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1. 发明授权

US5804045A Cathode for reduction of carbon dioxide and method for manufacturing such a cathode 失效
标题翻译：用于还原二氧化碳的阴极及其制造方法
公开(公告)号：US5804045A
公开(公告)日：1998-09-08
申请号：US839311
申请日：1997-04-18
申请人： Marc Orillon , Sylvie Chardon-Noblat , Marie Noelle Colomb-Dunand Sauthier , Alain Deronzier , Raymond Ziessel , Daniela Zsoldos
发明人： Marc Orillon , Sylvie Chardon-Noblat , Marie Noelle Colomb-Dunand Sauthier , Alain Deronzier , Raymond Ziessel , Daniela Zsoldos
IPC分类号： C08G61/00 , C08G79/00 , C25B11/06 , C25B11/00
CPC分类号： C08G61/00 , C08G79/00 , C25B11/04 , C25B3/04
摘要： The invention relates to a cathode based on a transition metal (M) for reduction of carbon dioxide into formate in a hydro-organic or purely aqueous medium, particularly for air decarbonation applications for industry and in general for atmospheric pollution control and regeneration of breathable air in a confined or unconfined environment, characterized by including a transition metal molecular complex formed of: a bidentate ligand functional by identical or different electroattractive groups A and A', the ligand comprising a basic molecular group allowing the reduction redox potential of the complex to be reduced in a range of -1.40 to +0.80 V relative to an Ag/Ag.sup.+ reference electrode, at least one of the groups A or A' being electropolymerizable; two identical or different labile groups Y and Y' with trans stereochemistry taken from the following series: halide anion (Cl.sup.-, Br.sup.-, I.sup.-), acetate anion (CH.sub.3 COO.sup.-), neutral acetonitrile or dimethylformamide or dimethylsulfoxide molecule; two identical or different stabilizing ligands Z and Z' with cis stereochemistry, representing a donor and attractor group of the carbonyl (--CO) or phosphine type (PR.sub.3 with R=alkyl, aryl, pyridine); the complex having the structure of Formula (I). ##STR1##
摘要翻译：本发明涉及一种用于在水力有机或纯水介质中将二氧化碳还原成甲酸盐的过渡金属（M）的阴极，特别是用于工业的空气脱碳应用，并且一般用于大气污染控制和透气空气再生在有限的或无约束的环境中，其特征在于包括由以下物质形成的过渡金属分子复合物：由相同或不同的电吸引基团A和A'起作用的双齿配体，所述配体包含允许络合物的还原氧化还原电位为相对于Ag / Ag +参比电极在-1.40至+0.80V的范围内降低，A或A'组中的至少一个可电聚合; 两个相同或不同的不稳定基团Y和Y'具有以下系列的反式立体化学：卤素阴离子（Cl-，Br-，I-），乙酸根阴离子（CH 3 COO-），中性乙腈或二甲基甲酰胺或二甲基亚砜分子; 两个相同或不同的稳定配体Z和Z'具有顺式立体化学，代表羰基（-CO）或膦类型（PR = R 3 =烷基，芳基，吡啶）的供体和吸引子基团。该络合物具有式（I）的结构。

2. 发明授权

US07446186B2 Pyrroles substituted by oligonucleotides 失效
标题翻译：由寡核苷酸取代的吡咯
公开(公告)号：US07446186B2
公开(公告)日：2008-11-04
申请号：US10536317
申请日：2003-12-16
申请人： Bernard Mandrand , Daniela Zsoldos , Alain Laurent , Carole Chaix , Nicolas Spinelli
发明人： Bernard Mandrand , Daniela Zsoldos , Alain Laurent , Carole Chaix , Nicolas Spinelli
IPC分类号： C07H21/00 , C12Q1/68
CPC分类号： C07H21/00 , Y02P20/55
摘要： The invention relates to novel pyrrole derivatives of the formula (I) which make it possible to immobilize and address oligonucleotides by electropolymerization. Said invention also relates to thus produced electroactive polymers and to methods for using them for detecting, identifying and dosing analytes in a sample. (I) wherein R1 is one type of oligonucleotide, Y is S or O, X is a spacer arm selected from —(CH2)—O—, —(CH2) P O—[(CH2)2—O]q—, —(CH2)r; —CO—NR′—(CH2)r—O—, —CH2r—NCH3—(CH2)r—O—, —CH2)rCO—NR′—[CH2)2—O]s—, —(CH2)rNCH3[(CH2)2—O] S —, R′ is H or CH3, n is an integer number ranging from 1 to 5, p is an integer number ranging from 1 to 2, q is an integer number ranging from 1 to 4, r is an integer number ranging from 1 to 3, r′ is an integer number ranging from 1 to 3, s is an integer number ranging from 1 to 3, n, p, q, r, r′ and s are identical or different, a pyrrole cycle is substituted in a position 2, 3, 4 or 5.
摘要翻译：本发明涉及式（I）的新型吡咯衍生物，其可以通过电聚合固定和解决寡核苷酸。所述发明还涉及如此制备的电活性聚合物以及使用它们用于检测，鉴定和给药样品中分析物的方法。（I）其中R 1是一种类型的寡核苷酸，Y是S或O，X是选自以下的间隔臂 - （CH 2）2 - ， - （ CH 2 O - [（CH 2）2 -O] q - ， - （CH 2）n - -CO-NR' - （CH 2）2 -O - ， - CH 2 R n -NCH 3 - （CH 2）n -O - ， - CH 2）n CO-NR' - [CH 2 - 2 - > - - - - - - - - - - - - - - - - （CH 2） [（CH 2）2 -O] -SS - ，R'是H或CH 3， 3 ，n为1〜5的整数，p为1〜2的整数，q为1〜4的整数，r为1〜3的整数， r'为1〜3的整数，s为1〜3的整数，n，p，q，r，r'和s相同或不同，吡咯环在2位， 3，4或5。

3. 发明申请

US20060189555A1 Pyrroles substituted by oligonucleotides 失效
标题翻译：由寡核苷酸取代的吡咯
公开(公告)号：US20060189555A1
公开(公告)日：2006-08-24
申请号：US10536317
申请日：2003-12-16
申请人： Bernard Mandrand , Daniela Zsoldos , Alain Laurent , Carole Chaix , Nicolas Spinelli
发明人： Bernard Mandrand , Daniela Zsoldos , Alain Laurent , Carole Chaix , Nicolas Spinelli
IPC分类号： A61K48/00 , A61K31/7056 , C07H21/02 , C07H19/04
CPC分类号： C07H21/00 , Y02P20/55
摘要： The invention relates to novel pyrrole derivatives of the formula (I) which make it possible to immobilize and address oligonucleotides by electropolymerization. Said invention also relates to thus produced electroactive polymers and to methods for using them for detecting, identifying and dosing analytes in a sampe. (I) wherein R1 is one type of oligonucleotide, Y is S or O, X is a spacer arm selected from —(CH2)—O—, —(CH2) P O—[(CH2)2—O]q—, —(CH2)r; —CO—NR—(CH2)r-0-, —CH2r—NCH3—(CH2)r—O—, —CH2)rCO—NR′—[CH2)2—O]s—, —(CH2)rNCH3[(CH2)2—O] S —, R′ is H or CH3, n is an integer number ranging from 1 to 5, p is an integer number ranging from 1 to 2, q is an integer number ranging from 1 to 4, r is an integer number ranging from 1 to 3, r′ is an integer number ranging from 1 to 3, s is an integer number ranging from 1 to 3, n, p, q, r, r′ and s are identical or different, a pyrrole cycle is substituted in a position 2, 3, 4 or 5.
摘要翻译：本发明涉及式（I）的新型吡咯衍生物，其可以通过电聚合固定和解决寡核苷酸。所述发明还涉及由此产生的电活性聚合物及其用于检测，鉴定和给予分析物的方法。（I）其中R 1是一种类型的寡核苷酸，Y是S或O，X是选自以下的间隔臂 - （CH 2）2 - ， - （ CH 2 O - [（CH 2）2 -O] q > - ， - （CH 2）r < -CO-NR-（CH 2）r -O - ， - CH 2 R n -NCH 3 - （CH 2） -O - ， - CH 2）NR CO - NR' - [CH 2 N 2） 2 - - - - - - - - - - - - - - - - - - - （CH 2） [（CH 2）2 -O] -S SB， - R'是H或CH 3，n是 1〜5的整数，p为1〜2的整数，q为1〜4的整数，r为1〜3的整数，r'为从 1至3，s为1至3的整数，n，p，q，r，r'和s相同或不同，在2,3,4或5位置上取代吡咯环。

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