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    • 7. 发明申请
    • PHOSPHOR, LIGHT-EMITTING DEVICE AND USE THEREOF
    • 磷光体,发光装置及其用途
    • US20130328478A1
    • 2013-12-12
    • US13885096
    • 2011-11-16
    • Hideyuki Emoto
    • Hideyuki Emoto
    • C09K11/77H05B33/14
    • C09K11/7721C09K11/0883H01L33/502H05B33/14Y02B20/181
    • The present invention provides: a phosphor which can be combined with a blue LED to emit white light having a low color temperature as in the case where the phosphor is used singly, has a broad fluorescence spectrum, high light emission efficiency, and thermal/chemical stability, and rarely undergoes the deterioration in brightness at higher temperatures. This phosphor is represented by the general formula: Mx(Si,Al)2(N,O)3±y (wherein M independently represent Li or at least one alkali earth metal element; and x and y fulfill the requirement represented by the formulae: 0.52≦x≦0.9 and 0≦y≦0.3) wherein some of M are substituted by element Ce, and wherein the Si/Al atomic ratio is 1.5 to 6 inclusive, the O/N atomic ratio is 0 to 0.1 inclusive, 5-50 mol % of M's is Li, and 0.5-10 mol % of M is Ce.
    • 本发明提供:与单独使用荧光体的情况相同,可以与蓝色LED组合发光色温度低的白光的荧光体具有宽荧光光谱,高发光效率和热/化学 稳定性,并且在较高温度下很少发生亮度劣化。 该荧光体由以下通式表示:Mx(Si,Al)2(N,O)3±y(其中M独立地表示Li或至少一种碱土金属元素; x和y满足式 :0.52 @ x @ 0.9和0 @ y @ 0.3)其中M中的一些被元素Ce取代,并且其中Si / Al原子比为1.5〜6,其中O / N原子比为0〜0.1,其中5 -50摩尔%的M为Li,0.5-10摩尔%的M为Ce。
    • 9. 发明授权
    • β type sialon fluorescent substance
    • &bgr 型赛隆荧光物质
    • US08003011B2
    • 2011-08-23
    • US11914272
    • 2006-05-10
    • Naoto HirosakiHideyuki EmotoMasahiro Ibukiyama
    • Naoto HirosakiHideyuki EmotoMasahiro Ibukiyama
    • C09K11/64
    • C09K11/0883C09K11/7734Y02B20/181
    • A β type Sialon fluorescent substance is disclosed that is capable of achieving enhanced brightness of a white light emitting diode using blue to ultraviolet light as a light source. In the fluorescent substance which contains not less than 90% by mass of a β type Sialon composition represented by general formula: Si6-zAlzOzN8-z as a host material wherein z is not less than 0.24 and not more than 0.42, Eu is present dissolved in solid solution as a luminescent center at a content of 0.05 to 0.2% by atom. The β type Sialon fluorescent substance is preferably in the form of a powder having an average particle size of not less than 1 μm and not more than 20 μm. A white LED of good luminescent characteristics can be obtained by using a blue or ultraviolet light emitting diode as a excitation light source in combination with a fluorescent substance that emits yellow or red light.
    • A&bgr 公开了能够实现使用蓝色至紫外光作为光源的白色发光二极管的增强亮度的型号赛隆荧光物质。 在含有不少于90质量%的&bgr的荧光物质中, 由通式Si 6-z Al z O z N 8-z表示的Sialon组合物作为主体材料,其中z不小于0.24且不大于0.42,Eu以0.05-0.2%的含量溶解在作为发光中心的固溶体中,Eu以0.05-0.2%的含量存在 原子。 &bgr 赛隆型荧光物质优选为平均粒径为1μm以上且20μm以下的粉末状。 通过使用蓝色或紫外线发光二极管作为激发光源与发出黄色或红色光的荧光物质组合,可以获得良好发光特性的白色LED。