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1. 发明授权

US07019089B2 Suspended chrome catalyst containing titanium and the use thereof for producing ethylene homopolymers and copolymers 有权
标题翻译：含有钛的悬浮铬催化剂及其用于生产乙烯均聚物和共聚物的用途
公开(公告)号：US07019089B2
公开(公告)日：2006-03-28
申请号：US10332045
申请日：2001-06-28
申请人： Martin Schneider , Rainer Karer , Dieter Lilge , Volker Rauschenberger , Philipp Rosendorfer , Joachim Wulff-Döring , Günther Schweier , Martin Lux , Peter Bauer
发明人： Martin Schneider , Rainer Karer , Dieter Lilge , Volker Rauschenberger , Philipp Rosendorfer , Joachim Wulff-Döring , Günther Schweier , Martin Lux , Peter Bauer
IPC分类号： C08F10/02 , C08F4/24 , C08F4/18
CPC分类号： C08F210/16 , C08F2410/04 , C08F4/24 , C08F4/69 , C08F4/025 , C08F210/14 , C08F2500/12 , C08F2500/17 , C08F2500/04 , C08F2500/26
摘要： Novel supported, titanized chromium catalysts can be used for the homopolymerization of ethylene and the copolymerization of ethylene with α-olefins.
摘要翻译：新型负载的钛化铬催化剂可用于乙烯的均聚和乙烯与α-烯烃的共聚合。

2. 发明授权

US07348384B2 Supported, titanized chromium catalyst and its use for preparing homopolymers and copolymers of ethylene 有权
标题翻译：负载型，钛酸化铬催化剂及其制备乙烯均聚物和共聚物的用途
公开(公告)号：US07348384B2
公开(公告)日：2008-03-25
申请号：US11330071
申请日：2006-01-12
申请人： Martin Schneider , Rainer Karer , Dieter Lilge , Volker Rauschenberger , Philipp Rosendorfer , Joachim Wulff-Döring , Günther Schweier , Martin Lux , Peter Bauer
发明人： Martin Schneider , Rainer Karer , Dieter Lilge , Volker Rauschenberger , Philipp Rosendorfer , Joachim Wulff-Döring , Günther Schweier , Martin Lux , Peter Bauer
IPC分类号： C08F10/02 , C08F4/24 , C08F4/18
CPC分类号： C08F210/16 , C08F2410/04 , C08F4/24 , C08F4/69 , C08F4/025 , C08F210/14 , C08F2500/12 , C08F2500/17 , C08F2500/04 , C08F2500/26
摘要： Novel supported, titanized chromium catalysts for the homopolymerization of ethylene and the copolymerization of ethylene with α-olefins, a process for preparing them and to their use for the polymerization of olefins.
摘要翻译：用于乙烯均聚和乙烯与α-烯烃的共聚合的新型负载的钛化铬催化剂，其制备方法及其用于烯烃聚合的方法。

3. 发明授权

US06649709B1 Gas phase fluidized bed method and ethylene homo- and copolymers obtained using said method 有权
标题翻译：气相流化床法和使用所述方法获得的乙烯均聚物和共聚物
公开(公告)号：US06649709B1
公开(公告)日：2003-11-18
申请号：US09555594
申请日：2000-05-31
申请人： Peter Bauer , Armin Lange , Rainer Karer , Philipp Rosendorfer , Manfred Hecker , Günther Schweier , Wolfgang Micklitz , Kaspar Evertz , Hans-Jacob Feindt
发明人： Peter Bauer , Armin Lange , Rainer Karer , Philipp Rosendorfer , Manfred Hecker , Günther Schweier , Wolfgang Micklitz , Kaspar Evertz , Hans-Jacob Feindt
IPC分类号： C08F234
CPC分类号： C08F10/02 , C08F4/24 , C08F2/34
摘要： A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I T H = 171 + 6 ⁢ d ′ 0.84 - d ′ ( I ) and a lower envelope defined by equation II T L = 173 + 7.3 ⁢ d ′ 0.837 - d ′ , ( II ) in which the variables have the following meanings: TH is the highest reaction temperature in ° C.; TL is the lowest reaction temperature in ° C.; d′ is the numerical value of the density d of the (co)polymer to be synthesized.
摘要翻译：用于制备密度为0.87至0.97g / cm 3的乙烯均聚物和共聚物的连续气相流化床方法，其中乙烯或乙烯和C 3 -C 8α-单烯烃的混合物（共）聚合在负载的铬催化剂的存在下，在气相流化床反应器的聚合区域的存在下，在压力范围为1至100巴，温度范围为30至125℃，气相在搅拌床包含颗粒聚合物的散装材料，通过冷却再循环的反应器气体除去所得到的聚合热，并将所得（共）聚合物从气相流化床反应器中除去，其中，为制备（共）聚合物特定密度d，（共）聚合在由等式I定义的上包络限制的范围内进行，并且由等式IIin定义的下包络，其中变量具有以下含义：T H是最高的反应温度，单位°C; TL是最低反应温度（℃）; d'是待合成的（共）聚合物的密度d的数值。

4. 发明授权

US06849699B2 Vapor-phase fluidized-bed process and ethylene homopolymers and copolymers produced thereby 失效
标题翻译：气相流化床方法和由此制备的乙烯均聚物和共聚物
公开(公告)号：US06849699B2
公开(公告)日：2005-02-01
申请号：US10658916
申请日：2003-09-11
申请人： Peter Bauer , Armin Lange , Rainer Karer , Philipp Rosendorfer , Manfred Hecker , Günther Schweier , Wolfgang Micklitz , Kaspar Evertz , Hans-Jacob Feindt
发明人： Peter Bauer , Armin Lange , Rainer Karer , Philipp Rosendorfer , Manfred Hecker , Günther Schweier , Wolfgang Micklitz , Kaspar Evertz , Hans-Jacob Feindt
IPC分类号： C08J5/18 , C08F2/34 , C08F4/02 , C08F4/24 , C08F4/69 , C08F10/02 , C08F210/02
CPC分类号： C08F10/02 , C08F4/24 , C08F2/34
摘要： A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I T H = 171 + 6 ⁢ ⁢ d ′ 0.84 - d ′ ( I ) and a lower envelope defined by equation II T L = 173 + 7.3 ⁢ ⁢ d ′ 0.837 - d ′ , ( II ) in which the variables have the following meanings: TH is the highest reaction temperature in ° C.; TL is the lowest reaction temperature in ° C.; d′ is the numerical value of the density d of the (co)polymer to be synthesized.
摘要翻译：用于制备密度为0.87至0.97g / cm 3的乙烯均聚物和共聚物的连续气相流化床方法，其中乙烯或乙烯和C 3 -C 8α-单烯烃的混合物（共）聚合在负载的铬催化剂的存在下，在气相流化床反应器的聚合区域的存在下，在压力范围为1至100巴，温度范围为30至125℃，气相在搅拌床包含颗粒聚合物的散装材料，通过冷却再循环的反应器气体除去所得到的聚合热，并将所得（共）聚合物从气相流化床反应器中除去，其中，为制备（共）聚合物特定密度d，（共）聚合在由等式I定义的上包络限制的范围内进行，并且由等式IIin定义的下包络，其中变量具有以下含义：T H是最高的反应温度，单位°C; TL是最低反应温度（℃）; d'是待合成的（共）聚合物的密度d的数值。

5. 发明授权

US07026421B2 Random propylene copolymers 有权
标题翻译：无规丙烯共聚物
公开(公告)号：US07026421B2
公开(公告)日：2006-04-11
申请号：US10971079
申请日：2004-10-25
申请人： David Appleyard , Franz Langhauser , Murray Horton , Roland Hingmann , Günther Schweier , Volker Rauschenberger , Ingolf Hennig , Dieter Lilge , Werner Schöne , Meinolf Kersting
发明人： David Appleyard , Franz Langhauser , Murray Horton , Roland Hingmann , Günther Schweier , Volker Rauschenberger , Ingolf Hennig , Dieter Lilge , Werner Schöne , Meinolf Kersting
IPC分类号： C08F210/06 , C08F210/08
CPC分类号： D01F6/30 , C08F210/06 , C08F210/16 , Y10T428/31938 , C08F4/6546 , C08F210/08 , C08F2500/12
摘要： Random copolymers of propylene with other 1-alkenes having up to carbon atoms, whose content of comonomers is in the range from 0.7 to 1.4% by weight if the only comonomer present in the propylene copolymers is ethylene, or whose content of comonomers is in the range from 0.7 to 3.0% by weight if at least one C4–C10-1-alkene is present as comonomer, and whose cold-xylene-soluble fraction is from 1.0 to 2.5% by weight if ethylene is present as a comonomer in the propylene copolymers, or whose cold-xylene-soluble fraction is from 0.75 to 2.0% by weight if the only comonomers present are C4–C10-1-alkenes, and a process for preparing the random copolymers of propylene is described, as is their use for producing films, fibers or moldings, and also the films, fibers and moldings themselves and biaxially stretched films made from random propylene copolymers of this type and processes for their production.
摘要翻译：丙烯与具有至多碳原子的其它1-烯烃的无规共聚物，如果丙烯共聚物中存在的共聚单体中唯一的共聚单体为共聚单体，其共聚单体的含量为0.7-1.4重量％，或其共聚单体的含量为如果至少一个C 4 -C 10 - 1-烯烃作为共聚单体存在，其冷二甲苯可溶成分为如果乙烯作为丙烯共聚物中的共聚单体存在，则其重量为1.0至2.5重量％，或者如果仅存在共聚单体为C 4 - 4，则冷二甲苯可溶成分为0.75-2.0重量％描述了用于制备膜，纤维或模制品的方法，以及薄膜，纤维和模制品本身以及双轴的方法制备丙烯的无规共聚物的方法。由这种类型的无规丙烯共聚物制成的拉伸薄膜及其生产方法。

6. 发明授权

US06593442B2 Semicrystalline propylene polymer compositions with good suitability for producing biaxially oriented films 有权
标题翻译：具有良好适用于生产双轴取向膜的半结晶丙烯聚合物组合物
公开(公告)号：US06593442B2
公开(公告)日：2003-07-15
申请号：US09737848
申请日：2000-12-18
申请人： Wolfgang Bidell , Roland Hingmann , Franz Langhauser , Dieter Lilge , Volker Rauschenberger , Günther Schweier , Florian Stricker , Jürgen Suhm
发明人： Wolfgang Bidell , Roland Hingmann , Franz Langhauser , Dieter Lilge , Volker Rauschenberger , Günther Schweier , Florian Stricker , Jürgen Suhm
IPC分类号： C08F1006
CPC分类号： C08F297/08 , C08F4/65904 , C08F4/65908 , C08F4/65916 , C08F10/06 , C08F110/06 , C08F210/06 , C08L23/14 , C08L2205/02 , C08L2314/06 , Y10S264/901 , Y10S428/91 , Y10S526/905 , C08F4/65927 , C08F2/001 , C08L2666/04 , C08F2500/26 , C08F210/16
摘要： A semicrystalline propylene polymer composition with good suitability for producing biaxially oriented films and prepared by polymerizing propylene, ethylene and/or C4-C18-1-alkenes, where at least 50 mol % of the monomer units present arise from the polymerization of propylene. Also described is the use of the semicrystalline propylene polymer composition for producing films, fibers or moldings, the films, fibers and moldings made from these compositions, biaxially stretched films made from the semicrystalline propylene polymer compositions, and also a method for characterizing the semicrystalline propylene polymer compositions.
摘要翻译：一种半结晶丙烯聚合物组合物，其具有良好的适用于生产双轴取向薄膜并通过聚合丙烯，乙烯和/或C 4 -C 18 -1-烯烃制备，其中存在至少50摩尔％的单体单元来自丙烯的聚合。还描述了使用半结晶丙烯聚合物组合物来生产膜，纤维或模制品，由这些组合物制成的膜，纤维和模制品，由半结晶丙烯聚合物组合物制成的双轴向拉伸膜，以及用于表征半结晶丙烯聚合物组合物。

7. 发明授权

US07001965B2 Random propylene copolymers 有权
标题翻译：无规丙烯共聚物
公开(公告)号：US07001965B2
公开(公告)日：2006-02-21
申请号：US10971080
申请日：2004-10-25
申请人： David Appleyard , Franz Langhauser , Murray Horton , Roland Hingmann , Günther Schweier , Volker Rauschenberger , Ingolf Hennig , Dieter Lilge , Werner Schöne , Meinolf Kersting
发明人： David Appleyard , Franz Langhauser , Murray Horton , Roland Hingmann , Günther Schweier , Volker Rauschenberger , Ingolf Hennig , Dieter Lilge , Werner Schöne , Meinolf Kersting
IPC分类号： C08F210/06
CPC分类号： D01F6/30 , C08F210/06 , C08F210/16 , Y10T428/31938 , C08F4/6546 , C08F210/08 , C08F2500/12
摘要： Random copolymers of propylene with other 1-alkenes having up to carbon atoms, whose content of comonomers is in the range from 0.7 to 1.4% by weight if the only comonomer present in the propylene copolymers is ethylene, or whose content of comonomers is in the range from 0.7 to 3.0% by weight if at least one C4–C10-1-alkene is present as comonomer, and whose cold-xylene-soluble fraction is from 1.0 to 2.5% by weight if ethylene is present as a comonomer in the propylene copolymers, or whose cold-xylene-soluble fraction is from 0.75 to 2.0% by weight if the only comonomers present are C4–C10-1-alkenes, and a process for preparing the random copolymers of propylene is described, as is their use for producing films, fibers or moldings, and also the films, fibers and moldings themselves and biaxially stretched films made from random propylene copolymers of this type and processes for their production.
摘要翻译：丙烯与其中具有至多碳的其它1-烯烃的无规共聚物

8. 发明授权

US06919412B1 Monocyclopentadienyl complexes of chromium, molybdenum or tungsten with a donor bridge 有权
标题翻译：铬，钼或钨与供体桥的单环戊二烯基络合物
公开(公告)号：US06919412B1
公开(公告)日：2005-07-19
申请号：US10049455
申请日：2000-08-01
申请人： Shahram Mihan , Dieter Lilge , Paulus de Lange , Günther Schweier , Martin Schneider , Ursula Rief , Udo Handrich , Johannes Hack , Markus Enders , Gunter Ludwig , Ralph Rudolph
发明人： Shahram Mihan , Dieter Lilge , Paulus de Lange , Günther Schweier , Martin Schneider , Ursula Rief , Udo Handrich , Johannes Hack , Markus Enders , Gunter Ludwig , Ralph Rudolph
IPC分类号： B01J31/00 , C07F17/00 , C08F4/659 , C08F4/6592 , C08F10/00 , G08F4/44
CPC分类号： C08F10/00 , C08F4/63912 , C08F4/63916 , C08F4/6392 , C08F2410/03 , C08F2420/01 , Y10S526/943 , C08F4/63904
摘要： Substituted monocyclopentadienyl, monoindenyl, monofluorenyl or heterocyclopentadienyl complexes of chromium, molybdenum or tungsten, wherein at least one of the substituents of the cyclopentadienyl ring carries a rigid donor function which is not exclusively bonded through sp3-hybridized carbon or silicon atoms, and a process for polymerizing olefins.
摘要翻译：铬，钼或钨的取代的单环戊二烯基，单茚基，单芴基或杂环戊二烯基络合物，其中环戊二烯基环的至少一个取代基具有刚性供体功能，其不是通过sp3-3杂环碳完全结合的或硅原子，以及烯烃聚合方法。

9. 发明授权

US06437161B1 Monocyclopentadienyl complexes of chromium, molybdenum or tungsten 有权
标题翻译：铬，钼或钨的单环戊二烯基络合物
公开(公告)号：US06437161B1
公开(公告)日：2002-08-20
申请号：US09373715
申请日：1999-08-13
申请人： Shahram Mihan , Dieter Lilge , Paulus de Lange , Günther Schweier , Martin Schneider , Ursula Rief , Udo Handrich , Johannes Hack , Markus Enders , Gunter Ludwig , Ralph Rudolph
发明人： Shahram Mihan , Dieter Lilge , Paulus de Lange , Günther Schweier , Martin Schneider , Ursula Rief , Udo Handrich , Johannes Hack , Markus Enders , Gunter Ludwig , Ralph Rudolph
IPC分类号： C07F1700
CPC分类号： B01J31/143 , B01J31/2295 , B01J2231/12 , B01J2531/60 , B01J2531/62 , C07F17/00 , C08F4/63908 , C08F4/63912 , C08F4/63916 , C08F10/00 , C08F10/02 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2410/03 , C08F2420/01 , Y10S526/943 , C08F4/63925 , C08F4/6392 , C08F2500/03 , C08F2500/04 , C08F2500/17 , C08F2500/10
摘要： Substituted monocyclopentadienyl, monoindenyl, monofluorenyl and heterocyclopentadienyl complexes of chromium, molybdenum or tungsten in which at least one of the substituents on the cyclopentadienyl ring carries a donor function which is bonded rigidly, not exclusively via sp3-hybridized carbon or silicon atoms, and a process for the polymerization of olefins.
摘要翻译：铬，钼或钨的取代的单环戊二烯基，单茚基，单芴基和杂环戊二烯基络合物，其中环戊二烯基环上的至少一个取代基具有刚性键合的供体功能，不排他地通过sp3杂化的碳或硅原子，用于烯烃的聚合。

10. 发明授权

US06787498B2 Monocyclopentadienyl complexes of chromium, molybdenum or tungsten 有权
标题翻译：铬，钼或钨的单环戊二烯基络合物
公开(公告)号：US06787498B2
公开(公告)日：2004-09-07
申请号：US10166140
申请日：2002-06-11
申请人： Shahram Mihan , Dieter Lilge , Paulus de Lange , Günther Schweier , Martin Schneider , Ursula Rief , Udo Handrich , Johannes Hack , Markus Enders , Gunter Ludwig , Ralph Rudolph
发明人： Shahram Mihan , Dieter Lilge , Paulus de Lange , Günther Schweier , Martin Schneider , Ursula Rief , Udo Handrich , Johannes Hack , Markus Enders , Gunter Ludwig , Ralph Rudolph
IPC分类号： B01J3100
CPC分类号： B01J31/143 , B01J31/2295 , B01J2231/12 , B01J2531/60 , B01J2531/62 , C07F17/00 , C08F4/63908 , C08F4/63912 , C08F4/63916 , C08F10/00 , C08F10/02 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2410/03 , C08F2420/01 , Y10S526/943 , C08F4/63925 , C08F4/6392 , C08F2500/03 , C08F2500/04 , C08F2500/17 , C08F2500/10
摘要： Substituted monocyclopentadienyl, monoindenyl, monofluorenyl and heterocyclopentadienyl complexes of chromium, molybdenum or tungsten in which at least one of the substituents on the cyclopentadienyl ring carries a donor function which is bonded rigidly, not exclusively via sp3-hybridized carbon or silicon atoms, and a process for the polymerization of olefins.
摘要翻译：铬，钼或钨的取代的单环戊二烯基，单茚基，单芴基和杂环戊二烯基络合物，其中至少一个环戊二烯基环上的取代基具有刚性键合的供体功能，不排他地通过sp 3杂化的碳或硅原子，和烯烃聚合方法。

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