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1. 发明授权

US06538139B1 Preparation of pyrrole and pyridine 有权
标题翻译：制备吡咯和吡啶
公开(公告)号：US06538139B1
公开(公告)日：2003-03-25
申请号：US10234169
申请日：2002-09-05
申请人： Martin Schäfer , Arnd Böttcher , Andreas Kramer , Arthur Höhn , Reinhard Kaczmarek , Erhard Henkes
发明人： Martin Schäfer , Arnd Böttcher , Andreas Kramer , Arthur Höhn , Reinhard Kaczmarek , Erhard Henkes
IPC分类号： C07D213133
CPC分类号： C07D207/323 , B01J23/42 , B01J23/44 , B01J23/63 , C07D213/06
摘要： Pyrroles of the formula (I) are prepared by dehydrogenating pyrrolidines of the formula (II) where R1 and R2, independently of one another, are hydrogen or an aliphatic radical of 1 to 6 carbon atoms, or pyridines of the formula (III) are prepared by dehydrogenating piperidines of the formula (IV) where R3, R4 and R5, independently of one another, are hydrogen or an aliphatic radical of 1 to 6 carbon atoms, in the presence of a supported noble metal catalyst, by a process in which the dehydrogenation is carried out in the presence of from 1 to 50% by weight, based on the pyrrolidine or piperidine and water, of water.
摘要翻译：式（I）的吡咯通过使式（II）的吡咯烷脱氢制备，其中R1和R2彼此独立地是氢或具有1至6个碳原子的脂肪族基团，或者制备式（III）的吡啶通过使负载型贵金属催化剂存在下，式（IV）的哌啶脱氢，其中R 3，R 4和R 5彼此独立地是氢或1-6个碳原子的脂族基团，其中脱氢在1至50重量％的存在下，基于吡咯烷或哌啶和水的水进行。

2. 发明授权

US06689914B2 Preparation of amines 失效
标题翻译：胺的制备
公开(公告)号：US06689914B2
公开(公告)日：2004-02-10
申请号：US10234170
申请日：2002-09-05
申请人： Martin Schäfer , Arnd Böttcher , Andreas Kramer , Arthur Höhn , Shelue Liang , Frank Funke
发明人： Martin Schäfer , Arnd Böttcher , Andreas Kramer , Arthur Höhn , Shelue Liang , Frank Funke
IPC分类号： C07C2926
CPC分类号： C07C209/26
摘要： The preparation of amines of the formula (I): R1R2CH—N R3R4 (I) in which R1, R2, R3 and R4, independently of one another, are hydrogen, straight-chain or branched C1-C12-alkyl, C3-C12-cycloalkyl, C6-C10-aryl or C7-C11-aralkyl, takes place by catalytic, reductive amination of mixtures comprising carbonyl compounds of the formula (II) and/or alcohols of the formula (III) R1—C(═O)—R2 (II) R1—CH(OH)—R2 (III) which also comprise at least 50 ppm, based on the mixtures, of halogen, with nitrogen compounds of the formula (IV): H N R3 R4 (IV) with the abovementioned meanings for R1 to R4, in the presence of Co- and/or Ni-containing catalysts, which comprises carrying out the reductive amination additionally in the presence of solid acidic cocatalysts.
摘要翻译：式（I）的胺的制备：其中R 1，R 2，R 3和R 4彼此独立地是氢，直链或支链的C 1 -C 12 - 烷基，C 3 -C 12 - 环烷基，C 6 -C 10 - 芳基或C 7 -C 11 - 芳烷基，其通过催化还原胺化包括式（II）的羰基化合物和/或式（III）的醇，包含基于混合物的卤素至少50ppm与式（IV）的氮化合物：在上述对R 1至R 4的含义中，在Co-和/或Ni- 其包括另外在固体酸性助催化剂存在下进行还原胺化。

3. 发明授权

US06677495B1 Oligomer mixtures derived from cyclopentene; method for the production and use thereof 失效
标题翻译：衍生自环戊烯的低聚物混合物; 生产和使用方法
公开(公告)号：US06677495B1
公开(公告)日：2004-01-13
申请号：US09331417
申请日：1999-06-21
申请人： Peter Schwab , Martin Schäfer , Arthur Höhn
发明人： Peter Schwab , Martin Schäfer , Arthur Höhn
IPC分类号： C07C606
CPC分类号： C07C6/06 , C07C2531/22 , C07C2531/24
摘要： A process for preparing cyclopentene oligomer mixtures of the formula I comprises reacting in a homogeneously or heterogeneously catalyzed metathesis reaction a hydrocarbon mixture which contains cyclopentene and acyclic monoolefins and which originates from petroleum processing by cracking (C5 fraction); cyclopentene oligomers of the formula I obtainable by this process and their use are also described.
摘要翻译：制备式I的环戊烯低聚物混合物的方法包括在均匀或不均匀催化的复分解反应中反应含有环戊烯和非环状单烯烃的烃混合物，其通过裂化（C5馏分）来源于石油加工;式I的环戊烯低聚物可通过还描述了该过程及其用途。

4. 发明授权

US06245948B1 Preparation of tetrahydrofuran from dialkoxybutenes 失效
标题翻译：由二烷氧基丁烯制备四氢呋喃
公开(公告)号：US06245948B1
公开(公告)日：2001-06-12
申请号：US09417652
申请日：1999-10-14
申请人： Rolf Fischer , Rolf Pinkos , Martin Schäfer , Arthur Höhn , Peter Schwab
发明人： Rolf Fischer , Rolf Pinkos , Martin Schäfer , Arthur Höhn , Peter Schwab
IPC分类号： C07C4105
CPC分类号： C07C41/18 , C07C41/26 , C07C41/32 , C07D307/08 , C07C43/15 , C07C43/13
摘要： A process for preparing tetrahydrofuran, which comprises reacting 1,4-butenediol diethers of the formulae I and/or II RO—CH2—CH═CH—CH2—OR I RO—CH2—CH2═CH—CH2—OR II, where the R radicals can be identical or different and are C1-C15-alkyl or cycloalkyl radicals, C6-C12-aryl radicals or C7-C15-aralkyl radicals, with water and hydrogen at from 20 to 300° C. under from 1 to 300 bar in the presence of catalysts or catalyst combinations which comprise components which are both capable of hydrogenation and have acidic or basic centers and a novel process for preparing 1,4-butanediol diethers of the formula I by metathesis are described.
摘要翻译：一种制备四氢呋喃的方法，其包括使式I和/或II的1,4-丁烯二醇二醚反应，其中R基团可以相同或不同，为C 1 -C 15 - 烷基或环烷基，C 6 -C 12 - 芳基或C 7 -C 15 - 芳烷基，其中水和氢在20-300℃，在1-300巴下，在催化剂或催化剂组合的存在下，其包含能够氢化并具有酸性或碱性中心的组分，以及新颖的描述了通过复分解制备式I的1,4-丁二醇二醚的方法。

5. 发明授权

US06548704B2 Racemization of optically active amines 失效
公开(公告)号：US06548704B2
公开(公告)日：2003-04-15
申请号：US10012344
申请日：2001-12-12
申请人： Frank Funke , Shelue Liang , Andreas Kramer , Rainer Stürmer , Arthur Höhn
发明人： Frank Funke , Shelue Liang , Andreas Kramer , Rainer Stürmer , Arthur Höhn
IPC分类号： C07C2968
CPC分类号： C07C213/02 , B01J23/80 , B01J35/023 , B01J37/0009 , B01J37/0201 , B01J37/031 , B01J37/035 , C07B2200/07 , C07C209/68 , C07C209/88 , C07C217/08 , C07C211/07
摘要： Optically active amines of the formula I where R1 and R2 are different and R1, R2, R3 are alkyl, cycloalkyl, arylalkyl, aryl, heteroaryl and heterocyclic radicals and R3 may also be hydrogen (H), with the radicals being able to bear substituents selected from the group consisting of alkyl, cycloalkyl, alkoxy, aryloxy, amino, alkylamino and dialkylamino, are racemized by reacting the optically active amine I in the presence of hydrogen and a hydrogenation or dehydrogenation catalyst at elevated temperature, wherein the catalyst comprises the active components copper and zinc oxide and a support material.

6. 发明授权

US06576795B1 Racemization of optically active amines 失效
标题翻译：光学活性胺的外消旋化
公开(公告)号：US06576795B1
公开(公告)日：2003-06-10
申请号：US10261123
申请日：2002-10-01
申请人： Frank Funke , Shelue Liang , Andreas Kramer , Rainer Stürmer , Arthur Höhn
发明人： Frank Funke , Shelue Liang , Andreas Kramer , Rainer Stürmer , Arthur Höhn
IPC分类号： C07C2968
CPC分类号： C07C213/02 , B01J23/80 , B01J35/023 , B01J37/0009 , B01J37/0201 , B01J37/031 , B01J37/035 , C07B2200/07 , C07C209/68 , C07C209/88 , C07C217/08 , C07C211/07
摘要： Optically active amines of the formula I where R1 and R2 are different and R1, R2, R3 are alkyl, cycloalkyl, arylalkyl, aryl, heteroaryl and heterocyclic radicals and R3 may also be hydrogen (H), with the radicals being able to bear substituents selected from the group consisting of alkyl, cycloalkyl, alkoxy, aryloxy, amino, alkylamino and dialkylamino, are racemized by reacting the optically active amine I in the presence of hydrogen and a hydrogenation or dehydrogenation catalyst at elevated temperature, wherein the catalyst comprises the active components copper and zinc oxide and a support material.
摘要翻译：式I的光学活性胺，其中R 1和R 2不同，R 1，R 2，R 3是烷基，环烷基，芳基烷基，芳基，杂芳基和杂环基，R 3也可以是氢（H），其中基团能够承载取代基由烷基，环烷基，烷氧基，芳氧基，氨基，烷基氨基和二烷基氨基组成的组通过使光学活性胺I在氢气和氢化或脱氢催化剂的存在下在升高的温度下反应进行外消旋化，其中催化剂包含活性组分铜和氧化锌和支撑材料。

7. 发明授权

US06417353B1 Preparing amines 失效
标题翻译：制备胺
公开(公告)号：US06417353B1
公开(公告)日：2002-07-09
申请号：US09520908
申请日：2000-03-07
申请人： Frank Funke , Joachim Wulff-Döring , Gerhard Schulz , Wolfgang Siegel , Andreas Kramer , Johann-Peter Melder , Arthur Höhn , Philipp Buskens , Wolfgang Reif , Jan Nouwen
发明人： Frank Funke , Joachim Wulff-Döring , Gerhard Schulz , Wolfgang Siegel , Andreas Kramer , Johann-Peter Melder , Arthur Höhn , Philipp Buskens , Wolfgang Reif , Jan Nouwen
IPC分类号： C07B4304
CPC分类号： C07C209/26 , B01J23/885 , B01J37/03 , C07C213/02 , C07C2601/08 , C07C2602/10 , C07C211/06 , C07C211/07 , C07C211/17 , C07C211/27 , C07C211/30 , C07C211/35 , C07C211/38 , C07C217/58
摘要： Amines are prepared by reacting aldehydes or ketones at elevated temperature under elevated pressure with nitrogen compounds selected from the group of ammonia, primary and secondary amines, and with hydrogen in the presence of a catalyst containing copper, wherein the catalytically active mass of the catalyst contains, before the reduction with hydrogen, 20 to 85% by weight of oxygen-containing compounds of zirconium, calculated as ZrO2, 1 to 30% by weight of oxygen-containing compounds of copper, calculated as CuO, 14 to 70% by weight of oxygen-containing compounds of nickel, calculated as NiO, 0 to 5% by weight of oxygen-containing compounds of molybdenum, calculated as MoO3, and 0 to 10% by weight of oxygen-containing compounds of aluminum, calculated as Al2O3.
摘要翻译：胺在升高的温度下在升高的温度下与选自氨，伯胺和仲胺的氮化合物和氢气在含催化剂的聚合物的存在下反应制备，其中催化剂活性物质含有，在用氢还原之前，以ZrO 2计为20〜85重量％的含氧化合物，以30重量％计，氧化铝为14〜70重量％，氧化铝为100重量％以NiO表示的镍化合物，以MoO 3计为0〜5重量％的含氧化合物的钼和0〜10重量％的按Al 2 O 3计算的含氧化合物的铝。

8. 发明授权

US08889917B2 Method of supplementing the catalyst in continuous hydroformylation 有权
标题翻译：在连续加氢甲酰化中补充催化剂的方法
公开(公告)号：US08889917B2
公开(公告)日：2014-11-18
申请号：US13860631
申请日：2013-04-11
申请人： Edgar Zeller , Armin Ulonska , Arthur Höhn , Volker Uhrig , Rene Magnie , Reimund Fattler
发明人： Edgar Zeller , Armin Ulonska , Arthur Höhn , Volker Uhrig , Rene Magnie , Reimund Fattler
IPC分类号： C07C45/50
CPC分类号： C07C45/50 , C07C47/02
摘要： The present invention relates to a method of supplementing the catalyst in continuous hydroformylation during ongoing operation.
摘要翻译：本发明涉及在持续操作期间补充催化剂在连续加氢甲酰化中的方法。

9. 发明授权

US06723880B2 Preparation of secondary amines from primary amines 有权
标题翻译：从伯胺制备仲胺
公开(公告)号：US06723880B2
公开(公告)日：2004-04-20
申请号：US10173774
申请日：2002-06-19
申请人： Peter Neumann , Johann-Peter Melder , Christoph Benisch , Arthur Höhn , Joachim Pfeffinger
发明人： Peter Neumann , Johann-Peter Melder , Christoph Benisch , Arthur Höhn , Joachim Pfeffinger
IPC分类号： C07D41702
CPC分类号： C07C209/64 , C07C211/13
摘要： A process for producing secondary amines of the formula R1R2N—A—NH—A—NR1R2, where R1 and R2 are linear or branched C1-20-alkyl radicals, optionally substituted with from 1 to 5 phenyl groups; or cyclohexyl radicals; or together with the nitrogen atom to which they are bound, form a 3 to 7 membered saturated ring, optionally containing further hetero atoms selected from the group consisting of N, O and S, and optionally substituted with from 1 to 5 C1-2-alkyl groups. The group A is a linear or branched C2-20-alkylene group, optionally containing from 1 to 5 phenylene groups; or a radical of the formula —CH(R3)—[CH2]k—X—[CH(R3)—[CH2]k—X]m—CH(R3)—[CH2]k—, where R3 is H or CH3, X is O, S or NR4, R4 is H or a linear or branched C1-4-alkyl group, k is 1 or 2, and m is an integer from 0 to 4; or a group of the formula where n, o, p, and q are, independently, integers from 1 to 4. In this process, primary amines of the formula R1R2N—A—NH2 are reacted in the presence of hydrogen and a catalyst comprising at least one element or compound of an element of groups VIII and IB of the Periodic Table, preferably group IB, and in particular, Cu. Through this process, a high selectivity of the desired amines can be achieved.
摘要翻译：一种制备式R 1 R 2 NA-NH-A-NR 1 R 2的仲胺的方法，其中R 1和R 2是直链或支链C 1-20 - 任选被1至5个苯基取代的烷基; 或环己基; 或与其结合的氮原子一起形成3至7元饱和环，任选地含有选自N，O和S的另外的杂原子，并且任选被1至5个C 1-2 - 烷基。基团A是任选含有1至5个亚苯基的直链或支链C 2-20 - 亚烷基; 或式-CH（R 3） - [CH 2] k X- [CH（R 3） - [CH 2] k X] m -CH（R 3） - [CH 2] k - 的基团，其中R 3是H或CH 3，X是O，S或NR 4，R 4是H或直链或支链C 1-4 - 烷基，k是1或2，m是整数从0到4; 或一组式n，o，p和q独立地为1至4的整数。在该方法中，式R 1 R 2 NA-NH 2的伯胺在存在下反应氢和包含元素周期表第VIII和IB族元素的至少一种元素或化合物的催化剂，优选IB族，特别是Cu。通过该方法，可以实现所需胺的高选择性。

10. 发明授权

US06403845B1 Preparation of pentanediols from alkoxydihydropyrans 失效
标题翻译：从烷氧基二氢吡喃制备戊二醇
公开(公告)号：US06403845B1
公开(公告)日：2002-06-11
申请号：US09625487
申请日：2000-07-25
申请人： Joachim Pfeffinger , Peter Wahl , Jan Nouwen , Karsten Eller , Arthur Höhn , Jürgen Hunger
发明人： Joachim Pfeffinger , Peter Wahl , Jan Nouwen , Karsten Eller , Arthur Höhn , Jürgen Hunger
IPC分类号： C07C2700
CPC分类号： C07C29/132 , C07C29/141 , C07C31/20
摘要： are prepared by single-stage reaction of alkoxydihydropyrans of the formula (II) with water and hydrogen in the presence of a catalyst comprising oxides of nickel, zirconium and copper. In the formulae (I) and (II), R, R′, R″, R′″ can be identical or different and are each hydrogen or a linear or branched saturated hydrocarbon radical having from 1 to 20 carbon atoms in which the hydrocarbon chain may contain O, S and N as heteroatoms and which may be monosubstituted or polysubstituted by hydroxy, thiol or amino groups or halogens.
摘要翻译：在式（I）和（II）的催化剂存在下，通过式（II）的烷氧基二氢吡喃与水和氢的单步反应制备。在式（I）和（II）中，R，R' R“，R”可以相同或不同，并且各自为氢或具有1至20个碳原子的直链或支链饱和烃基，其中烃链可以含有O，S和N作为杂原子，并且其可以是被羟基，硫醇或氨基或卤素单取代或多取代。

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