the calibration sample. A transformation factor, that is a function of this data and the standardized function, is applied to spectral data for test samples to effect standardized information. In another embodiment, the standard sample has known true spectral data, and the basic sample is omitted. In either case, the transformation factor is applied to the sample data in logarithm form, the antilogarithm of the result effects the standardized information.
    • 对于影响光谱信息中的固有失真的FTIR光谱仪器实现标准化,失真与孔径尺寸相关联。 规定了光谱线形状的理想化功能。 使用小的校准孔径,获得具有已知“真实”光谱数据的基本样品的光谱数据,并且还为标准样品获得标准光谱数据。 对于较大的正常尺寸的孔径,再次为校准样品获得标准光谱数据。 作为该数据和标准化函数的函数的变换因子被应用于测试样本的光谱数据以实现标准化信息。 在另一个实施例中,标准样品具有已知的真实光谱数据,并省略了基本样品。 在任一种情况下,转换因子以对数形式应用于样本数据,结果的反对数效应影响标准化信息。
    • 10. 发明授权
    • Optical resonance analysis system
    • 光学共振分析系统
    • US06600563B1
    • 2003-07-29
    • US09486424
    • 2000-07-17
    • Dar BahattJerry E. CahillKoichi NishikidaEnrico G. PicozzaPaul G. SavianoDavid H. TracyYongdong Wang
    • Dar BahattJerry E. CahillKoichi NishikidaEnrico G. PicozzaPaul G. SavianoDavid H. TracyYongdong Wang
    • G01N2155
    • G01N21/7703G01N21/553
    • An optical resonance analysis system comprising a sensor means (60) and an illumination means (400) for generating non-monochromatic illumination. The illumination means (400) further comprises a means for generating illumination at a plurality of angles, a lens system for projecting said illumination at said plurality of angles (390) and a dispersive device (380) for dispersing said illumination at each of said plurality of angles so that there is a correlation between said plurality of angles and the wavelengths of said illumination such that a resonance condition is generated on said sensor mean (60) for all wavelengths generated by said non-monochromatic source simultaneously. The analysis system also comprises a detection means (90) for detecting the reflected or transmitted illumination. Another embodiment comprises an anamorphic imaging means (120).
    • 一种光学共振分析系统,包括传感器装置(60)和用于产生非单色照明的照明装置(400)。 照明装置(400)还包括用于以多个角度产生照明的装置,用于以所述多个角度(390)投射所述照明的透镜系统和用于将所述照明分散在所述多个角度的分散装置(380) 的角度,使得在所述多个角度和所述照明的波长之间存在相关性,使得对于由所述非单色源同时产生的所有波长的所述传感器平均值(60)产生共振条件。 分析系统还包括用于检测反射或透射照明的检测装置(90)。 另一实施例包括变形成像装置(120)。