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1. 发明授权

US5846895A Supported metallocene complex and process for its preparation 失效
标题翻译：负载金属茂络合物及其制备方法
公开(公告)号：US5846895A
公开(公告)日：1998-12-08
申请号：US837898
申请日：1997-04-22
申请人： Liliana Gila , Antonio Proto , Evelina Ballato , Diego Vigliarolo , Gabriele Lugli
发明人： Liliana Gila , Antonio Proto , Evelina Ballato , Diego Vigliarolo , Gabriele Lugli
IPC分类号： C07F17/00 , C08F4/02 , C08F4/656 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6592 , Y10S526/941
摘要： A supported metallocene complex of a metal M selected from Ti, Zr or Hf, is prepared by a process comprising, in a first step, the reaction of an inorganic carrier containing hydroxyl groups with a compound (II) containing a cyclopentadienyl group and at least one alkoxysilane group reactive with said hydroxyl groups so as to chemically bind said cyclopentadienyl group to said carrier; and in a second step the reaction with a complex of said metal M capable of reacting with said supported cyclopentadienyl group without carrying out any intermediate metallation of the latter. This process is simple and convenient, and enables high concentrations of metal stably bound to the carrier, to be reached. The complex thus obtained can be used as solid component of a catalyst active in the polymerization of .alpha.-olefins, in the presence of a suitable co-catalyst, preferably consisting of an organo-oxygenated derivative of aluminum.
摘要翻译：选自Ti，Zr或Hf的金属M的负载茂金属络合物通过以下方法制备，所述方法包括：在第一步中，将含有羟基的无机载体与含有环戊二烯基的化合物（II）一个烷氧基硅烷基团与所述羟基反应，以便将所述环戊二烯基化学结合到所述载体上; 并且在第二步中与能够与所述负载的环戊二烯基反应的所述金属M的络合物进行反应而不进行后者的任何中间金属化。该方法简单方便，可达到稳定结合载体的高浓度金属。由此获得的络合物可以在合适的助催化剂，优选由铝的有机 - 氧化衍生物组成的情况下用作在α-烯烃的聚合中有活性的催化剂的固体组分。

2. 发明授权

US5861352A Supported metallocene catalyst for olefins (co)polymerization 失效
标题翻译：用于烯烃（共）聚合的负载金属茂催化剂
公开(公告)号：US5861352A
公开(公告)日：1999-01-19
申请号：US593523
申请日：1996-01-30
申请人： Liliana Gila , Antonio Proto , Evelina Ballato , Diego Vigliarolo , Gabriele Lugli
发明人： Liliana Gila , Antonio Proto , Evelina Ballato , Diego Vigliarolo , Gabriele Lugli
IPC分类号： C08F4/642 , C08F4/60 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , B01J31/00 , B01J37/00 , C08F4/02
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/6592 , Y10S526/943
摘要： A solid catalyst component for the polymerization and copolymerization of ethylene and alpha- olefins, containing a metallocene supported on an inorganic solid carrier constituted by a porous silicon oxide, the supported metallocene having the formula (I): ##STR1## wherein M is a group of metal, R' and R" are dialkylamide groups, R'" has the same definition as R' or is a cyclopentadienyl consisting ligand, and A is an anion containing an .eta..sup.5 -cyclopentadienyl ring coordinated to metal M, and wherein a carbon atom of the .eta..sup.5 -cyclopentadienyl ring of anion A is covalently bonded to the surface of the porous inorganic solid carrier.
摘要翻译：一种用于乙烯和α-烯烃的聚合和共聚的固体催化剂组分，其包含负载在由多孔氧化硅构成的无机固体载体上的金属茂，所述支化金属茂具有式（I）：其中M 是一组金属，R'和R“是二烷基酰胺基团，R”具有与R'相同的定义，或是作为环戊二烯基的配体，A是含有与金属M配位的η5环戊二烯基环的阴离子并且其中阴离子A的η5 5-环戊二烯基环的碳原子共价键合到多孔无机固体载体的表面。

3. 发明授权

US06495641B1 Catalysts based on vanadium, their preparation and use in the (CO) polymerization of &agr;-olefins 有权
标题翻译：基于钒的催化剂，它们的制备和在α-烯烃（CO））聚合中的应用
公开(公告)号：US06495641B1
公开(公告)日：2002-12-17
申请号：US09442647
申请日：1999-11-18
申请人： Francesco Masi , Liliana Gila , Roberto Santi , Antonio Proto , Evelina Ballato , Anna Maria Romano
发明人： Francesco Masi , Liliana Gila , Roberto Santi , Antonio Proto , Evelina Ballato , Anna Maria Romano
IPC分类号： C08F468
CPC分类号： C07F9/005 , C08F10/00 , C08F210/16 , C08F210/18 , C08F4/68 , C08F210/06 , C08F2500/03 , C08F2500/25
摘要： Vanadium complex having general formula (I) (RCOO)nVXpLm (I) wherein R is a monofunctional hydrocarbon radical having from 1 to 20 carbon atoms and from 1 to 6 halogen atoms, selected from chlorine and bromine, preferably chlorine; X is chlorine or bromine, preferably chlorine; L is an electron donor; p+n=3, 4 or 5, preferably=3; n is greater than or equal to 1; m is between 0 and 3. The preparation of the above complex is also described together with its use in the (co)polymerization of &agr;-olefins.
摘要翻译：具有通式（I）的钒络合物，其中R是具有1至20个碳原子和1至6个选自氯和溴，优选氯的卤素原子的单官能烃基; X是氯或溴，优选氯; L是电子给体; p + n = 3,4或5，优选= 3; n大于或等于1; m在0和3之间。上述络合物的制备也与其在α-烯烃的（共）聚合中的应用一起被描述。

4. 发明授权

US06274529B1 Catalytic system for the (co)polymerization of alpha-olefins 失效
标题翻译： α-烯烃（共）聚合的催化体系
公开(公告)号：US06274529B1
公开(公告)日：2001-08-14
申请号：US08736063
申请日：1996-10-22
申请人： Roberto Fusco , Luca Longo , Antonio Proto , Diego Vigliarolo , Gianfranco Guglielmetti , Liliana Gila
发明人： Roberto Fusco , Luca Longo , Antonio Proto , Diego Vigliarolo , Gianfranco Guglielmetti , Liliana Gila
IPC分类号： B01J3122
CPC分类号： C08F10/00 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/61922 , Y10S526/943
摘要： A catalytic system with an increased activity for the (co)polymerization of alpha-olefins comprises a catalyst of the metallocene type, which is capable of polymerizing olefins without aluminoxane, and a weak coordinating compound, which, when used in a polymerization process, enables a higher productivity than an analogous process carried out with the metallocene type catalyst per se.
摘要翻译：具有增加的α-烯烃（共）聚合活性的催化体系包括能够聚合没有铝氧烷的烯烃的金属茂型催化剂，以及在聚合过程中使用的弱配位化合物比用茂金属型催化剂本身进行的类似方法更高的生产率。

5. 发明授权

US5936051A Substituted metallocene catalyst for the (co)polymerization of olefins 失效
标题翻译：用于烯烃（共）聚合的取代茂金属催化剂
公开(公告)号：US5936051A
公开(公告)日：1999-08-10
申请号：US802875
申请日：1997-02-19
申请人： Roberto Santi , Giampiero Borsotti , Cecilia Querci , Liliana Gila , Antonio Proto
发明人： Roberto Santi , Giampiero Borsotti , Cecilia Querci , Liliana Gila , Antonio Proto
IPC分类号： C07F17/00 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02
CPC分类号： C07F17/00 , C08F10/00 , Y10S526/904 , Y10S526/943
摘要： Metallocene complexes of a metal M selected from titanium, zirconium and hafnium, comprising at least one anionic group A containing an .eta..sup.5 -cyclopentadienyl ring co-ordinated with the metal M, wherein the anionic group is substituted in at least one position of the cyclopentadienyl ring with a radical having the formula:Ph*--(CR.sup.6 R.sup.7).sub.nwherein: R.sup.6 and R.sup.7 are independently hydrogen, halogen or a C.sub.1 -C.sub.4 alkyl group, preferably hydrogen, "n" is 0 or 1, preferably 1, Ph* is a C.sub.6 -C.sub.14 group comprising an aromatic ring linked to --CR.sup.6 R.sup.7 -- or to A and substituted with at least one and up to a maximum of three electron-attractor groups, on the condition that, when A is an .eta..sup.5 -indenyl group and "n" is 0, at least one Ph group is linked to A in position 1 or 3 of indenyl.These complexes can be used in (co)polymerization processes of .alpha.-olefins, possibly in the presence of a suitable co-catalyst, for the production of polyolefins with a very high molecular weight.
摘要翻译：选自钛，锆和铪的金属M的茂金属络合物，其包含至少一个阴离子基团A，其含有与金属M配位的η5-环戊二烯基环，其中阴离子基团在至少一个位置的环戊二烯基具有下式的基团：Ph * - （CR 6 R 7）n其中R 6和R 7独立地是氢，卤素或C 1 -C 4烷基，优选氢，“n”是0或1，优选1，Ph *是包含与-CR 6 R 7 - 或A连接的芳环的C 6 -C 14基团，并且被A至5个茚基取代，并且被至少一个和最多三个吸电子基团取代， n“为0，至少有一个Ph基与茚基的1位或3位的A连接。这些络合物可用于α-烯烃的（共）聚合方法中，可能在合适的助催化剂存在下，用于生产具有非常高分子量的聚烯烃。

6. 发明授权

US5753578A Metallocene catalyst for the (CO)polymerization of .alpha.-olefins 失效
标题翻译：用于α-烯烃（（CO））聚合的茂金属催化剂
公开(公告)号：US5753578A
公开(公告)日：1998-05-19
申请号：US667622
申请日：1996-06-21
申请人： Roberto Santi , Giampiero Borsotti , Antonio Proto , Liliana Gila , Karel Bujadoux
发明人： Roberto Santi , Giampiero Borsotti , Antonio Proto , Liliana Gila , Karel Bujadoux
IPC分类号： C07C13/38 , C07C1/32 , C07F17/00 , C08F4/60 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C07C1/328 , C07F17/00 , C08F10/00 , C07C2101/10 , C07C2102/08 , C08F4/65908 , C08F4/65912 , C08F4/65927
摘要： A catalyst active in the (co)polymerization of .alpha.-olefins is obtained by putting the following components in contact with each other: (i) a "bridged" bis-metallocene derivative of a metal M selected from titanium, zirconium or hafnium, wherein the divalent "bridge" has a rigid structure linked to two .eta..sup.5 -cyclopentadienyl ring with two methylene groups having a distance from each other of less than 3.5 .ANG.;(ii) a co-catalyst consisting of an organic derivative of a metal M' selected from boron, aluminium, gallium and tin. Such a catalyst allows high polymerization rates to be reached and is particularly suitable for high temperature polymerization process and co-polymerization of ethylene with other .alpha.-olefins.
摘要翻译：通过使以下组分彼此接触获得在α-烯烃的（共）聚合中有活性的催化剂：（i）选自钛，锆或铪的金属M的“桥连”双茂金属衍生物，其中二价“桥”具有与两个具有小于3.5的距离的两个亚甲基的两个η5-环戊二烯基连接的刚性结构; （ii）由选自硼，铝，镓和锡的金属M'的有机衍生物组成的助催化剂。这种催化剂允许达到高聚合速率，并且特别适合于高温聚合方法和乙烯与其它α-烯烃的共聚。

7. 发明授权

US5629392A Process for the preparation of (co)polymers of .alpha.-olefins 失效
标题翻译： α-烯烃（共）聚合物的制备方法
公开(公告)号：US5629392A
公开(公告)日：1997-05-13
申请号：US652821
申请日：1996-05-23
申请人： Roberto Santi , Giuseppe Cometti , Liliana Gila , Antonio Proto
发明人： Roberto Santi , Giuseppe Cometti , Liliana Gila , Antonio Proto
IPC分类号： C08F4/60 , C08F4/622 , C08F4/64 , C08F4/642 , C08F4/6592 , C08F4/68 , C08F10/00 , C08F110/02
CPC分类号： C08F10/00 , C08F110/02
摘要： Process for the preparation of (co) polymers of .alpha.-olefins which comprises polymerizing at least one .alpha.-olefin in the presence of a catalytic system consisting essentially of:a) a complex of a metal of groups VIB or VB having general formula (I):M(OCONRR').sub.n (I)wherein M represents a transition metal selected from the group consisting of Ti, Zr, H& and V; R and R', the same or different, represent a C.sub.1 -C.sub.12 aliphatic or C.sub.18 aromatic radical whereas n represents the oxidation state of the metal; andb) a cocatalyst consisting of aluminoxane.
摘要翻译：制备α-烯烃的（共）聚合物的方法，其包括在催化体系存在下聚合至少一种α-烯烃，所述催化体系基本上由以下组成：a）具有通式（I）的VIB或VB族金属的络合物）：M（OCONRR'）n（I）其中M表示选自Ti，Zr，H和V的过渡金属; R和R'相同或不同，表示C1-C12脂族或C18芳族基，而n表示金属的氧化态; 和b）由铝氧烷组成的助催化剂。

8. 发明申请

US20140303379A1 LUMINESCENT SOLAR CONCENTRATOR COMPRISING DISUBSTITUTED BENZOSELENADIAZOLE COMPOUNDS 审中-公开
标题翻译：包含分离的苯并噻唑化合物的发光太阳能浓缩器
公开(公告)号：US20140303379A1
公开(公告)日：2014-10-09
申请号：US14128987
申请日：2012-07-05
申请人： Samuele Santarelli , Roberto Fusco , Antonio Proto , Luciano Caccianotti
发明人： Samuele Santarelli , Roberto Fusco , Antonio Proto , Luciano Caccianotti
IPC分类号： H01L51/00
CPC分类号： H01L51/0068 , C09B57/00 , H01L31/055 , H01L51/0071 , Y02E10/52
摘要： Luminescent solar concentrator (LSC) comprising at least one disubstituted benzoselenadiazole compound having general formula (I): R1, R2, R3, R4 and R5, equal to or different from each other, represent a hydrogen atom; or they are selected from linear or branched C1-C20, preferably C1-C10, alkyl groups, cycloalkyl groups optionally substituted, aryl groups optionally substituted, linear or branched C1-C20, preferably C1-C10, alkoxyl groups, optionally substituted; or R1 and R2, can be possibly bound to each other so as to form, together with the carbon atoms to which they are bound, a cycle or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, possibly containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; or R3 and R4, can be possibly bound to each other so as to form, together with the carbon atoms to which they are bound, a cycle or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, possibly containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; or R4 and R5, can be possibly bound to each other so as to form, together with the carbon atoms to which they are bound, a cycle or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, possibly containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium.
摘要翻译：包含通式（I）的至少一种二取代苯并硒二唑化合物的发光太阳能聚光器（LSC）：相互相同或不同的R1，R2，R3，R4和R5表示氢原子; 或者它们选自直链或支链C 1 -C 20，优选C 1 -C 10烷基，任选取代的环烷基，任选取代的芳基，直链或支链C 1 -C 20，优选C 1 -C 10烷氧基，任选取代的; 或R 1和R 2可以彼此结合，以便与它们所结合的碳原子一起形成含有3至14个碳原子，优选4至6个碳原子的环状或多环体系，饱和的，不饱和的或芳族的，可能含有一个或多个杂原子，例如氧，硫，氮，硅，磷，硒; 或R 3和R 4可以彼此结合，以便与它们所键合的碳原子一起形成含有3至14个碳原子，优选4至6个碳原子的环状或多环体系，饱和的，不饱和的或芳族的，可能含有一个或多个杂原子，例如氧，硫，氮，硅，磷，硒; 或R4和R5可以彼此结合，以便与它们所结合的碳原子一起形成含有3至14个碳原子，优选4至6个碳原子的循环或多环体系，饱和的，不饱和的或芳族的，可能含有一个或多个杂原子，例如氧，硫，氮，硅，磷，硒。

9. 发明申请

US20060014631A1 Supported catalyst containing active titanium in the homo, co-, and ter-polymerization of olefin-unsaturated compounds 有权
标题翻译：在烯烃不饱和化合物的同质，共聚和三聚中的含有活性钛的载体催化剂
公开(公告)号：US20060014631A1
公开(公告)日：2006-01-19
申请号：US10497549
申请日：2002-12-06
申请人： Francesco Masi , Roberto Santi , Maria Rivellini , Stefano Santi , Laura Santi , Anna Sommazzi , Antonio Proto , Mario Polesello , Andrea Vallieri
发明人： Francesco Masi , Roberto Santi , Maria Rivellini , Stefano Santi , Laura Santi , Anna Sommazzi , Antonio Proto , Mario Polesello , Andrea Vallieri
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , C07C53/16 , C07C53/19 , C07C57/52 , C07C57/58 , C07F3/003 , C08F110/06 , C08F110/14 , C08F210/02 , C08F210/06 , C08F210/18 , C08F4/6555 , C08F4/025 , C08F2500/04 , C08F232/00 , C08F210/16 , C08F2500/24 , C08F236/20 , C08F2500/25
摘要： The present invention relates to a supported catalyst containing titanium, its preparation and it use in the homo-, co-, and ter-polymerization of olefin-unsaturated compounds. The present invention also relates to a catalytic system comprising a supported catalyst based on titanium and a co-catalyst selected from organo-derivatives of aluminum. More, specifically, the present invention relates to catalyst supported on silica, obtained by reacting a titanium halocarboxylate and a magnesium halocarboxylate with an aluminum chloroakylderivative, in the presente of a carrier consisting of high porosity silica. The above reaction essentially takes place in the pores of the silica itself.
摘要翻译：本发明涉及含钛的负载型催化剂，其制备方法及其用于烯烃 - 不饱和化合物的均相，共聚和三元共聚。本发明还涉及包含基于钛的负载催化剂和选自铝的有机衍生物的助催化剂的催化体系。更具体地，本发明涉及在由高孔隙率二氧化硅组成的载体的存在下，通过使卤代钛卤化物和卤代羧酸镁与氯代氯酰卤衍生物反应而获得的二氧化硅上负载的催化剂。上述反应基本上发生在二氧化硅本身的孔中。

10. 发明授权

US06459007B1 Process for the preparation of 1-hexene 有权
标题翻译： 1-己烯的制备方法
公开(公告)号：US06459007B1
公开(公告)日：2002-10-01
申请号：US09926555
申请日：2002-02-11
申请人： Roberto Santi , Anna Maria Romano , Manuela Grande , Anna Sommazzi , Francesco Masi , Antonio Proto
发明人： Roberto Santi , Anna Maria Romano , Manuela Grande , Anna Sommazzi , Francesco Masi , Antonio Proto
IPC分类号： C07C234
CPC分类号： C07C2/32 , C07C2531/22 , C07C11/107
摘要： Process for the preparation of 1-hexane consisting in effecting the oligomerization of ethylene in the presence of a catalyst comprising a vanaduim complex having the formula: (arene)2 VX wherein the term arene represents benzene or mono-, di-, or tri-alkylsubstituted benzene, V is a vanaduim ion with a low wxidation state, and X is an anion selected from non-coordinated anions such as B(Ar)4—, AlCl4—, carboxylates and sulfonates.
摘要翻译：在含催化剂的催化剂存在下进行乙烯低聚制备的1-己烷的方法，所述催化剂包含具有下式的（芳烃）2 VX的钒纳夫复合物，其中术语芳烃代表苯或单 - ，二 - 或三 - 烷基取代的苯，V是具有低氧化态的钒酸根离子，X是选自非配位阴离子如B（Ar）4，AlCl 4 - ，羧酸酯和磺酸酯的阴离子。

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