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1. 发明授权

US06403845B1 Preparation of pentanediols from alkoxydihydropyrans 失效
标题翻译：从烷氧基二氢吡喃制备戊二醇
公开(公告)号：US06403845B1
公开(公告)日：2002-06-11
申请号：US09625487
申请日：2000-07-25
申请人： Joachim Pfeffinger , Peter Wahl , Jan Nouwen , Karsten Eller , Arthur Höhn , Jürgen Hunger
发明人： Joachim Pfeffinger , Peter Wahl , Jan Nouwen , Karsten Eller , Arthur Höhn , Jürgen Hunger
IPC分类号： C07C2700
CPC分类号： C07C29/132 , C07C29/141 , C07C31/20
摘要： are prepared by single-stage reaction of alkoxydihydropyrans of the formula (II) with water and hydrogen in the presence of a catalyst comprising oxides of nickel, zirconium and copper. In the formulae (I) and (II), R, R′, R″, R′″ can be identical or different and are each hydrogen or a linear or branched saturated hydrocarbon radical having from 1 to 20 carbon atoms in which the hydrocarbon chain may contain O, S and N as heteroatoms and which may be monosubstituted or polysubstituted by hydroxy, thiol or amino groups or halogens.
摘要翻译：在式（I）和（II）的催化剂存在下，通过式（II）的烷氧基二氢吡喃与水和氢的单步反应制备。在式（I）和（II）中，R，R' R“，R”可以相同或不同，并且各自为氢或具有1至20个碳原子的直链或支链饱和烃基，其中烃链可以含有O，S和N作为杂原子，并且其可以是被羟基，硫醇或氨基或卤素单取代或多取代。

2. 发明授权

US06790995B2 Preparation of primary and secondary amines from nitriles 失效
标题翻译：从腈制备伯胺和仲胺
公开(公告)号：US06790995B2
公开(公告)日：2004-09-14
申请号：US10033912
申请日：2002-01-03
申请人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
发明人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
IPC分类号： C07C20948
CPC分类号： C07C213/02 , C07C209/48 , C07C211/11 , C07C215/08
摘要： Mixtures of primary amines of the formula (I) X—CH2—NH2 (I) and secondary amines of the formula (II) (X—CH2—)2NH (II) where X is C1-20-alkyl, C2-20-alkenyl or C3-8-cycloalkyl which may be unsubstituted or substituted by C1-20-alkyl, C3-8-cycloalkyl, C4-20-alkylcycloalkyl, C4-20-cycloalkylalkyl, C2-20-alkoxyalkyl, C6-14-aryl, C7-20-alkylaryl, C7-20-aralkyl, C1-20-alkoxy, hydroxy, C1-20-hydroxyalkyl, amino, C1-20-alkylamino, C2-20-dialkylamino, C2-12-alkenylamino. C3-8-cycloalkylamino, arylamino, diarylamino, aryl-C1-8-alkylamino, halogen, mercapto, C2-20-alkenyloxy, C3-8-cycloalkoxy, aryloxy and/or C2-8-alkoxycarbonyl are prepared by reacting nitriles of the formula (III) X—CN (III) with hydrogen at from 50 to 250° C. and pressures of from 5 to 350 bar in the presence of a Pd-containing catalyst comprising, based on the total weight of the catalyst, from 0.1 to 10% by weight of Pd on a support.
摘要翻译：式（I）的伯胺和式（II）的仲胺的混合物，其中X是可以未被取代或被C 1-20烷基取代的C 1-20 - 烷基，C 2-20 - 烯基或C 3-8 - 环烷基，C 3-8 - 环烷基，C 4-20 - 烷基环烷基，C 4-20 - 环烷基烷基，C 2-20烷氧基烷基，C 6-14 - 芳基，C 7-20 - 烷基芳基，C 7-20 - 芳烷基，C 1-20 - 烷氧基，羟基，C 1-20羟烷基，氨基，C 1-20烷基氨基，C 2-20 - 二烷基氨基，C 2-12 - 烯基氨基。 C 3-8 - 环烷基氨基，芳基氨基，二芳基氨基，芳基-C 1-8 - 烷基氨基，卤素，巯基，C 2-20 - 烯氧基，C 3-8 - 环烷氧基，芳氧基和/或C 2-8烷氧基羰基，（III）与氢气在50-250℃下反应，压力为5-350巴，在含Pd催化剂的存在下，基于催化剂的总重量计，为0.1-10重量％的Pd 在支持上。

3. 发明授权

US06525223B2 Preparation of secondary amines from nitriles 失效
标题翻译：从腈制备仲胺
公开(公告)号：US06525223B2
公开(公告)日：2003-02-25
申请号：US10026900
申请日：2001-12-27
申请人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
发明人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
IPC分类号： C07C20948
CPC分类号： C07C209/48 , C07C211/11
摘要： Secondary amines of the formula (II) (X—CH2—)2NH (II) where X is a C1-20-alkyl, C2-20-alkenyl or C3-8-cycloalkyl group which may be unsubstituted or substituted by C1-20-alkyl, C3-8-cycloalkyl, C4-20-alkylcycloalkyl, C4-20-cycoalkylalkyl, C2-20-alkoxyalkyl, C6-14-aryl, C7-20-alkylaryl, C7-20-aralkyl, C1-20-alkoxy, hydroxy, C1-20-hydroxyalkyl, amino, C1-20-alkylamino, C2-20-dialkylamino, C2-12-alkenylamino, C3-8-cycloalkylamino, arylamino, diarylamino, aryl-C1-8-alkylamino, halogen, mercapto, C2-20-alkenyloxy, C3-8-cycloalkoxy, aryloxy and/or C2-8-alkoxycarbonyl, are prepared by reacting nitriles of the formula (III) X—CN (III) with hydrogen at from 20 to 250° C. and pressures of from 60 to 350 bar in the presence of an Rh-containing catalyst comprising from 0.1 to 5% by weight, based on the total weight of the catalyst, of Rh on a support to give mixtures of primary amines of the formula (I) X—CH2—NH2 (I) and secondary amines of the formula (II) (X—CH2—)2NH (II) and returning at least part of the primary amines separated from the mixtures obtained to the reaction.
摘要翻译：式（II）的仲胺，其中X是可以是未取代的或被C 1-20 - 烷基，C 3-8 - 环烷基，C 4 -C 18环烷基，C 3-8 - C 20-20烷基烷基，C 2-20 - 烷氧基烷基，C 6-14 - 芳基，C 7-20 - 烷基芳基，C 7-20 - 芳烷基，C 1-20 - 烷氧基，羟基，C 1-20 - 羟基烷基，氨基， C 1-20 - 烷基氨基，C 2-20 - 二烷基氨基，C 2-12 - 烯基氨基，C 3-8 - 环烷基氨基，芳基氨基，二芳基氨基，芳基-C 1-8 - 烷基氨基，卤素，巯基，C 2-20 - 烯氧基，环烷氧基，芳氧基和/或C 2-8 - 烷氧基羰基，通过在含Rh的催化剂存在下，使式（III）的腈与20至250℃的压力和60至350巴的压力反应来制备包含基于催化剂总重量的0.1至5重量％的Rh在载体上以得到式（I）的伯胺和式（II）的仲胺的混合物，并使至少部分从获得的混合物中分离出伯胺反应。

4. 发明授权

US06723880B2 Preparation of secondary amines from primary amines 有权
标题翻译：从伯胺制备仲胺
公开(公告)号：US06723880B2
公开(公告)日：2004-04-20
申请号：US10173774
申请日：2002-06-19
申请人： Peter Neumann , Johann-Peter Melder , Christoph Benisch , Arthur Höhn , Joachim Pfeffinger
发明人： Peter Neumann , Johann-Peter Melder , Christoph Benisch , Arthur Höhn , Joachim Pfeffinger
IPC分类号： C07D41702
CPC分类号： C07C209/64 , C07C211/13
摘要： A process for producing secondary amines of the formula R1R2N—A—NH—A—NR1R2, where R1 and R2 are linear or branched C1-20-alkyl radicals, optionally substituted with from 1 to 5 phenyl groups; or cyclohexyl radicals; or together with the nitrogen atom to which they are bound, form a 3 to 7 membered saturated ring, optionally containing further hetero atoms selected from the group consisting of N, O and S, and optionally substituted with from 1 to 5 C1-2-alkyl groups. The group A is a linear or branched C2-20-alkylene group, optionally containing from 1 to 5 phenylene groups; or a radical of the formula —CH(R3)—[CH2]k—X—[CH(R3)—[CH2]k—X]m—CH(R3)—[CH2]k—, where R3 is H or CH3, X is O, S or NR4, R4 is H or a linear or branched C1-4-alkyl group, k is 1 or 2, and m is an integer from 0 to 4; or a group of the formula where n, o, p, and q are, independently, integers from 1 to 4. In this process, primary amines of the formula R1R2N—A—NH2 are reacted in the presence of hydrogen and a catalyst comprising at least one element or compound of an element of groups VIII and IB of the Periodic Table, preferably group IB, and in particular, Cu. Through this process, a high selectivity of the desired amines can be achieved.
摘要翻译：一种制备式R 1 R 2 NA-NH-A-NR 1 R 2的仲胺的方法，其中R 1和R 2是直链或支链C 1-20 - 任选被1至5个苯基取代的烷基; 或环己基; 或与其结合的氮原子一起形成3至7元饱和环，任选地含有选自N，O和S的另外的杂原子，并且任选被1至5个C 1-2 - 烷基。基团A是任选含有1至5个亚苯基的直链或支链C 2-20 - 亚烷基; 或式-CH（R 3） - [CH 2] k X- [CH（R 3） - [CH 2] k X] m -CH（R 3） - [CH 2] k - 的基团，其中R 3是H或CH 3，X是O，S或NR 4，R 4是H或直链或支链C 1-4 - 烷基，k是1或2，m是整数从0到4; 或一组式n，o，p和q独立地为1至4的整数。在该方法中，式R 1 R 2 NA-NH 2的伯胺在存在下反应氢和包含元素周期表第VIII和IB族元素的至少一种元素或化合物的催化剂，优选IB族，特别是Cu。通过该方法，可以实现所需胺的高选择性。

5. 发明授权

US08828267B2 Use of a stereoisomer mixture of diaminomethylcyclohexane as a hardener for epoxy resins 有权
标题翻译：使用二氨基甲基环己烷的立体异构体混合物作为环氧树脂的硬化剂
公开(公告)号：US08828267B2
公开(公告)日：2014-09-09
申请号：US13496993
申请日：2010-09-20
申请人： Joachim Pfeffinger , Daniela Malkowsky , Stephan Goettke
发明人： Joachim Pfeffinger , Daniela Malkowsky , Stephan Goettke
IPC分类号： C08G59/50 , C08L63/00 , C08L63/02 , C08L63/04
CPC分类号： C08G59/5026 , C08L63/00
摘要： The present invention provides a composition which comprises at least one epoxy resin and a mixture comprising the 7 stereoisomers of diaminomethylcyclohexane in very specific ratios relative to one another, a process for preparing the composition, the use of the composition for producing hardened epoxides, adhesives, composite materials and moldings, a mixture comprising the 7 stereoisomers of diaminomethylcyclohexane in the specific ratios, and the use of this mixture for producing the composition.
摘要翻译：本发明提供一种组合物，其包含至少一种环氧树脂和包含二氨基甲基环己烷的7种立体异构体的混合物，其相对于彼此具有非常特定的比例，制备该组合物的方法，该组合物用于生产硬化环氧化物，粘合剂，复合材料和模制品，以特定比例包含二氨基甲基环己烷的7种立体异构体的混合物，以及该混合物用于制备组合物的用途。

6. 发明申请

US20120245377A1 PROCESS FOR PREPARING ISOCYANATES BY THERMALLY CLEAVING CARBAMATES 有权
标题翻译：通过热清除碳酸钙制备异氰酸酯的方法
公开(公告)号：US20120245377A1
公开(公告)日：2012-09-27
申请号：US13513460
申请日：2010-11-30
申请人： Michael Bock , Eckhard Stroefer , Robert Baumann , Axel Franzke , Joachim Pfeffinger
发明人： Michael Bock , Eckhard Stroefer , Robert Baumann , Axel Franzke , Joachim Pfeffinger
IPC分类号： C07C263/04
CPC分类号： C07C263/04 , C07C265/14
摘要： A process is proposed for preparing isocyanates by thermally cleaving carbamates to obtain a carbamate cleavage gas comprising the corresponding isocyanate and the corresponding alcohol, which comprises quenching the carbamate cleavage gas in the presence of an ether which functions as an inhibitor for the reverse reaction of the isocyanate with the alcohol.
摘要翻译：提出了通过热裂解氨基甲酸酯制备异氰酸酯以获得包含相应的异氰酸酯和相应的醇的氨基甲酸酯裂解气体的方法，该方法包括在醚的存在下猝灭氨基甲酸酯裂解气体，该醚用作反应的反应的抑制剂异氰酸酯与醇。

7. 发明申请

US20110137083A1 CONTINUOUS METHOD AND REACTOR FOR HYDROGENATING ORGANIC COMPOUNDS 审中-公开
标题翻译：氢化有机化合物的连续方法和反应器
公开(公告)号：US20110137083A1
公开(公告)日：2011-06-09
申请号：US12994575
申请日：2009-05-20
申请人： Joachim Pfeffinger
发明人： Joachim Pfeffinger
IPC分类号： C07C211/35 , B01J19/26
CPC分类号： B01J4/002 , B01J8/025 , B01J8/226 , B01J8/228 , B01J19/246 , B01J19/2465 , B01J19/30 , B01J19/32 , B01J2219/00777 , C07C29/147 , C07C29/19 , C07C209/72 , C07C2601/14 , C07C211/36
摘要： The present invention relates to a continuous process for hydrogenating organic compounds in a polyphasic system in the presence of a homogeneous or heterogeneous catalyst, which comprises performing the process in two stages, the first stage being performed in a loop reactor with an external heat exchanger and the second stage in a bubble column reactor with limited backmixing.The present invention further relates to a hydrogenation reactor (1) in a tall cylindrical design comprising a concentric guide tube (2) arranged in the lower reaction region and a mixing nozzle (3) directed upward, through which reactants and reaction mixture can be supplied, a pump (4) and a heat exchanger (5), which are present in an external pump circulation system which leads from the reactor to the mixing pump, and with one or more gas- and liquid-permeable internals (10) mounted in the upper region of the reactor, where the ratio of total length to diameter of the hydrogenation reactor (1) is in the range from 5:1 to 100:1 and the ratio of the volume of the upper region of the reactor to the volume of the lower region of the reactor is from 0.05:1 to 10:1.
摘要翻译：本发明涉及一种用于在均相或多相催化剂存在下在多相体系中氢化有机化合物的连续方法，其包括在两个阶段中进行该过程，第一阶段在具有外部热交换器的环管反应器中进行，泡沫塔式反应器的第二阶段有限的回混。本发明还涉及一种具有高圆柱形设计的氢化反应器（1），其包括布置在下部反应区域中的同心引导管（2）和向上引导的混合喷嘴（3），从而可以提供反应物和反应混合物，存在于从反应器引导到混合泵的外部泵循环系统中的泵（4）和热交换器（5），以及安装在一个或多个气体和液体可透过的内部构件（10）中的泵反应器的上部区域，其中氢化反应器（1）的总长度与直径的比率在5:1至100:1的范围内，并且反应器的上部区域的体积与体积的比率的反应器的下部区域为0.05:1至10:1。

8. 发明授权

US08940250B2 Method of conveying liquids 有权
标题翻译：输送液体的方法
公开(公告)号：US08940250B2
公开(公告)日：2015-01-27
申请号：US13382740
申请日：2010-07-06
申请人： Joachim Pfeffinger , Willi Gilcher , Juergen Morell
发明人： Joachim Pfeffinger , Willi Gilcher , Juergen Morell
IPC分类号： B01L3/00 , F04B53/14 , F04B15/04 , F04B39/00 , F04B43/02 , F04F1/02 , F04F1/14 , F04F1/18
CPC分类号： F04B53/141 , F04B15/04 , F04B39/0011 , F04B43/02 , F04F1/02 , F04F1/14 , F04F1/18 , Y10T137/0318 , Y10T436/2575
摘要： The present invention relates to a method of continuously conveying a liquid which is used as starting material in a chemical reaction by means of a displacement pump having physically separate forward-transport valves and a liquid-filled bidirectional flow line between displacement pump and forward-transport valves, wherein an auxiliary liquid which is a product or a starting material of the chemical reaction and has a melting point which is below the melting point or below the saturation temperature of the liquid to be conveyed is present in the bidirectional flow line.The present invention additionally provides for the use of a product formed by hydrogenation of an aromatic compound as auxiliary liquid for conveying an aromatic compound and also the use of an alcohol or an ester derived from alcohol and carboxylic acid as auxiliary liquid for conveying carboxylic acids or carboxylic acid derivatives.
摘要翻译：本发明涉及一种连续输送液体的方法，该液体通过具有物理分离的前向输送阀的位移泵和位移泵与前进运输之间的液体填充双向流动管线在化学反应中用作原料阀，其中作为化学反应的产物或原料的辅助液体存在于双向流动管线中，所述辅助液体的熔点低于待输送的液体的熔点或低于饱和温度。本发明另外提供了通过芳族化合物氢化形成的产物作为用于输送芳族化合物的辅助液体的用途，还提供了使用来自醇和羧酸的醇或酯作为用于输送羧酸的辅助液体的用途，或羧酸衍生物。

9. 发明申请

US20120116099A1 METHOD OF CONVEYING LIQUIDS 有权
标题翻译：输送液体的方法
公开(公告)号：US20120116099A1
公开(公告)日：2012-05-10
申请号：US13382740
申请日：2010-07-06
申请人： Joachim Pfeffinger , Willi Gilcher , Juergen Morell
发明人： Joachim Pfeffinger , Willi Gilcher , Juergen Morell
IPC分类号： C07C209/72 , C07C29/20 , C07D307/89 , C07C51/36 , F17D3/00 , C07C211/36 , C07C35/21 , C07C61/08 , C07C31/00 , C07C69/00 , C07C209/48 , C07C67/08
CPC分类号： F04B53/141 , F04B15/04 , F04B39/0011 , F04B43/02 , F04F1/02 , F04F1/14 , F04F1/18 , Y10T137/0318 , Y10T436/2575
摘要： The present invention relates to a method of continuously conveying a liquid which is used as starting material in a chemical reaction by means of a displacement pump having physically separate forward-transport valves and a liquid-filled bidirectional flow line between displacement pump and forward-transport valves, wherein an auxiliary liquid which is a product or a starting material of the chemical reaction and has a melting point which is below the melting point or below the saturation temperature of the liquid to be conveyed is present in the bidirectional flow line.The present invention additionally provides for the use of a product formed by hydrogenation of an aromatic compound as auxiliary liquid for conveying an aromatic compound and also the use of an alcohol or an ester derived from alcohol and carboxylic acid as auxiliary liquid for conveying carboxylic acids or carboxylic acid derivatives.
摘要翻译：本发明涉及一种连续输送液体的方法，该液体通过具有物理分离的前向输送阀的位移泵和位移泵与前进运输之间的液体填充双向流动管线在化学反应中用作原料阀，其中作为化学反应的产物或原料的辅助液体存在于双向流动管线中，所述辅助液体的熔点低于待输送的液体的熔点或低于饱和温度的熔点。本发明另外提供了通过芳族化合物氢化形成的产物作为用于输送芳族化合物的辅助液体的用途，还提供了使用来自醇和羧酸的醇或酯作为用于输送羧酸的辅助液体的用途，或羧酸衍生物。

10. 发明授权

US08987517B2 Process for preparing cycloaliphatic amines 有权
标题翻译：脂环族胺的制备方法
公开(公告)号：US08987517B2
公开(公告)日：2015-03-24
申请号：US12863137
申请日：2009-01-14
申请人： Joachim Pfeffinger , Willi Doell
发明人： Joachim Pfeffinger , Willi Doell
IPC分类号： C07C211/35 , C07C211/36 , C08K5/14 , C07C209/72 , C07C211/44
CPC分类号： C08K5/14 , C07C209/72 , C07C211/44 , C07C2601/14 , C08K5/17 , Y02P20/582 , C07C211/35 , C07C211/36
摘要： A process for preparing cycloaliphatic amines by hydrogenating the corresponding aromatic compounds with hydrogen-comprising gas at a temperature of from 30 to 280° C. and a pressure of 50-350 bar, in the presence of ruthenium catalysts. The hydrogenation is performed in the presence of from 1% by weight to 500% by weight, based on the catalyst calculated as elemental ruthenium (Ru), of suspended inorganic additives, and to the use of the cycloaliphatic amines as a synthesis unit.
摘要翻译：在钌催化剂存在下，在30〜280℃的温度和50〜350巴的压力下，用含氢气体氢化相应的芳族化合物，制备环脂族胺的方法。基于以元素钌（Ru）计算的催化剂，悬浮的无机添加剂的1重量％至500重量％的存在，以及使用脂环族胺作为合成单元进行氢化。

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