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1. 发明授权

US06548704B2 Racemization of optically active amines 失效
公开(公告)号：US06548704B2
公开(公告)日：2003-04-15
申请号：US10012344
申请日：2001-12-12
申请人： Frank Funke , Shelue Liang , Andreas Kramer , Rainer Stürmer , Arthur Höhn
发明人： Frank Funke , Shelue Liang , Andreas Kramer , Rainer Stürmer , Arthur Höhn
IPC分类号： C07C2968
CPC分类号： C07C213/02 , B01J23/80 , B01J35/023 , B01J37/0009 , B01J37/0201 , B01J37/031 , B01J37/035 , C07B2200/07 , C07C209/68 , C07C209/88 , C07C217/08 , C07C211/07
摘要： Optically active amines of the formula I where R1 and R2 are different and R1, R2, R3 are alkyl, cycloalkyl, arylalkyl, aryl, heteroaryl and heterocyclic radicals and R3 may also be hydrogen (H), with the radicals being able to bear substituents selected from the group consisting of alkyl, cycloalkyl, alkoxy, aryloxy, amino, alkylamino and dialkylamino, are racemized by reacting the optically active amine I in the presence of hydrogen and a hydrogenation or dehydrogenation catalyst at elevated temperature, wherein the catalyst comprises the active components copper and zinc oxide and a support material.

2. 发明授权

US06576795B1 Racemization of optically active amines 失效
标题翻译：光学活性胺的外消旋化
公开(公告)号：US06576795B1
公开(公告)日：2003-06-10
申请号：US10261123
申请日：2002-10-01
申请人： Frank Funke , Shelue Liang , Andreas Kramer , Rainer Stürmer , Arthur Höhn
发明人： Frank Funke , Shelue Liang , Andreas Kramer , Rainer Stürmer , Arthur Höhn
IPC分类号： C07C2968
CPC分类号： C07C213/02 , B01J23/80 , B01J35/023 , B01J37/0009 , B01J37/0201 , B01J37/031 , B01J37/035 , C07B2200/07 , C07C209/68 , C07C209/88 , C07C217/08 , C07C211/07
摘要： Optically active amines of the formula I where R1 and R2 are different and R1, R2, R3 are alkyl, cycloalkyl, arylalkyl, aryl, heteroaryl and heterocyclic radicals and R3 may also be hydrogen (H), with the radicals being able to bear substituents selected from the group consisting of alkyl, cycloalkyl, alkoxy, aryloxy, amino, alkylamino and dialkylamino, are racemized by reacting the optically active amine I in the presence of hydrogen and a hydrogenation or dehydrogenation catalyst at elevated temperature, wherein the catalyst comprises the active components copper and zinc oxide and a support material.
摘要翻译：式I的光学活性胺，其中R 1和R 2不同，R 1，R 2，R 3是烷基，环烷基，芳基烷基，芳基，杂芳基和杂环基，R 3也可以是氢（H），其中基团能够承载取代基由烷基，环烷基，烷氧基，芳氧基，氨基，烷基氨基和二烷基氨基组成的组通过使光学活性胺I在氢气和氢化或脱氢催化剂的存在下在升高的温度下反应进行外消旋化，其中催化剂包含活性组分铜和氧化锌和支撑材料。

3. 发明授权

US06689914B2 Preparation of amines 失效
标题翻译：胺的制备
公开(公告)号：US06689914B2
公开(公告)日：2004-02-10
申请号：US10234170
申请日：2002-09-05
申请人： Martin Schäfer , Arnd Böttcher , Andreas Kramer , Arthur Höhn , Shelue Liang , Frank Funke
发明人： Martin Schäfer , Arnd Böttcher , Andreas Kramer , Arthur Höhn , Shelue Liang , Frank Funke
IPC分类号： C07C2926
CPC分类号： C07C209/26
摘要： The preparation of amines of the formula (I): R1R2CH—N R3R4 (I) in which R1, R2, R3 and R4, independently of one another, are hydrogen, straight-chain or branched C1-C12-alkyl, C3-C12-cycloalkyl, C6-C10-aryl or C7-C11-aralkyl, takes place by catalytic, reductive amination of mixtures comprising carbonyl compounds of the formula (II) and/or alcohols of the formula (III) R1—C(═O)—R2 (II) R1—CH(OH)—R2 (III) which also comprise at least 50 ppm, based on the mixtures, of halogen, with nitrogen compounds of the formula (IV): H N R3 R4 (IV) with the abovementioned meanings for R1 to R4, in the presence of Co- and/or Ni-containing catalysts, which comprises carrying out the reductive amination additionally in the presence of solid acidic cocatalysts.
摘要翻译：式（I）的胺的制备：其中R 1，R 2，R 3和R 4彼此独立地是氢，直链或支链的C 1 -C 12 - 烷基，C 3 -C 12 - 环烷基，C 6 -C 10 - 芳基或C 7 -C 11 - 芳烷基，其通过催化还原胺化包括式（II）的羰基化合物和/或式（III）的醇，包含基于混合物的卤素至少50ppm与式（IV）的氮化合物：在上述对R 1至R 4的含义中，在Co-和/或Ni- 其包括另外在固体酸性助催化剂存在下进行还原胺化。

4. 发明授权

US06462236B2 Preparation of amines 有权
标题翻译：胺的制备
公开(公告)号：US06462236B2
公开(公告)日：2002-10-08
申请号：US09983307
申请日：2001-10-24
申请人： Shelue Liang , Frank Funke , Arthur Höhn
发明人： Shelue Liang , Frank Funke , Arthur Höhn
IPC分类号： C07C20926
CPC分类号： C07C209/26 , C07C211/29
摘要： Amines of the formula (I) R1R2CH—NR3R4 (I) where R1, R2, R3 and R4 are each, independently of one another, hydrogen, straight-chain or branched C1-C12-alkyl, C3-C12-cycloalkyl, C6-C10-aryl or C7-C11-aralkyl, where at least one of the radicals R1 and R2 is aryl or aralkyl whose aromatic unit is substituted by at least one halogen, are prepared by catalytic, hydrogenative amination of carbonyl compounds of the formula (II) or alcohols of the formula (III) R1—C(═O)—R2 (II) R1—CH(OH)—R2 (III) by means of nitrogen compounds of the formula (IV) HNR3R4 (IV) where R1 to R4 are as defined above, in the presence of Co- and/or Ni-containing catalysts, in the additional presence of solid acid cocatalysts and in the absence of organic sulfur compounds.
摘要翻译：式（I）的胺其中R 1，R 2，R 3和R 4各自独立地为氢，直链或支链C 1 -C 12 - 烷基，C 3 -C 12 - 环烷基，C 6 -C 10 - 芳基或C 7 -C 12 - C 11 - 芳烷基，其中基团R 1和R 2中的至少一个是其芳族单元被至少一个卤素取代的芳基或芳烷基，其通过式（II）的羰基化合物的催化，氢化胺化或式（III）通过其中R 1至R 4如上所定义的式（Ⅳ）的氮化合物在存在Co和/或Ni的催化剂的情况下，在固体酸助催化剂的另外存在下，在不存在有机硫化合物。

5. 发明授权

US6140545A Preparation of alcohols 失效
标题翻译：醇的制备
公开(公告)号：US6140545A
公开(公告)日：2000-10-31
申请号：US251462
申请日：1999-02-17
申请人： Martin Merger , Shelue Liang , Rolf Fischer , Joachim Wulff-Doring
发明人： Martin Merger , Shelue Liang , Rolf Fischer , Joachim Wulff-Doring
IPC分类号： C07C29/149 , C07C37/08
CPC分类号： C07C29/149 , C07C2101/14
摘要： In a process for preparing alcohols by gas phase hydrogenation of carboxylic acids or esters thereof at elevated temperature and elevated pressure in the presence of catalysts consisting of or comprising, as hydrogenating components, oxides of main group VI and/or subgroup IV, the hydrogenation is carried outa) at from 250.degree. C. to 400.degree. C. and from 5 bar to 100 bar in the presence ofb) primary or secondary alcohols, the molar hydrogen/alcohol ratio being at most 800.
摘要翻译：在通过在升高的温度和升高的压力下，在由主要VI族和/或第IV族的氧化物组成或包含氢化组分的催化剂存在下，在羧酸或其酯的气相氢化制备醇的方法中，氢化是在b）伯醇或仲醇的存在下，在250℃至400℃和5巴至100巴下进行a），氢/醇摩尔比为至多800。

6. 发明授权

US06384154B1 Preparation of halogen-free, reactive polyisobutene 失效
标题翻译：无卤素，反应性聚异丁烯的制备
公开(公告)号：US06384154B1
公开(公告)日：2002-05-07
申请号：US09744256
申请日：2001-01-31
申请人： Christoph Sigwart , Thomas Narbeshuber , Eugen Gehrer , Rolf Fischer , Ulrich Steinbrenner , Shelue Liang
发明人： Christoph Sigwart , Thomas Narbeshuber , Eugen Gehrer , Rolf Fischer , Ulrich Steinbrenner , Shelue Liang
IPC分类号： C08F11010
CPC分类号： C08F110/10 , C08F2/00 , C08F4/10 , C08F4/26 , C08F4/24 , C08F4/12 , C08F4/06 , C08F4/18 , C08F4/22
摘要： A process for preparing halogen-free, reactive polyisobutene having a terminal double bond content of more than 60 mol % and an average molecular weight Mn of 800-3000 dalton by cationic polymerization in the liquid phase of isobutene over an acidic, essentially halogen-free heterogeneous catalyst, where a) a hydrocarbon mixture of essentially C4-hydrocarbons comprising isobutene in an amount of from 10 to 80% by weight is used as the starting material and b) polymerization is carried out continuously at from −30 to 0° C. with average starting material residence times of one hour or less, where the temperature and the residence time are selected such that the isobutene conversion is less than 60% and, after separation from the resulting polyisobutene, the isobutene is either enriched in the partially converted hydrocarbon mixture and returned to the polymerization or passed to another isobutene reaction coupled with the polymerization.
摘要翻译：一种通过阳离子聚合在异丁烯液相中酸性，基本上不含卤素的方式制备末端双键含量大于60mol％，平均分子量Mn为800-3000道尔顿的无卤素的活性聚异丁烯的方法非均相催化剂，其中将基本上含有10-80重量％异丁烯的C 4烃的烃混合物用作原料，和b）在-30℃至0℃下连续进行聚合，平均起始材料停留时间为1小时或更短，其中选择温度和停留时间使得异丁烯转化率小于60％，并且在从所得聚异丁烯分离后，异丁烯富含部分转化的烃混合物，返回聚合反应或通过与聚合偶联的另一异丁烯反应。

7. 发明授权

US07084312B1 Catalyst and method for hydrogenating carbonyl compounds 有权
标题翻译：氢化羰基化合物的催化剂和方法
公开(公告)号：US07084312B1
公开(公告)日：2006-08-01
申请号：US10070275
申请日：2000-08-22
申请人： Sylvia Huber , Michael Jolyon Sprague , Boris Breitscheidel , Joachim Wulff-Döring , Michael Hesse , Rolf Pinkos , Shelue Liang , Otto Kumberger , Marc Walter
发明人： Sylvia Huber , Michael Jolyon Sprague , Boris Breitscheidel , Joachim Wulff-Döring , Michael Hesse , Rolf Pinkos , Shelue Liang , Otto Kumberger , Marc Walter
IPC分类号： C07C29/136 , C07C29/14 , C07C29/141 , C07C29/143 , C07C29/147
CPC分类号： B01J23/80 , C07C29/149 , C07C31/20
摘要： A process for the hydrogenation of an organic compound containing at least one carbonyl group comprises bringing the organic compound in the presence of hydrogen into contact with a shaped body which can be produced by a process in which (i) an oxidic material comprising copper oxide, zinc oxide and aluminum oxide is made available, (ii) pulverulent metallic copper or pulverulent cement or a mixture thereof is added to the oxidic material, and (iii) the mixture resulting from (ii) is shaped to form a shaped body.
摘要翻译：氢化含有至少一个羰基的有机化合物的方法包括使氢存在下的有机化合物与成形体接触，成形体可以通过以下工艺制备，其中（i）包含氧化铜的氧化物，提供氧化锌和氧化铝，（ii）将粉末状金属铜或粉状水泥或其混合物加入到氧化物中，和（iii）由（ii）得到的混合物成形为成形体。

8. 发明授权

US06828464B2 Preparation of cyclopentenones 失效
标题翻译：环戊烯酮的制备
公开(公告)号：US06828464B2
公开(公告)日：2004-12-07
申请号：US10718795
申请日：2003-11-24
申请人： Shelue Liang , Rolf-Hartmuth Fischer , Sylvia Huber-Dirr , Andrea Haunert
发明人： Shelue Liang , Rolf-Hartmuth Fischer , Sylvia Huber-Dirr , Andrea Haunert
IPC分类号： C07C4554
CPC分类号： B01J23/04 , C07C45/48 , Y02P20/582 , C07C49/597
摘要： The present invention provides a process for preparing 2-cyclopentenones of the general formula: where R1 to R4 are each hydrogen atoms or are alkyl or alkenyl radicals having from 1 to 12 carbon atoms, cycloalkyl or cycloalkenyl radicals having from 5 to 7 carbon atoms, aralkylene or aryl radicals, by converting hexenedioic acids and/or their esters of the general formulae where R1 to R4 are each as defined above and R5 and R6 are each hydrogen atoms or are alkyl radicals having from 1 to 12 carbon atoms, cycloalkyl radicals having 5 or 6 carbon atoms, aralkyl or aryl radicals, at temperatures of from 150 to 450° C., over solid, oxidic catalysts, wherein the catalysts on an oxidic support material comprise from 0.01 to 5% by weight of at least one alkali metal oxide.
摘要翻译：本发明提供一种制备以下通式的2-环戊烯酮的方法：其中R 1至R 4各自为氢原子或具有1至12个碳原子的烷基或烯基，环烷基或环烯基具有 5-7个碳原子的亚芳基或芳基，通过将通式R 1至R 4的通式所示的己烯二酸和/或它们的酯各自如上所定义，R 5和R 6各自为氢原子或具有1至12个碳原子的烷基，具有5或6个碳原子的环烷基，芳烷基或芳基，在150-450℃的温度下，在固体，氧化催化剂上，其中催化剂在氧化载体材料包含0.01至5重量％的至少一种碱金属氧化物。

9. 发明申请

US20070232833A1 Method for the Continuous Production of an Amine 失效
标题翻译：连续生产胺的方法
公开(公告)号：US20070232833A1
公开(公告)日：2007-10-04
申请号：US11596292
申请日：2005-05-04
申请人： Frank Haese , Arnd Bottcher , Bernd Stein , Wolfgang Reif , Johann-Peter Melder , Karl-Heinz Ross , Heinz Rutter , Shelue Liang , Stefan Rittinger
发明人： Frank Haese , Arnd Bottcher , Bernd Stein , Wolfgang Reif , Johann-Peter Melder , Karl-Heinz Ross , Heinz Rutter , Shelue Liang , Stefan Rittinger
IPC分类号： C07C209/60
CPC分类号： C07C209/26 , C07C209/16 , C07C213/02 , C07D295/027 , C07D295/03 , C07D295/088 , C08G59/50 , Y02P20/582 , C07C211/06 , C07C211/08 , C07C211/35 , C07C217/08
摘要： Process for the continuous preparation of an amine by reaction of a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary and secondary amines at a temperature in the range from 60 to 300° C in the presence of a copper-containing catalyst, wherein the catalytically active composition of the catalyst prior to reduction with hydrogen comprises from 20 to 85% by weight of aluminum oxide (Al2O3), zirconium dioxide (ZrO2), titanium dioxide (TiO2) and/or silicon dioxide (SiO2), from 1 to 70% by weight of oxygen-containing compounds of copper, calculated as CuO, from 0 to 50% by weight of oxygen-containing compounds of magnesium, calculated as MgO, oxygen-containing compounds of chromium, calculated as Cr2O3, oxygen-containing compounds of zinc, calculated as ZnO, oxygen-containing compounds of barium, calculated as BaO, and/or oxygen-containing compounds of calcium, calculated as CaO, and less than 30% by weight of oxygen-containing compounds of nickel, calculated as NiO, based on the oxygen-containing compounds of copper, calculated as CuO, and the reaction is carried out isothermally in the gas phase in a tube reactor.
摘要翻译：通过伯醇或仲醇，醛和/或酮与氢和选自氨，伯胺和仲胺的氮化合物在60至300℃的温度下反应来连续制备胺的方法在含铜催化剂存在下，其中催化剂在用氢还原之前的催化活性组合物包含20至85重量％的氧化铝（Al 2 O 3） 3），二氧化锆（ZrO 2），二氧化钛（TiO 2）和/或二氧化硅（SiO 2），1至70重量％的以CuO计的含氧化合物的铜，0至50重量％的以氧化镁计的含氧化合物，以氧化铬计算的含铬化合物，以ZnO计算的含氧化合物锌，以BaO计的钡的含氧化合物和/ 或以CaO计的含氧化合物的钙，小于30重量％的按NiO计的含氧化合物的镍，以CuO计算的含氧化合物计算，并进行反应在管式反应器中在气相中等温。

10. 发明授权

US06387224B1 Method for distilling mixtures containing butanediol 有权
标题翻译：蒸馏含丁二醇的混合物的方法
公开(公告)号：US06387224B1
公开(公告)日：2002-05-14
申请号：US09623109
申请日：2000-08-29
申请人： Rolf Pinkos , Rolf Fischer , Shelue Liang
发明人： Rolf Pinkos , Rolf Fischer , Shelue Liang
IPC分类号： B01D334
CPC分类号： C07D307/20 , C07C29/80 , C07C45/82 , C07C47/19 , C07C31/207
摘要： A process for the separation by distillation of a mixture of 1,4-butanediol and at least one 4-hydroxybutyraldehyde, its cyclic hemiacetal and its cyclic full acetals with at least one further alcohol by carrying out the distillation in the presence of an alkaline compound. The mixture to be separated preferably contains a cyclic full acetal of 4-hydroxybutyraldehyde with a further alcohol which has a lower boiling point than butanediol and also the further alcohol in free form. The process is particularly suitable for the separation by distillation of mixtures formed in the hydrogenation of maleic acid derivatives.
摘要翻译：通过在碱性化合物的存在下进行蒸馏来通过蒸馏分离1,4-丁二醇和至少一种4-羟基丁醛的混合物的方法，其环状半缩醛和其环状全缩醛与至少一种其它醇进行蒸馏。要分离的混合物优选含有4-羟基丁醛的环状全缩醛，另外具有低于丁二醇的沸点的醇，还有另外的游离形式的醇。该方法特别适用于通过蒸馏分离在马来酸衍生物的氢化中形成的混合物。

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