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    • 1. 发明授权
    • Standardizing a spectrometric instrument
    • 标准化光谱仪
    • US6049762A
    • 2000-04-11
    • US993482
    • 1997-12-18
    • Alan M. GanzYongdong WangDavid H. TracyRobert A. HoultJerry E. CahillDavid A. Huppler
    • Alan M. GanzYongdong WangDavid H. TracyRobert A. HoultJerry E. CahillDavid A. Huppler
    • G01J3/28G01J3/453G01R35/00
    • G01J3/453G01J2003/2866
    • Standardization is achieved for FTIR spectrometric instruments that effect an intrinsic distortion in spectral information, the distortion being associated with an aperture size. An idealized function of spectral line shape is specified. With a small calibration aperture, spectral data is obtained for a basic sample having known "true" spectral data, and standard spectral data also is obtained for a standard sample. With a larger, normal sized aperture, standard spectral data is obtained again for the calibration sample. A transformation factor, that is a function of this data and the standardized function, is applied to spectral data for test samples to effect standardized information. In another embodiment, the standard sample has known true spectral data, and the basic sample is omitted. In either case, the transformation factor is applied to the sample data in logarithm form, the antilogarithm of the result effects the standardized information.
    • 对于影响光谱信息中的固有失真的FTIR光谱仪器实现标准化,失真与孔径尺寸相关联。 规定了光谱线形状的理想化功能。 使用小的校准孔径,获得具有已知“真实”光谱数据的基本样品的光谱数据,并且还为标准样品获得标准光谱数据。 对于较大的正常尺寸的孔径,再次为校准样品获得标准光谱数据。 作为该数据和标准化函数的函数的变换因子被应用于测试样本的光谱数据以实现标准化信息。 在另一个实施例中,标准样品具有已知的真实光谱数据,并省略了基本样品。 在任一种情况下,转换因子以对数形式应用于样本数据,结果的反对数效应影响标准化信息。
    • 2. 发明授权
    • Standardizing and calibrating a spectrometric instrument
    • 标准化和校准光谱仪
    • US5303165A
    • 1994-04-12
    • US834448
    • 1992-02-12
    • Alan M. GanzDavid H. TracyRobert A. Hoult
    • Alan M. GanzDavid H. TracyRobert A. Hoult
    • G01J3/02G01J3/28G02B5/28G01R35/00G01J3/42
    • G01J3/2803G01J3/28G01J2003/2866
    • A spectrometric instrument which exhibits an intrinsic profile for a sharp spectral line produces profile data for narrow spectral lines. The spectral lines are effected with a high finesse etalon of gold coated polymer. A transformation filter is computed for transforming the profile data to a gaussian profile. A wavelength calibration is combined with the filter to effect a correction matrix which is applied to sample data to generate calibrated standardized data. Iteratively a correction matrix is applied to calibration data to generate standardized calibration data which is utilized for the wavelength calibration. Calibration is effected with an optical standard, an interference etalon and a fringe formula. Etalon effective thickness is first estimated and then precisely determined so that fringe peaks calibrate wavelength.
    • 显示锋利光谱线的固有分布的光谱仪可以产生窄谱线的谱图数据。 光谱线用金涂层聚合物的高精密标准具实现。 计算转换滤波器以将简档数据变换为高斯分布。 波长校准与滤波器组合以实现校正矩阵,其被应用于采样数据以产生校准的标准化数据。 迭代地将校正矩阵应用于校准数据以产生用于波长校准的标准化校准数据。 用光学标准,干涉标准具和边缘公式进行校准。 首先估计Etalon有效厚度,然后精确确定边缘峰值校准波长。
    • 3. 发明授权
    • Optical probe for measuring light transmission of liquid
    • 用于测量液体透光性的光学探头
    • US5077481A
    • 1991-12-31
    • US603593
    • 1990-10-25
    • Robert A. Hoult
    • Robert A. Hoult
    • G01N21/03G01N21/27G01N21/59G01N21/85
    • G01N21/8507
    • An optical probe is for measurement of light transmission of liquid. A tubular housing three equally configured legs defining three arcuately spaced openings in the housing wall. A solid cylindrical member formed of glass or fused silica has a flat transparent end surface and an opposing curved surface silvered to form an internally concave reflector. The cylindrical member is retained in the housing with the transparent end surface adjacent to the openings. A transparent rod member has a flat first end surface and a flat second end surface parallel to the first end surface. The rod member is retained in the housing with the second end surface adjacent to the openings and spaced from the transparent end surface parallel thereto so as to define a cavity therebetween such that, upon immersion of the probe, liquid passes through the openings into the cavity. The first end surface is spaced from the concave reflector so that conjugate focal spots of the concave reflector are located at the first end surface. Two first optical fibers are affixed respectively to the focal spots. Light entering through one optical fiber passes twice through the liquid in the opening while being reflected by the concave reflector into the other optical fiber.
    • 光学探针用于测量液体的透光性。 管状壳体,三个相同构造的腿,其在壳体壁中限定三个弧形间隔开的开口。 由玻璃或熔融二氧化硅形成的实心圆柱形构件具有平坦的透明端面和镀银的相对曲面,以形成内凹反射器。 圆柱形构件保持在壳体中,透明端表面邻近开口。 透明杆构件具有平坦的第一端面和平行于第一端面的平坦的第二端面。 杆构件保持在壳体中,第二端表面与开口相邻并且与平行于其的透明端表面间隔开,以便在其间限定一个空腔,使得在浸入探针时,液体通过开口进入空腔 。 第一端表面与凹面反射器间隔开,使得凹面反射器的共轭焦斑位于第一端面。 两个第一光纤分别固定在焦点上。 通过一根光纤进入的光通过开口中的液体两次,同时被凹面反射器反射成另一根光纤。
    • 5. 发明授权
    • Optical device for measuring displacement
    • 用于测量位移的光学装置
    • US5099116A
    • 1992-03-24
    • US603587
    • 1990-10-25
    • Robert A. Hoult
    • Robert A. Hoult
    • G01D5/38G03F7/20G03F9/00
    • G03F7/70616G01D5/38G03F9/70
    • In optical device for measuring displacement an optical grating is formed of alternating transparent and opaque stripes having equal widths. The grating is in an aperture plane with the stripes parallel to a central plane that is perpendicular to the aperture plane. Respective subpluralities of the stripes are located in an aperture area in the aperture plane, so that incident light rays on the aperture area are at least partially passed as beams by the transparent strips in the aperture area. A concave mirror has it center of curvature at the aperture area so as to return the beams back to the aperture area. The return beams are further passed by the transparent strips in the aperture area as return light. The grating is displaceable laterally to the cental plane, such that a corresponding responsiveness of the return light intensity to the lateral position provides a measure of displacement of the grating relative to the central plane. Alternative device with reflecting strips function similarly.
    • 在用于测量位移的光学装置中,光栅由具有相等宽度的交替的透明和不透明条形成。 光栅处于孔平面中,条带平行于垂直于孔平面的中心平面。 条纹的各个子结构位于孔平面中的开口区域中,使得开口区域上的入射光线至少部分地作为光束通过孔区域中的透明条带传播。 凹面镜具有在孔径区域处的曲率中心,以使光束返回到孔径区域。 返回光束进一步通过作为返回光的孔区域中的透明条带。 光栅可以侧向移动到中心平面,使得返回光强度相对于横向位置的相应响应性提供了光栅相对于中心平面的位移的量度。 具有反射条的替代装置功能类似。
    • 6. 发明授权
    • Method and apparatus for comparing spectra
    • 比较光谱的方法和装置
    • US5023804A
    • 1991-06-11
    • US355587
    • 1989-05-23
    • Robert A. Hoult
    • Robert A. Hoult
    • G01J3/28G01N21/35
    • G01N21/35G01J3/28
    • In a method and a system for analyzing spectral data including a spectrophotometer and a spectral detector, a data station receives first transmittance spectrum data points and has a file register containing second transmittance spectrum data points. The first and second transmittance data points are transformed respectively to set of first and second absorbance spectrum data points. The first and second absorbance points are band pass filtered at a characteristic frequency nominally associated with spectral bandwidth so as to produce respective sets of first and second filtered data points. A set of weighting factors are established, each corresponding to the square of the sum of a first transmittance point and a second transmittance point for a selected frequency. A comparison factor is generated as a normalized sum of products over a selected spectral frequency range, each product being formed of a weighting factor and corresponding first and second absorbance data points for each selected spectral frequency.
    • 在用于分析分光光度计和光谱检测器的光谱数据的方法和系统中,数据站接收第一透射光谱数据点并具有包含第二透射光谱数据点的文件寄存器。 第一和第二透射率数据点分别变换为第一和第二吸收光谱数据点的集合。 第一吸收点和第二吸收点以与频谱带宽标称相关联的特征频率进行带通滤波,以产生各组第一和第二滤波数据点。 建立一组加权因子,每一个加权因子对应于所选频率的第一透射点和第二透射点之和的平方。 生成比较因子作为在所选光谱频率范围内的产物的归一化和,每个乘积由加权因子和对应于所选频谱频率的对应的第一和第二吸光度数据点形成。
    • 9. 发明授权
    • Optical switching device
    • 光开关器件
    • US5056886A
    • 1991-10-15
    • US603592
    • 1990-10-25
    • Robert A. Hoult
    • Robert A. Hoult
    • G02B6/35
    • G02B6/352G02B6/3556G02B6/3558G02B6/3574G02B6/3582
    • An optical switching device includes a first optical fiber terminating in a first window, and a plurality of second optical fibers each terminating in a corresponding second window. A concave mirror is selectively positionable with conjugate foci located respectively at the first window and selectively at any one of the second windows so as to reciprocally image the first window and a selected second window on each other. The imaging mirror is rotated about an axis spaced from and parallel to the optical axis of the mirror, so as to rotate the mirror among a plurality of arcuately spaced selected positions. In each selected position the imaging means closes a light circuit between the first optical fiber and a selected second optical fiber.
    • 一种光学开关装置包括终止在第一窗口中的第一光纤和多个第二光纤,每个第二光纤终止在相应的第二窗口中。 凹面镜可以选择性地定位于分别位于第一窗口处并且选择性地位于第二窗口中的任何一个的共轭焦点,以便使第一窗口和所选择的第二窗口彼此往复成像。 成像反射镜围绕与镜的光轴间隔开并平行的轴线旋转,以便使反射镜在多个弧形间隔的选定位置之间旋转。 在每个选择的位置,成像装置关闭第一光纤和所选择的第二光纤之间的光电路。
    • 10. 发明授权
    • Interactive smoothing system
    • 互动平滑系统
    • US4974209A
    • 1990-11-27
    • US497802
    • 1990-03-21
    • Robert A. Hoult
    • Robert A. Hoult
    • G01J3/02G01J3/28
    • G01J3/02G01J3/027G01J3/28
    • A method identifies components in a sample by spectrally analyzing the sample in a spectrophotometer. The sample data points output from the spectrophotometer are detected in a detector before being stored in an array in a data station. A preselected smoothing bandwidth is entered into the data station from a keyboard. The bandwidth is converted to a strength parameter; and thereafter each of the smoothed data points is stored before being output as an array of smoothed data points to form a modified spectral display, which identifies the components in the sample.
    • 方法通过在分光光度计中对样品进行光谱分析来识别样品中的组分。 在分光光度计输出的样品数据点在检测器中被检测到数据位于阵列中之前。 预先选择的平滑带宽从键盘输入数据站。 带宽转换为强度参数; 然后在平滑化的数据点的数组输出之前存储每个平滑的数据点,以形成修改的频谱显示,其标识样本中的分量。