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    • 4. 发明授权
    • Liquid crystal device
    • 液晶装置
    • US5858273A
    • 1999-01-12
    • US684864
    • 1996-07-25
    • Masanobu AsaokaYasuaki TakedaYukio HanyuIkuo NakazawaNobuhiro ItoYasufumi AsaoTakashi Moriyama
    • Masanobu AsaokaYasuaki TakedaYukio HanyuIkuo NakazawaNobuhiro ItoYasufumi AsaoTakashi Moriyama
    • C09K19/04C09K19/34C09K19/56C09K19/02C09K19/52G02F1/1337
    • C09K19/04C09K19/34Y10T428/1027
    • A liquid crystal device is constituted by a pair of transparent substrates each having thereon a transparent electrode, and a chiral smectic liquid crystal composition disposed between the substrates so as to assume at least two optically stable states. At least one of the substrates is provided with an alignment film which comprises a polyimide represented by a recurring unit of formula (I) shown below and has been subjected to a uniaxial aligning treatment. ##STR1## wherein A denotes a planar tetravalent organic residue group comprising an aromatic ring, an aromatic polycyclic ring, a heterocyclic ring or a condensed polycyclic ring, and B denotes a divalent aliphatic group comprising .paren open-st.CH.sub.2 .paren close-st..sub.n (n: an integer of at least 1) or an alicyclic ring. The chiral smectic liquid crystal composition may contain at least one species of fluorine-containing mesomorphic compound comprising a fluorocarbon terminal portion and a hydrocarbon terminal portion connected with a central core and having a smectic phase or a latent smectic phase.
    • 液晶装置由一对透明基板构成,每个透明基板上具有透明电极,并且手性近晶液晶组合物设置在基板之间以便呈现至少两个光学稳定状态。 至少一个基板设置有取向膜,该取向膜包含由下述式(I)的重复单元表示的聚酰亚胺,并进行单轴对准处理。 式(I):其中A表示包括芳香环,芳族多环,杂环或稠合多环的平面四价有机残基,B表示包含+545CH 2 + 546 + E,ovs n + EE(n:至少为1的整数)或脂环族环。 手性近晶液晶组合物可以含有至少一种含氟介晶化合物,其含氟碳末端部分和与中心核心连接并具有近晶相或潜层晶相的烃末端部分。