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1. 发明申请

US20140031505A1 POLYOLEFIN GAS PHASE POLYMERIZATION WITH 3-SUBSTITUTED C4-10-ALKENE 审中-公开
标题翻译：具有3-取代的C4-10-烷基的聚烯烃气相聚合
公开(公告)号：US20140031505A1
公开(公告)日：2014-01-30
申请号：US14042799
申请日：2013-10-01
申请人： Michael GRASS , Ted M. Pettijohn , Stefan Buchholz , Gerhard Ellermann , Pal Bentzrod , Tore Dreng , Jarmo Lindroos
发明人： Michael GRASS , Ted M. Pettijohn , Stefan Buchholz , Gerhard Ellermann , Pal Bentzrod , Tore Dreng , Jarmo Lindroos
IPC分类号： C08F4/52
CPC分类号： C08F4/52 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08F2/34 , C08F4/65925 , C08F210/14 , C08F2500/08 , C08F2500/17 , C08F2500/12 , C08F2/001 , C08F2500/04 , C08F2500/11 , C08F2500/26 , C08F210/08
摘要： An alkene interpolymer is prepared by polymerizing at least one 3-substituted C4-10 alkene and at least one C2-8 alkene in a gas phase polymerization using a Ziegler Natta polymerization catalyst system.
摘要翻译：烯烃互聚物是通过使用齐格勒 - 纳塔（Ziegler Natta）聚合催化剂体系在气相聚合中聚合至少一种3-取代的C 4-10烯烃和至少一种C 2-8烯烃来制备的。

2. 发明申请

US20120010354A1 PE FILM SS COMPRISING INTERPOLYMERS WITH 3-SUBSTITUTED C4-10-ALKENE WITH SINGLE SITE CATALYSTS 审中-公开
标题翻译： PE膜包含具有单取代的C4-10-烷基单体催化剂的嵌段共聚物
公开(公告)号：US20120010354A1
公开(公告)日：2012-01-12
申请号：US13145199
申请日：2010-01-12
申请人： Michael Grass , Ted M. Pettijohn , Stefan Buchholz , Gerhard Ellermann , Tore Dreng , Arild Follestad , Jarmo Lindroos
发明人： Michael Grass , Ted M. Pettijohn , Stefan Buchholz , Gerhard Ellermann , Tore Dreng , Arild Follestad , Jarmo Lindroos
IPC分类号： C08L23/20 , B29C47/06 , C08L23/06 , C08L23/24 , C08F210/14 , C08F210/08
CPC分类号： C08J5/18 , C08F210/16 , C08J2323/08 , C08F210/08 , C08F2500/03 , C08F2500/08 , C08F2500/12 , C08F2500/17 , C08F2500/26
摘要： A film, comprising: an interpolymer of ethylene; and a 3-substituted C4-10 alkene, wherein said interpolymer is prepared using a catalyst system comprising a single site catalyst.
摘要翻译：一种膜，包括：乙烯的互聚物; 和3-取代的C4-10烯烃，其中所述互聚物是使用包含单中心催化剂的催化剂体系来制备的。

3. 发明授权

US08604142B2 Polyolefin gas phase polymerization with 3-substituted C4-10-alkene 失效
标题翻译：聚烯烃气相聚合与3-取代的C4-10-烯烃
公开(公告)号：US08604142B2
公开(公告)日：2013-12-10
申请号：US13145013
申请日：2010-01-12
申请人： Michael Grass , Ted Pettijohn , Stefan Buchholz , Gerhard Ellermann , Pal Bentzrod , Tore Dreng , Jarmo Lindroos
发明人： Michael Grass , Ted Pettijohn , Stefan Buchholz , Gerhard Ellermann , Pal Bentzrod , Tore Dreng , Jarmo Lindroos
IPC分类号： C08F4/24
CPC分类号： C08F4/52 , C08F210/06 , C08F210/16 , C08F2/34 , C08F210/14 , C08F2500/07 , C08F2500/08 , C08F2500/17 , C08F2500/12 , C08F2500/04
摘要： An alkene interpolymer is prepared by polymerizing at least one 3-substituted C4-10 alkene and at least one C2-8 alkene in a gas phase polymerization using a polymerization catalyst system.
摘要翻译：通过使用聚合催化剂体系在气相聚合中聚合至少一种3-取代的C4-10烯烃和至少一种C2-8烯烃来制备烯烃互聚物。

4. 发明申请

US20120022223A1 POLYOLEFIN GAS PHASE POLYMERIZATION WITH 3-SUBSTITUTED C4-10-ALKENE 失效
标题翻译：具有3-取代的C4-10-烷基的聚烯烃气相聚合
公开(公告)号：US20120022223A1
公开(公告)日：2012-01-26
申请号：US13145013
申请日：2010-01-12
申请人： Michael Grass , Ted Pettijohn , Stefan Buchholz , Gerhard Ellermann , Pal Bentzrod , Tore Dreng , Jarmo Lindroos
发明人： Michael Grass , Ted Pettijohn , Stefan Buchholz , Gerhard Ellermann , Pal Bentzrod , Tore Dreng , Jarmo Lindroos
IPC分类号： C08F2/34 , C08F210/04 , C08F210/14
CPC分类号： C08F4/52 , C08F210/06 , C08F210/16 , C08F2/34 , C08F210/14 , C08F2500/07 , C08F2500/08 , C08F2500/17 , C08F2500/12 , C08F2500/04
摘要： An alkene interpolymer is prepared by polymerizing at least one 3-substituted C4-10 alkene and at least one C2-8 alkene in a gas phase polymerization using a polymerization catalyst system.
摘要翻译：通过使用聚合催化剂体系在气相聚合中聚合至少一种3-取代的C4-10烯烃和至少一种C2-8烯烃来制备烯烃互聚物。

5. 发明授权

US09012564B2 Polyethylene/3-substituted alkene film made with Ziegler-Natta or chromium oxide catalyst 有权
标题翻译：用齐格勒 - 纳塔或氧化铬催化剂制成的聚乙烯/ 3-取代烯烃膜
公开(公告)号：US09012564B2
公开(公告)日：2015-04-21
申请号：US13145043
申请日：2010-01-12
申请人： Ted M Pettijohn , Michael Grass , Stefan Buchholz , Gerhard Ellermann , Anne Britt Bjaland , Arild Follestad , Jarmo Lindroos
发明人： Ted M Pettijohn , Michael Grass , Stefan Buchholz , Gerhard Ellermann , Anne Britt Bjaland , Arild Follestad , Jarmo Lindroos
IPC分类号： C08L23/18 , B29C49/22 , C08F210/14 , C08F210/08 , C08L23/06 , C08F210/16 , C08J5/18
CPC分类号： C08J5/18 , C08F210/16 , C08J2323/04 , C08J2323/08 , C08F210/08 , C08F2500/17 , C08F210/14
摘要： A film containing an interpolymer of ethylene and a 3-substituted C4-10 alkene is prepared using a catalyst system comprising a Ziegler Natta or chromium oxide catalyst.
摘要翻译：使用包含齐格勒纳塔或氧化铬催化剂的催化剂体系制备含有乙烯和3-取代的C 4-10烯烃互聚物的膜。

6. 发明申请

US20120022208A1 PE MIB FILM ZN/CR 有权
标题翻译： PE MIB FILM ZN / CR
公开(公告)号：US20120022208A1
公开(公告)日：2012-01-26
申请号：US13145043
申请日：2010-01-12
申请人： Ted M. Pettijohn , Michael Grass , Stefan Buchholz , Gerhard Ellermann , Anne Brit Bjaland , Arild Follestad , Jarmo Lindroos
发明人： Ted M. Pettijohn , Michael Grass , Stefan Buchholz , Gerhard Ellermann , Anne Brit Bjaland , Arild Follestad , Jarmo Lindroos
IPC分类号： C08L23/18 , B29C49/22 , C08F210/14 , C08F210/08 , C08L23/06
CPC分类号： C08J5/18 , C08F210/16 , C08J2323/04 , C08J2323/08 , C08F210/08 , C08F2500/17 , C08F210/14
摘要： A film containing an interpolymer of ethylene and a 3-substituted C4-10 alkene is prepared using a catalyst system comprising a Ziegler Natta or chromium oxide catalyst.
摘要翻译：使用包含齐格勒纳塔或氧化铬催化剂的催化剂体系制备含有乙烯和3-取代的C 4-10烯烃互聚物的膜。

7. 发明申请

US20120142882A1 PE MIB SLURRY POLYMERISATION 审中-公开
标题翻译： PE MIB浆液聚合
公开(公告)号：US20120142882A1
公开(公告)日：2012-06-07
申请号：US13145263
申请日：2010-01-12
申请人： Michael Grass , Ted Pettijohn , Stefan Buchholz , Gerhard Ellermann , Anne Britt Bjaland , Arild Follestad , Morten Lundquist
发明人： Michael Grass , Ted Pettijohn , Stefan Buchholz , Gerhard Ellermann , Anne Britt Bjaland , Arild Follestad , Morten Lundquist
IPC分类号： C08F210/08
CPC分类号： C08F210/16 , C08F4/65925 , C08F210/14 , C08F2/14 , C08F2500/03 , C08F2500/08 , C08F2500/12
摘要： An alkene interpolymer is prepared by polymerizing at least one 3-substituted C4-10 alkene and at least one C2-8 alkene in a slurry polymerization using a particulate catalyst system containing a single site catalyst.
摘要翻译：通过使用含有单位点催化剂的颗粒催化剂体系，在淤浆聚合中聚合至少一种3-取代的C 4-10烯烃和至少一种C 2-8烯烃来制备烯烃互聚物。

8. 发明授权

US08431638B2 Citric ester mixtures and their use 失效
标题翻译：柠檬酸酯混合物及其用途
公开(公告)号：US08431638B2
公开(公告)日：2013-04-30
申请号：US12990225
申请日：2009-05-05
申请人： Michael Grass , Stefan Buchholz , Wilfried Bueschken
发明人： Michael Grass , Stefan Buchholz , Wilfried Bueschken
IPC分类号： C08K5/10
CPC分类号： C07C69/704 , C08K5/0016 , C08K5/11
摘要： The present invention relates to mixtures of citric esters of the formula I, in which each of R1, R2 and R3 is an aliphatic C5 or C9 moiety, wherein the average chain length of the aliphatic moieties in the mixture is in the range from greater than 5 to 7, and the average degree of branching of the aliphatic C9 moieties is in the range from 0.9 to 2.2. The present invention also relates to the use of the citric ester mixture as a plasticizer in plastics compositions.
摘要翻译：本发明涉及式I的柠檬酸酯的混合物，其中R 1，R 2和R 3各自为脂族C 5或C 9部分，其中混合物中脂族部分的平均链长在大于 5至7，并且脂族C 9部分的平均支化度在0.9至2.2的范围内。本发明还涉及柠檬酸酯混合物作为塑料组合物中的增塑剂的用途。

9. 发明申请

US20110046283A1 CITRIC ESTER MIXTURES AND THEIR USE 失效
标题翻译： CITRIC ESTER MIXTURES及其使用
公开(公告)号：US20110046283A1
公开(公告)日：2011-02-24
申请号：US12990225
申请日：2009-05-05
申请人： Michael Grass , Stefan Buchholz , Wilfried Bueschken
发明人： Michael Grass , Stefan Buchholz , Wilfried Bueschken
IPC分类号： C08K5/12 , C08K5/11 , C09K3/00
CPC分类号： C07C69/704 , C08K5/0016 , C08K5/11
摘要： The present invention relates to mixtures of citric esters of the formula I, in which each of R1, R2 and R3 is an aliphatic C5 or C9 moiety, characterized in that the average chain length of the aliphatic moieties in the mixture is in the range from greater than 5 to 7, and the average degree of branching of the aliphatic C9 moieties is in the range from 0.9 to 2.2.The present invention also relates to the use of the citric ester mixture according to the invention as plasticizer in plastics compositions.The present invention also relates to a composition comprising the citric ester mixture according to the invention in a mixture with further components, comprising plasticizers from the group of the alkyl esters of aromatic polycarboxylic acids, of the cyclohexanepolycarboxylic acids, of benzoic acid or of adipic acid, and also to the use of this type of plasticizer composition in plastics compositions, in adhesives, in sealing compounds, in coatings, in paints, in plastisols or in inks. Plastics products produced from the plasticizers according to the invention can be, for example: profiles, gaskets, food packaging, foils, toys, medical items, roof sheeting, synthetic leather, floor coverings, underbody protection, coated textiles, wallpapers, cables and wire sheathing.
摘要翻译：本发明涉及式I的柠檬酸酯的混合物，其中R 1，R 2和R 3各自为脂族C 5或C 9部分，其特征在于混合物中脂族部分的平均链长在大于5至7，并且脂族C 9部分的平均支化度在0.9至2.2的范围内。本发明还涉及根据本发明的柠檬酸酯混合物在塑料组合物中作为增塑剂的用途。本发明还涉及包含根据本发明的柠檬酸酯混合物与其它组分的混合物的组合物，其包含来自芳族多元羧酸的烷基酯，环己烷多羧酸，苯甲酸或己二酸的增塑剂，以及在塑料组合物，粘合剂，密封化合物，涂料，涂料，增塑溶胶或油墨中使用这种类型的增塑剂组合物。根据本发明的由增塑剂生产的塑料产品可以是例如型材，垫圈，食品包装，箔，玩具，医疗用品，屋顶板，合成皮革，地板覆盖物，底部保护，涂布纺织品，壁纸，电缆和线护套

10. 发明申请

US20100291644A1 PROCESS FOR PREPARING METHACRYLIC ACID OR METHACRYLIC ESTERS 有权
标题翻译：制备甲基丙烯酸或甲基丙烯酸酯的方法
公开(公告)号：US20100291644A1
公开(公告)日：2010-11-18
申请号：US12602593
申请日：2008-05-30
申请人： Achim Marx , Markus Poetter , Stefan Buchholz , Alexander May , Hermann Siegert , Birgit Alber , Georg Fuchs , Lothar Eggeling
发明人： Achim Marx , Markus Poetter , Stefan Buchholz , Alexander May , Hermann Siegert , Birgit Alber , Georg Fuchs , Lothar Eggeling
IPC分类号： C12P7/62 , C12P7/40 , C12P7/44
CPC分类号： C12P7/42 , C08F120/06 , C08F120/10 , C12N9/0008 , C12N9/001 , C12N9/1096 , C12N9/16 , C12N9/88 , C12P7/40 , C12P7/52 , C12P7/625 , C12Y102/04004 , C12Y103/99012 , C12Y206/01042 , C12Y301/02004 , C12Y402/01017
摘要： The present invention relates to a process for the preparation of methacrylic acid or methacrylic esters, comprising the process steps of IA) preparation of 3-hydroxyisobutyric acid by a process comprising the process step of bringing a cell which has been genetically modified in comparison with its wild type in such a way that it is capable of forming more 3-hydroxyisobutyric acid, or polyhydroxyalkanoates based on 3-hydroxyisobutyric acid in comparison with its wild type, into contact with a nutrient medium comprising, as carbon source, carbohydrates, glycerol, carbon dioxide, methanol, L-valine or L-glutamate under conditions under which 3-hydroxyisobutyric acid or polyhydroxyalkanoates based on 3-hydroxyisobutyric acid are formed from the carbon source, if appropriate, isolation of the 3-hydroxyisobutyric acid from the nutrient medium and also, if appropriate, neutralization of the 3-hydroxyisobutyric acid, IB) dehydration of the 3-hydroxyisobutyric acid with formation of methacrylic acid and also, where appropriate, esterification methacrylic acid. The invention also relates to a process for the preparation of polymethacrylic acid or polymethacrylic esters.
摘要翻译：本发明涉及一种制备甲基丙烯酸或甲基丙烯酸酯的方法，其包括以下工艺步骤：IA）通过包括以下步骤的方法制备3-羟基异丁酸，所述方法包括将经遗传修饰的细胞与其野生型，使得其能够形成更多的3-羟基异丁酸或与其野生型相比基于3-羟基异丁酸的聚羟基链烷酸酯与营养培养基接触，所述营养培养基包含作为碳源的碳水化合物，甘油，碳二氧化物，甲醇，L-缬氨酸或L-谷氨酸盐，其中3-羟基异丁酸或基于3-羟基异丁酸的聚羟基链烷酸酯由碳源形成的条件下，如果合适，则从营养培养基中分离出3-羟基异丁酸，如果适当，中和3-羟基异丁酸，IB）3-羟基异丁酸脱水形成甲基丙烯酸酸，并且在适当的情况下酯化甲基丙烯酸。本发明还涉及一种制备聚甲基丙烯酸或聚甲基丙烯酸酯的方法。

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