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    • 6. 发明申请
    • BLENDS OF POLYARYLENE ETHERS AND POLYARYLENE SULFIDES
    • 聚乙烯醚和聚亚烷基硫化物的混合物
    • US20120252962A1
    • 2012-10-04
    • US13515905
    • 2010-12-14
    • Martin WeberChristian MaletzkoSusanne ZeiherMark VölkelNorbert GüntherbergRüdiger Bluhm
    • Martin WeberChristian MaletzkoSusanne ZeiherMark VölkelNorbert GüntherbergRüdiger Bluhm
    • C08L81/06C08L81/04
    • C08L81/06C08G2650/40C08L2205/02C08L81/02C08L71/00
    • The present invention relates to thermoplastic molding materials comprising the following components: (A) at least one polyarylene ether, (B) at least one polyarylene sulfide, (C) at least one functionalized polyarylene ether comprising carboxyl groups having a viscosity number according to DIN EN ISO 1628-1 of 45 to 65 ml/g measured in 1% strength by weight solution in N-methyl-2-pyrrolidone at 25° C., (D) at least one fibrous or particulate filler and (E) optionally further additives and/or processing assistants. In addition, the present invention relates to a process for the preparation of the thermoplastic molding materials according to the invention, the use thereof for the production of shaped articles and the use of functionalized polyarylene ethers comprising carboxyl groups having a viscosity number according to DIN EN ISO 1628-1 of 45 to 65 ml/g measured in 1% strength by weight solution in N-methyl-2-pyrrolidone at 25° C. for increasing the elongation at break and for improving the impact strength.
    • 本发明涉及包含以下组分的热塑性模塑材料:(A)至少一种聚亚芳基醚,(B)至少一种聚芳硫醚,(C)至少一种官能化聚亚芳基醚,其含有根据DIN 在25℃下,在N-甲基-2-吡咯烷酮中的1重量%的重量溶液中测量的EN ISO 1628-1为45至65ml / g,(D)至少一种纤维或颗粒填料和(E)任选进一步 添加剂和/或加工助剂。 此外,本发明涉及一种制备本发明的热塑性成型材料的方法,其用于生产成型制品的用途,以及使用包含羧基的官能化聚亚芳基醚,其粘度值根据DIN EN 在25℃下在1-甲基-2-吡咯烷酮中的1重量%溶液中测量的ISO 1628-1为45至65ml / g,用于增加断裂伸长率和改善冲击强度。
    • 9. 发明申请
    • PROCESS FOR PRODUCING THERMOPLASTIC MOLDING COMPOSITIONS BASED ON STYRENE COPOLYMERS AND POLYAMIDE WITH IMPROVED TOUGHNESS
    • 基于苯乙烯共聚物和具有改善的韧性的聚酰胺制造热塑性成型组合物的方法
    • US20110178205A1
    • 2011-07-21
    • US12986718
    • 2011-01-07
    • Martin WeberMarko BlinzlerNorbert Güntherberg
    • Martin WeberMarko BlinzlerNorbert Güntherberg
    • C08K5/151
    • C08L77/00C08K5/1539C08K7/00C08L25/12C08L33/20C08L51/04
    • The invention relates to processes for producing thermoplastic molding compositions, where the thermoplastic molding compositions comprise a) as component A, from 3 to 79% by weight of one or more (methyl)styrene-acrylonitrile copolymers, which have no maleic-anhydride-derived units. b) as component B, from 15 to 91% by weight of one or more polyamides, c) as component C, from 5 to 50% by weight of one or more rubbers, d) as component D, from 1 to 25% by weight of one or more compatibilizers, e) as component E, from 0 to 2% by weight of one or more low-molecular-weight compounds which comprise a dicarboxylic anhydride group, f) as component F, from 0 to 50% by weight of one or more fibrous or particulate fillers, and g) as component G, from 0 to 40% by weight of further additives, where each of the % by weight values is based on the total weight of components A to G, and these give a total of 100% by weight, via mixing of components A to G in the melt, which comprises producing a melt comprising components A, B, and C in a first step of the process, in the absence of component D, and delaying the mixing to incorporate component D into this melt until a subsequent second step of the process, and also to thermoplastic molding compositions obtainable by these processes, the use of these thermoplastic molding compositions, and also moldings, fibers, and foils comprising these thermoplastic molding compositions.
    • 本发明涉及生产热塑性模塑组合物的方法,其中热塑性模塑组合物包含a)作为组分A,3至79重量%的一种或多种(甲基)苯乙烯 - 丙烯腈共聚物,其不具有马来酸酐衍生物 单位。 b)作为组分B,15至91重量%的一种或多种聚酰胺,c)作为组分C,5至50重量%的一种或多种橡胶,d)作为组分D,1至25重量% 一种或多种增容剂的重量,e)作为组分E,0至2重量%的一种或多种低分子量化合物,其包含二羧酸酐基团,f)作为组分F,0至50重量% 的一种或多种纤维或颗粒填料,和g)作为组分G,0至40重量%的另外的添加剂,其中每个重量%的值基于组分A至G的总重量,并且这些给出 总共100重量%,通过混合熔体中的组分A至G,其包括在该方法的第一步中产生包含组分A,B和C的熔体,在不存在组分D的情况下,并延迟 混合以将组分D掺入该熔体中,直到该方法的随后的第二步,以及可通过这些方法获得的热塑性模塑组合物 这些热塑性模塑组合物的使用,以及包含这些热塑性模塑组合物的模制品,纤维和箔。
    • 10. 发明授权
    • Thermoplastic moulding compounds
    • 热塑性模塑料
    • US06235839B1
    • 2001-05-22
    • US09254917
    • 1999-03-17
    • Norbert GüntherbergMartin WeberKonrad KnollGerhard Lindenschmidt
    • Norbert GüntherbergMartin WeberKonrad KnollGerhard Lindenschmidt
    • C08L5100
    • C08L51/003C08F265/04C08L25/12C08L53/02C08L2666/24
    • Thermoplastic molding compositions comprising A) a graft polymer comprising 1) an elastomeric graft core, obtainable by copolymerization of one or more C1-C10-alkyl acrylates, and a monomer with crosslinking effect, and 2) a graft shell comprising a styrene compound or a C1-C8-alkyl acrylate or methacrylate, or a mixture of the styrene compound and the C1-C8-alkyl acrylate or methacrylate, and B) a thermoplastic polymer comprising C) an elastomeric block copolymer in which all or virtually all of the olefinic double bonds have been hydrogenated, comprising at least one block A, which forms a hard phase and contains, in its polymer chain, units of a vinylaromatic monomer, and/or a block B, which forms a first elastomeric (soft) phase and contains diene monomers, and at least one elastomeric block B/A, which forms a soft phase, and contains, randomly in its polymer chain, units of both a vinylaromatic monomer and a diene, where the glass transition temperature Tg of the block A is above 25° C. and that of the block B/A is below 25° C. and the phase-volume ratio of block A to block B/A is chosen so that the proportion of the hard phase in the entire block copolymer is from 1 to 40% by volume and the proportion by weight of the diene is less than 50% by weight.
    • 包含A)接枝聚合物的热塑性成型组合物,其包含1)通过一种或多种丙烯酸C 1 -C 10烷基酯的共聚获得的弹性体接枝核心和具有交联效应的单体,和2)包含苯乙烯化合物或C 1 -C 8 烷基丙烯酸酯或甲基丙烯酸酯,或苯乙烯化合物和丙烯酸或甲基丙烯酸C 1 -C 8烷基酯的混合物,和B)包含C)弹性体嵌段共聚物的热塑性聚合物,其中所有或几乎所有的烯属双键已被氢化, 包含至少一个嵌段A,其形成硬质相并且在其聚合物链中包含乙烯基芳族单体和/或嵌段B的单元,所述单元形成第一弹性体(软)相并含有二烯单体,并且至少 一个弹性体嵌段B / A,其形成软相,并且在其聚合物链中随机含有乙烯基芳族单体和二烯的单元,其中嵌段A的玻璃化转变温度Tg高于25° 并且块B / A的相体积比低于25℃,并且选择块A与嵌段B / A的相体积比,使得整个嵌段共聚物中硬相的比例为1至40 体积比,二烯重量比小于50重量%。