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1. 发明授权

US07838299B2 Lanthanide complexes, preparation and uses thereof 有权
标题翻译：镧系元素络合物，其制备和用途
公开(公告)号：US07838299B2
公开(公告)日：2010-11-23
申请号：US12714357
申请日：2010-02-26
申请人： Loïc Charbonniere , Raymond Ziessel , Nicolas Weibel , Aldo Roda , Massimo Guardigli
发明人： Loïc Charbonniere , Raymond Ziessel , Nicolas Weibel , Aldo Roda , Massimo Guardigli
IPC分类号： G01N33/20
CPC分类号： C09K11/06 , C07D213/79 , C07D401/14 , C09K2211/182 , G01N33/582
摘要： The invention relates to compounds, to the complexes they form with a lanthanide, and to the use of the complexes for fluorescence marking or NMR imaging. The complex consists of an Ln ion and a ligand R2—C(X—R1)(R3)—NR4R5. R1 is a functional group, X is a single bond or a hydrocarbon-based chain consisting of at least one alkylene or alkenylene group optionally comprising at least one hetero atom or an arylene. R2 is an anionic group A2 or a C1-C4 alkylene or alkenylene group bearing at least one such group A2 and optionally comprising at least one hetero atom. R3 is H or a C1-C5 alkylene or alkenylene group optionally containing at least one hetero atom, and optionally bearing at least one anionic group A3. R4 is a substituent with light-absorbing properties that forms chelate rings with Ln. R5 is a substituent that forms chelate rings with Ln.
摘要翻译：本发明涉及化合物，其与镧系元素形成的络合物，以及复合物用于荧光标记或NMR成像的用途。络合物由Ln离子和配体R2-C（X-R1）（R3）-NR4R5组成。 R1是官能团，X是单键或由至少一个亚烷基或亚烯基组成的烃基链，任选地包含至少一个杂原子或亚芳基。 R2是具有至少一个这样的基团A2和任选地包含至少一个杂原子的阴离子基团A2或C1-C4亚烷基或亚烯基。 R3是H或任选地含有至少一个杂原子的C1-C5亚烷基或亚烯基，并且任选地带有至少一个阴离子基团A3。 R4是与Ln形成螯合环的具有光吸收性质的取代基。 R5是与Ln形成螯合环的取代基。

2. 发明授权

US07709263B2 Lanthanide complexes preparation and uses thereof 有权
标题翻译：镧系配合物的制备及其用途
公开(公告)号：US07709263B2
公开(公告)日：2010-05-04
申请号：US10565804
申请日：2004-07-20
申请人： Loïc Charbonniere , Raymond Ziessel , Nicolas Weibel , Aldo Roda , Massimo Guardigli
发明人： Loïc Charbonniere , Raymond Ziessel , Nicolas Weibel , Aldo Roda , Massimo Guardigli
IPC分类号： G01N33/20
CPC分类号： C09K11/06 , C07D213/79 , C07D401/14 , C09K2211/182 , G01N33/582
摘要： The invention relates to compounds, to the complexes they form with a lanthanide, and to the use of the complexes for fluorescence marking or NMR imaging.The complex consists of an Ln ion and a ligand R2—C(X—R1)(R3)—NR4R5. R1 is a functional group, X is a single bond or a hydrocarbon-based chain consisting of at least one alkylene or alkenylene group optionally comprising at least one hetero atom or an arylene. R2 is an anionic group A2 or a C1-C4 alkylene or alkenylene group bearing at least one such group A2 and optionally comprising at least one hetero atom. R3 is H or a C1-C5 alkylene or alkenylene group optionally containing at least one hetero atom, and optionally bearing at least one anionic group A3. R4 is a substituent with light-absorbing properties that forms chelate rings with Ln. R5 is a substituent that forms chelate rings with Ln.
摘要翻译：本发明涉及化合物，其与镧系元素形成的络合物，以及复合物用于荧光标记或NMR成像的用途。络合物由Ln离子和配体R2-C（X-R1）（R3）-NR4R5组成。 R1是官能团，X是单键或由至少一个亚烷基或亚烯基组成的烃基链，任选地包含至少一个杂原子或亚芳基。 R2是具有至少一个这样的基团A2和任选地包含至少一个杂原子的阴离子基团A2或C1-C4亚烷基或亚烯基。 R3是H或任选地含有至少一个杂原子的C1-C5亚烷基或亚烯基，并且任选地带有至少一个阴离子基团A3。 R4是与Ln形成螯合环的具有光吸收性质的取代基。 R5是与Ln形成螯合环的取代基。

3. 发明申请

US20080044923A1 Lanthanide Complexes Preparation and Uses Thereof 有权
标题翻译：镧系配合物的制备及其用途
公开(公告)号：US20080044923A1
公开(公告)日：2008-02-21
申请号：US10565804
申请日：2005-07-20
申请人： Loic Charbonniere , Raymond Ziessel , Nicolas Weibel , Aldo Roda , Massimo Guardigli
发明人： Loic Charbonniere , Raymond Ziessel , Nicolas Weibel , Aldo Roda , Massimo Guardigli
IPC分类号： G01N21/76 , C07D401/14 , C07F5/00
CPC分类号： C09K11/06 , C07D213/79 , C07D401/14 , C09K2211/182 , G01N33/582
摘要： The invention relates to compounds, to the complexes they form with a lanthanide, and to the use of the complexes for fluorescence marking or NMR imaging.The complex consists of an Ln ion and a ligand R2-C(X-R1)(R3)-NR4R5. R1 is a functional group, X is a single bond or a hydrocarbon-based chain consisting of at least one alkylene or alkenylene group optionally comprising at least one hetero atom or an arylene. R2 is an anionic group A2 or a C1-C4 alkylene or alkenylene group bearing at least one such group A2 and optionally comprising at least one hetero atom. R3 is H or a C1-C5 alkylene or alkenylene group optionally containing at least one hetero atom, and optionally bearing at least one anionic group A3. R4 is a substituent with light-absorbing properties that forms chelate rings with Ln. R5 is a substituent that forms chelate rings with Ln.
摘要翻译：本发明涉及化合物，其与镧系元素形成的络合物，以及复合物用于荧光标记或NMR成像的用途。络合物由Ln离子和配体R 2 -C（XR 1）（R 3） - NR 4， / SUP> R＆lt; 5＆gt;。 R 1是官能团，X是单键或由至少一个亚烷基或亚烯基组成的烃基链，任选地包含至少一个杂原子或亚芳基。 R 2是至少带有阴离子基团A 2或C 1 -C 4 -C 4亚烷基或亚烯基一个这样的基团A 2，并且任选地包含至少一个杂原子。 R 3是H或C 1 -C 5亚烷基或亚烯基，任选地含有至少一个杂原子，并且任选地带有至少一个阴离子基团A 3。 R 4是具有与Ln形成螯合环的光吸收性质的取代基。 R 5是与Ln形成螯合环的取代基。

4. 发明申请

US20100216252A1 Lanthanide Complexes, Preparation and Uses Thereof 有权
标题翻译：镧系配合物，其制备和用途
公开(公告)号：US20100216252A1
公开(公告)日：2010-08-26
申请号：US12714357
申请日：2010-02-26
申请人： Loïc Charbonniere , Raymond Ziessel , Nicolas Weibel , Aldo Roda , Massimo Guardigli
发明人： Loïc Charbonniere , Raymond Ziessel , Nicolas Weibel , Aldo Roda , Massimo Guardigli
IPC分类号： G01N21/76 , C07F5/00
CPC分类号： C09K11/06 , C07D213/79 , C07D401/14 , C09K2211/182 , G01N33/582
摘要： The invention relates to compounds, to the complexes they form with a lanthanide, and to the use of the complexes for fluorescence marking or NMR imaging.The complex consists of an Ln ion and a ligand R2—C(X—R1)(R3)—NR4R5. R1 is a functional group, X is a single bond or a hydrocarbon-based chain consisting of at least one alkylene or alkenylene group optionally comprising at least one hetero atom or an arylene. R2 is an anionic group A2 or a C1-C4 alkylene or alkenylene group bearing at least one such group A2 and optionally comprising at least one hetero atom. R3 is H or a C1-C5 alkylene or alkenylene group optionally containing at least one hetero atom, and optionally bearing at least one anionic group A3. R4 is a substituent with light-absorbing properties that forms chelate rings with Ln. R5 is a substituent that forms chelate rings with Ln.
摘要翻译：本发明涉及化合物，其与镧系元素形成的络合物，以及复合物用于荧光标记或NMR成像的用途。络合物由Ln离子和配体R2-C（X-R1）（R3）-NR4R5组成。 R1是官能团，X是单键或由至少一个亚烷基或亚烯基组成的烃基链，任选地包含至少一个杂原子或亚芳基。 R2是具有至少一个这样的基团A2和任选地包含至少一个杂原子的阴离子基团A2或C1-C4亚烷基或亚烯基。 R3是H或任选地含有至少一个杂原子的C1-C5亚烷基或亚烯基，并且任选地带有至少一个阴离子基团A3。 R4是与Ln形成螯合环的具有光吸收性质的取代基。 R5是与Ln形成螯合环的取代基。

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