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    • 2. 发明授权
    • Method for producing polybutadiene latex with an optimized thermal current profile
    • 具有优化的热电流分布的聚丁二烯胶乳的生产方法
    • US06852797B2
    • 2005-02-08
    • US10257717
    • 2001-04-24
    • Sabine OepenMichael BreulmannNorbert GüntherbergKlaus-Dieter HungenbergNorbert NiessnerBernhard CzaudernaWil Duijzings
    • Sabine OepenMichael BreulmannNorbert GüntherbergKlaus-Dieter HungenbergNorbert NiessnerBernhard CzaudernaWil Duijzings
    • C08F2/22C08F2/32C08F236/06C08F279/02C08F279/04
    • C08F279/02C08F236/06Y10S525/942C08F2/22
    • A polybutadiene latex is prepared by a process in which butadiene is polymerized by free radical emulsion polymerization in the presence of initiator and, if required, dispersants and further conventional assistants, the polymerization being carried out in the presence of reactive comonomers in such a way that the heat flow of 43 watt/kg solids content of the polymerization mixture is not exceeded. Owing to the presence of reactive comonomers, the reaction rate at the beginning of the reaction is increased, with the result that an overall flatter heat flow profile is obtained. A preferred reactive comonomer is styrene. Preferably, the process is carried out by a semi-batch procedure in which (a) in a first stage, a portion of butadiene and at least one portion of reactive comonomer in the form of an aqueous emulsion are initially taken with a thermal polymerization initiator and, if required, dispersants and further conventional assistants and the polymerization is initiated, (b) in a second stage, the remaining amount of butadiene and, if required, the remaining amount of reactive comonomer are added undiluted or in the form of an aqueous emulsion, if required with dispersants and, if required, further conventional assistants, as a feed.
    • 聚丁二烯胶乳是通过一种方法制备的,其中丁二烯在引发剂存在下通过自由基乳液聚合聚合,如果需要的话,通过分散剂和其它常规助剂,聚合反应在反应性共聚单体的存在下进行,使得 不超过聚合混合物的43瓦特/千克固体含量的热流。 由于反应性共聚单体的存在,反应开始时的反应速率增加,结果得到整体平坦的热流分布。 优选的反应性共聚单体是苯乙烯。 优选地,该方法通过半间歇方法进行,其中(a)在第一阶段中,一部分丁二烯和至少一部分水性乳液形式的反应性共聚单体最初用热聚合引发剂 并且如果需要,分散剂和其它常规助剂并开始聚合,(b)在第二阶段中,剩余量的丁二烯和如果需要的话,反应性共聚单体的剩余量未稀释或以水性形式加入 乳液,如果需要与分散剂,并且如果需要,作为进料的其它常规助剂。
    • 3. 发明授权
    • Method for producing caoutchouc particles
    • 橡胶颗粒的制备
    • US06723774B2
    • 2004-04-20
    • US10221080
    • 2002-09-10
    • Norbert GüntherbergBernhard CzaudernaMichael BreulmannSabine OepenWil DuijzingsNorbert Niessner
    • Norbert GüntherbergBernhard CzaudernaMichael BreulmannSabine OepenWil DuijzingsNorbert Niessner
    • C08F3600
    • C08F36/04Y10S525/902C08F2/24
    • The invention relates to a method for producing caoutchouc particles (K) by means of emulsion polymerisation in the presence of an emulsifier and a polymerisation initiator. Said particles contain A) 80 to 100 wt. % of one or more conjugated diene monomers (A) in relation to (K) and B) 0 to 20 wt. % of one or more monoethylenically unsaturated comonomers (B) in relation to (K) in the polymerised form. The inventive method is characterised in that 1) a mixture (M1) containing water and an emulsifier is provided, 2) a mixture (M2) containing one or more monomers in the monomer or polymerised form selected from styrole, &agr;-methylstyrole, butadiene, n-butylacrylate, MMA and acrylnitrile and optionally comonomers is added, 3) polymerisation of the obtained mixture starts in the presence of a polymerisation initiator at temperature of 5 to 95° C., 4) a mixture (M3) containing 0 to 100 wt. % of the comonomers (B) in relation to (B) and 0 to 25 wt. % of the diene monomers (A) in relation to (A) is added, 5) a mixture (M4) containing the (remaining) diene monomers (A) and the (remaining) comonomers (B) is proportioned and polymerised and 6) polymerisation is terminated when there is conversion of more than 90 and less than 95% in relation to the sum of the monomers.
    • 本发明涉及一种在乳化剂和聚合引发剂存在下,通过乳液聚合来生产酚醛树脂颗粒(K)的方法。 所述颗粒包含A)80至100重量% 一个或多个共轭二烯单体(A)相对于(K)和B)的%为0-20重量% %的一种或多种单烯属不饱和共聚单体(B)相对于聚合形式的(K)。 本发明的方法的特征在于:1)提供含有水和乳化剂的混合物(M1),2)含有一种或多种选自苯乙烯,α-甲基苯甲醛,丁二烯的单体或聚合形式的单体的混合物(M2) 丙烯酸正丁酯,MMA和丙烯腈和任选的共聚单体; 3)所得混合物的聚合在聚合引发剂存在下开始,温度为5至95℃,4)含有0-100重量份的混合物 。 共聚单体(B)的相对于(B)和0-25重量% 加入相对于(A)的二烯单体(A)的%,5)含有(剩余的)二烯单体(A)和(剩余的)共聚单体(B)的混合物(M4)成比例和聚合,和6) 当相对于单体的总和转化率大于90且小于95%时,聚合终止。
    • 8. 发明授权
    • Process for producing thermoplastic molding compositions based on styrene copolymers and polyamide with improved toughness
    • 基于苯乙烯共聚物和具有改进韧性的聚酰胺生产热塑性模塑组合物的方法
    • US08648143B2
    • 2014-02-11
    • US13547830
    • 2012-07-12
    • Martin WeberMarko BlinzlerNorbert Güntherberg
    • Martin WeberMarko BlinzlerNorbert Güntherberg
    • C08G81/02C08L67/02C09B67/00
    • C08L77/00C08K5/1539C08K7/00C08L25/12C08L33/20C08L51/04
    • Processes for producing thermoplastic molding compositions, which comprise a) from 3 to 79% by weight of one or more (methyl)styrene-acrylonitrile copolymers, which have no maleic-anhydride-derived units, b) from 15 to 91% by weight of one or more polyamides, c) from 5 to 50% by weight of one or more rubbers, d) from 1 to 25% by weight of one or more compatibilizers, e) from 0 to 2% by weight of one or more low-molecular-weight compounds which comprise a dicarboxylic anhydride group, f) from 0 to 50% by weight of one or more fibrous or particulate fillers, and g) from 0 to 40% by weight of further additives, by producing a melt comprising components A, B, and C in a first step and subsequently incorporating D, Also, thermoplastic molding compositions obtainable by these processes, the use of these thermoplastic molding compositions, and moldings, fibers, and foils comprising these thermoplastic molding compositions.
    • 制备热塑性模塑组合物的方法,其包含a)3至79重量%的一种或多种(甲基)苯乙烯 - 丙烯腈共聚物,其不具有马来酸酐衍生的单元,b)15至91重量% 一种或多种聚酰胺,c)5至50重量%的一种或多种橡胶,d)1至25重量%的一种或多种相容剂,e)0至2重量%的一种或多种低聚物, 包含二羧酸酐基团的分子量化合物,f)0至50重量%的一种或多种纤维或颗粒填料,和g)0至40重量%的其它添加剂,通过制备包含组分A ,B和C,并且随后掺入D。此外,可通过这些方法获得的热塑性模塑组合物,这些热塑性模塑组合物的使用以及包含这些热塑性模塑组合物的模制品,纤维和箔。
    • 9. 发明授权
    • Rotor/stator device and method for salt-free coagulation of polymer dispersions
    • 转子/定子装置和聚合物分散体的无盐凝结方法
    • US08362200B2
    • 2013-01-29
    • US11816362
    • 2006-02-08
    • Norbert GüntherbergWolfgang FischerManfred Radulla
    • Norbert GüntherbergWolfgang FischerManfred Radulla
    • C08F6/00
    • B02C7/06B02C2/10B02C7/14B29B7/7657B29B15/04C08F6/22
    • A process for the salt-free coagulation of polymer dispersions in a rotor/stator assembly is disclosed. The rotor/stator assembly includes a casing, a rotor shaft rotatably mounted within the casing, a rotor having a conical surface affixed to the rotor shaft, and a stator affixed to the casing and concentrically associated with the rotor. The conical surface faces a surface of the stator to form an adjustable shear gap, which is surrounded by an annular space. A polymer dispersion is fed into the assembly and conveyed through the shear gap. During this conveyance, the polymer dispersion is precipitated at a predetermined shear rate and a predetermined shear deformation. The polymer dispersion is discharged from the assembly through an outlet neck, and the assembly is flushed with water using one or more ports formed in at least one of a pipeline coupled to the axial feed neck, the stator, and the casing.
    • 公开了一种用于转子/定子组件中聚合物分散体的无盐凝结的方法。 转子/定子组件包括壳体,可旋转地安装在壳体内的转子轴,具有固定到转子轴上的锥形表面的转子和固定到壳体并与转子同心相关的定子。 锥形表面面向定子的表面以形成由环形空间包围的可调剪切间隙。 将聚合物分散体进料到组件中并通过剪切间隙输送。 在该输送过程中,聚合物分散体以预定的剪切速率和预定的剪切变形沉淀。 聚合物分散体通过出口颈部从组件排出,并且使用在耦合到轴向进料颈部,定子和壳体的管道中的至少一个中形成的一个或多个端口用水冲洗组件。