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1. 发明授权

US5258567A Dehydrogenation of hydrocarbons 失效
标题翻译：烃的脱氢
公开(公告)号：US5258567A
公开(公告)日：1993-11-02
申请号：US935503
申请日：1992-08-26
申请人： Michael C. Kerby , Kenneth L. Riley , Fred M. Long , Jack W. Johnson , John F. Brody
发明人： Michael C. Kerby , Kenneth L. Riley , Fred M. Long , Jack W. Johnson , John F. Brody
IPC分类号： C07C5/09 , C07C5/32 , C07C5/333
CPC分类号： B01J29/049 , C07C5/324 , C07C5/325 , C07C5/3337
摘要： This invention relates to a process for the dehydrogenation of C.sub.2 -C.sub.10 hydrocarbons at dehydrogenation conditions with a pillared mica catalyst which contains an active metal selected from the group consisting of Pt, Cr and mixtures thereof, and a first modifier metal selected from the group consisting of Sn, Ga and mixtures thereof. The micas may also contain a second modifier metal selected from the group consisting of alkali metals, alkaline earth metals, and rare earth metals, and mixtures thereof.
摘要翻译：本发明涉及使用含有选自Pt，Cr及其混合物的活性金属的柱撑云母催化剂在脱氢条件下脱氢C2-C10烃的方法和选自以下的第一种改性金属：的Sn，Ga及其混合物。云母还可以含有选自碱金属，碱土金属和稀土金属的第二改性金属及其混合物。

2. 发明授权

US5340657A Pillared micas 失效
标题翻译：柱状云母
公开(公告)号：US5340657A
公开(公告)日：1994-08-23
申请号：US935504
申请日：1992-08-26
申请人： Michael C. Kerby , Kenneth L. Riley , Fred M. Long , Jack W. Johnson , John F. Brody
发明人： Michael C. Kerby , Kenneth L. Riley , Fred M. Long , Jack W. Johnson , John F. Brody
IPC分类号： B01J29/04 , B22F5/00 , B28D1/32
CPC分类号： B01J29/049 , Y10T428/12056
摘要： This invention relates to pillared micas, which comprise an active metal selected from the group consisting of Pt, Cr, Pd, It, Rh and mixtures thereof, and a first modifier metal selected from the group consisting of Sn, Ga and mixtures thereof. The mica may also be modified with a second modifier metal selected from the group consisting of alkali metals, alkaline earth metals, or rare earth metals and mixtures thereof. This invention further relates to a process for preparing such a catalyst.
摘要翻译：本发明涉及柱状云母，其包含选自Pt，Cr，Pd，It，Rh及其混合物的活性金属和选自Sn，Ga及其混合物的第一修饰金属。云母也可以用选自碱金属，碱土金属或稀土金属的第二种改性金属及其混合物进行改性。本发明还涉及制备这种催化剂的方法。

3. 发明授权

US5346871A Catalyst for dehydrogenation of paraffins 失效
标题翻译：石蜡脱氢催化剂
公开(公告)号：US5346871A
公开(公告)日：1994-09-13
申请号：US28442
申请日：1993-03-09
申请人： John L. Robbins , Elise Marucchi-Soos , Jack W. Johnson , John F. Brody
发明人： John L. Robbins , Elise Marucchi-Soos , Jack W. Johnson , John F. Brody
IPC分类号： B01J23/60 , B01J23/62 , B01J29/04 , C07C5/32 , C07C5/333 , B01J21/16 , B01J23/06 , B01J23/08
CPC分类号： B01J29/049 , B01J23/60 , B01J23/62 , C07C5/325 , C07C5/3337
摘要： The present invention is directed to a novel catalyst composition and its use in the dehydrogenation of paraffins to olefins. The catalyst comprises an alloy of a Group VIII noble metal and a metal selected from the group consisting of zinc and gallium on a support selected from the group consisting of silica, zinc oxide modified silica and zinc oxide modified silica-pillared clays when said alloy is a zinc alloy, and silica, gallium oxide modified silica and gallium oxide modified silica-pillared clays when said alloy is a gallium alloy. The instant catalyst is an active and selective catalyst for the catalytic dehydrogenation of paraffins to olefins, especially gaseous paraffins, having the added benefit of retaining high activity and selectivity even following repeated regeneration by calcination in oxygen containing gas at temperatures of 450.degree. C. to 650.degree. C., preferably 450.degree. C. to 500.degree. C.
摘要翻译：本发明涉及新型催化剂组合物及其在链烷烃脱氢成烯烃中的应用。所述催化剂包含由选自二氧化硅，氧化锌改性二氧化硅和氧化锌改性二氧化硅柱状粘土的载体上的第八族贵金属和选自锌和镓的金属的合金，当所述合金为锌合金，二氧化硅，氧化镓改性二氧化硅和氧化镓改性二氧化硅柱状粘土。本催化剂是用于将链烷烃催化脱氢成烯烃，特别是气态烷烃的活性和选择性催化剂，具有保持高活性和选择性的附加益处，即使在含氧气体中通过在450℃至450℃的温度下煅烧反复再生， 650℃，优选450℃至500℃

4. 发明授权

US5248644A Zirconia-pillared clays and micas 失效
标题翻译：氧化锆柱状粘土和云母
公开(公告)号：US5248644A
公开(公告)日：1993-09-28
申请号：US867581
申请日：1992-04-13
申请人： Jack W. Johnson , John F. Brody
发明人： Jack W. Johnson , John F. Brody
IPC分类号： B01J21/16 , B01D53/86 , B01J29/00 , B01J29/04 , C01B33/26 , C01B33/42 , C01B39/00
CPC分类号： B01J29/049
摘要： The present invention is directed to improved zirconia-pillared clays exhibiting high crystallinity and layer spacing and significantly higher thermal stability prepared using zirconyl acetate as the pillaring agent by: (a) mixing a clay selected from the group consisting of smectite clays and fluoromicas with a solution of zirconyl acetate for a time and at a temperature sufficient to form a pillared clay product; (b) separating said pillared clay product formed from the solution; (c) washing the separated pillared clay product with water; (d) drying the separated, washed pillared clay product at a temperature from about 50.degree. to 200.degree. C.; (e) calcining the dried pillared clay product at a temperature from about 300.degree. to 700.degree. C.
摘要翻译：本发明涉及改进的氧化锆柱状粘土，其表现出高结晶度和层间距，并且使用乙酸氧锆酯作为起始剂制备了显着更高的热稳定性，其方法是：（a）将选自蒙脱石粘土和氟代核的粘土与乙酸氧锆溶液一段时间并在足以形成柱状粘土产物的温度下进行; （b）分离由溶液形成的柱状粘土产品; （c）用水洗涤分离的柱状粘土产品; （d）在约50℃至200℃的温度下干燥分离的经洗涤的柱状粘土产品; （e）在约300℃至700℃的温度下煅烧干燥的柱状粘土产品。

5. 发明授权

US5476982A Catalyst for dehydrogenation of paraffins 失效
标题翻译：石蜡脱氢催化剂
公开(公告)号：US5476982A
公开(公告)日：1995-12-19
申请号：US259717
申请日：1994-06-14
申请人： John L. Robbins , Elise Marucchi-Soos , Jack W. Johnson , John F. Brody
发明人： John L. Robbins , Elise Marucchi-Soos , Jack W. Johnson , John F. Brody
IPC分类号： B01J23/60 , B01J23/62 , B01J29/04 , C07C5/32 , C07C5/333
CPC分类号： B01J29/049 , B01J23/60 , B01J23/62 , C07C5/325 , C07C5/3337
摘要： The present invention is directed to a novel catalyst composition and its use in the dehydrogenation of paraffins to olefins. The catalyst comprises an alloy of a Group VIII noble metal and a metal selected from the group consisting of zinc and gallium on a support selected from the group consisting of silica, zinc oxide modified silica and zinc oxide modified silica-pillared clays when said alloy is a zinc alloy, and silica, gallium oxide modified silica and gallium oxide modified silica-pillared clays when said alloy is a gallium alloy. The instant catalyst is an active and selective catalyst for the catalytic dehydrogenation of paraffins to olefins, especially gaseous paraffins, having the added benefit of retaining high activity and selectivity even following repeated regeneration by calcination in oxygen containing gas at temperatures of 450.degree. C. to 650.degree. C., preferably 450.degree. C. to 500.degree. C.
摘要翻译：本发明涉及新型催化剂组合物及其在链烷烃脱氢成烯烃中的应用。所述催化剂包含由选自二氧化硅，氧化锌改性二氧化硅和氧化锌改性二氧化硅 - 柱状粘土的载体上的第八族贵金属和选自锌和镓的金属的合金，当所述合金为锌合金，二氧化硅，氧化镓改性二氧化硅和氧化镓改性二氧化硅柱状粘土。本催化剂是用于将链烷烃催化脱氢成烯烃，特别是气态烷烃的活性和选择性催化剂，具有保持高活性和选择性的附加益处，即使在含氧气体中通过在450℃至450℃的温度下煅烧反复再生， 650℃，优选450℃至500℃

6. 发明授权

US5330734A Silica pillared micas 失效
标题翻译：硅胶柱状云母
公开(公告)号：US5330734A
公开(公告)日：1994-07-19
申请号：US28485
申请日：1993-03-09
申请人： Jack W. Johnson , John F. Brody
发明人： Jack W. Johnson , John F. Brody
IPC分类号： B01J20/12 , B01J21/16 , B01J29/04 , C01B33/42 , C01B39/00 , C01B33/26
CPC分类号： B01J29/049 , B01J20/12
摘要： Microporous materials of low acidity useful as sorbents and catalytic supports have been produced by pillaring tetrasilicic mica with silica polyoxocations generated by hydrolysis of organosilane precursors. Calcination at an intermediate temperature followed by washing of the solid with water is important in producing highly microporous material.
摘要翻译：通过用有机硅烷前体水解生成的二氧化硅聚氧化苯撑，将四硅云母作为吸附剂和催化剂载体，制备了低酸度的微孔材料。在中间温度下煅烧，然后用水洗涤固体对于生产高度微孔的材料是重要的。

7. 发明申请

US20180169617A1 Self-Supporting Structures Having Active Materials 审中-公开
公开(公告)号：US20180169617A1
公开(公告)日：2018-06-21
申请号：US15826269
申请日：2017-11-29
申请人： John F. Brody , Bradley Wooler , Francesco J. Altera , Paul J. Tindall , Yi Du
发明人： John F. Brody , Bradley Wooler , Francesco J. Altera , Paul J. Tindall , Yi Du
IPC分类号： B01J20/28 , B01D53/047 , B01D53/04 , B01D53/26 , B01J20/30 , B01J35/04 , B01J37/00 , B01J37/08
摘要： A method and system for manufacturing and using a self-supporting structure in processing unit for adsorption or catalytic processes. The self-supporting structure has greater than 50% by weight of the active material in the self-supporting structure to provide an open-celled structure providing access to the active material. The self-supporting structures, which may be disposed in a processing unit, may be used in swing adsorption processes and other processes to enhance the recovery of hydrocarbons.

8. 发明授权

US4078455A Broadhead arrow sharpening accessory 失效
标题翻译： Broadhead箭头磨刀配件
公开(公告)号：US4078455A
公开(公告)日：1978-03-14
申请号：US784163
申请日：1977-04-04
申请人： John F. Brody
发明人： John F. Brody
IPC分类号： B23D71/04 , B21K5/06
CPC分类号： B23D71/04
摘要： A broadhead arrow sharpening accessory adapted to receive a flat file between end blocks for sharpening the broadhead blades. The end blocks contain end slots formed therein for receiving the ends of the file. Parallel rods extend between the end blocks alongside the side edges of the flat file. Support carriages are slidably mounted on the rods for receiving the broadheads with a blade extending outward frictionally engaging a file surface. The carriage and broadhead are moved in unison along the rod with the blade edge frictionally engaging the filing surface to sharpen the blade edge at the desired bevel angle.
摘要翻译：一种宽头箭头磨刀配件，适用于在端块之间接收平面文件，用于磨削宽幅刀片。端块包含形成在其中的端槽，用于接收文件的端部。平行的杆在平面文件的侧边缘之间的端块之间延伸。支撑托架可滑动地安装在杆上，用于接收具有向外摩擦地与文件表面接合的刀片的宽头。托架和宽头杆沿着杆一致地移动，刀片边缘摩擦地接合到压片表面，以便以期望的斜角角度锐化叶片边缘。

9. 发明申请

US20180169565A1 Self-Supporting Structures Having Active Materials 审中-公开
公开(公告)号：US20180169565A1
公开(公告)日：2018-06-21
申请号：US15826283
申请日：2017-11-29
申请人： John F. Brody , Paul J. Tindall
发明人： John F. Brody , Paul J. Tindall
IPC分类号： B01D53/04 , C10L3/10 , B01J20/28 , B01J20/30
摘要： A method and system for manufacturing and using a self-supporting structure in processing unit for adsorption or catalytic processes. The self-supporting structure has greater than 50% by weight of the active material in the self-supporting structure to provide a foam-geometry structure providing access to the active material. The self-supporting structures, which may be disposed in a processing unit, may be used in swing adsorption processes and other processes to enhance the recovery of hydrocarbons.

10. 发明授权

US10001091B2 Vehicle powertrain with onboard catalytic reformer 有权
公开(公告)号：US10001091B2
公开(公告)日：2018-06-19
申请号：US15345715
申请日：2016-11-08
申请人： Brian M. Weiss , Walter Weissman , Tilman W. Beutel , John F. Brody , Eugine Choi , Wenjun Li , Paul D. Madiara , Chris E. Esther Kliewer , Karl G. Strohmaier , Scott J. Weigel , Brett Loveless , Makoto Kioke , Hiroshi Miyagawa
发明人： Brian M. Weiss , Walter Weissman , Tilman W. Beutel , John F. Brody , Eugine Choi , Wenjun Li , Paul D. Madiara , Chris E. Esther Kliewer , Karl G. Strohmaier , Scott J. Weigel , Brett Loveless , Makoto Kioke , Hiroshi Miyagawa
IPC分类号： F01N3/20 , F02M27/02 , C10L3/10 , F02B43/12 , F02B51/02 , F02M21/02 , B01J29/44 , B01J29/74 , B01J29/80 , C10L3/00 , C01B3/40 , B01J23/63 , B01J29/068 , F02M26/35 , F02M26/36 , F02M26/20 , B01J21/04 , B01J21/08 , B01J23/10 , B01J23/46 , B01J29/00 , B01J29/70 , B01J29/85 , C10L3/08 , F02B37/013 , F02B43/10 , F02M26/05
CPC分类号： F02M27/02 , B01J21/04 , B01J21/08 , B01J23/10 , B01J23/464 , B01J23/63 , B01J29/005 , B01J29/068 , B01J29/44 , B01J29/70 , B01J29/743 , B01J29/80 , B01J29/85 , B01J2523/00 , C01B3/40 , C01B2203/0233 , C01B2203/0238 , C01B2203/1047 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1241 , C01B2203/1247 , C01B2203/84 , C10L3/00 , C10L3/08 , C10L3/10 , C10L2230/22 , C10L2270/02 , C10L2290/02 , C10L2290/06 , C10L2290/24 , F01N3/20 , F02B37/013 , F02B43/12 , F02B51/02 , F02B61/02 , F02B2043/103 , F02M21/0227 , F02M26/05 , F02M26/20 , F02M26/35 , F02M26/36 , Y02P20/142 , Y02P20/52 , Y02T10/126 , Y02T10/32 , B01J2523/31 , B01J2523/3706 , B01J2523/3712 , B01J2523/48 , B01J2523/822
摘要： Catalyst compositions suitable for use in the exhaust gas recycle stream of an internal combustion engine are provided. Such catalyst compositions typically provide significant amounts of methane in addition to syngas. A reformer incorporating such a catalyst for use in an exhaust gas recycle portion of an internal combustion engine powertrain is described. A powertrain incorporating such a reformer, a method of increasing the octane rating of an exhaust gas recycle stream, and a method of operating an internal combustion engine using methane-assisted combustion are also described.

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