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    • 5. 发明授权
    • Polyurethane coatings produced from (1) a polyisocyanate mixture of
polyisocyanates from the diphenol methane series and a polyhydroxy
polyether containing at least one tertiary amine nitrogen with (2) a
polyol in a two component coating system
    • 由(1)来自二酚系列的多异氰酸酯的多异氰酸酯混合物和含有至少一种叔胺氮的多羟基聚醚与(2)多元醇在双组分涂布体系中的多异氰酸酯混合物
    • US4296230A
    • 1981-10-20
    • US938165
    • 1978-08-30
    • Josef PedainWalter UerdingenHans-Jurgen Muller
    • Josef PedainWalter UerdingenHans-Jurgen Muller
    • C08G18/00C08G18/10C08G18/50C08G18/72C08G18/76C09D5/46C09D175/00
    • C08G18/7664C08G18/10C08G18/5021Y10T428/31551
    • The present invention relates to a process for the production of coatings by coating substrates of any type with a coating composition of which the binder consists essentially of a mixture of:(a) a polyisocyanate component and(b) at least one organic polyhydroxyl compound, distinguished by the fact that the polyisocyanate component(a) is a reaction product obtained from:(i) a polyisocyanate mixture which, in addition to from about 20 to 80%, by weight, of 2,4'-diisocyanato diphenyl methane, contains a total of from about 80 to 20%, by weight, of 2,2'-diisocyanato diphenyl methane, 4,4'-diisocyanato diphenyl methane and, optionally, higher nuclear polyisocyanates of the diphenyl methane series and(ii) a polyhydroxy polyether containing at least one tertiary amine nitrogen atom and having an average molecular weight of from about 500 to 10,000 or a polyhydroxy polyether mixture containing at least one such polyhydroxy polyether and having an average molecular weight of from about 500 to 10,000.components (i) and (ii) having been reacted in an NCO:OH equivalent ratio of from about 300:1 to 10:1 to form a reaction product containing free isocyanate groups and urethane groups.
    • 本发明涉及一种通过用涂料组合物涂覆任何类型的基材来生产涂料的方法,其中粘合剂基本上由下列混合物组成:(a)多异氰酸酯组分和(b)至少一种有机多羟基化合物, 其特征在于多异氰酸酯组分(a)是由以下物质获得的反应产物:(i)多异氰酸酯混合物,除了约20至80重量%的2,4'-二异氰酸酯二苯基甲烷外, 总共约80至20重量%的2,2'-二异氰酸根合二苯基甲烷,4,4'-二异氰酸根合二苯基甲烷和任选的二苯基甲烷系列的较高核多异氰酸酯和(ii)多羟基聚醚 含有至少一个叔胺氮原子并且具有约500至10,000的平均分子量或包含至少一种这样的多羟基聚醚并且平均分子量为约50的多羟基聚醚混合物 0到10,000。 组分(i)和(ii)以约300:1至10:1的NCO:OH当量比反应形成含有游离异氰酸酯基团和氨基甲酸酯基团的反应产物。
    • 6. 发明授权
    • Low-molecular weight acrylate resins and a process for their production
    • 低分子量丙烯酸酯树脂及其制备方法
    • US4137389A
    • 1979-01-30
    • US871248
    • 1978-01-23
    • Frank WinglerJosef PedainWalter Uerdingen
    • Frank WinglerJosef PedainWalter Uerdingen
    • C08F2/02C08F220/12C08J3/09C08F2/00C08F4/38C08F16/12
    • C08J3/095C08F2/02C08F220/12C08K5/06C08J2333/06
    • A process for the production of a crosslinkable low-molecular weight acrylic resin containing hydroxyl-groups and having a low-molecular consistency factor by the radical bulk copolymerization of(A) 0 to 30 parts by weight of a hydroxyalkyl ester of acrylic acid or methacrylic acid or mixtures thereof;(B) 0 to 60 parts by wt. of styrene or a substituted styrene or methyl methacrylate or mixtures thereof;(C) 10 to 90 parts by weight of an acrylic acid ester or of a methacrylic acid ester with 2 to 12 carbon atoms in the alcohol radical or mixtures thereof;(D) 0 to 30 parts by weight of an .alpha.,.beta.-monoolefinically saturated mono- or di-carboxylic acid with 3 to 5 carbon atoms or of a maleic acid semiester or mixtures thereof or reaction products thereof with a monoglycidyl compound, in the presence of 10 to 70 parts by weight of a monoallyl ether of an at least trihydric alcohol,The sum of the parts by weight of all the monomers A - E amounting to 100,Wherein the indicated quantity of monomer E is initially introduced and, at temperatures above 100.degree. C, monomers A to D together with 0.5 to 6% by weight, based on A to D, of an initiator with a half-life period at 100 to 160.degree. C of 0.01 to 100 minutes, are introduced over a period of 1 to 6 hours and polymerized, at least 98% by weight of the monomers A to D and from 36 to 95% by weight of monomer E being converted. Acrylate resins of this type are eminently suitable for the production of readily processible binder mixtures which although low in viscosity, have a very high solids content.
    • 一种通过(A)0-30重量份的丙烯酸或甲基丙烯酸羟烷基酯的自由基本体共聚生产含羟基并具有低分子稠度因子的可交联的低分子量丙烯酸树脂的方法 酸或其混合物; (B)0〜60重量份。 的苯乙烯或取代的苯乙烯或甲基丙烯酸甲酯或其混合物; (C)10至90重量份的丙烯酸酯或醇基中具有2至12个碳原子的甲基丙烯酸酯或其混合物; (D)0至30重量份具有3至5个碳原子的α,β-单烯烃饱和的单羧酸或二羧酸或马来酸半酯或其混合物或其与单缩水甘油基化合物的反应产物,在 存在10至70重量份的至少三元醇的单烯丙基醚,所有单体A-E的重量份数为100,由于初始引入了单体E的指示数量,并且在 温度高于100℃,单体A至D和基于A至D的0.5至6重量%的引发剂,其在100至160℃下的半衰期为0.01至100分钟的引发剂通过 时间为1至6小时并聚合,至少98重量%的单体A至D和36至95重量%的单体E被转化。 这种类型的丙烯酸酯树脂非常适用于生产易于加工的粘合剂混合物,尽管粘度低,但固体含量非常高。
    • 7. 发明授权
    • Process for the production of combinations of organic polyisocyanates
and at least partly blocked polyamines, the combinations obtainable by
this process and their use for the production of lacquers, coating or
sealing compositions
    • 用于生产有机多异氰酸酯和至少部分封闭的多胺的组合的方法,可通过该方法获得的组合及其用于生产漆,涂料或密封组合物的用途
    • US4481345A
    • 1984-11-06
    • US583918
    • 1984-02-27
    • Klaus NachtkampManfred BockReinhard HalpaapJosef Pedain
    • Klaus NachtkampManfred BockReinhard HalpaapJosef Pedain
    • C09K3/10C08G18/10C08G18/32C08G18/65C09D175/00C09D175/02C09D175/04C08G18/38
    • C08G18/3256C08G18/10
    • Process for the production of water-hardenable compositions of organic polyisocyanates and polyamines containing at least partly blocked amino groups present as ketimines, the combinations essentially representing mixtures and optionally reaction products containing urea groups by mixing the organic polyisocyanates with the polyamines in such quantities that the equivalent ratio of isocyanate groups to blocked and free amino groups is between about 0.9:1 and 4:1 and reacting any free amino groups present with some of the isocyanate groups in the polyisocyanate to form ureas, characterized in that the polyamines containing at least partly blocked amino groups used are mixtures comprising(a) from about 50 to 95 amine equivalent percent of organic compounds which are free from primary and secondary amino groups and which contain at least two ketimine groups corresponding to the following formula ##STR1## in which R.sup.1 represents an alkyl or cycloalkyl radical and R.sup.2 represents hydrogen or an alkyl or cycloalkyl radical or in which R.sup.1 and R.sup.2 form a cycloaliphatic hydrocarbon radical together with the two carbon atoms of the ketimine group and(b) from about 5 to 40 amine equivalent percent of organic compounds which are free from primary and secondary amino groups and which contain at least two ketimine groups of which one corresponds to the formula ##STR2## in which R.sup.1 and R.sup.2 are as defined above, the other ketimine group(s) present correspond(s) to the formula shown in (a).
    • 用于生产有机多异氰酸酯和含有至少部分封闭的胺基的多胺的水可硬化组合物作为酮亚胺存在的方法,所述组合基本上代表混合物和任选的含有尿素基团的反应产物,通过将有机多异氰酸酯与多胺混合, 异氰酸酯基与封端和游离氨基的当量比为约0.9:1至4:1,并使与多异氰酸酯中存在的一些异氰酸酯基团存在的任何游离氨基反应形成脲,其特征在于,含有至少部分 使用的封闭氨基是包含(a)约50至95胺当量百分比的不含伯和仲氨基并且含有至少两个对应于下式的酮亚胺基的有机化合物的混合物:其中R 1表示 烷基或环烷基,R 2表示氢或a n烷基或环烷基,或其中R1和R2与酮亚胺基团的两个碳原子一起形成脂环族烃基,和(b)约5至40胺当量百分比的不含伯和仲氨基的有机化合物 并且其包含至少两个酮亚胺基,其中一个对应于式(Ia)其中R 1和R 2如上所定义的式“IMAGE”,其它酮亚胺基与(a)所示的式表示。
    • 9. 发明授权
    • Process for the production of compounds containing isocyanurate groups
and olefinic double bonds and their use as binders
    • 用于生产含有异氰脲酸酯基和烯属双键的化合物的方法及其作为粘合剂的用途
    • US4870152A
    • 1989-09-26
    • US262623
    • 1988-10-26
    • Jurgen MeixnerManfred BockJosef PedainManfred Schonfelder
    • Jurgen MeixnerManfred BockJosef PedainManfred Schonfelder
    • C07D251/34C08G18/42C08G18/67C08G18/72C08G18/79C08G18/81C09D175/00C09D175/14
    • C08G18/672C07D251/34C08G18/4216C08G18/4238C08G18/792C08G18/8175
    • Binders which are hardenable by radiation or peroxides and are useful in coating compositions are compounds containing isocyanurate groups and olefinic double bonds produced by the reaction of components (a), (b) and (c) wherein(a) is a polyisocyanate component containing isocyanurate polyisocyanates which is(i) N,N',N"-tris-(isocyanatohexyl)-isocyanurate alone or in admixture with its higher homologs containing more than one isocyanurate ring or(ii) mixtures of the polyisocyanates (i) with up to 40 NCO-equivalent-%, based on the total component (a), of other polyisocyanates containing aliphatically or cycloaliphatically bound isocyanate groups;(b) is an olefinically unsaturated alcohol component comprising at least one hydroxyalkyl ester of acrylic acid or methacrylic acid; and(c) is a polyol component consisting essentially of a polyester polyol having an OH value of 80 to 350 based on (i) an acid component, of which at least 80 carboxyl equivalent-% is adipic acid, isophthalic acid or a mixture of both and (ii) a polyhydroxy component of which at least 70 hydroxyl equivalent-% is hexane-1, 6-diol;wherein component (c) amounts to 20 to 150% by weight, based on the weight of component (b), and the reaction is carried out at with an NCO:OH equivalent ratio maintained at 0.9:1 to 1.1:1, and wherein components (b) and (c) are reacted with the polyisocyanate component in any order or in admixture.
    • 通过辐射或过氧化物可硬化并且可用于涂料组合物的粘合剂是含有通过组分(a),(b)和(c)反应生成的异氰脲酸酯基团和烯属双键的化合物,其中(a)是含有异氰脲酸酯的多异氰酸酯组分 多异氰酸酯,其是单独的或与其含有多于一个异氰脲酸酯环的较高同系物混合的(i)N,N',N“ - 三 - (异氰酸根合己基) - 异氰脲酸酯的多异氰酸酯,或(ii)多异氰酸酯(i) 基于总组分(a),含有脂族或环脂族结合的异氰酸酯基团的其它多异氰酸酯的40NCO当量%; (b)是包含至少一种丙烯酸或甲基丙烯酸的羟烷基酯的烯属不饱和醇组分; 和(c)是基于(i)酸组分的羟值为80至350的聚酯多元醇组成的多元醇组分,其中至少80羧基当量 - %是己二酸,间苯二甲酸或 两者和(ii)多羟基组分,其中至少70个羟基当量 - %是己烷-1,6-二醇; 其中组分(c)基于组分(b)的重量计为20至150重量%,并且以保持在0.9:1至1.1:1的NCO:OH当量比进行反应,其中 组分(b)和(c)以多异氰酸酯组分的任何顺序或混合物反应。