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1. 发明授权

US5804045A Cathode for reduction of carbon dioxide and method for manufacturing such a cathode 失效
标题翻译：用于还原二氧化碳的阴极及其制造方法
公开(公告)号：US5804045A
公开(公告)日：1998-09-08
申请号：US839311
申请日：1997-04-18
申请人： Marc Orillon , Sylvie Chardon-Noblat , Marie Noelle Colomb-Dunand Sauthier , Alain Deronzier , Raymond Ziessel , Daniela Zsoldos
发明人： Marc Orillon , Sylvie Chardon-Noblat , Marie Noelle Colomb-Dunand Sauthier , Alain Deronzier , Raymond Ziessel , Daniela Zsoldos
IPC分类号： C08G61/00 , C08G79/00 , C25B11/06 , C25B11/00
CPC分类号： C08G61/00 , C08G79/00 , C25B11/04 , C25B3/04
摘要： The invention relates to a cathode based on a transition metal (M) for reduction of carbon dioxide into formate in a hydro-organic or purely aqueous medium, particularly for air decarbonation applications for industry and in general for atmospheric pollution control and regeneration of breathable air in a confined or unconfined environment, characterized by including a transition metal molecular complex formed of: a bidentate ligand functional by identical or different electroattractive groups A and A', the ligand comprising a basic molecular group allowing the reduction redox potential of the complex to be reduced in a range of -1.40 to +0.80 V relative to an Ag/Ag.sup.+ reference electrode, at least one of the groups A or A' being electropolymerizable; two identical or different labile groups Y and Y' with trans stereochemistry taken from the following series: halide anion (Cl.sup.-, Br.sup.-, I.sup.-), acetate anion (CH.sub.3 COO.sup.-), neutral acetonitrile or dimethylformamide or dimethylsulfoxide molecule; two identical or different stabilizing ligands Z and Z' with cis stereochemistry, representing a donor and attractor group of the carbonyl (--CO) or phosphine type (PR.sub.3 with R=alkyl, aryl, pyridine); the complex having the structure of Formula (I). ##STR1##
摘要翻译：本发明涉及一种用于在水力有机或纯水介质中将二氧化碳还原成甲酸盐的过渡金属（M）的阴极，特别是用于工业的空气脱碳应用，并且一般用于大气污染控制和透气空气再生在有限的或无约束的环境中，其特征在于包括由以下物质形成的过渡金属分子复合物：由相同或不同的电吸引基团A和A'起作用的双齿配体，所述配体包含允许络合物的还原氧化还原电位为相对于Ag / Ag +参比电极在-1.40至+0.80V的范围内降低，A或A'组中的至少一个可电聚合; 两个相同或不同的不稳定基团Y和Y'具有以下系列的反式立体化学：卤素阴离子（Cl-，Br-，I-），乙酸根阴离子（CH 3 COO-），中性乙腈或二甲基甲酰胺或二甲基亚砜分子; 两个相同或不同的稳定配体Z和Z'具有顺式立体化学，代表羰基（-CO）或膦类型（PR = R 3 =烷基，芳基，吡啶）的供体和吸引子基团。该络合物具有式（I）的结构。

2. 发明授权

US07799726B2 Composites based on carbon nanotubes or nanofibers deposited on an activated support for use in catalysis 失效
标题翻译：基于碳纳米管或沉积在活化载体上用于催化的纳米纤维的复合材料
公开(公告)号：US07799726B2
公开(公告)日：2010-09-21
申请号：US10496495
申请日：2002-11-20
申请人： Cuong Pham-Huu , Ricardo Vieira , Marc J. Ledoux , Loïc Charbonniere , Raymond Ziessel
发明人： Cuong Pham-Huu , Ricardo Vieira , Marc J. Ledoux , Loïc Charbonniere , Raymond Ziessel
IPC分类号： B01J21/18 , D01C5/00 , D01F9/12
CPC分类号： B82Y30/00 , B01D53/885 , B01D53/94 , B01J21/18 , B01J21/185 , B01J23/468 , B01J23/74 , B01J23/745 , B01J23/755 , B01J35/002 , B01J35/0026 , B01J35/06 , B01J35/1014 , B01J35/1038 , B01J37/0201 , B01J37/084 , B64G1/401 , B82Y40/00 , C01B32/162 , C01B32/50 , C06D5/04 , H01M4/8605 , H01M4/90 , H01M4/96 , Y10S977/742 , Y10S977/744 , Y10S977/748
摘要： A composite comprising a support activated by impregnation and carbon nanotubes or nanofibers formed by vapor deposition, wherein the weight of said carbon nanotubes or nanofibers formed on the said support is at least equal to 10.
摘要翻译：包含通过浸渍活化的载体和通过气相沉积形成的碳纳米管或纳米纤维的复合物，其中形成在所述载体上的所述碳纳米管或纳米纤维的重量至少等于10。

3. 发明申请

US20080044923A1 Lanthanide Complexes Preparation and Uses Thereof 有权
标题翻译：镧系配合物的制备及其用途
公开(公告)号：US20080044923A1
公开(公告)日：2008-02-21
申请号：US10565804
申请日：2005-07-20
申请人： Loic Charbonniere , Raymond Ziessel , Nicolas Weibel , Aldo Roda , Massimo Guardigli
发明人： Loic Charbonniere , Raymond Ziessel , Nicolas Weibel , Aldo Roda , Massimo Guardigli
IPC分类号： G01N21/76 , C07D401/14 , C07F5/00
CPC分类号： C09K11/06 , C07D213/79 , C07D401/14 , C09K2211/182 , G01N33/582
摘要： The invention relates to compounds, to the complexes they form with a lanthanide, and to the use of the complexes for fluorescence marking or NMR imaging.The complex consists of an Ln ion and a ligand R2-C(X-R1)(R3)-NR4R5. R1 is a functional group, X is a single bond or a hydrocarbon-based chain consisting of at least one alkylene or alkenylene group optionally comprising at least one hetero atom or an arylene. R2 is an anionic group A2 or a C1-C4 alkylene or alkenylene group bearing at least one such group A2 and optionally comprising at least one hetero atom. R3 is H or a C1-C5 alkylene or alkenylene group optionally containing at least one hetero atom, and optionally bearing at least one anionic group A3. R4 is a substituent with light-absorbing properties that forms chelate rings with Ln. R5 is a substituent that forms chelate rings with Ln.
摘要翻译：本发明涉及化合物，其与镧系元素形成的络合物，以及复合物用于荧光标记或NMR成像的用途。络合物由Ln离子和配体R 2 -C（XR 1）（R 3） - NR 4， / SUP> R＆lt; 5＆gt;。 R 1是官能团，X是单键或由至少一个亚烷基或亚烯基组成的烃基链，任选地包含至少一个杂原子或亚芳基。 R 2是至少带有阴离子基团A 2或C 1 -C 4 -C 4亚烷基或亚烯基一个这样的基团A 2，并且任选地包含至少一个杂原子。 R 3是H或C 1 -C 5亚烷基或亚烯基，任选地含有至少一个杂原子，并且任选地带有至少一个阴离子基团A 3。 R 4是具有与Ln形成螯合环的光吸收性质的取代基。 R 5是与Ln形成螯合环的取代基。

4. 发明授权

US08497501B2 Organic electroluminescence generating devices 有权
公开(公告)号：US08497501B2
公开(公告)日：2013-07-30
申请号：US13541653
申请日：2012-07-03
申请人： Michele Muccini , Paul Heremans , Johan Lieven Hendrik Reynaert , Raymond Ziessel , Aline Hepp , Roland Schmechel , Heinz Von Seggern , Holger Heil
发明人： Michele Muccini , Paul Heremans , Johan Lieven Hendrik Reynaert , Raymond Ziessel , Aline Hepp , Roland Schmechel , Heinz Von Seggern , Holger Heil
IPC分类号： H01L29/08
CPC分类号： H01L51/5092 , H01L51/5088 , H01L51/5203 , H01L51/5265 , H01L51/5275 , H01L51/5296
摘要： An electroluminescence generating device comprising a channel of organic semiconductor material, said channel being able to carry both types of charge carriers, said charge carriers being electrons and holes; an electron electrode, said electron electrode being in contact with said channel and positioned on top of a first side of said channel layer or within said channel layer, said electron electrode being able to inject electrons in said channel layer; a hole electrode, said hole electrode being spaced apart from said electron electrode, said hole channel and positioned on top of within said channel layer, said hole electrode being able to inject holes into said channel; a control electrode positioned on said first side or on a second side of said channel; whereby light emission of said electroluminescence generating device can be acquired by applying an electrical potential difference between said electron electrode and said hole electrode.

5. 发明授权

US08476461B2 Dipyrromethene-boron hydrophilic fluorescent compounds 有权
标题翻译：二吡咯亚甲基 - 硼亲水性荧光化合物
公开(公告)号：US08476461B2
公开(公告)日：2013-07-02
申请号：US13142845
申请日：2009-12-18
申请人： Gilles Ulrich , Raymond Ziessel , Song-Lin Niu , Alexandre Haefele , Thomas Bura
发明人： Gilles Ulrich , Raymond Ziessel , Song-Lin Niu , Alexandre Haefele , Thomas Bura
IPC分类号： C07D209/56 , C07F5/02 , G01N21/76
CPC分类号： C07F5/02
摘要： Dipyrromethene-boron hydrophilic fluorescent compoundsThe invention concerns fluorescent and hydrophilic compounds meeting following formula (I): wherein: S1 is a group of formula —C≡C-L′-A where L′ is a linkage group and A is a polar functional group; S2 is a —C≡C-L′-A group the same or different from S1; —F; —H; or a hydrocarbon chain optionally interrupted by one or more oxygen atoms, and use thereof, in particular in aqueous or hydrophilic media.
摘要翻译：二吡咯亚甲基 - 硼亲水性荧光化合物本发明涉及符合下列通式（I）的荧光和亲水性化合物：其中：S1为式-C = C-L'-A的基团，其中L'为连接基团，A为极性官能团组; S2是与S1相同或不同的-C = C-L-A基团; -F; -H; 或任选被一个或多个氧原子中断的烃链，及其用途，特别是在水性或亲水介质中。

6. 发明申请

US20100216252A1 Lanthanide Complexes, Preparation and Uses Thereof 有权
标题翻译：镧系配合物，其制备和用途
公开(公告)号：US20100216252A1
公开(公告)日：2010-08-26
申请号：US12714357
申请日：2010-02-26
申请人： Loïc Charbonniere , Raymond Ziessel , Nicolas Weibel , Aldo Roda , Massimo Guardigli
发明人： Loïc Charbonniere , Raymond Ziessel , Nicolas Weibel , Aldo Roda , Massimo Guardigli
IPC分类号： G01N21/76 , C07F5/00
CPC分类号： C09K11/06 , C07D213/79 , C07D401/14 , C09K2211/182 , G01N33/582
摘要： The invention relates to compounds, to the complexes they form with a lanthanide, and to the use of the complexes for fluorescence marking or NMR imaging.The complex consists of an Ln ion and a ligand R2—C(X—R1)(R3)—NR4R5. R1 is a functional group, X is a single bond or a hydrocarbon-based chain consisting of at least one alkylene or alkenylene group optionally comprising at least one hetero atom or an arylene. R2 is an anionic group A2 or a C1-C4 alkylene or alkenylene group bearing at least one such group A2 and optionally comprising at least one hetero atom. R3 is H or a C1-C5 alkylene or alkenylene group optionally containing at least one hetero atom, and optionally bearing at least one anionic group A3. R4 is a substituent with light-absorbing properties that forms chelate rings with Ln. R5 is a substituent that forms chelate rings with Ln.
摘要翻译：本发明涉及化合物，其与镧系元素形成的络合物，以及复合物用于荧光标记或NMR成像的用途。络合物由Ln离子和配体R2-C（X-R1）（R3）-NR4R5组成。 R1是官能团，X是单键或由至少一个亚烷基或亚烯基组成的烃基链，任选地包含至少一个杂原子或亚芳基。 R2是具有至少一个这样的基团A2和任选地包含至少一个杂原子的阴离子基团A2或C1-C4亚烷基或亚烯基。 R3是H或任选地含有至少一个杂原子的C1-C5亚烷基或亚烯基，并且任选地带有至少一个阴离子基团A3。 R4是与Ln形成螯合环的具有光吸收性质的取代基。 R5是与Ln形成螯合环的取代基。

7. 发明申请

US20080102534A1 Unsaturated Dipyrromethene-Boron Borocarbons 有权
标题翻译：不饱和二吡咯亚甲基硼硼烷
公开(公告)号：US20080102534A1
公开(公告)日：2008-05-01
申请号：US11884360
申请日：2006-02-14
申请人： Gilles Ulrich , Raymond Ziessel , Christine Goze
发明人： Gilles Ulrich , Raymond Ziessel , Christine Goze
IPC分类号： G01N21/76 , C07F5/02
CPC分类号： C07F5/02
摘要： The invention relates to unsaturated dipyrromethene-boron borocarbons of formula (I) and the use thereof for fluorescence or electroluminescent analysis. The fluorescent properties are provided by the central ring of six atoms comprising the —N—B—N— sequence, R1 to R7 permitting the modification of the compound properties (fluorescence emission wavelength, quantitative fluorescent yield), at least one of the substituents S1 and S2 has a chromophore end group which permits an excitation of the molecule at wavelengths close to those of the substituent chromophore. A preferably selected from the chromophore substituents with a wavelength close to the ultraviolet which significantly increases the Stokes displacement.
摘要翻译：本发明涉及式（I）的不饱和二吡咯甲硼 - 硼硼烷及其用于荧光或电致发光分析的用途。荧光性质由包含-NBN-序列，R 1至R 7的六个原子的中心环提供，允许修饰化合物性质（荧光发射波长，定量荧光产率），至少一个取代基S 1和S 2 2具有发色团端基，其允许在接近于取代基的波长处的分子的激发发色团优选选自具有接近紫外线的波长的发色团取代基，其显着增加斯托克斯位移。

8. 发明申请

US20050103990A1 Composites based on carbon nanotubes or nanofibers deposited on an activated support for use in catalysis 失效
标题翻译：基于碳纳米管或纳米纤维的复合材料沉积在活化载体上用于催化
公开(公告)号：US20050103990A1
公开(公告)日：2005-05-19
申请号：US10496495
申请日：2002-11-20
申请人： Cuong Pham-Huu , Ricardo Vieira , Marc Ledoux , Loic Charbonniere , Raymond Ziessel
发明人： Cuong Pham-Huu , Ricardo Vieira , Marc Ledoux , Loic Charbonniere , Raymond Ziessel
IPC分类号： B01D53/88 , B01D53/94 , B01J21/18 , B01J23/46 , B01J23/74 , B01J23/745 , B01J23/755 , B01J35/06 , B01J35/10 , B01J37/02 , B01J37/025 , B01J37/08 , B64G1/40 , C01B31/02 , C01B31/20 , C06D5/04 , H01M4/86 , H01M4/90 , H01M4/96 , H01J49/00
CPC分类号： B82Y30/00 , B01D53/885 , B01D53/94 , B01J21/18 , B01J21/185 , B01J23/468 , B01J23/74 , B01J23/745 , B01J23/755 , B01J35/002 , B01J35/0026 , B01J35/06 , B01J35/1014 , B01J35/1038 , B01J37/0201 , B01J37/084 , B64G1/401 , B82Y40/00 , C01B32/162 , C01B32/50 , C06D5/04 , H01M4/8605 , H01M4/90 , H01M4/96 , Y10S977/742 , Y10S977/744 , Y10S977/748
摘要： A composite comprising a support activated by impregnation and carbon nanotubes or nanofibers formed by vapor deposition, wherein the weight of said carbon nanotubes or nanofibers formed on the said support is at least equal to 10.
摘要翻译：包含通过浸渍活化的载体和通过气相沉积形成的碳纳米管或纳米纤维的复合物，其中形成在所述载体上的所述碳纳米管或纳米纤维的重量至少等于10。

9. 发明授权

US08993781B2 Fluorescent boron-substituted dipyrromethenes and use thereof for diagnosis 有权
标题翻译：荧光硼取代二吡咯并芘及其用于诊断
公开(公告)号：US08993781B2
公开(公告)日：2015-03-31
申请号：US13141850
申请日：2009-12-28
申请人： Jean De Barry , Corinne Liegeois , Alexandre Haefele , Thomas Bura , Gilles Ulrich , Raymond Ziessel
发明人： Jean De Barry , Corinne Liegeois , Alexandre Haefele , Thomas Bura , Gilles Ulrich , Raymond Ziessel
IPC分类号： C07D209/56 , C07F5/02
CPC分类号： C07F5/02 , C07D209/56
摘要： The invention relates to novel fluorescent compounds derived from non-fluorinated dipyrromethene-boron, to a method for preparing same and to the use thereof for the fluorescent marking of biological molecules. The invention also relates to biological molecules marked with said fluorescent compounds, and to the use thereof in detection methods such as medical diagnosis methods. More particularly, the detection methods of the invention are particularly useful for diagnosing neurodegenerative diseases such as Alzheimer's disease.
摘要翻译：本发明涉及衍生自非氟化二吡咯亚甲基 - 硼的新型荧光化合物，其制备方法及其用于生物分子荧光标记的用途。本发明还涉及标记有所述荧光化合物的生物分子，以及其在诸如医学诊断方法的检测方法中的用途。更具体地，本发明的检测方法对于诊断神经变性疾病如阿尔茨海默病特别有用。

10. 发明申请

US20110287473A1 Novel Fluorescent Boron-Substituted Dipyrromethenes and Use Thereof for Diagnosis 有权
标题翻译：新型荧光硼取代Dipyrromethenes及其用途诊断
公开(公告)号：US20110287473A1
公开(公告)日：2011-11-24
申请号：US13141850
申请日：2009-12-28
申请人： Jean De Barry , Corinne Liegeois , Alexandre Haefele , Thomas Bura , Gilles Ulrich , Raymond Ziessel
发明人： Jean De Barry , Corinne Liegeois , Alexandre Haefele , Thomas Bura , Gilles Ulrich , Raymond Ziessel
IPC分类号： C12Q1/02 , C07H19/04 , C07K14/435 , G01N21/64 , C07F5/02
CPC分类号： C07F5/02 , C07D209/56
摘要： The invention relates to novel fluorescent compounds derived from non-fluorinated dipyrromethene-boron, to a method for preparing same and to the use thereof for the fluorescent marking of biological molecules. The invention also relates to biological molecules marked with said fluorescent compounds, and to the use thereof in detection methods such as medical diagnosis methods. More particularly, the detection methods of the invention are particularly useful for diagnosing neurodegenerative diseases such as Alzheimer's disease.
摘要翻译：本发明涉及衍生自非氟化二吡咯亚甲基 - 硼的新型荧光化合物，其制备方法及其用于生物分子荧光标记的用途。本发明还涉及标记有所述荧光化合物的生物分子，以及其在诸如医学诊断方法的检测方法中的用途。更具体地，本发明的检测方法对于诊断神经变性疾病如阿尔茨海默病特别有用。

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