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    • 6. 发明授权
    • Novel clay mineral color developer for pressure sensitive recording
paper and process for producing same
    • 用于压敏记录纸的新型粘土矿物显色剂及其制造方法
    • US4405371A
    • 1983-09-20
    • US279191
    • 1981-06-30
    • Yujiro Sugahara, deceasedKoichi UsuiMasahide OgawaTeiji SatoYasuo MizoguchiSeiji Kojima
    • Yujiro Sugahara, deceasedKoichi UsuiMasahide OgawaTeiji SatoYasuo MizoguchiSeiji Kojima
    • C01B33/22B41M5/155C01B33/26C01B33/38C09D11/00
    • B41M5/1555
    • A color developer for pressure-sensitive recording paper which is derived from a clay mineral having a layer-structure composed of regular tetrahedrons of silica and which shows(A) the diffraction pattern attributable to the crystals of layer-structure composed of regular tetrahedrons of silica when subjected to an electron diffraction analysis, but(B) substantially no diffraction pattern attributable to the crystals of said layer-structure when subjected to an X-ray diffraction analysis, and which(C) contains as the constituting elements besides oxygen, at least silicon, magnesium and/or aluminum.This color developer is produced by acid-treating a clay mineral having a layer-structure composed of regular tetrahedrons of silica until its SiO.sub.2 content reaches 82-96.5% by weight on dry basis (drying at 105.degree. C. for 3 hours), contacting the resulting clay mineral, in an aqueous medium, with a magnesium and/or an aluminum compound or compounds which are at least partially soluble in said aqueous medium, neutralizing the system with an alkali or an acid to form hydroxide when the soluble compound or compounds employed are other than hydroxides, whereby introducing into the acid-treated clay mineral a magnesium and/or an aluminum component, and drying the product if desired. The color developer of this invention exhibits an improved color-developing ability particularly to the primary color development dye and an improved color-developing ability to the secondary color development dye, and shows excellent light resistance after the color development, little reduction in the color-developing ability after storage in an atmosphere of a high humidity and high temperature.
    • 一种压敏记录纸的彩色显影剂,其由具有由二氧化硅的正四面体组成的层结构的粘土矿物得到,并且其显示(A)归因于由二氧化硅的正四面体组成的层结构的晶体的衍射图案 当进行电子衍射分析时,(B)基本上不存在归因于所述层结构的晶体的衍射图案,当进行X射线衍射分析时,(C)除了氧以外还含有作为构成元素的至少 硅,镁和/或铝。 该彩色显影剂是通过酸性处理具有由二氧化硅规则四面体构成的层结构的粘土矿物制成的,直到其SiO 2含量以干基计重量为82-96.5重量%(在105℃下干燥3小时),接触 所得粘土矿物在水性介质中与镁和/或铝化合物或至少部分可溶于所述水性介质的化合物或者当可溶性化合物或化合物 所用的不是氢氧化物,其中将酸和镁组分和/或铝组分引入酸处理的粘土矿物中,并且如果需要则干燥产物。 本发明的彩色显影剂特别是显色原色显色剂的显色能力和二次显色染料的显色能力提高,显色性显示出优异的耐光性, 在高湿度和高温气氛中储存后的显影能力。