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1. 发明授权

US5721299A Electrically conductive and abrasion/scratch resistant polymeric materials, method of fabrication thereof and uses thereof 失效
标题翻译：导电和耐磨损/耐刮擦的聚合材料，其制造方法及其用途
公开(公告)号：US5721299A
公开(公告)日：1998-02-24
申请号：US193926
申请日：1994-02-09
申请人： Marie Angelopoulos , Ali Afzali-Ardakani , Jack A. Dickerson , Thomas B. Pillsbury , Karl J. Puttlitz , Jane M. Shaw , Jeffrey D. Gelorme
发明人： Marie Angelopoulos , Ali Afzali-Ardakani , Jack A. Dickerson , Thomas B. Pillsbury , Karl J. Puttlitz , Jane M. Shaw , Jeffrey D. Gelorme
IPC分类号： C08G61/12 , H01B1/12 , H01J29/86 , H01L23/498 , H01L23/60 , H01L33/38 , H01L33/42 , H05K9/00 , H01B1/06
CPC分类号： H05K9/0079 , C08G61/12 , H01B1/125 , H01B1/127 , H01B1/128 , H01J29/868 , H01L23/49894 , H01L23/60 , H01L33/40 , H01L33/42 , H01L2924/0002
摘要： Electrically conductive and abrasion resistant polymeric compositions, methods of fabrication thereof and uses thereof are described. Admixtures of abrasion resistant materials and electrically conductive polymeric materials are formed. Many of these admixtures are light transmitting and can be used as an abrasion resistant light transmitting electrostatic discharge layers. The light transmitting discharge layer is useful as a surface coating for visual displays such as CRT screens to avoid electrostatic accumulation of dust and scratching. The compositions can be admixtures of abrasion resistant silicones, polysiloxanes, acrylates, epoxies, methacrylates, epoxyacrylates, epoxymethacrylates, styrenes and electrically conductive polymers selected from the group of substituted and unsubstituted polyanilines, polyparaphenylenevinyles, substituted and unsubstituted polythiophenes substituted and unsubstituted poly-p-phenylene sulfides, substituted and unsubstituted polyfuranes, substituted and unsubstituted polypyrroles, substituted and unsubstituted polyselenophenes, polyacetylines formed from soluble precursors, combinations thereof and blends thereof with other polymers. The compositions can be a layer of an electrically conductive polymer with an abrasion resistant layer thereover.
摘要翻译：描述了导电和耐磨聚合物组合物，其制造方法及其用途。形成耐磨材料和导电聚合材料的外加剂。这些混合物中的许多是透光性的并且可以用作耐磨光透射静电放电层。透光放电层可用作诸如CRT屏幕的视觉显示器的表面涂层，以避免灰尘和划痕的静电积累。组合物可以是耐磨硅氧烷，聚硅氧烷，丙烯酸酯，环氧树脂，甲基丙烯酸酯，环氧丙烯酸酯，环氧甲基丙烯酸酯，苯乙烯和选自取代和未取代的聚苯胺的聚合物，聚对亚苯基乙烯基，取代和未取代的聚噻吩的取代和未取代的聚对 - 取代和未取代的聚吡咯，取代和未取代的聚硒吩，可溶性前体形成的聚乙酰胺，其组合以及与其它聚合物的共混物。组合物可以是其上具有耐磨层的导电聚合物层。

2. 发明授权

US06193909B1 Cross-linked electrically conductive polymers, precursors thereof 失效
标题翻译：交联导电聚合物及其前体
公开(公告)号：US06193909B1
公开(公告)日：2001-02-27
申请号：US08595853
申请日：1996-02-02
申请人： Marie Angelopoulos , Jeffrey D. Gelorme , Yun Hsin Liao , Jane M. Shaw
发明人： Marie Angelopoulos , Jeffrey D. Gelorme , Yun Hsin Liao , Jane M. Shaw
IPC分类号： H01B112
CPC分类号： C08G73/1071 , H01B1/128
摘要： Cross-linked electrically conductive polymers, in particular electrically conductive, polyaniline are described. Dopants and substituents having pendant cross-linkable functionality are used which form a cross-linked conducting polymer network. The cross-linking functionality can be hydrogen-bonding as well as chemically polymerizable or cross-linkable. A conjugated path between chains can also be incorporated. The resulting cross-linked conducting polymers have enhanced thermal and environmental stability. The dopant cannot readily be washed out with solvents or diffuse out upon exposure to heat. In addition, the cross-linked polymers have enhanced electrical conductivity.
摘要翻译：描述了交联的导电聚合物，特别是导电的聚苯胺。使用具有侧链可交联官能团的掺杂剂和取代基，其形成交联的导电聚合物网络。交联官能团可以是氢键合以及化学上可聚合的或可交联的。还可以并入链之间的共轭路径。所得的交联导电聚合物具有增强的热和环境稳定性。掺杂剂不容易用溶剂洗涤或在暴露于热量时扩散出来。此外，交联聚合物具有增强的导电性。

3. 发明授权

US6030550A Methods of fabrication of cross-linked electrically conductive polymers and precursors thereof 失效
公开(公告)号：US6030550A
公开(公告)日：2000-02-29
申请号：US594680
申请日：1996-02-02
申请人： Marie Angelopoulos , Jeffrey D. Gelorme , Yun Hsin Liao , Jane M. Shaw
发明人： Marie Angelopoulos , Jeffrey D. Gelorme , Yun Hsin Liao , Jane M. Shaw
IPC分类号： H01B1/12
CPC分类号： H01B1/128 , H01B1/125 , H01B1/127
摘要： Cross-linked electrically conductive polymers, in particular electrically conductive, polyaniline are described. Dopants and substituents having pendant cross-linkable functionality are used which form a cross-linked conducting polymer network. The cross-linking functionality can be hydrogen-bonding as well as chemically polymerizable or cross-linkable. A conjugated path between chains can also be incorporated. The resulting cross-linked conducting polymers have enhanced thermal and environmental stability. The dopant cannot readily be washed out with solvents or diffuse out upon exposure to heat. In addition, the cross-linked polymers have enhanced electrical conductivity.

4. 发明授权

US5382637A Solid state chain extension polymerization between Lewis acid oligomers and deblocked Lewis bases 失效
标题翻译：路易斯酸低聚物和解封路易斯碱之间的固态链延伸聚合
公开(公告)号：US5382637A
公开(公告)日：1995-01-17
申请号：US785734
申请日：1991-10-31
申请人： Marie Angelopoulos , Claudius Feger , Jeffrey D. Gelorme , Jane M. Shaw
发明人： Marie Angelopoulos , Claudius Feger , Jeffrey D. Gelorme , Jane M. Shaw
IPC分类号： C08G73/10 , G03F7/004 , G03F7/038 , C08L77/00 , C08L79/08
CPC分类号： C08G73/101 , G03F7/0045 , G03F7/0387
摘要： A solid state chain extension method provides for the formation of a solid state film comprised of a high molecular weight polymer by chain extending a deblocked Lewis base with Lewis acid oligomers while the reactants are in a solid state form. In one embodiment, a negative resist is prepared by selectively exposing regions of the solid state film. The Lewis base is deblocked at the exposed regions by a suitable deblocking means. The Lewis acid oligomers and the deblocked Lewis base chain extend at the exposed regions. Development of the film removes the non-polymerized reactants. Optionally, the Lewis acid oligomers, when radiation-cross-linking, are cross-linked with one another prior to deblocking the Lewis base to form a negative resist. The cross-linked oligomers polymerize with the subsequently deblocked base to provide a high molecular weight polymer film. In an alternative embodiment, a positive resist is used by degrading and removing phot-sensitive Lewis acid oligomers using selective exposure lithography techniques and, subsequently, deblocking the Lewis base and chain extending the remaining oligomers with the deblocked Lewis base at the unexposed regions.
摘要翻译：固态链延伸方法提供了通过将路易斯酸低聚物链路延伸解链路易斯碱同时反应物呈固态形式形成由高分子量聚合物构成的固态膜。在一个实施方案中，通过选择性地暴露固态膜的区域来制备负性抗蚀剂。路易斯碱通过合适的去块装置在暴露区域解封。路易斯酸低聚物和解封的路易斯碱基链在暴露的区域延伸。膜的开发除去未聚合的反应物。任选地，当辐射交联时，路易斯酸低聚物在将路易斯碱解封以形成负性抗蚀剂之前彼此交联。交联的低聚物与随后的解封底物聚合以提供高分子量聚合物膜。在替代实施方案中，通过使用选择性曝光光刻技术降解和除去光敏路易斯酸低聚物，并且随后使路易斯碱和链在未曝光区域上与解封的路易斯碱扩展剩余的低聚物，使用正性抗蚀剂。

5. 发明授权

US06383415B1 Methods of fabrication of cross-linked electrically conductive polymers and precursors thereof 有权
标题翻译：交联导电聚合物及其前体的制备方法
公开(公告)号：US06383415B1
公开(公告)日：2002-05-07
申请号：US09444985
申请日：1999-11-22
申请人： Marie Angelopoulos , Jeffrey D. Gelorme , Yun Hsin Liao , Jane M. Shaw
发明人： Marie Angelopoulos , Jeffrey D. Gelorme , Yun Hsin Liao , Jane M. Shaw
IPC分类号： H01B112
CPC分类号： H01B1/128 , H01B1/125 , H01B1/127
摘要： Cross-linked electrically conductive polymers, in particular electrically conductive, polyaniline are described. Dopants and substituents having pendant cross-linkable functionality are used which form a cross-linked conducting polymer network. The cross-linking functionality can be hydrogen-bonding as well as chemically polymerizable or cross-linkable. A conjugated path between chains can also be incorporated. The resulting cross-linked conducting polymers have enhanced thermal and environmental stability. The dopant cannot readily be washed out with solvents or diffuse out upon exposure to heat. In addition, the cross-linked polymers have enhanced electrical conductivity.
摘要翻译：描述了交联的导电聚合物，特别是导电的聚苯胺。使用具有侧链可交联官能团的掺杂剂和取代基，其形成交联的导电聚合物网络。交联官能团可以是氢键合以及化学上可聚合的或可交联的。还可以并入链之间的共轭路径。所得的交联导电聚合物具有增强的热和环境稳定性。掺杂剂不容易用溶剂洗涤或在暴露于热量时扩散出来。此外，交联聚合物具有增强的导电性。

6. 发明授权

US06746770B1 Electrically conductive and abrasion/scratch resistant polymeric materials, method of fabrication thereof and uses thereof 失效
标题翻译：导电和耐磨损/耐刮擦的聚合材料，其制造方法及其用途
公开(公告)号：US06746770B1
公开(公告)日：2004-06-08
申请号：US08476141
申请日：1995-06-07
申请人： Ali Afzali-Ardakani , Marie Angelopoulos , Jack Alvin Dickerson , Thomas Baird Pillsbury , Karl Joseph Puttlitz , Jane Margaret Shaw , Jeffrey Donald Gelorme
发明人： Ali Afzali-Ardakani , Marie Angelopoulos , Jack Alvin Dickerson , Thomas Baird Pillsbury , Karl Joseph Puttlitz , Jane Margaret Shaw , Jeffrey Donald Gelorme
IPC分类号： B32B904
CPC分类号： H05K9/0096 , C08G61/12 , H01B1/125 , H01J29/868 , H01L23/49894 , H01L23/60 , H01L33/42 , H01L2924/0002 , H01L2924/12044 , Y10T428/31504 , Y10T428/31511 , Y10T428/31663 , Y10T428/31667 , Y10T428/31797 , Y10T428/31855 , Y10T428/31909 , Y10T428/31924 , Y10T428/31931 , H01L2924/00
摘要： Electrically conductive and abrasion resistant polymeric compositions, methods of fabrication thereof and uses thereof are described. Admixtures of abrasion resistant materials and electrically conductive polymeric materials are formed. Many of these admixtures arc light transmitting and can be used as an abrasion resistant light transmitting electrostatic discharge layers. The light transmitting discharge layer is useful as a surface coating for visual displays such as CRT screens to avoid electrostatic accumulation of dust and scratching. The compositions can be admixtures of abrasion resistant silicones, polysiloxanes, acrylates, epoxies, methacrylates, epoxyacrylates, epoxymethacrylates, styrenes and electrically conductive polymers selected from the group of substituted and unsubstituted polyanilines, polyparaphenylenevinyles, substituted and unsubstituted polythiophenes substituted and unsubstituted poly-p-phenylene sulfides, substituted and unsubstituted polyfuranes, substituted and unsubstituted polypyrroles, substituted and unsubstituted polyselenophenes, polyacetylines formed from soluble precursors, combinations thereof and blends thereof with other polymers. The compositions can be a layer or an electrically conductive polymer with an abrasion resistant layer thereover.
摘要翻译：描述了导电和耐磨聚合物组合物，其制造方法及其用途。形成耐磨材料和导电聚合材料的外加剂。这些混合物中的许多都是透光的，可以用作耐磨光透射静电放电层。透光放电层可用作诸如CRT屏幕的视觉显示器的表面涂层，以避免灰尘和划痕的静电积累。组合物可以是耐磨硅氧烷，聚硅氧烷，丙烯酸酯，环氧树脂，甲基丙烯酸酯，环氧丙烯酸酯，环氧甲基丙烯酸酯，苯乙烯和选自取代和未取代的聚苯胺的聚合物，聚对亚苯基乙烯基，取代和未取代的聚噻吩的取代和未取代的聚对 - 取代和未取代的聚吡咯，取代和未取代的聚硒吩，可溶性前体形成的聚乙酰胺，其组合以及与其它聚合物的共混物。组合物可以是其上具有耐磨层的层或导电聚合物。

7. 发明授权

US5619357A Flat panel display containing black matrix polymer 失效
标题翻译：含黑色矩阵聚合物的平板显示器
公开(公告)号：US5619357A
公开(公告)日：1997-04-08
申请号：US466317
申请日：1995-06-06
申请人： Marie Angelopoulos , Ali Afzali-Ardakani , Claudius Feger , Chandrasekhar Narayan
发明人： Marie Angelopoulos , Ali Afzali-Ardakani , Claudius Feger , Chandrasekhar Narayan
IPC分类号： G02F1/1335
CPC分类号： G02F1/133512
摘要： A thin film transistor display that comprises a black matrix polymer layer, comprising a polymer having an optical density of at least about 0.8 per .mu.m and being self-absorbent of visible light and being selected from the group consisting of substituted and unsubstituted polyanilines, substituted and unsubstituted polyparaphenylenevinylenes, substituted and unsubstituted polythiophenes, substituted and unsubstituted polyazines, substituted and unsubstituted polyparaphenylenes, substituted and unsubstituted polyfuranes, substituted and unsubstituted polypyrroles, substituted and unsubstituted polyselenophene, substituted and unsubstituted poly-p-phenylene sulfides and substituted and unsubstituted polyacetylenes, and mixtures thereof, and copolymers thereof. The layer also comprises one or more pigments. The resistivity of the black matrix composite is 10E12 to 10E14 ohm cm.
摘要翻译：一种薄膜晶体管显示器，其包括黑矩阵聚合物层，其包含光密度为至少约0.8每μm的聚合物，并且是可吸收的可见光，并且选自取代和未取代的聚苯胺，取代的取代和未取代的聚噻吩，取代和未取代的聚噻吩，取代和未取代的聚嗪，取代和未取代的聚对苯二烯，取代和未取代的聚呋喃，取代和未取代的聚吡咯，取代和未取代的聚硒吩，取代和未取代的聚对苯硫醚和取代和未取代的聚乙炔，其混合物，及其共聚物。该层还包含一种或多种颜料。黑色矩阵复合材料的电阻率为10E12至10E14欧姆厘米。

8. 发明授权

US6149840A Electrically conductive polymeric materials and use thereof 失效
标题翻译：导电聚合材料及其用途
公开(公告)号：US6149840A
公开(公告)日：2000-11-21
申请号：US838296
申请日：1997-09-29
申请人： Ali Afzali Ardakani , Marie Angelopoulos , Vincent Albert Bourgault , Liam David Comerford , Michael Wayne Mirre , Steven Earle Molis , Ravi Saraf , Jane Margaret Shaw , Peter Joseph Spellane , Niranjan Mohanlal Patel
发明人： Ali Afzali Ardakani , Marie Angelopoulos , Vincent Albert Bourgault , Liam David Comerford , Michael Wayne Mirre , Steven Earle Molis , Ravi Saraf , Jane Margaret Shaw , Peter Joseph Spellane , Niranjan Mohanlal Patel
IPC分类号： C08L33/00 , C08G61/02 , C08G61/12 , C08G75/02 , C08L33/04 , C08L53/02 , C08L65/00 , C08L69/00 , C08L79/00 , C08L79/02 , C08L79/04 , C08L81/02 , C08L81/04 , C08L101/00 , C08L101/12 , H01B1/00 , H01B1/12 , C08G73/06
CPC分类号： H01B1/128 , C08G61/02 , C08G61/123 , C08G75/0209 , C08G75/0295 , C08L101/12 , C08L65/00 , C08L69/00 , C08L79/02 , C08L79/04 , C08L81/02 , H01B1/00 , H01B1/124 , C08L53/02 , C08L81/04
摘要： A polymer blend composition, capable of being made electrically conductive by application of heat having an electrically conductive upon doping polymer in undoped form; the undoped polymer is selected from the group consisting of substituted and unsubstituted polyparaphenylenevinylenes, polyanilines, polyazines, polythiophenes, poly-p-phenylene sulfides, polyfuranes, polyselenophenes, polyacetylenes filtered from soluble precursors and combinations and blends thereof, compounded and blended at a molecular scale with a dielectric polymer; wherein the dielectric polymer is selected from the group consisting of interpolymers of acrylonitrile-butadiene-styrene, acetal acrylic liquid crystal polymers, polybutylene terephthalate, polycarbonate, polyester, polyetherimide, polyethersulfone, polyethylene, polyethylene terephthalate, polyphenylene oxide, polyphenylene sulfide, polypropylene, polystyrene, polyurethane, polyvinychloride, styrene-acrylonitrile copolymer, fluoropolymers, nylon polyesters, and thermoplastic elastomers, and a thermally deblockable dopant selected from the group consisting of triflates, tosylates and borates, the electrically conductive upon doping polymer having enhanced solubility in undoped form with said dielectric polymer to form a compatible molecularly mixed blend in solution; doping of the polymer occurs only after exposure to heat.
摘要翻译：一种聚合物共混组合物，其能够通过施加具有未掺杂形式的具有导电性的掺杂聚合物的热而导电; 未掺杂的聚合物选自取代和未取代的聚对亚苯基亚乙烯基，聚苯胺，聚嗪，聚噻吩，聚对苯硫醚，聚呋喃，聚硒吩，可溶性前体过滤的聚乙炔及其组合和共混物，以分子量配混和共混与介电聚合物; 所述介电聚合物选自丙烯腈 - 丁二烯 - 苯乙烯，缩醛丙烯酸类液晶聚合物，聚对苯二甲酸丁二醇酯，聚碳酸酯，聚酯，聚醚酰亚胺，聚醚砜，聚乙烯，聚对苯二甲酸乙二醇酯，聚苯醚，聚苯硫醚，聚丙烯，聚苯乙烯聚氨酯，聚氯乙烯，苯乙烯 - 丙烯腈共聚物，含氟聚合物，尼龙聚酯和热塑性弹性体，以及选自三氟甲磺酸酯，甲苯磺酸酯和硼酸酯的热可去结合的掺杂剂，所述导电的一次性掺杂聚合物具有增强的未掺杂形式的溶解度，电介质聚合物在溶液中形成相容的分子混合共混物; 聚合物的掺杂仅在暴露于热之后才发生。

9. 发明授权

US06168732A Electrically conductive polymeric materials and use thereof 失效
标题翻译：导电聚合材料及其用途
公开(公告)号：US06168732A
公开(公告)日：2001-01-02
申请号：US09118619
申请日：1998-07-17
申请人： Ali Afzali Ardakani , Marie Angelopoulos , Vincent Albert Bourgault , Liam David Comerford , Michael Wayne Mirre , Steven Earle Molis , Ravi Saraf , Jane Margaret Shaw , Peter Joseph Spellane , Niranjan Mohanlal Patel
发明人： Ali Afzali Ardakani , Marie Angelopoulos , Vincent Albert Bourgault , Liam David Comerford , Michael Wayne Mirre , Steven Earle Molis , Ravi Saraf , Jane Margaret Shaw , Peter Joseph Spellane , Niranjan Mohanlal Patel
IPC分类号： H01B112
CPC分类号： H01B1/128 , C08G61/02 , C08G61/123 , C08G75/0209 , C08G75/0295 , C08L53/02 , C08L65/00 , C08L69/00 , C08L79/02 , C08L79/04 , C08L81/02 , C08L81/04 , C08L101/12 , H01B1/00 , H01B1/124 , C08L2666/04 , C08L2666/02 , C08L2666/14
摘要： The present invention relates to electrically conductive polymer blend compositions comprising a non-conducting polymeric component and an electrically conducting polymeric component and specific applications to which the blend compositions can be put.
摘要翻译：本发明涉及包含非导电聚合物组分和导电聚合物组分的导电聚合物共混物组合物以及掺合组合物可以放置的特定应用。

10. 发明授权

US07585431B1 Electrically conductive polymeric materials and use thereof 失效
标题翻译：导电聚合材料及其用途
公开(公告)号：US07585431B1
公开(公告)日：2009-09-08
申请号：US08118475
申请日：1993-09-07
申请人： Ali Afzali-Ardakani , Marie Angelopoulos , Vincent Albert Bourgault , Liam David Comerford , Michael Wayne Mirre , Steven Earle Molis , Ravi Saraf , Jane Margaret Shaw , Peter Joseph Spellane , Niranjan Mohanlal Patel
发明人： Ali Afzali-Ardakani , Marie Angelopoulos , Vincent Albert Bourgault , Liam David Comerford , Michael Wayne Mirre , Steven Earle Molis , Ravi Saraf , Jane Margaret Shaw , Peter Joseph Spellane , Niranjan Mohanlal Patel
IPC分类号： H01B1/24
CPC分类号： H01B1/128 , C08G61/02 , C08G61/123 , C08G75/0209 , C08G75/0295 , C08L53/02 , C08L65/00 , C08L69/00 , C08L79/02 , C08L79/04 , C08L81/02 , C08L81/04 , C08L101/12 , H01B1/00 , H01B1/124 , C08L2666/04 , C08L2666/02 , C08L2666/14
摘要： This invention is concerned with an electrically conductive polymer blend composition which is a liquid compatible blend, comprising a doped product formed form blending a first solution comprising a Lewis base electrically conductive polymer in undoped form in a first organic solvent with a second solution comprising a Lewis acid polymer dopant in a second organic solvent, wherein said Lewis acid polymer dopant dopes said Lewis base electrically conductive polymer in undoped form to obtain said electrically conductive polymer blend, the resulting doped conductive product being soluble in the combination of said first and said second organic solvents and mixable at the molecular level.
摘要翻译：本发明涉及一种导电聚合物共混组合物，其是液体相容的共混物，其包含形成的掺杂产物，其形成为在第一有机溶剂中将包含未掺杂形式的路易斯碱导电聚合物的第一溶液与包含路易斯酸性聚合物掺杂剂，其中所述路易斯酸聚合物掺杂剂以未掺杂形式掺杂所述路易斯碱导电聚合物以获得所述导电聚合物共混物，所得掺杂导电产物可溶于所述第一和所述第二有机溶剂的组合溶剂和分子水平混合。

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