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1. 发明授权

US08709283B2 Phosphor, light emitting apparatus, and liquid crystal display apparatus using the same 有权
标题翻译：荧光体，发光装置和使用其的液晶显示装置
公开(公告)号：US08709283B2
公开(公告)日：2014-04-29
申请号：US13500803
申请日：2010-12-16
申请人： Masatsugu Masuda , Masamichi Harada , Hitoshi Matsushita , Kenji Terashima
发明人： Masatsugu Masuda , Masamichi Harada , Hitoshi Matsushita , Kenji Terashima
IPC分类号： C09K11/64 , C09K11/08 , C09K11/62 , H01L33/50 , G02F1/13357 , C09K11/77 , G02F1/1335
CPC分类号： H01L33/504 , C09K11/0883 , C09K11/7734 , G02F1/1336 , G02F1/133603 , H01L33/502 , H01L2224/48091 , H01L2224/48247 , H01L2224/48257 , Y10T428/2982 , H01L2924/00014
摘要： A phosphor as a divalent europium-activated oxynitride green light emitting phosphor which is a β-type SiAlON substantially represented by a general formula (A): EuaSibAlcOdNe (where a, b, c, d, and e are numbers satisfying 0.005≦a≦0.4, b+c=12, and d+e=16), and having an average particle size (d1) (determined by an air permeability method) of 9 to 16 μm, a median diameter (50% D) in particle size distribution of 12.5 to 35 μm, 50% D/d1 of 1.4 to 2.2, and an absorptance at 600 nm of not more than 8.0%, and a light emitting apparatus, a BL light source apparatus, and a liquid crystal display device using the same are provided, to provide a light emitting apparatus with a high efficiency and a stable characteristic and a liquid crystal display apparatus using the same by using the β-type SiAlON having controlled dispersibility and improved transparency.
摘要翻译：作为基本上由通式（A）表示的基本上由通式（A）表示的SiAlON的二价铕活化的氮氧化物绿色发光荧光体的荧光体：EuaSibAlcOdNe（其中a，b，c，d和e是满足0.005＆nlE的数; a，n = e，0.4，b + c = 12，d + e = 16），平均粒径（d1）（透气度法测定）为9〜16μm，中值粒径（50％D）粒径分布为12.5〜35μm，50％D / d1为1.4〜2.2，吸收率为600nm以下为8.0％以下，发光装置，BL光源装置以及液晶显示装置提供了使用它们以提供具有高效率和稳定特性的发光装置，以及使用具有受控分散性和改进的透明度的“SiAlON”的液晶显示装置。

2. 发明申请

US20120194762A1 PHOSPHOR, LIGHT EMITTING APPARATUS, AND LIQUID CRYSTAL DISPLAY APPARATUS USING THE SAME 有权
标题翻译：磷光体，发光装置和使用其的液晶显示装置
公开(公告)号：US20120194762A1
公开(公告)日：2012-08-02
申请号：US13500803
申请日：2010-12-16
申请人： Masatsugu Masuda , Masamichi Harada , Hitoshi Matsushita , Kenji Terashima
发明人： Masatsugu Masuda , Masamichi Harada , Hitoshi Matsushita , Kenji Terashima
IPC分类号： G02F1/1335 , C01B33/00 , H01L33/44
CPC分类号： H01L33/504 , C09K11/0883 , C09K11/7734 , G02F1/1336 , G02F1/133603 , H01L33/502 , H01L2224/48091 , H01L2224/48247 , H01L2224/48257 , Y10T428/2982 , H01L2924/00014
摘要： A phosphor as a divalent europium-activated oxynitride green light emitting phosphor which is a β-type SiAlON substantially represented by a general formula (A): EuaSibAlcOdNe (where a, b, c, d, and e are numbers satisfying 0.005≦a≦0.4, b+c=12, and d+e=16), and having an average particle size (d1) (determined by an air permeability method) of 9 to 16 μm, a median diameter (50% D) in particle size distribution of 12.5 to 35 μm, 50% D/d1 of 1.4 to 2.2, and an absorptance at 600 nm of not more than 8.0%, and a light emitting apparatus, a BL light source apparatus, and a liquid crystal display device using the same are provided, to provide a light emitting apparatus with a high efficiency and a stable characteristic and a liquid crystal display apparatus using the same by using the β-type SiAlON having controlled dispersibility and improved transparency.
摘要翻译：作为基本上由通式（A）表示的基本上由通式（A）表示的SiAlON的二价铕活化的氮氧化物绿色发光荧光体的荧光体：EuaSibAlcOdNe（其中a，b，c，d和e是满足0.005＆nlE的数; a，n = e，0.4，b + c = 12，d + e = 16），平均粒径（d1）（透气度法测定）为9〜16μm，中值粒径（50％D）粒径分布为12.5〜35μm，50％D / d1为1.4〜2.2，吸收率为600nm以下为8.0％以下，发光装置，BL光源装置以及液晶显示装置提供了使用它们以提供具有高效率和稳定特性的发光装置，以及使用具有受控分散性和改进的透明度的“SiAlON”的液晶显示装置。

3. 发明申请

US20130037846A1 RED LIGHT EMITTING PHOSPHOR, METHOD FOR MANUFACTURING THE SAME AND LIGHT EMITTING APPARATUS EMPLOYING RED LIGHT EMITTING PHOSPHOR 审中-公开
标题翻译：红色发光磷光体，其制造方法和使用红色发光磷光体的发光装置
公开(公告)号：US20130037846A1
公开(公告)日：2013-02-14
申请号：US13655148
申请日：2011-04-05
申请人： Masamichi Harada , Toyonori Uemura , Hiroshi Fukunaga , Hitoshi Matsushita , Kenji Terashima
发明人： Masamichi Harada , Toyonori Uemura , Hiroshi Fukunaga , Hitoshi Matsushita , Kenji Terashima
IPC分类号： C09K11/79 , C09K11/80 , H01L33/50
CPC分类号： C09K11/0883 , C09K11/7734 , H01L33/502 , H01L2224/48091 , H01L2224/48247 , H01L2224/48257 , H01L2224/73265 , H01L2924/181 , H01L2924/00014 , H01L2924/00012
摘要： The present invention relates to a divalent europium-activated nitride red light emitting phosphor substantially represented by a general formula: (MI1-xEux)MIISiN3 (1) (in the formula (1), MI is an alkaline-earth metal element and represents at least one element selected from the group consisting of Mg, Ca, Sr, and Ba; MII is a trivalent metal element and represents at least one element selected from the group consisting of Al, Ga, In, Sc, Y, La, Gd, and Lu; and x is the number satisfying 0.001≦x≦0.10), in which the electrical conductivity of a supernatant liquid of the solution containing 10 parts by mass of pure water with respect to 1 part by mass of the red light emitting phosphor is not more than 10 mS/cm.
摘要翻译：本发明涉及一种基本上由通式（MI1-xEux）MIISiN3（1）表示的二价铕活化氮化物红色发光荧光体（式（1）中，MI为碱土金属元素，选自Mg，Ca，Sr和Ba中的至少一种元素; MII是三价金属元素，并且表示选自Al，Ga，In，Sc，Y，La，Gd中的至少一种元素，和Lu; x是满足0.001＆nlE; x＆nlE; 0.10）的数量，其中相对于1质量份的红色发光荧光体，含有10质量份纯水的溶液的上清液的电导率不超过10 mS / cm。

4. 发明授权

US08686631B2 Phosphor particle group and light emitting apparatus using the same 有权
标题翻译：荧光体组和使用其的发光装置
公开(公告)号：US08686631B2
公开(公告)日：2014-04-01
申请号：US13303907
申请日：2011-11-23
申请人： Tetsuya Hanamoto , Masatsugu Masuda , Kenji Terashima
发明人： Tetsuya Hanamoto , Masatsugu Masuda , Kenji Terashima
IPC分类号： H01L51/50
CPC分类号： H01L33/502 , C01B21/0826 , C01P2004/54 , C01P2004/61 , C01P2006/60 , C04B35/597 , C04B2235/3224 , C04B2235/5296 , C04B2235/5436 , C04B2235/767 , C04B2235/9646 , C09K11/0883 , C09K11/7734 , H01L2224/48091 , H01L2224/48247 , H01L2224/48257 , H01L2224/73265 , H01L2924/181 , Y10T428/2982 , H01L2924/00014 , H01L2924/00012
摘要： Provided is a phosphor particle group of divalent europium-activated oxynitride green light emitting phosphor particles each of which is a β-type SiAlON substantially represented by a general formula: EuaSibAlcOdNe, where 0.005≦a≦0.4, b+c=12, d+e=16, wherein 60% or more of the phosphor particle group is composed of the phosphor particles in which a value obtained by dividing a longer particle diameter by a shorter particle diameter is greater than 1.0 and not greater than 3.0. A high-efficiency and stable light emitting apparatus using a β-type SiAlON, which includes a light converter using the phosphor particle group, and a phosphor particle group therefor are also provided.
摘要翻译：本发明提供一种二价铕活化氮氧化物绿色发光荧光体颗粒的荧光体颗粒，其各自为基本上由通式：EuaSibAlcOdNe表示的“SiAlON”，其中0.005≤n1E; a＆nlE; 0.4，b + c = 12， d + e = 16，其中，荧光体粒子群的60％以上由荧光体粒子构成，其中通过将更长的粒径除以更短的粒径而获得的值大于1.0且不大于3.0。还提供了一种使用包含使用荧光体颗粒基团的光转换器和其荧光体粒子群的“SiAlON”的高效稳定的发光装置。

5. 发明申请

US20110043101A1 LIGHT-EMITTING DEVICE 有权
标题翻译：发光装置
公开(公告)号：US20110043101A1
公开(公告)日：2011-02-24
申请号：US12920516
申请日：2009-02-06
申请人： Masatsugu Masuda , Kenji Terashima
发明人： Masatsugu Masuda , Kenji Terashima
IPC分类号： H01J1/63
CPC分类号： H01L33/504 , C09K11/0883 , C09K11/7734 , G02F1/1336 , G02F2001/133614 , H01L33/32 , H01L33/502 , H01L33/505 , H01L33/507 , H01L33/56 , H01L2224/48091 , H01L2224/48247 , H05B33/14 , H01L2924/00014
摘要： Disclosed is a light-emitting device including a light-emitting element emitting primary light, and a light converter absorbing a part of the primary light emitted from the light-emitting element and emitting secondary light having a longer wavelength than the primary light. The light converter contains a green light-emitting phosphor and a red light-emitting phosphor. The green light-emitting phosphor is composed of at least one phosphor selected from a divalent europium-activated oxynitride phosphor substantially represented by the following formula: EuaSibAlcOdNe and a divalent europium-activated silicate phosphor substantially represented by the following formula: 2(Ba1-f-gMIfEug)O.SiO2, while the red light-emitting phosphor is composed of at least one phosphor selected from tetravalent manganese-activated fluoro-tetravalent metalate phosphors substantially represented by the following formulae: MII2(MIII1-hMnh)F6 and/or MIV(MIII1-hMnh)F6. Consequently, the light-emitting device has excellent color gamut (NTSC ratio).
摘要翻译：公开了一种发光装置，其包括发射初级光的发光元件和吸收从发光元件发射的一次光的一部分并发射具有比初级光更长波长的二次光的光转换器。光转换器包含绿色发光荧光体和红色发光荧光体。绿色发光荧光体由至少一种选自基本上由下式表示的二价铕活化氮氧化物荧光体的荧光体组成：EuaSibAlcOdNe和基本上由下式表示的二价铕活化硅酸盐荧光体：2（Ba1-f -gMIfEug）O.SiO 2，而红色发光荧光体由至少一种选自基本上由下式表示的四价锰活化的氟代四价金属化物荧光体的荧光体组成：MII2（MIII1-hMnh）F6和/或MIV （MIII1-hMnh）F6。因此，发光装置具有优异的色域（NTSC比）。

6. 发明授权

US08362685B2 Light-emitting device 有权
公开(公告)号：US08362685B2
公开(公告)日：2013-01-29
申请号：US13542051
申请日：2012-07-05
申请人： Masatsugu Masuda , Kenji Terashima
发明人： Masatsugu Masuda , Kenji Terashima
IPC分类号： H01J1/62 , H01J63/04 , C09K11/08
CPC分类号： H01L33/504 , C09K11/0883 , C09K11/7734 , G02F1/1336 , G02F2001/133614 , H01L33/32 , H01L33/502 , H01L33/505 , H01L33/507 , H01L33/56 , H01L2224/48091 , H01L2224/48247 , H05B33/14 , H01L2924/00014
摘要： Disclosed is a light-emitting device (1) including a light-emitting element (2) emitting primary light, and a light converter (3) absorbing a part of the primary light emitted from the light-emitting element (2) and emitting secondary light having a longer wavelength than the primary light. The light converter (3) contains a green light-emitting phosphor (4) and a red light-emitting phosphor (5). The green light-emitting phosphor (4) is composed of at least one phosphor selected from a divalent europium-activated oxynitride phosphor substantially represented by the following formula: EuaSibAlcOdNe and a divalent europium-activated silicate phosphor substantially represented by the following formula: 2(Ba1-f-gMIfEug)O.SiO2, while the red light-emitting phosphor (5) is composed of at least one phosphor selected from tetravalent manganese-activated fluoro-tetravalent metalate phosphors substantially represented by the following formulae: MII2(MIII1-hMnh)F6 and/or MIV(MIII1-hMnh)F6. Consequently, the light-emitting device (1) has excellent color gamut (NTSC ratio).

7. 发明申请

US20120267669A1 LIGHT-EMITTING DEVICE 有权
标题翻译：发光装置
公开(公告)号：US20120267669A1
公开(公告)日：2012-10-25
申请号：US13542051
申请日：2012-07-05
申请人： Masatsugu MASUDA , Kenji Terashima
发明人： Masatsugu MASUDA , Kenji Terashima
IPC分类号： H01L33/50
CPC分类号： H01L33/504 , C09K11/0883 , C09K11/7734 , G02F1/1336 , G02F2001/133614 , H01L33/32 , H01L33/502 , H01L33/505 , H01L33/507 , H01L33/56 , H01L2224/48091 , H01L2224/48247 , H05B33/14 , H01L2924/00014
摘要： Disclosed is a light-emitting device (1) including a light-emitting element (2) emitting primary light, and a light converter (3) absorbing a part of the primary light emitted from the light-emitting element (2) and emitting secondary light having a longer wavelength than the primary light. The light converter (3) contains a green light-emitting phosphor (4) and a red light-emitting phosphor (5). The green light-emitting phosphor (4) is composed of at least one phosphor selected from a divalent europium-activated oxynitride phosphor substantially represented by the following formula: EuaSibAlcOdNe and a divalent europium-activated silicate phosphor substantially represented by the following formula: 2(Ba1-f-gMIfEug)O.SiO2, while the red light-emitting phosphor (5) is composed of at least one phosphor selected from tetravalent manganese-activated fluoro-tetravalent metalate phosphors substantially represented by the following formulae: MII2(MIII1-hMnh)F6 and/or MIV(MIII1-hMnh)F6. Consequently, the light-emitting device (1) has excellent color gamut (NTSC ratio).
摘要翻译：公开了一种发光装置（1），其包括发射初级光的发光元件（2）和吸收从发光元件（2）发射的一次光的一部分并发射次级的光转换器（3）具有比初级光更长的波长的光。光转换器（3）包含绿色发光荧光体（4）和红色发光荧光体（5）。绿色发光荧光体（4）由选自实质上由下式表示的二价铕活化氮氧化物荧光体中的至少一种荧光体构成：EuaSibAlcOdNe和基本上由下式表示的二价铕活化硅酸盐荧光体：2（ BaI-f-gMIfEug）O.SiO 2，而红色发光荧光体（5）由至少一种选自基本上由下式表示的四价锰活化的氟代四价金属化物荧光体的荧光体组成：MII2（MIII1-hMnh ）F6和/或MIV（MIII1-hMnh）F6。因此，发光装置（1）具有优异的色域（NTSC比）。

8. 发明申请

US20120026426A1 GROUP OF PHOSPHOR PARTICLES, LIGHT-EMITTING DEVICE USING SAME, AND LIQUID CRYSTAL TELEVISION RECEIVER 有权
标题翻译：磷化物颗粒组，使用相同的发光装置和液晶电视接收器
公开(公告)号：US20120026426A1
公开(公告)日：2012-02-02
申请号：US13263053
申请日：2010-04-02
申请人： Tetsuya Hanamoto , Masatsugu Masuda , Kenji Terashima , Hideyuki Emoto , Hironori Nagasaki
发明人： Tetsuya Hanamoto , Masatsugu Masuda , Kenji Terashima , Hideyuki Emoto , Hironori Nagasaki
IPC分类号： G02F1/1335 , C09K11/80 , H01L33/44
CPC分类号： C09K11/7734 , C09K11/0883 , H01L33/502 , H05B33/14
摘要： Provided is a phosphor particle group of divalent europium-activated oxynitride green light emitting phosphor particles (1) each of which is a β-type SiAlON represented by a general formula: EuaSibAlcOdNe, where 0.005≦a≦0.4, b+c=12, d+e=16, wherein a mean value of a value obtained by dividing a longer particle diameter by a shorter particle diameter is not greater than 1.75. Also provided are a light emitting apparatus (11) using the phosphor particle group in a light converter (13), and a liquid crystal display television using the light emitting apparatus (11). With these, a high-efficiency and stable light emitting apparatus using a β-type SiAlON, and a phosphor particle group therefor are provided.
摘要翻译：本发明提供一种二价铕活化氮氧化物绿色发光荧光体颗粒（1）的荧光体粒子群，每一种都是由通式：EuaSibAlcOdNe表示的“SiAlON”，其中0.005＆nlE; a＆nlE; 0.4，b + c = 12，d + e = 16，其中通过将较长粒径除以更短粒径而获得的值的平均值不大于1.75。还提供了在光转换器（13）中使用荧光体颗粒群的发光装置（11）和使用该发光装置的液晶显示电视机。利用这些，提供了使用“SiAlON”型的高效稳定的发光装置及其荧光体粒子群。

9. 发明授权

US09000664B2 Phosphor particle group, light emitting apparatus using the same, and liquid crystal display television 有权
标题翻译：荧光体粒子群，使用其的发光装置，以及液晶显示电视机
公开(公告)号：US09000664B2
公开(公告)日：2015-04-07
申请号：US13263053
申请日：2010-04-02
申请人： Tetsuya Hanamoto , Masatsugu Masuda , Kenji Terashima , Hideyuki Emoto , Hironori Nagasaki
发明人： Tetsuya Hanamoto , Masatsugu Masuda , Kenji Terashima , Hideyuki Emoto , Hironori Nagasaki
IPC分类号： C09K11/64 , C09K11/78 , H01L33/50 , C09K11/77 , C09K11/08 , H05B33/14
CPC分类号： C09K11/7734 , C09K11/0883 , H01L33/502 , H05B33/14
摘要： Provided is a phosphor particle group of divalent europium-activated oxynitride green light emitting phosphor particles each of which is a β-type SiAlON represented by a general formula: EuaSibAlcOdNe, where 0.005≦a≦0.4, b+c=12, d+e=16, wherein a mean value of a value obtained by dividing a longer particle diameter by a shorter particle diameter is not greater than 1.75. Also provided are a light emitting apparatus using the phosphor particle group in a light converter, and a liquid crystal display television using the light emitting apparatus. With these, a high-efficiency and stable light emitting apparatus using a β-type SiAlON, and a phosphor particle group therefor are provided.
摘要翻译：提供了二价铕激活的氮氧化物绿色发光荧光体颗粒的荧光体颗粒组，每个都是由通式EuaSibAlcOdNe表示的“SiAlON”，其中0.005和nlE; a＆nlE; 0.4，b + c = 12，d + e = 16，其中通过将较长粒径除以更短粒径而获得的值的平均值不大于1.75。还提供了在光转换器中使用荧光体粒子群的发光装置和使用该发光装置的液晶显示电视机。利用这些，提供了使用“SiAlON”型的高效稳定的发光装置及其荧光体粒子群。

10. 发明授权

US08237348B2 Light-emitting device 有权
标题翻译：发光装置
公开(公告)号：US08237348B2
公开(公告)日：2012-08-07
申请号：US12920516
申请日：2009-02-06
申请人： Masatsugu Masuda , Kenji Terashima
发明人： Masatsugu Masuda , Kenji Terashima
IPC分类号： H01J1/62 , H01J63/04 , C09K11/08
CPC分类号： H01L33/504 , C09K11/0883 , C09K11/7734 , G02F1/1336 , G02F2001/133614 , H01L33/32 , H01L33/502 , H01L33/505 , H01L33/507 , H01L33/56 , H01L2224/48091 , H01L2224/48247 , H05B33/14 , H01L2924/00014
摘要： Disclosed is a light-emitting device including a light-emitting element emitting primary light, and a light converter absorbing a part of the primary light emitted from the light-emitting element and emitting secondary light having a longer wavelength than the primary light. The light converter contains a green light-emitting phosphor and a red light-emitting phosphor. The green light-emitting phosphor is composed of at least one phosphor selected from a divalent europium-activated oxynitride phosphor substantially represented by the following formula: EuaSibAlcOdNe and a divalent europium-activated silicate phosphor substantially represented by the following formula: 2 (Ba1-f-gMIfEug)O.SiO2, while the red light-emitting phosphor is composed of at least one phosphor selected from tetravalent manganese-activated fluoro-tetravalent metalate phosphors substantially represented by the following formulae: MII2(MIII1-hMnh)F6 and/or MIV(MIII1-hMnh)F6. Consequently, the light-emitting device has excellent color gamut (NTSC ratio).
摘要翻译：公开了一种发光装置，其包括发射初级光的发光元件和吸收从发光元件发射的一次光的一部分并发射具有比初级光更长波长的二次光的光转换器。光转换器包含绿色发光荧光体和红色发光荧光体。绿色发光荧光体由至少一种选自基本上由下式表示的二价铕活化氮氧化物荧光体的荧光体组成：EuaSibAlcOdNe和基本上由下式表示的二价铕活化硅酸盐荧光体：2（Ba1-f -gMIfEug）O.SiO 2，而红色发光荧光体由至少一种选自基本上由下式表示的四价锰活化的氟代四价金属化物荧光体的荧光体组成：MII2（MIII1-hMnh）F6和/或MIV （MIII1-hMnh）F6。因此，发光装置具有优异的色域（NTSC比）。

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